WO2003021708A3 - Recycling used electric cells by hydrometallurgical treatment - Google Patents

Recycling used electric cells by hydrometallurgical treatment Download PDF

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Publication number
WO2003021708A3
WO2003021708A3 PCT/FR2002/002522 FR0202522W WO03021708A3 WO 2003021708 A3 WO2003021708 A3 WO 2003021708A3 FR 0202522 W FR0202522 W FR 0202522W WO 03021708 A3 WO03021708 A3 WO 03021708A3
Authority
WO
WIPO (PCT)
Prior art keywords
manganese
upgradable
electric cells
starting product
cells
Prior art date
Application number
PCT/FR2002/002522
Other languages
French (fr)
Other versions
WO2003021708A2 (en
Inventor
Farouk Tedjar
Original Assignee
Recupyl Sa
Farouk Tedjar
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Recupyl Sa, Farouk Tedjar filed Critical Recupyl Sa
Priority to EP02770030A priority Critical patent/EP1454376B1/en
Priority to DK02770030T priority patent/DK1454376T3/en
Priority to DE2002623399 priority patent/DE60223399T2/en
Publication of WO2003021708A2 publication Critical patent/WO2003021708A2/en
Publication of WO2003021708A3 publication Critical patent/WO2003021708A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
    • C22B7/006—Wet processes
    • C22B7/007—Wet processes by acid leaching
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/20—Obtaining zinc otherwise than by distilling
    • C22B19/26—Refining solutions containing zinc values, e.g. obtained by leaching zinc ores
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/30—Obtaining zinc or zinc oxide from metallic residues or scraps
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B47/00—Obtaining manganese
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/52—Reclaiming serviceable parts of waste cells or batteries, e.g. recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Processing Of Solid Wastes (AREA)
  • Secondary Cells (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention concerns a method for treating electric cells for recovering upgradable elements, by combining basic washing to eliminate soluble salts and in particular chlorides through an attrition process, with ultrasound-aided sulphuric acid leaching in the presence of a reducing agent. The solution derived from said treatment is purified in two steps to separate mercury first and subsequently heavy metals. The resulting purified solution is treated to separate zinc and manganese which are respectively recovered in the form of neutral or basic zinc salt and manganese carbonate. The manganese carbonate is upgradable as such. In an embodiment of the present invention it is used as starting product for preparing manganese sulphate. In another embodiment, said manganese sulphate is used as starting product for making electroactive manganese dioxide for making cathodes of saline and alkaline Leclanché cells.
PCT/FR2002/002522 2001-07-23 2002-07-16 Recycling used electric cells by hydrometallurgical treatment WO2003021708A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP02770030A EP1454376B1 (en) 2001-07-23 2002-07-16 Recycling used electric cells by hydrometallurgical treatment
DK02770030T DK1454376T3 (en) 2001-07-23 2002-07-16 Recycling of used electric batteries during hydrometallurgical treatment
DE2002623399 DE60223399T2 (en) 2001-07-23 2002-07-16 RECYCLING USED ELECTRIC CELLS BY HYDROMETALLURGIC TREATMENT

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0109791 2001-07-23
FR0109791A FR2827710B1 (en) 2001-07-23 2001-07-23 IMPROVEMENT FOR THE TREATMENT OF USED ELECTRIC BATTERIES BY HYDROMETALLURGICAL ROUTE

Publications (2)

Publication Number Publication Date
WO2003021708A2 WO2003021708A2 (en) 2003-03-13
WO2003021708A3 true WO2003021708A3 (en) 2004-06-17

Family

ID=8865794

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2002/002522 WO2003021708A2 (en) 2001-07-23 2002-07-16 Recycling used electric cells by hydrometallurgical treatment

Country Status (8)

