WO2002101299A1 - Vorrichtung zur anreicherung von luft mit einem luftbehandlungsmittel insbesondere zur luftentkeimung, luftbeduftung und/oder geruchsmaskierung - Google Patents
Vorrichtung zur anreicherung von luft mit einem luftbehandlungsmittel insbesondere zur luftentkeimung, luftbeduftung und/oder geruchsmaskierung Download PDFInfo
- Publication number
- WO2002101299A1 WO2002101299A1 PCT/EP2002/006157 EP0206157W WO02101299A1 WO 2002101299 A1 WO2002101299 A1 WO 2002101299A1 EP 0206157 W EP0206157 W EP 0206157W WO 02101299 A1 WO02101299 A1 WO 02101299A1
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- WO
- WIPO (PCT)
- Prior art keywords
- air
- treatment agent
- air treatment
- evaporation
- storage container
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
- A61L9/145—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes air-liquid contact processes, e.g. scrubbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/02—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/02—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
- A61L9/03—Apparatus therefor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F6/00—Air-humidification, e.g. cooling by humidification
- F24F6/02—Air-humidification, e.g. cooling by humidification by evaporation of water in the air
- F24F6/025—Air-humidification, e.g. cooling by humidification by evaporation of water in the air using electrical heating means
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F6/00—Air-humidification, e.g. cooling by humidification
- F24F6/02—Air-humidification, e.g. cooling by humidification by evaporation of water in the air
- F24F6/08—Air-humidification, e.g. cooling by humidification by evaporation of water in the air using heated wet elements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/20—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by sterilisation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
- F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
- F24F8/50—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by odorisation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D17/00—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
- F25D17/04—Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
- F25D17/042—Air treating means within refrigerated spaces
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2317/00—Details or arrangements for circulating cooling fluids; Details or arrangements for circulating gas, e.g. air, within refrigerated spaces, not provided for in other groups of this subclass
- F25D2317/04—Treating air flowing to refrigeration compartments
- F25D2317/041—Treating air flowing to refrigeration compartments by purification
- F25D2317/0415—Treating air flowing to refrigeration compartments by purification by deodorizing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Definitions
- Device for enriching air with an air treatment agent in particular for air disinfection, air scenting and / or odor masking
- the invention relates to a device for enriching air with an air treatment agent, in particular for air disinfection, air scenting and odor masking.
- Air treatment is required, for example, in living rooms (e.g. of allergy sufferers), in office buildings, means of transport and transportation, hygiene areas and in healthcare.
- Evaporators are known for air treatment, in which an air treatment agent is evaporated with the aid of an evaporation device. With such evaporation of the air treatment agent, the air is relatively strongly enriched with treatment agents, so that the treatment agent is deposited in the room to be treated. Precipitation of the air treatment agent cannot be avoided even by clocking an evaporator operating due to the supply of heat. The precipitation is only limited in time. The precipitation of air treatment agents on cold objects such as windows and the like. The like disturbs the user and also leads to easier soiling of these objects, since dust is attracted by the precipitation, for example. The precipitation on wooden furniture u. Like. Can also lead to damage to the furniture.
- Spray-compressed air systems for spraying air treatment agents are also known.
- a fine atomization of the Air treatment agent Even when using spray-compressed air systems, the occurrence of precipitation of the air treatment agent is not avoided.
- Another area of application for air treatment agents is, for example, the introduction of disinfectants when cooling baked goods after the baking process. It must be avoided that mold germs are deposited on the surface of the baked goods before packaging. Since precipitation of the air treatment agent is also unacceptable in this area, complex air filter systems with different filter systems are used. The problem here is that the mold germs can be deposited in the air filter system and act as mold growth spots for the air filter itself. As a result, the filters have to be replaced frequently and cleaned very thoroughly.
- Air treatment is also required for the storage of cheese after ripening, since after the ripening, mold growth in the air causes undesirable mold formation on the cheese surface.
- cheese is covered with a covering agent, for example, which contains an antibiotic.
- the antibiotic penetrates the outside of the cheese due to diffusions.
- antibiotics are undesirably added to the human body when the cheese is enjoyed.
- the use of filter systems in cheese preparation has the same disadvantage as in the preparation of baked goods.
- the object of the invention is to provide a device for enriching air with an air treatment agent, in which the precipitation of the air treatment agent is avoided.
- the device according to the invention has a storage container for holding liquid air treatment agent and an evaporation device connected to the storage container, for example via a pipe or a hose, for heating the air treatment agent.
- a metering device is arranged between the storage container and the evaporation device, ie for example in the hose or tube. The metering device ensures a quantity-limited supply of liquid air treatment agent to the evaporation device.
- a mixing container is connected to the evaporation device, in which the evaporated air treatment agent is mixed with air.
- the mixing container has an outlet opening for discharging the mixture of air and vaporous air treatment agent.
- the inlet openings in relation to the small amount of liquid air treatment agent supplied, so much air is supplied that it is possible to supply the room to be treated with an air treatment agent fraction per hour and cubic meter of air which is between 0.1 and 0.00001 ml is preferably between 0.01 and 0.001 ml. Due to this small amount of air treatment agent that is supplied to the room to be treated, no precipitation of the air treatment agent can be detected in the room. A disturbing precipitation on cool windows or the like does not occur.
- the device of the invention is thus particularly for living rooms, waiting rooms and. Like. Suitable.
