WO2003029384A1 - Appareil de pyrolyse permettant de traiter des granules grossiers de dechets de plastique et de caoutchouc - Google Patents

Appareil de pyrolyse permettant de traiter des granules grossiers de dechets de plastique et de caoutchouc Download PDF

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Publication number
WO2003029384A1
WO2003029384A1 PCT/HU2001/000120 HU0100120W WO03029384A1 WO 2003029384 A1 WO2003029384 A1 WO 2003029384A1 HU 0100120 W HU0100120 W HU 0100120W WO 03029384 A1 WO03029384 A1 WO 03029384A1
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WO
WIPO (PCT)
Prior art keywords
elements
combustion chamber
inner chamber
plastic
products
Prior art date
Application number
PCT/HU2001/000120
Other languages
English (en)
Inventor
Zoltan Szinay
Ferenc Kiss
Ferenc Czako
Original Assignee
Zoltan Szinay
Ferenc Kiss
Ferenc Czako
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zoltan Szinay, Ferenc Kiss, Ferenc Czako filed Critical Zoltan Szinay
Publication of WO2003029384A1 publication Critical patent/WO2003029384A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B1/00Retorts
    • C10B1/02Stationary retorts
    • C10B1/04Vertical retorts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/18Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with moving charge
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/0476Cutting or tearing members, e.g. spiked or toothed cylinders or intermeshing rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B2017/0424Specific disintegrating techniques; devices therefor
    • B29B2017/0496Pyrolysing the materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00Use of unspecified rubbers as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2101/00Use of unspecified macromolecular compounds as moulding material
    • B29K2101/12Thermoplastic materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/143Feedstock the feedstock being recycled material, e.g. plastics
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/52Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