Country Link
EP (1) EP1454376B1 (en)
AT (1) ATE377847T1 (en)
DE (1) DE60223399T2 (en)
DK (1) DK1454376T3 (en)
ES (1) ES2295405T3 (en)
FR (1) FR2827710B1 (en)
PT (1) PT1454376E (en)
WO (1) WO2003021708A2 (en)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2868603B1 (en) 2004-04-06 2006-07-14 Recupyl Sa Sa METHOD FOR RECYCLING BATTERY MIXTURES AND BATTERIES BASED ON LITHIUM ANODE
ITRM20040578A1 (en) * 2004-11-25 2005-02-25 Univ Roma PROCESS AND PLANT FOR THE TREATMENT OF EXHAUSTED PILE.
US8323510B2 (en) * 2008-04-02 2012-12-04 Fengchun Xie Ultrasound assisted heavy metal recovery
BE1018637A3 (en) * 2009-02-02 2011-05-03 Recyclage Et Valorisation Tech PROCESS FOR TREATING ALKALINE AND SALINE BATTERIES FOR THE VALORIZATION OF ZINC AND MANGANESE
CN103168109B (en) * 2010-08-18 2015-12-16 美国锰业股份有限公司 The process of manganous sulfate/manganous dithionate liquid
WO2012025568A2 (en) 2010-08-24 2012-03-01 Akkuser Oy Metal ion recovery from battery waste
EP2631987A1 (en) 2012-02-24 2013-08-28 Rec Alkaline Oy Metal ion recovery from battery waste using ammonia
TWI535479B (en) * 2014-09-18 2016-06-01 朝陽科技大學 Valuable metals recovering method
WO2019150005A1 (en) 2018-02-05 2019-08-08 Tracegrow Oy Processes for production of micronutrients from spent alkaline batteries
CN108695571B (en) * 2018-04-28 2019-12-31 杭州电子科技大学 Method for improving flotation separation effect of waste lithium battery through gamma ray irradiation
CN111924892A (en) * 2020-07-24 2020-11-13 中国科学院过程工程研究所 Method for selectively recovering lithium ion battery electrode powder
EP4112757A1 (en) 2021-07-01 2023-01-04 BRAIN Biotech AG A bio-based process for extracting metals from batteries

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61281467A (en) * 1985-06-06 1986-12-11 Kiresuto Giken:Kk Recovery process for manganese dry battery
JPH05247554A (en) * 1992-03-03 1993-09-24 Tsukishima Kikai Co Ltd Method for recovering zinc from waste manganese dry cell
EP0620607A1 (en) * 1993-04-16 1994-10-19 Institut National Polytechnique De Grenoble Method for electrolytical processing of used batteries
EP0652603A1 (en) * 1993-11-05 1995-05-10 Keramchemie GmbH Method for the hydrometallurgical treatment of used domestic and appliance batteries
ES2134725A1 (en) * 1997-06-13 1999-10-01 Tecnicas Reunidas S A Method for processing spent electrochemical dry batteries for domestic use, with recovery of component elements

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61281467A (en) * 1985-06-06 1986-12-11 Kiresuto Giken:Kk Recovery process for manganese dry battery
JPH05247554A (en) * 1992-03-03 1993-09-24 Tsukishima Kikai Co Ltd Method for recovering zinc from waste manganese dry cell
EP0620607A1 (en) * 1993-04-16 1994-10-19 Institut National Polytechnique De Grenoble Method for electrolytical processing of used batteries
EP0652603A1 (en) * 1993-11-05 1995-05-10 Keramchemie GmbH Method for the hydrometallurgical treatment of used domestic and appliance batteries
ES2134725A1 (en) * 1997-06-13 1999-10-01 Tecnicas Reunidas S A Method for processing spent electrochemical dry batteries for domestic use, with recovery of component elements

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE EPODOC EUROPEAN PATENT OFFICE, THE HAGUE, NL; XP002195317 *
PATENT ABSTRACTS OF JAPAN vol. 011, no. 143 (E - 504) 9 May 1987 (1987-05-09) *
PATENT ABSTRACTS OF JAPAN vol. 018, no. 004 (C - 1149) 6 January 1994 (1994-01-06) *

Also Published As

Publication number Publication date
WO2003021708A2 (en) 2003-03-13
FR2827710B1 (en) 2004-07-16
DE60223399T2 (en) 2008-08-28
EP1454376A2 (en) 2004-09-08
FR2827710A1 (en) 2003-01-24
PT1454376E (en) 2008-02-14
ATE377847T1 (en) 2007-11-15
DK1454376T3 (en) 2008-03-25
ES2295405T3 (en) 2008-04-16
EP1454376B1 (en) 2007-11-07
DE60223399D1 (en) 2007-12-20

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