- the air treatment agent portion is preferably less than 100 ppb (parts per billion) and in particular less than 10 ppb.
- the mixing container is preferably assigned a means for generating an air flow, such as a fan. Air is sucked or blown into the mixing container by the fan through the air inlet openings provided in the mixing container. Furthermore, the means for generating an air flow serves to expel or blow out the mixture of air and vaporous air treatment agent from the outlet opening.
- an amount of 0.01 ml per cubic meter per hour to 0.005 ml per cubic meter per hour of air treatment agent is supplied to the room to be treated.
- a space of, for example, 50 cubic meters of air 0.5 ml per hour to 0.25 ml per hour are thus fed from the storage container to the evaporation device and evaporated therein.
- the conveying capacity of the agent for conveying the air stream must not be too great.
- a relatively high delivery volume is required to achieve an extremely low proportion of air treatment agents per cubic meter of air.
- the volume flow of air conveyed is preferably 25-35 m 3 per hour.
- the ratio between the amount of air conveyed and the amount of air treatment agent supplied to the evaporation device is thus in the range from 140/1 to 50/1, preferably 100/1 to 70/1.
- the at least one air inlet opening of the mixing container is larger in cross section than the at least one outlet opening. If there are several outlet or several inlet openings, the sum of the cross-sectional areas of the outlet openings is smaller than the sum of the cross-sectional areas of the air inlet openings. In a preferred embodiment of the invention there is a continuous supply of air treatment agent to the
- the metering device preferably has an outlet opening, through which the air treatment agent exits in the direction of the evaporation device, the cross-sectional area of which is less than 0.078 cm, in particular less than 0.000314 cm. With a round outlet opening, this corresponds to a diameter of 0.1 mm or 0.2 mm. It is preferably a fixed, non-variable outlet opening. The diameter of the outlet opening can be varied, for example, by changing the corresponding disk or the like in which the outlet opening is provided.
- pane or the like with a relatively large outlet opening and to reduce the amount of air treatment agent which is supplied to the evaporation device by providing panes with smaller outlet openings in the flow direction in front of or behind the pane with large air outlet openings.
- insertion slots for inserting such panes can be provided, for example, in a tube or hose arranged between the storage container and the evaporation device.
- the storage container is preferably arranged opposite the evaporation device in such a way that there is a difference in height between these two parts of the device, the storage container being arranged higher.
- the fluid connection such as the hose or the tube
- the evaporation device preferably has a temperature of 40-70 ° C.
- a peristaltic pump or another suitable conveying means for conveying the air treatment agent.
- air treatment agents are preferably conveyed continuously.
- the amount of air treatment agent depends on the one hand on the delivery volume of the fan and on the other hand on the size of the room to be treated.
- continuous delivery it is also possible to supply the air treatment agent to the evaporation device at intervals. This has the advantage that conventional, low-cost peristaltic pumps can be used.
- the storage container preferably has a pressure compensation device, so that ambient pressure and no negative pressure always prevail in the storage container. Negative pressure would influence the amount of air treatment agent that is supplied to the evaporation device.
- the storage container is preferably closed with a lid or the like.
- the lid which can be removed for filling the storage container, preferably has a particle filter.
- the particle filter is designed such that air can flow into the storage container for pressure equalization, but on the other hand prevents particles such as dust from getting into the storage container. Such particles can clog the metering device or impair the flow rate.
- the pressure compensation device which is preferably an opening provided with a particle filter, is preferably provided in the cover. However, it can also be arranged at a different location on the storage container.
- a second preferred embodiment of the invention for enriching air with an air treatment agent also has a storage container for holding liquid air treatment agent and an evaporation device connected to the storage container for heating the air treatment agent.
- This preferred embodiment of the invention has an inclined evaporation surface of the evaporation device. The air treatment agent flows over this inclined evaporation surface.
- a return device is connected to the evaporation device, which returns the non-evaporated air treatment agent to the storage container.
- a thin film of air treatment agent thus preferably forms on the evaporation surface of the evaporation device, so that uniform evaporation of the air treatment agent takes place over the entire surface of the evaporation surface.
- the provision of a return device through which excess air treatment agent is collected and returned to the storage container means that the amount of air treatment agent that is fed to the evaporation device does not have to be determined so precisely. Rather, the amount of air treatment agent that evaporates and is supplied to the air to be treated essentially depends on the temperature of the evaporation surface of the evaporation device. The amount of air treatment agent that is supplied to the air to be treated can thus be easily adjusted by regulating the temperature of the evaporation surface. Furthermore, the device according to the invention has the advantage that, due to the preferably continuous flow of the air treatment agent over the evaporation surface, no deposits are formed on the evaporation surface. The efficiency of the evaporation device can be impaired by deposits. It is also necessary to clean the evaporation device regularly. Such cleaning is at the device according to the invention is not required or at most only at very large intervals.
- the inclination of the evaporation surface which is preferably arranged in one plane, is preferably 10 ° to 30 ° with respect to a horizontal. An inclination of 15 ° to 25 ° is particularly preferred.
- the evaporation surface preferably has transport grooves running in the flow direction of the air treatment agent.
- the second embodiment of the invention preferably has a mixing container designed in accordance with the first embodiment of the invention described above.
- a means for generating an air flow such as a fan, is preferably arranged within the mixing container.
- the arrangement of the fan below the evaporation device is particularly preferred, so that the air flows past the evaporation device and is thereby enriched with evaporated air evaporation means.