Definitions

  • the invention relates to an apparatus for the environment-friendly processing of non-domestic wastes, which are generated continuously and accumulated on a large scale. More particularly, the present invention relates to an apparatus for the processing of coarse granules produced from environment polluting wastes which are difficult to process, namely, plastic and rubber scraps and for the production of hydrocarbon products.
  • the apparatus according to the present invention comprises an inner chamber with a vertical axis, serving as a pyrolysis reactor, a combustion chamber, an outer reactor housing, inlet and outlet elements for the products, heating elements and stirring elements.
  • Wastes are generally used in power plants, i.e., for energy production. Most traditional heat production processes seriously harm environment. Another danger emerges from the inefficient processing of wastes, i.e., mainly due to the lack of classification, they are burnt under uncontrolled circumstances.
  • wastes are generally burnt in power plants or used as secondary raw materials. All kinds of wastes can be burnt in thermal power plants and in cement works, so burning is a general large-scale process.
  • the said utility model is based on the discovery that, due to the large dimen- sions of the traditional drum reactors, the reaction space is almost totally filled with the gases and vapours emerging from the decomposition of the fine-grained granules which are continuously fed into the reactor, further, non-desired condensations, the precipitation of impurities or lengthy downs may occur due to the feeding errors, heating errors or other operational disorders.
  • the main feature of the above utility model is that it has a vertical pyrolysis reactor with a top inlet and a bottom outlet.
  • the reactor is preferably indirectly heated by the burners mounted horizontally and tangentially at the lower part of the combustion chamber.
  • the object of the present invention is to improve the process according to Hungarian utility model No. 1 853 and to eliminate the drawback mentioned above.
  • the present invention comprises an inner chamber with a vertical axis, serving as a pyrolysis reactor, a combustion chamber, an outer reactor housing, inlet and outlet elements for the products, heating elements and stirring elements, wherein the top and bottom of the inner chamber are conical, the inner chamber has discrete heat-baffle elements facing the combustion chamber, there is a reverse screw mounted on its axis in the pre-feeding tank and the lower blade of the agitator has side scraper elements.
  • the apparatus has a heat-resistant steel outer case.
  • the heating elements are preferably arranged tangentially and diagonally to each other. Further, the bottom of the combustion chamber of a preferable embodiment is provided with a fire-clay lining while the outer case has a ceramic thermal insulator.
  • inner chamber 3 with a vertical axis (pyrolysis reactor) is surrounded concentrically by combustion chamber 1.
  • the lower boundary element of inner chamber 3 is bottom plate 2 which is shared by combustion chamber 1; thus, bottom plate 2 closes both inner chamber 3 and combustion chamber 1.
  • Bolt lock 15 and outlet pipe 20 for the products are located on dome cover 5.
  • the upper boundary element of combustion chamber 1 is rimmed cover 4 which is fastened to the rim of the outer case and to the neck rim of inner chamber 3 by a screwed connection in the preferred embodiment according to the figure.
  • Agitator 13 is located in the centre of the bottom part of inner chamber 3. It is equipped with side scraper elements 14.
  • Opening 23 for inserting axis 12 and opening 9 for carbon black removal are also located in the centre of the bottom part of inner chamber 3.
  • the apparatus is driven by a cross drive mechanism.
  • Tangential heating elements 7 which are arranged diagonally to each other, in this case block burners mounted on fire tubes, are located in the lower third of combustion chamber 1.
  • Bolt lock 15 mounted on dome cover 5 and lower bolt lock 16 of feeding tank 17 form a gate and the feeding device is formed together with a reverse axis, single-shaft screw mounted on axis 18 above the gate.
  • the lower boundary section of inner chamber 3 is bolt lock 8 for slag removal.
  • the starting material is fed by an individual conveyor to feeding tank 17 and, after opening bolt locks 15 and 16 by a level-control, it is loosened continuously due to gravitation and to the operation of the reverse screw mounted on axis 18.
  • the agglomerating and compacting of the material can be avoided and it can be fed quickly.
  • Combustion chamber 1 is heated to the pre-set temperature by burners 7 mounted on the fire tube.
  • the diagonal arrangement of the burners leads to favourable air engineering characteristics and the burners do not disturb the operation of each other in contrast with other arrangements.
  • the desired operation pressure is achieved by agitating the charge by the periodic movement of side scraper elements 14 of agitator 13. Due to the agitation, the amount of the material to be decomposed increases on the heat transfer surface.
  • the oil vapours generated by the decomposition of coarse granules transfer a part of their heat content to the loosened charge which means a secondary heat transfer.
  • Inner chamber 3 according to the present invention comprises lower and upper cy- lindrical elements, in contrast with cylindrical reactors or those with only an upper conical part, and this shape is more suitable for increasing the surface and processing the charge than those of known reactors.
  • the moving of the charge is favourably influenced by crossbar 19 which is fastened to axis-end 12 and holds side-wing (scraper element) 14 fastened to the lower scraper blade with a screwed connection.
  • the slag remaining on bottom 2 is mainly carbon black. If the starting material does not comprise metallic reinforcing materials its residues are removed together with carbon black when lower bolt lock 8 is opened; then upper bolt locks 15 and 16 are closed.
  • the intensive heat transfer between combustion chamber 1 and inner chamber 3 is favourably increased by baffles 6 welded on the wall of inner chamber 3 and facing combustion chamber 1. They also facilitate the spiral flow of the hot flue gases which leave combustion chamber 1 at smoke-pipe 25.
  • the heat storage of the apparatus is provided by the fire-clay lining (not shown in the figure) covering the bottom of combustion chamber 1.
  • the slow heat response of the apparatus is not influenced by the warming up of ceramic thermal insulation 21, 22 mounted on the outer case. This light insulation is fixed by a plate cover.
  • the inner chamber according to the present invention is 2,5 times larger than that of Hungarian utility model No. 1 853. Therefore, the amount to be fed and the amount of charge to be processed are increased by the same factor.
  • inner chamber 3 has a conical shape also at the bottom and it allows a greater amount of material to con- tact simultaneously the heat transfer surface along the inner envelope.
  • baffles 6 has the same effect; they improve heat transfer, prevent the turbulent flow of the flue gases and enable the spiral flow of the gases in combustion chamber 1. It was also found that the efficiency of heat transfer may improve in a smaller combustion chamber. It is further increased by the heat resistant outer steel case which is used instead of the fire-clay wall and directs radiated heat to the walls of inner chamber 3.
  • the change of the heat resistant walls leads to a further advantage, namely, the heat storage of the furnace does not generate a fire hazard, and the apparatus can be heated and cooled quickly.
  • the feeding of the material to be treated is improved by the reverse screw on axis 18 mounted into feeding tank 17; the screw prevents the clogging of feeding opening 24 as it loosens the granules agglomerating in the centre by lifting them and sprinkles them towards the envelope, thus, the feeding is fast and free from clogging.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L'invention concerne un appareil de pyrolyse permettant de traiter des granules grossiers produits à partir de déchets de plastique et de caoutchouc, et de fabriquer des produits d'hydrocarbures. Cet appareil comprend une chambre intérieure (3) avec un axe vertical, servant de réacteur de pyrolyse, une chambre de combustion (1), un boîtier de réacteur extérieur, des orifices d'entrée et de sortie pour les produits (17, 18, 20, 24, 9), des éléments chauffants (7) et des éléments d'agitation (13). La chambre intérieure (3) est conique au niveau de son sommet et de son fond, possède des éléments d'écran thermique discrets (6) faisant face à la chambre de combustion (1), une vis de changement de marche est fixée sur l'axe (18) dans la cuve de pré-alimentation (17) et la pale inférieure de l'agitateur (13) possède des éléments racleurs latéraux (14).
PCT/HU2001/000120 2001-10-02 2001-11-26 Appareil de pyrolyse permettant de traiter des granules grossiers de dechets de plastique et de caoutchouc WO2003029384A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
HU20010100243U HU2291U (en) 2001-10-02 2001-10-02 Pirtolisating apparatus for processing coarse chips produced from plastic and rubber waste
HUU0100243 2001-10-02

