WO2003011913A1 - Procede de polymerisation et injecteur destine a etre utilise dans le cadre du procede de polymerisation - Google Patents

Procede de polymerisation et injecteur destine a etre utilise dans le cadre du procede de polymerisation Download PDF

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Publication number
WO2003011913A1
WO2003011913A1 PCT/JP2002/007173 JP0207173W WO03011913A1 WO 2003011913 A1 WO2003011913 A1 WO 2003011913A1 JP 0207173 W JP0207173 W JP 0207173W WO 03011913 A1 WO03011913 A1 WO 03011913A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
polymerization
nozzle
polymerization method
polymerizable monomer
Prior art date
Application number
PCT/JP2002/007173
Other languages
English (en)
French (fr)
Inventor
Taisuke Ishii
Yoshiaki Mori
Shunichi Himori
Kiichi Itoh
Original Assignee
Mitsubishi Chemical Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2001230823A external-priority patent/JP2003040904A/ja
Application filed by Mitsubishi Chemical Corporation filed Critical Mitsubishi Chemical Corporation
Priority to EP02746061A priority Critical patent/EP1424346A4/en
Publication of WO2003011913A1 publication Critical patent/WO2003011913A1/ja
Priority to US10/953,620 priority patent/US7288610B2/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J14/00Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/247Suited for forming thin films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/025Nozzles having elongated outlets, e.g. slots, for the material to be sprayed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/06Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane
    • B05B7/061Spray pistols; Apparatus for discharge with at least one outlet orifice surrounding another approximately in the same plane with several liquid outlets discharging one or several liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/08Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point
    • B05B7/0807Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets
    • B05B7/0846Spray pistols; Apparatus for discharge with separate outlet orifices, e.g. to form parallel jets, i.e. the axis of the jets being parallel, to form intersecting jets, i.e. the axis of the jets converging but not necessarily intersecting at a point to form intersecting jets with jets being only jets constituted by a liquid or a mixture containing a liquid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/02Spray pistols; Apparatus for discharge
    • B05B7/10Spray pistols; Apparatus for discharge producing a swirling discharge
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00243Mathematical modelling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/02Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape
    • B05B1/04Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, or having an outlet of particular shape in flat form, e.g. fan-like, sheet-like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/34Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
    • B05B1/3405Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
    • B05B1/341Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
    • B05B1/3421Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
    • B05B1/3426Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels emerging in the swirl chamber perpendicularly to the outlet axis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/915Redox catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/919Catalyst injection technique in addition polymerization processes
PCT/JP2002/007173 2001-07-31 2002-07-15 Procede de polymerisation et injecteur destine a etre utilise dans le cadre du procede de polymerisation WO2003011913A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP02746061A EP1424346A4 (en) 2001-07-31 2002-07-15 POLYMERIZATION PROCESS AND NOZZLE FOR USE IN THE POLYMERIZATION PROCESS
US10/953,620 US7288610B2 (en) 2001-07-31 2004-02-02 Method of polymerization and nozzle employed in same

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001-230822 2001-07-31
JP2001230823A JP2003040904A (ja) 2001-07-31 2001-07-31 重合方法
JP2001230822 2001-07-31
JP2001-230823 2001-07-31

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/953,620 Continuation US7288610B2 (en) 2001-07-31 2004-02-02 Method of polymerization and nozzle employed in same

Publications (1)

Publication Number Publication Date
WO2003011913A1 true WO2003011913A1 (fr) 2003-02-13

Family

ID=26619612

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/007173 WO2003011913A1 (fr) 2001-07-31 2002-07-15 Procede de polymerisation et injecteur destine a etre utilise dans le cadre du procede de polymerisation

Country Status (3)

Country Link
US (1) US7288610B2 (ja)
EP (1) EP1424346A4 (ja)
WO (1) WO2003011913A1 (ja)