- the arrangement of the fan below the evaporation device has the advantage that the evaporation surface is not cooled too much by the air flow generated by the fan, so that the desired evaporation rate is maintained.
- the second embodiment of the invention with an inclined evaporation surface can advantageously be further developed in accordance with the first embodiment described above.
- an antimicrobial composition is preferably used as air treatment agent.
- the antimicrobial composition preferably contains one, two or more GRAS (Generally Recognized As Safe) flavorings or their derivatives.
- GRAS Generally Recognized As Safe
- Preferred antimicrobial compositions with two or more GRAS flavoring agents are described in WO 01/03747 on pages 5-14, to which reference is hereby explicitly made.
- antimicrobial compositions can also be used with only one GRAS flavoring agent, as defined in more detail below.
- B. Compositions containing only one GRAS alcohol such as propylene glycol or benzyl alcohol.
- an odor-masked composition (Y) which has at least one odor-masking component (A) which is selected from terpenes, corn starch, manganese salts, essential oils and polyvinylpyrrolidone (DE 101 00 595).
- the preferred compound of the odor-masking component (A) is polyvinylpyrrolidone (Polyvidone; poly (2-oxo-1-pyrrolidinyl) ethylene; poly (1-vinyl-2-pyrrolidone; hereinafter also briefly "PVP”), in particular such PVP with a molecular weight from 10,000 to 60,000 g / mol, preferably 30,000 to 50,000 g / mol.
- PVP polyvinylpyrrolidone
- PVP with a molecular weight of about 40,000 g / mol, ie it is a PVP which has a certain degree of crosslinking (ie a viscosity of 15 to 25, preferably)
- the proportion of the odor-masking component (A) in the odor-masking composition is preferably in the range from 0.001 to 50% by weight, particularly preferably 0.1 to 10% by weight. -%.
- the odor-masking composition (Y) can contain a further functional flavor component (B).
- This preferably contains one or more of the following substances: hexyl butyrate, octyl acetate, isobutyl isobutyrate, cis-3-hexen-l-ylacetate cis-3, ⁇ -decalactone, ethyl caproate, butyl acetate, ethyl benzoate, ethyl butyrate, hexyl acetate, methyl caproate, phenylethyl alcohol, citryl ethyl alcohol, citryl ethyl alcohol, citryl ethyl alcohol , Benzylphenylacetate, cinnamic alcohol, eugenol, benzyl acetate, linalool, cis-jasmone, acetylmethylanthranilate, cis-3-hexen-l-ol,
- the proportion of the functional flavor component (B) is preferably 0.001 to 20% by weight, preferably 0.1 to 5% by weight, of the odor-masking composition.
- the odor-masking composition (Y) can further contain an aroma component (C), which is selected from essential oils, aromas and fragrances.
- the proportion of the flavoring component (C) in the odor-masking composition is 0.01 to 95% by weight, preferably 0.1 to 80% by weight.
- the flavoring component (C) contains antimicrobial substances, preferably it contains at least one GRAS (Generally Recognized As Safe) flavoring.
- GRAS Generally Recognized As Safe
- (bl) polyphenol compounds and (b2) GRAS aromatic acids or their derivatives are particularly suitable.
- the GRAS aroma alcohols mentioned and also the other GRAS aroma substances defined below are compounds which are mentioned in FEMA / FDA GRAS Flavor Substances Lists GRAS 3-15 No. 2001-3905 (status 2000).
- the flavoring component (C) or antimicrobial composition (X) can be any flavoring component (C) or antimicrobial composition (X).
- component (a) 0.1 to 99.9% by weight, preferably 0.5 to 99% by weight, component (a),
- component (b2) 0 to 70 wt .-%, preferably 0.01 to 30 wt .-%, contain component (b2).
- component (a) can contain one or more GRAS aroma alcohols.
- the use of two or three GRAS aroma alcohols is preferred.
- the following GRAS aroma alcohols can be used:
- Suitable derivatives are e.g. B. the esters, ethers and carbonates of the aforementioned GRAS aroma alcohols.
- Particularly preferred GRAS aroma alcohols are benzyl alcohol, 1-propanol, glycerin, propylene glycol, n-butyl alcohol, citronellol, hexanol, linalool, acetoin and their derivatives.
- polyphenols can be used as component (b1): pyrocatechol, resorcinol, hydroquinone, phloroglucin, pyrogallol, cyclohexane, usnic acid, acyl polyphenols, lignins, anthocyanins, flavones, catechins, gallic acid derivatives (e.g.
- tannins include tannins, gallotannin, tannic acids Tannic acids), (including the derivatives of the aforementioned compounds such as (2,5-dihydroxyphenyl) carboxyl and (2,5-dihydroxyphenyl) alkylene carboxyl substitutions, salts, esters, amides), coffee acid and its esters and amides, flavonoids (e.g. B.
- their possible derivatives e.g. B. salts, acids, esters, oxides and ethers can be used.
- the most preferred polyphenol is tannin (a GRAS compound).
- Phenylacetic acid ( ⁇ -toluenic acid), valeric acid (pentanoic acid), iso- valeric acid (3-methylbutanoic acid), cinnamic acid (3-phenylpropensic acid), citric acid, mandelic acid (hydroxyphenylacetic acid), tartaric acid (2,3-dihydroxybutanedioic acid; 2,3-dihydroxy acid), succinic acid Fumaric acid, tannic acid and their derivatives.