Publications (1)

Publication Number Publication Date
WO2003029384A1 true WO2003029384A1 (fr) 2003-04-10

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WO (1) WO2003029384A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004037949A1 (fr) * 2002-10-28 2004-05-06 Lekrinszki Istvan Appareil de pyrolyse de pneus laceres
WO2005021685A1 (fr) * 2003-08-27 2005-03-10 S.C. Pyroinvest S.A. Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques
WO2006056818A1 (fr) * 2004-11-26 2006-06-01 New Energy Kft. Dispositif permettant d'effectuer la pyrolyse de copeaux de caoutchouc et de separer les produits recuperes
WO2006092306A1 (fr) * 2005-03-02 2006-09-08 Clyvia Technology Gmbh Procede de depolymerisation de residus contenant des hydrocarbures et dispositif destine a la mise en oeuvre du procede
WO2009052709A1 (fr) * 2007-10-24 2009-04-30 Daguang Li Réacteur de craquage pour pneus usagés et plastique
CN103160306A (zh) * 2013-03-19 2013-06-19 启东金匙环保科技有限公司 一种连续化废弃橡胶低温微压无催化热解生产成套设备
CN105709679A (zh) * 2014-12-05 2016-06-29 雍自玲 一种省能源的炼油搅拌装置
WO2016089235A3 (fr) * 2014-11-28 2016-09-09 Finertec Fuels Centro , Lda. Mécanisme de production d'hydrocarbures par pyrolyse de déchets de matières plastiques et son procédé de production
CN106635116A (zh) * 2017-02-10 2017-05-10 武汉科技大学 一种废旧轮胎胶粒裂解器
RU2780833C1 (ru) * 2021-11-25 2022-10-04 Марина Игоревна Вепринцева Способ получения продуктов термической деструкции резиновой крошки, полученной из использованных автомобильных шин
AU2019348728B2 (en) * 2018-09-26 2023-01-12 Plastic Energy Limited A reactor assembly
IT202200006077A1 (it) * 2022-03-28 2023-09-28 Pierluigi Frenna Impianto di dissociazione molecolare
US11999920B2 (en) 2020-09-14 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock
US12031097B2 (en) 2021-10-14 2024-07-09 Ecolab Usa Inc. Antifouling agents for plastic-derived synthetic feedstocks

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US843599A (en) * 1906-06-12 1907-02-12 Clarence S Hammatt Process of distilling wood.
FR753783A (fr) * 1932-04-04 1933-10-24 Four continu pour la carbonisation et la distillation
JPS60130678A (ja) * 1983-12-15 1985-07-12 Mamoru Sano 熱分解乾溜機
US5618321A (en) * 1994-09-15 1997-04-08 Thermal Technologies, Inc. Pyrolysis gasifier with inner sleeve member
JPH09243043A (ja) * 1996-03-13 1997-09-16 Densen Sogo Gijutsu Center 廃プラスチック熱分解槽の攪拌及び残渣排出機構
US5824193A (en) * 1997-03-27 1998-10-20 Edwards; Raymond S. Method of thermally treating plastics material
EP0913360A1 (fr) * 1997-09-23 1999-05-06 Chien-Lang Teng Méthode continue/intermittente de préparation de charbon actif épuré à partir de déchets de pneus et son dispositif
US6048374A (en) * 1997-08-18 2000-04-11 Green; Alex E. S. Process and device for pyrolysis of feedstock