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US6260017B1 (en) * 1999-05-07 2001-07-10 Qualcomm Inc. Multipulse interpolative coding of transition speech frames
US7490738B2 (en) * 2004-10-01 2009-02-17 Angiotech Pharmaceuticals (Us), Inc. Mixing and dispensing fluid components of a multicomponent composition
US7727586B2 (en) 2005-01-28 2010-06-01 Basf Aktiengesellschaft Production of water-absorbing polymeric particles by dropletization polymerization in the gas phase
US7766900B2 (en) * 2005-02-21 2010-08-03 Biomet Manufacturing Corp. Method and apparatus for application of a fluid
EP1721661A1 (de) * 2005-05-12 2006-11-15 Basf Aktiengesellschaft Verfahren zur Herstellung von Polymerpartikeln durch Sprühpolymerisation
MY150001A (en) * 2006-07-19 2013-11-15 Basf Se Method for producing post-cured water-absorbent polymer particles with a higher absorption by polymerising droplets of a monomer solution
CN101489598B (zh) * 2006-07-19 2015-07-08 巴斯夫欧洲公司 通过聚合单体溶液液滴生产具有较高渗透性的吸水性聚合物颗粒的方法
BRPI0714447B1 (pt) * 2006-07-19 2019-02-19 Basf Se Processo para preparar partículas poliméricas absorvedoras de água, partículas poliméricas absorvedoras de água, uso das particulás poliméricas, e, artigo de higiene
DE502007006381D1 (de) * 2006-07-19 2011-03-10 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel mit hoher permeabilität durch polymerisation von tropfen einer monomerlösung
EP2076547B1 (de) 2006-10-05 2011-03-09 Basf Se Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung
US8518272B2 (en) 2008-04-04 2013-08-27 Biomet Biologics, Llc Sterile blood separating system
US8381323B2 (en) 2009-09-30 2013-02-26 Toto Ltd Sanitary washing apparatus
US20110121108A1 (en) * 2009-11-24 2011-05-26 Stephan Rodewald Plasma polymerization nozzle
US20110121107A1 (en) * 2009-11-24 2011-05-26 Frederic Gerard Auguste Siffer Plasma polymerization nozzle
CN101838372B (zh) * 2010-04-23 2014-06-11 苏州天立蓝环保科技有限公司 一种快速吸油材料的制备方法
DE102012000985A1 (de) * 2012-01-20 2013-07-25 Ecotecfuel Llc Verfahren und Vorrichtung zur Abtrennung ausdampfbarer Komponenten aus einem Fluid
FR3008899B1 (fr) 2013-07-25 2017-04-21 Arkema France Methode et systeme pour la distribution d'un liquide dans des capacites pour la preparation de monomeres (meth)acryliques
AU2014368759B2 (en) 2013-12-17 2018-11-01 Basf Se Method for producing polyamides by means of a spray nozzle arrangement for the collision of spray jets
ES2606957B1 (es) * 2015-09-28 2018-01-15 Ingeniatrics Tecnologías, S.L. Dispositivos y métodos para microencapsulación basados en capilares concéntricos
DE102018118165A1 (de) * 2018-07-26 2020-01-30 Fmp Technology Gmbh Fluid Measurements & Projects Verfahren und Vorrichtung zur Erzeugung von dauerhaft vereinzelten Tropfen aus einem flüssigen Medium

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JPS5834811A (ja) * 1981-08-22 1983-03-01 Mitsubishi Petrochem Co Ltd エチレンの重合法
JPH05132503A (ja) * 1991-11-13 1993-05-28 Jgc Corp 噴霧重合法及び噴霧重合用ノズル
JPH06211904A (ja) * 1992-04-20 1994-08-02 Jgc Corp 噴霧重合法及び噴霧重合用ノズル
JPH07309903A (ja) * 1994-05-19 1995-11-28 Mitsubishi Rayon Co Ltd メタクリル酸エステル系重合体の製造方法
JPH08208747A (ja) * 1995-01-31 1996-08-13 Mitsubishi Rayon Co Ltd メタクリル酸エステル系重合体の連続的製造方法
JPH09255704A (ja) * 1996-03-26 1997-09-30 Kao Corp ポリマーの製造方法及び噴霧重合用ノズル
JPH10251310A (ja) * 1997-03-17 1998-09-22 Nippon Shokubai Co Ltd 親水性重合体の製造方法
JPH1149805A (ja) * 1997-07-31 1999-02-23 Jgc Corp 噴霧重合法及び噴霧重合用スリット型ノズル

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54139986A (en) * 1978-04-24 1979-10-30 Tokuyama Soda Co Ltd Polymerization of propylene
JPS5834811A (ja) * 1981-08-22 1983-03-01 Mitsubishi Petrochem Co Ltd エチレンの重合法
JPH05132503A (ja) * 1991-11-13 1993-05-28 Jgc Corp 噴霧重合法及び噴霧重合用ノズル
JPH06211904A (ja) * 1992-04-20 1994-08-02 Jgc Corp 噴霧重合法及び噴霧重合用ノズル
JPH07309903A (ja) * 1994-05-19 1995-11-28 Mitsubishi Rayon Co Ltd メタクリル酸エステル系重合体の製造方法
JPH08208747A (ja) * 1995-01-31 1996-08-13 Mitsubishi Rayon Co Ltd メタクリル酸エステル系重合体の連続的製造方法
JPH09255704A (ja) * 1996-03-26 1997-09-30 Kao Corp ポリマーの製造方法及び噴霧重合用ノズル
JPH10251310A (ja) * 1997-03-17 1998-09-22 Nippon Shokubai Co Ltd 親水性重合体の製造方法
JPH1149805A (ja) * 1997-07-31 1999-02-23 Jgc Corp 噴霧重合法及び噴霧重合用スリット型ノズル

Also Published As

Publication number Publication date
EP1424346A1 (en) 2004-06-02
US7288610B2 (en) 2007-10-30
US20050119424A1 (en) 2005-06-02
EP1424346A4 (en) 2008-05-07

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