- Suitable derivatives of the acids mentioned in the context of the present invention are esters (eg. B. C ⁇ -6 alkyl esters and benzyl esters), amides (including N-substituted amides) and salts (alkali, alkaline earth and ammonium salts).
- esters eg. B. C ⁇ -6 alkyl esters and benzyl esters
- amides including N-substituted amides
- salts alkali, alkaline earth and ammonium salts.
- the term derivatives also encompasses modifications of the side chain hydroxy functions (for example acyl and alkyl derivatives) and modifications of the double bonds (for example the perhydrogenated and hydroxylated derivatives of the acids mentioned).
- the mixing ratio of component (a) to component (b) is preferably between 10,000: 1 and 1: 10,000, particularly preferably between 1000: 1 and 1: 1000 and very particularly preferably between 100: 1 and 1: 100.
- Suitable amounts of components (al), (a2), (bl) and (b2) are:
- component (a2) 0 to 99.8% by weight, preferably 0.01 to 99% by weight of component (a2); 0 to 25% by weight, preferably 0.01 to 10% by weight of component (bl) and / or
- component (b2) 0 to 70% by weight, preferably 0.01 to 30% by weight of component (b2).
- the flavoring component (C) or the antimicrobial composition (X) may also contain the following components (c) to (h), which are also flavoring substances that are listed in the FEMA / FDA GRAS Flavor Substances List as G.R.A.S. (Generally Recognized As Safe In Food) 3-15 No. 2001-3905 (status 2000).
- Thymol Methyleugenol, Acetyleugenol, Safrol, Eugenol, Isoeugenol, Anethol,
- Phenol methylchavicol (estragole; 3-4-methoxyphenyl-l-propene), carvacrol, ⁇ -
- GRAS esters include allicin and the following acetates iso-amyl acetate (3-methyl-1-butyl acetate), benzyl acetate, benzylphenylacetate, n-butyl acetate, cinnamyl acetate (3-phenylpropenylacetate), citric acid acetate, ethyl acetate (ethyl acetate) , Eugenol acetate (acetyleugenol), geranyl acetate, hexylacetate (hexanylethanoate), hydrocinnamate acetate (3-phenylpropylacetet), linalyl acetate, octyl acetate, phenylethyl acetate, terpinylacetate, triacetin (glyceryl triacetate), potassium acetate, sodium acetate, calcium acetate.
- Other suitable esters are the ester derivatives of the acids defined above (
- Usable acetals include e.g. B. acetal, acetaldehyde dibutylacetal, acetaldehyde dipropylacetal, Acetaldehyde phenethyl propylacetal, cinnamaldehyde ethylene glycol acetal,
- aldehydes component (g) z.
- B acetylaldehyde, anisaldehyde, benzaldehyde, iso-butylaldehyde (methyl-1-propanal), citral, citronellal, n-caprinaldehyde (n-decanal), ethylvanillin, fufurol, heliotropin (piperonal), heptylaldehyde (heptanal), hexylaldehyde (hexanal) , 2-hexenal (ß-propylacrolein), hydrocinnamaldehyde (3-phenyl-l-propanal), laurylaldehyde (docdecanal), nonylaldehyde (n-nonanal), octylaldehyde (n-octanal), phenylacetaldehyde (l-oxo-2-phenylethane)
- the essential oils listed below and / or the alcoholic, glycolic or extracts obtained from the plants mentioned (component (h)) obtained by high-pressure CO 2 processes can also be used according to the invention:
- oils or extracts with a high proportion of esters mustard, onion, garlic;
- the proportion of components (c) - (h) in the flavoring component (C) or (C) and in the antimicrobial composition (X) is preferably less than or equal to 25% by weight and is preferably in the range from 0.001 to 9% by weight .-%.
- Preferred among the other GRAS flavorings are the phenols (c) and essential oils (h).
- An example of such a composition is a mixture of benzyl alcohol, one or two of the above-mentioned GRAS aroma alcohols (a2) and tannin. This mixture preferably contains 0.1 to 99.9, particularly preferably 0.1 to 20% by weight of benzyl alcohol and 0.01 to 10% by weight of tannin.
- Another example of a preferred composition is a mixture of 2 alcohols, a polyphenol (especially tannin) and an essential oil (especially a phenolic essential oil, component (h3)).
- components (A) to (C) in addition to components (A) to (C), further compounds (D) such as alcohols (DI), emulsifiers (D2), stabilizers (D3), antioxidants (D4), preservatives ( D5), solvents (D6), carriers (D7) etc. can be used.
- the proportion of components (D) in the odor-masking composition may be up to 99% by weight, is preferably less than 50% by weight and is particularly preferably in the range from 0.1 to 20% by weight.
- the alcohols (DI) are monohydric or polyhydric alcohols having 2 to 10 C atoms, preferably having 2 to 7 C atoms, the GRAS alcohols (a) not being included in this.
- Such quantities of GRAS aroma alcohols (a) and further alcohols (DI) are preferably used that their mixing ratio between 1000: 1 and 1: 1000, in particular between 100: 1 and 1: 100 and particularly preferably between 10: 1 and 1:10.
- the carriers D7 are preferably polymeric compounds such as polyethylene glycol, polypropylene glycol, etc.
- odor-masking composition comes into contact with food or is used in rooms inhabited by people
- systems are used which are free of ethanol and isopropanol or free of questionable doses of ethanol and isopropanol, since these substances e.g. B. can be absorbed by food and can also be inhaled by the people in the treated rooms.