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US843599A (en) * 1906-06-12 1907-02-12 Clarence S Hammatt Process of distilling wood.
FR753783A (fr) * 1932-04-04 1933-10-24 Four continu pour la carbonisation et la distillation
JPS60130678A (ja) * 1983-12-15 1985-07-12 Mamoru Sano 熱分解乾溜機
US5618321A (en) * 1994-09-15 1997-04-08 Thermal Technologies, Inc. Pyrolysis gasifier with inner sleeve member
JPH09243043A (ja) * 1996-03-13 1997-09-16 Densen Sogo Gijutsu Center 廃プラスチック熱分解槽の攪拌及び残渣排出機構
US5824193A (en) * 1997-03-27 1998-10-20 Edwards; Raymond S. Method of thermally treating plastics material
US6048374A (en) * 1997-08-18 2000-04-11 Green; Alex E. S. Process and device for pyrolysis of feedstock
EP0913360A1 (fr) * 1997-09-23 1999-05-06 Chien-Lang Teng Méthode continue/intermittente de préparation de charbon actif épuré à partir de déchets de pneus et son dispositif

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004037949A1 (fr) * 2002-10-28 2004-05-06 Lekrinszki Istvan Appareil de pyrolyse de pneus laceres
WO2005021685A1 (fr) * 2003-08-27 2005-03-10 S.C. Pyroinvest S.A. Procede et installation de craquage thermique utilises pour la decomposition de dechets composes de caoutchouc et de matieres plastiques
WO2006056818A1 (fr) * 2004-11-26 2006-06-01 New Energy Kft. Dispositif permettant d'effectuer la pyrolyse de copeaux de caoutchouc et de separer les produits recuperes
WO2006092306A1 (fr) * 2005-03-02 2006-09-08 Clyvia Technology Gmbh Procede de depolymerisation de residus contenant des hydrocarbures et dispositif destine a la mise en oeuvre du procede
WO2009052709A1 (fr) * 2007-10-24 2009-04-30 Daguang Li Réacteur de craquage pour pneus usagés et plastique
CN103160306A (zh) * 2013-03-19 2013-06-19 启东金匙环保科技有限公司 一种连续化废弃橡胶低温微压无催化热解生产成套设备
CN103160306B (zh) * 2013-03-19 2014-11-26 启东金匙环保科技有限公司 一种连续化废弃橡胶低温微压无催化热解生产成套设备
WO2016089235A3 (fr) * 2014-11-28 2016-09-09 Finertec Fuels Centro , Lda. Mécanisme de production d'hydrocarbures par pyrolyse de déchets de matières plastiques et son procédé de production
CN105709679A (zh) * 2014-12-05 2016-06-29 雍自玲 一种省能源的炼油搅拌装置
CN106635116A (zh) * 2017-02-10 2017-05-10 武汉科技大学 一种废旧轮胎胶粒裂解器
CN106635116B (zh) * 2017-02-10 2018-07-17 武汉科技大学 一种废旧轮胎胶粒裂解器
AU2019348728B2 (en) * 2018-09-26 2023-01-12 Plastic Energy Limited A reactor assembly
US11708534B2 (en) 2018-09-26 2023-07-25 Plastic Energy Limited Reactor assembly
US11999920B2 (en) 2020-09-14 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock
US12031097B2 (en) 2021-10-14 2024-07-09 Ecolab Usa Inc. Antifouling agents for plastic-derived synthetic feedstocks
RU2780833C1 (ru) * 2021-11-25 2022-10-04 Марина Игоревна Вепринцева Способ получения продуктов термической деструкции резиновой крошки, полученной из использованных автомобильных шин
IT202200006077A1 (it) * 2022-03-28 2023-09-28 Pierluigi Frenna Impianto di dissociazione molecolare
RU2820182C1 (ru) * 2023-11-16 2024-05-30 Дмитрий Юрьевич Бирюков Технологическая линия получения технического углерода термической деструкцией резиновой крошки использованных автомобильных шин с применением углекислого газа

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Publication number Publication date
HU0100243V0 (en) 2001-11-28
HU2291U (en) 2002-05-28

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