- these substances e.g. B. can be absorbed by food and can also be inhaled by the people in the treated rooms.
- the device described above can also be used in connection with a cooling device such as a household refrigerator.
- a cooling device such as a household refrigerator.
- This makes it possible to introduce a small amount of air treatment agent, in particular air disinfectant or odor-masking air treatment agent, into the interior of the refrigerator or the cooling device.
- Another preferred use of the device according to the invention is in connection with a computer. Due to the heat occurring in a computer and the dust accumulating in the air, the fan introduces a large number of germs into the room air.
- the device according to the invention is therefore preferably arranged in the area of the blower of a computer.
- the air flow generated by the computer fan can now be used to remove the air treatment agent.
- the germ-laden exhaust air from the computer is immediately treated with an air treatment agent.
- the invention Device are arranged in the air intake area of the fan, so that the nucleation is already suppressed.
- the device according to the invention On the outside of the housing or inside the cooling device or the computer. It is also possible to use the heat sources of the refrigerator or the computer as an evaporation device. In the case of the computer in particular, an additional evaporation device can possibly be completely dispensed with.
- Fig. 3 is a schematic side view of another preferred embodiment
- Fig. 4 is a schematic side view of another preferred embodiment
- FIG. 5 is a sectional view taken along the line V-V in Fig. 4,
- FIG. 6 shows a schematic sectional view along the line VI-VI in FIG.
- FIG. 4 is a schematic view of a household refrigerator with an air enrichment device mounted outside the refrigerator.
- Fig. 8 is a schematic representation of a household refrigerator with a device for air enrichment and arranged within the refrigerator
- Fig. 9 is a schematic view of a computer with an inventive device for air enrichment.
- the device according to the invention has a storage container 10 for receiving air treatment agent 12.
- the container 10 is cylindrical in the illustrated embodiment. However, it can also be a rectangular or other shaped storage container.
- a bottom 14 of the storage container 10 is inclined in the direction of an outlet opening 16, so that the air treatment agent 12 flows in the direction of the outlet opening 16, even if only a small amount of air treatment agent 12 is still contained in the storage container 10.
- the volume of the storage container 10 is dimensioned such that the storage container 10 can be filled with an amount of air treatment agent 12 which is sufficient for about a month.
- the latter has a filling opening 18 which is connected to a cylindrical filling support 20.
- the filler supports 20 are closed with a cover 22 which is frustoconical in the exemplary embodiment shown.
- a cover 22 which is frustoconical in the exemplary embodiment shown.
- air inlet openings 24 which remain open even when the cover 22 is closed, the end of the cylindrical extension 22 pointing in the direction of the cover 22 is provided with crenellations or the like.
- the air inlet openings 24 ensure that there is always ambient pressure in the storage container 10 and none Influencing the delivered amount of air treatment agents can occur due to negative pressure.
- a fine-mesh filter can be provided in the outlet opening 16, for example.
- the provision of a filter in the area of the outlet opening 16 has the advantage that it can be easily exchanged and cleaned via the filler opening 18 arranged opposite the outlet opening 16.
- the filter is designed in such a way that particles up to a size of more than approximately 0.1 mm, preferably more than 0.02 mm, are filtered out.
- a corresponding particle filter can also be provided in the inlet openings 24.
- the tube 30 is connected to a mixing container 32, the end 34 of the tube 30 projecting into the mixing container 32.
- the tube 30 is closed at its end 34 with a preferably interchangeable plate or disk 36.
- An outlet opening 38 in the form of a circular hole is preferably arranged in the center of the disk 36 as the metering device.
- the hole has a diameter of preferably 0.02-0.1 mm. This ensures that the small amounts of air treatment agent 12 described above reach the mixing container 32.
- a shutoff valve 40 with a handwheel 42 is provided in the pipe 30 in order to interrupt the supply of air treatment agent to the mixing container 32.
- the valve 40 is therefore used only to turn off the device.
- a corresponding valve could also be arranged directly behind the outlet opening 16 of the storage container 10.
- a fine-meshed sieve 44 is arranged in the tube 30, which is provided in addition to or instead of a fine-meshed sieve provided in the outlet opening 16.
- the fine mesh of the sieve 44 preferably corresponds to that of the sieve possibly present in the outlet opening 16.
- the screen 44 can be replaced after the valve 40 has been closed, so that the screen 44 can be cleaned in a simple manner.
- the air treatment agent 12 is fed into the mixing container 32 exclusively due to gravity.
- the maximum difference in height between the outlet opening 38 and a maximum filling height of the storage container 10 is between 5 and 15 cm, in particular between 5 and 10 cm. This ensures that the air treatment agent 12 has only a slightly higher pressure than the ambient pressure at the outlet opening 38. The supply of the air treatment agent 12 to the mixing container 32 is thus virtually depressurized.
- the maximum height difference between a maximum and a minimum filling level of air treatment agent 12 in the storage container 10 is preferably less than 6 cm, in particular less than 4 cm.
- the size of the container is selected so that it has a volume of approximately 300-400 ml.
- An evaporation device 46 is arranged within the mixing container 32.
- the evaporation device 46 forms the bottom of the mixing container 32, so that the entire bottom of the mixing container 32 is designed as an evaporation device 46.
- the evaporation device 46 has an evaporation shell 48 consisting of a highly thermally conductive material.
- the evaporation tray is preferably made of aluminum.
- a heating foil 50 is provided on the underside of the evaporation tray, preferably on the outside thereof. The heating foil 50 is connected to an energy source.
- the heating foil 50 is preferably fed with a 12 volt energy source and has a power consumption of 10-15 watts.
- the heating shell 48 is preferably heated to 40-70, in particular 50-60 ° C. by the heating foil.
- the air treatment agent emerging from the outlet opening 38 thus evaporates relatively slowly in the receiving shell 48 and rises in the direction of an outlet opening 52 of the mixing container 32.
- the receptacle 48 is preferably inclined in a descending manner starting from the outlet opening 38, so that the air treatment agent supplied to the receptacle 48 is distributed over the heated bottom of the receptacle 48 and evaporates evenly.
- Air inlet openings 54 are provided in the side wall of the preferably rotationally symmetrical mixing container 32.
- the air inlet openings 54 are preferably evenly distributed around the circumference in order to ensure a uniform supply of ambient air into the mixing container 32.
- the air supply through the air inlet openings 54 into the mixing container 32 is realized by a means for generating an air flow, such as a fan 56.
- the fan 56 is arranged opposite the evaporation device 46 at the outlet opening 52 of the mixing container 32. Air is drawn in by the fan through the air inlet openings 54 in the direction of the arrows 58 into the interior of the mixing container 32 and released in the direction of the arrows 60 into the space to be treated.
- the funnel-shaped configuration of the mixing container 32 creates a chimney effect within the mixing container 32.
- the air inlet openings 54 are in one Distance to the evaporation device 46, ie arranged above the receiving shell 48.
- the distance between the air inlet openings 54 provided closest to the evaporation device 46 is preferably 2 to 8 cm, in particular 4-6 cm.
- FIG. 3 corresponds in principle to the embodiment shown in FIGS. 1 and 2. Identical or similar components of the device are therefore designated with the same reference numerals.
- the main difference between the two preferred embodiments is that the space required for the second preferred embodiment (FIG. 3) is smaller. This is achieved in that the mixing container 32 projects through a storage container 62.
- the storage container 62 therefore has openings 68, 70 in a bottom 64 and an opposite top wall 66.
- the mixing container 32 is inserted through the openings 68, 70, so that the fan 56 is arranged above the storage container 10.
- This arrangement of the storage container 62 with respect to the mixing container 32 has the result that the outlet opening 16 of the mixing container 62 is not arranged in the center but on one side of the storage container.
- the filling opening 18, the neck 20 and the cover 22 are in turn essentially arranged opposite the outlet opening 16.
- the storage container 62 preferably has an annular side wall 72 corresponding to the storage container 10.
- the mixing container 32 is not funnel-shaped, but circular cylindrical. However, it is also possible to provide a funnel-shaped mixing container 32 in this embodiment.
- FIG. 4 shows a further preferred embodiment compared to the preferred embodiments of the invention described in FIGS. 1 to 3 with the essential difference that the evaporation device 46 has an evaporation surface 74 which is inclined with respect to the horizontal. Similar components in the embodiment of the invention described with reference to FIGS. 4 to 6 are identified by the same reference numerals. In particular with regard to quantities supplied to the evaporation device 46 and the size of the storage container 10, this embodiment preferably essentially corresponds to the embodiments described above.
- the air treatment agent 12 is pumped from a storage container through pipes 78, 80 to the evaporation device 46 by means of a pump 76.
- the air treatment agent emerging from a feed nozzle 82 emerges from a slot-shaped outlet opening 84 of the feed nozzle.
- the slot 84 extends essentially over the entire width of the evaporation surface 74, which is rectangular in the exemplary embodiment shown.
- the evaporation surface 74 can be a simple sheet made of preferably aluminum or copper, ie of a material with high thermal conductivity.
- the evaporation surface 74 is heated by the heating film 50.
- the air treatment agent flows from an upper region 76 over the inclined evaporation surface 74, a large part of the air treatment agent is evaporated due to the heat supplied by the heating film 50.
- the excess part of the air treatment agent is collected by a return device 88 and returned to the storage container 10 via a pipe 90.
- the return device 88 is preferably funnel-shaped and extends over the entire width of the evaporation surface 74.
- the feed nozzle 82 and the return device 88 are thus arranged opposite one another, the feed nozzle in the upper region 86 of the evaporation surface 74 and the return device 88 in a lower region 92 the evaporation surface 74 is arranged.
- the embodiment shown in FIGS. 4 to 6 also has a means for generating an air flow, such as a fan 56.
- the fan 56 is arranged below the evaporation device 46.
- the air sucked in through the air inlet openings 54 in a mixing container 94 is thus directed by the fan 56 in the direction of the arrows 96.
- the air flows into the lower side of the evaporator it is directed outwards along the underside and flows on the outer sides, i. H. laterally past the evaporation device 46, upwards in the direction of outlet openings 52 and flows in the direction of the arrows 98 into the space to be treated.
- the mixing container 94 also serves as a housing for the pump 76, the fan 56 and the evaporation device 46. Furthermore, the storage container 10 is arranged inside the container 94 serving as a housing.
- a filler neck 100 which can be closed with a lid 102, is provided for filling the storage container 10.
- FIG. 7 shows a cooling device 110 with an outer wall 112, to which a device 114 for air enrichment is attached.
- the device 114 is, for example, the one in FIGS. 1 to 6 described embodiments of the invention.
- a separate storage container 116 is preferably provided, which can be arranged, for example, on an upper side 118 of the refrigerator.
- the storage container 116 is a storage container whose volume is selected in such a way that air treatment agent preferably has to be refilled only at intervals of approximately 6 and preferably approximately 12 months.
- the air enriched with the air treatment agent and emitted by the device 114 passes in the direction of an arrow 120 through a channel 122 into an interior 124 of the refrigerator 110.
- the device for air enrichment 114 is arranged inside the interior 124 of the refrigerator 110.
- Device 114 is preferably one of the preferred embodiments of the device described above. The deployment of the
- Air containing air treatment agents takes place directly in the refrigerator interior 124 in the direction of an arrow 126.
- a storage container can be arranged within the refrigerator 110.
- a larger storage container 116 is preferably arranged on an upper side 118 of the refrigerator.
- the storage container 116 is connected to the device 114 via a connecting hose 128.
- the device 114 can additionally have its own storage container, which has a smaller volume than the storage container 116 and, for example, an intermediate chamber or the like is automatically filled by the larger storage container 116.
- the device 116 thus serves to refill a storage chamber arranged within the device 114.
- the device 114 is preferably surrounded by an insulating housing in order to prevent the refrigerator from heating up by the provision of the device 114 according to the invention inside the cooling space 124.
- a device for air enrichment is arranged on the outside of a housing 130 of a computer.
- a device corresponding to FIG. 4 is provided.
- FIGS. 1 and 3 it is also possible to use the embodiments shown in FIGS. 1 and 3 or other embodiments of the device according to the invention.
- a special embodiment of the embodiment shown in FIG. 9 is that air outlet slots 132 of the computer housing 130 are provided at the level of the air inlet openings 54.
- a fan 134 of the computer thus directly transports the air provided with air treatment agents.
- a fan 56 can thus be omitted in the device 114. This makes it possible to arrange the device 114 within the computer housing.
- the invention further relates to a method for disinfecting and / or de-smelling a cooling device, in particular for disinfecting a refrigerator, comprising the vaporization of an antimicrobial composition and / or an odor masking
- composition in the cooling device by means of one as defined above
- Computer is set up comprising the vaporization of an antimicrobial
- composition by means of a device as defined above, which in
- the aforementioned antimicrobial compositions and the odor-masking composition are preferably the compositions (X) and (Y) defined above.
- the antimicrobial composition - depending on the refrigerator volume - is evaporated in an amount of 0.0001 to 0.5 ml per hour.
- the antimicrobial composition can also contain the odor-masking compound defined above, as a result of which the unpleasant odor that may be present in the refrigerator can be reduced.
- the antimicrobial composition is introduced in such a way that a room air concentration of less than or equal to 100 ppb (parts per billion), preferably of approximately 10 ppb, is ensured, which is ensured by introducing 0.01 ml / m 3 of space per hour ,
- HiQ®-Caire Consisting of 1% by weight of tannin, 0.5% by weight of essential oil and the rest of propylene glycol was used as the antimicrobial composition.
- Example 1 PC test. The germs in the PC and in the ambient air are removed by using HiQ®-Caire by introducing the device according to the invention inside the PC tower in the outflow area of the fan (see FIG. 9) with an application rate of 0.01 ml / m 3 / h (HiQ®Caire concentration «10 ppb) reduced to zero. The test results are shown in Table 1. Table 1
- Example 2 Refrigerator test. 0.5 ml per hour of HiQ-Caire was introduced into the refrigerator from the outside using an evaporation device according to the invention (see FIG. 7). This significantly reduced the germs on the food in the refrigerator. The test results are shown in Table 2.
Landscapes
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Packaging Of Annular Or Rod-Shaped Articles, Wearing Apparel, Cassettes, Or The Like (AREA)
- Respiratory Apparatuses And Protective Means (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003504021A JP2004532087A (ja) | 2001-06-13 | 2002-06-05 | 空気処理剤で空気を高質化するための、特に空気の殺菌、空気の賦香および/または匂いのマスキング用の装置 |
EP02747345A EP1395781B1 (de) | 2001-06-13 | 2002-06-05 | Vorrichtung zur anreicherung von luft mit einem luftbehandlungsmittel insbesondere zur luftentkeimung, luftbeduftung und/oder geruchsmaskierung |
CA002450745A CA2450745A1 (en) | 2001-06-13 | 2002-06-05 | Device for enriching air with an air treatment agent, especially for the disinfection of air, perfuming of air and/or for odor masking |
DE50207800T DE50207800D1 (de) | 2001-06-13 | 2002-06-05 | Vorrichtung zur anreicherung von luft mit einem luftbehandlungsmittel insbesondere zur luftentkeimung, luftbeduftung und/oder geruchsmaskierung |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10128563.9 | 2001-06-13 | ||
DE10128563A DE10128563A1 (de) | 2001-06-13 | 2001-06-13 | Vorrichtung zur Anreicherung von Luft mit einem Luftbehandlungsmittel insbesondere zur Luftentkeimung und/oder Luftbeduftung |
DE10141734A DE10141734A1 (de) | 2001-08-25 | 2001-08-25 | Vorrichtung zur Anreicherung von Luft mit einem Luftbehandlungsmittel insbesondere zur Luftentkeimung, Luftbeduftung und/oder Geruchsmaskierung |
DE10141734.9 | 2001-08-25 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002101299A1 true WO2002101299A1 (de) | 2002-12-19 |
Family
ID=26009514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2002/006157 WO2002101299A1 (de) | 2001-06-13 | 2002-06-05 | Vorrichtung zur anreicherung von luft mit einem luftbehandlungsmittel insbesondere zur luftentkeimung, luftbeduftung und/oder geruchsmaskierung |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP1395781B1 (de) |
JP (1) | JP2004532087A (de) |
AT (1) | ATE335967T1 (de) |
CA (1) | CA2450745A1 (de) |
DE (1) | DE50207800D1 (de) |
WO (1) | WO2002101299A1 (de) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112654372A (zh) * | 2018-09-09 | 2021-04-13 | 克莱米克斯公司 | 消毒方法和消毒装置 |
WO2022136741A1 (en) * | 2020-12-23 | 2022-06-30 | Nt Inno Oy | Method of dispensing an active substance and dispenser |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996029895A1 (de) | 1995-03-31 | 1996-10-03 | Schuer Joerg Peter | Verfahren zur haltbarkeitsverbesserung und/oder stabilisierung von mikrobiell verderblichen produkten |
DE19931185A1 (de) | 1999-07-07 | 2001-01-18 | Joerg Peter Schuer | Verfahren zur Entkeimung von Luft |
DE19940605A1 (de) | 1999-08-27 | 2001-03-01 | Joerg Peter Schuer | Imprägnierungsverfahren |
CN106290179B (zh) * | 2016-07-22 | 2019-04-05 | 新昌县勤勉贸易有限公司 | 液体固化分析检验装置 |
FI128865B (fi) * | 2018-09-09 | 2021-02-15 | Cleamix Oy | Desinfiointimenetelmä ja desinfiointilaite |
CN109821036B (zh) * | 2019-04-01 | 2021-04-16 | 曲阜师范大学 | 一种水蒸法呼吸面罩高温消毒装置 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2419477A (en) * | 1944-02-02 | 1947-04-22 | Thomas W Binder | Air conditioning |
JPS53105051A (en) * | 1977-02-25 | 1978-09-12 | Toshiba Electric Appliance Co Ltd | Humidifying apparatus |
EP0713060A1 (de) * | 1993-08-12 | 1996-05-22 | Komatsu Ltd. | Vorrichtung zur wasserversorgung für befeuchtung und damit versehene klimaanlage |
US5664730A (en) * | 1996-04-29 | 1997-09-09 | Technov International Inc. | Humidifier device |
WO2001003747A1 (de) | 1999-07-07 | 2001-01-18 | Schuer Joerg Peter | Verfahren und vorrichtung zur anreicherung von luft mit luftbehandlungsmittel |
DE10100595A1 (de) | 2001-01-09 | 2002-07-18 | Joerg Peter Schuer | Verfahren zur untoxischen Geruchsneutralisierung von Luft |
-
2002
- 2002-06-05 EP EP02747345A patent/EP1395781B1/de not_active Expired - Lifetime
- 2002-06-05 JP JP2003504021A patent/JP2004532087A/ja not_active Withdrawn
- 2002-06-05 AT AT02747345T patent/ATE335967T1/de not_active IP Right Cessation
- 2002-06-05 WO PCT/EP2002/006157 patent/WO2002101299A1/de active IP Right Grant
- 2002-06-05 CA CA002450745A patent/CA2450745A1/en not_active Abandoned
- 2002-06-05 DE DE50207800T patent/DE50207800D1/de not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2419477A (en) * | 1944-02-02 | 1947-04-22 | Thomas W Binder | Air conditioning |
JPS53105051A (en) * | 1977-02-25 | 1978-09-12 | Toshiba Electric Appliance Co Ltd | Humidifying apparatus |
EP0713060A1 (de) * | 1993-08-12 | 1996-05-22 | Komatsu Ltd. | Vorrichtung zur wasserversorgung für befeuchtung und damit versehene klimaanlage |
US5664730A (en) * | 1996-04-29 | 1997-09-09 | Technov International Inc. | Humidifier device |
WO2001003747A1 (de) | 1999-07-07 | 2001-01-18 | Schuer Joerg Peter | Verfahren und vorrichtung zur anreicherung von luft mit luftbehandlungsmittel |
DE10100595A1 (de) | 2001-01-09 | 2002-07-18 | Joerg Peter Schuer | Verfahren zur untoxischen Geruchsneutralisierung von Luft |
Non-Patent Citations (1)
Title |
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PATENT ABSTRACTS OF JAPAN vol. 002, no. 135 (M - 039) 10 November 1978 (1978-11-10) * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112654372A (zh) * | 2018-09-09 | 2021-04-13 | 克莱米克斯公司 | 消毒方法和消毒装置 |
CN112654372B (zh) * | 2018-09-09 | 2023-07-18 | 克莱米克斯公司 | 消毒方法和消毒装置 |
WO2022136741A1 (en) * | 2020-12-23 | 2022-06-30 | Nt Inno Oy | Method of dispensing an active substance and dispenser |
Also Published As
Publication number | Publication date |
---|---|
DE50207800D1 (de) | 2006-09-21 |
EP1395781A1 (de) | 2004-03-10 |
CA2450745A1 (en) | 2002-12-19 |
EP1395781B1 (de) | 2006-08-09 |
ATE335967T1 (de) | 2006-09-15 |
JP2004532087A (ja) | 2004-10-21 |
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