WO2002081811A1 - Improved polymer-grafted cotton fibers and products - Google Patents

Improved polymer-grafted cotton fibers and products Download PDF

Info

Publication number
WO2002081811A1
WO2002081811A1 PCT/US2002/009438 US0209438W WO02081811A1 WO 2002081811 A1 WO2002081811 A1 WO 2002081811A1 US 0209438 W US0209438 W US 0209438W WO 02081811 A1 WO02081811 A1 WO 02081811A1
Authority
WO
WIPO (PCT)
Prior art keywords
prepolymer
composition
emulsion
polymerizable
fiber
Prior art date
Application number
PCT/US2002/009438
Other languages
English (en)
French (fr)
Inventor
Mohan L. Sanduja
Carl Horowitz
Izabella Zilbert
Paul Thottathil
Gerald L. Williamson
Original Assignee
Healthtex Apparel Corp.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/824,732 external-priority patent/US6645255B2/en
Priority claimed from US09/825,287 external-priority patent/US6638319B2/en
Priority claimed from US09/825,283 external-priority patent/US6645256B2/en
Application filed by Healthtex Apparel Corp. filed Critical Healthtex Apparel Corp.
Priority to EP02723634.8A priority Critical patent/EP1377709B1/en
Priority to CA2442836A priority patent/CA2442836C/en
Priority to MXPA03009005A priority patent/MXPA03009005A/es
Priority to JP2002579563A priority patent/JP4647188B2/ja
Publication of WO2002081811A1 publication Critical patent/WO2002081811A1/en
Priority to HK05100085A priority patent/HK1068155A1/xx

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
    • D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
    • D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02—After-treatment
    • D06P5/04—After-treatment with organic compounds
    • D06P5/08—After-treatment with organic compounds macromolecular
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • printed cotton and "printed cotton/polyester” means fibers that have been exposed to a pigment and an adherent that helps bind the pigment to the fibers.
  • adherent also called an adhesive gum, is carboxylated butadiene acrylonitrile.
  • Nonfunctional and functional siloxanes as characterized above may be monomeric, (low molecular weight), or oligomeric or polymeric (high molecular weight) and either linear, branched or cyclic.
  • polymeric siloxane compounds include nonfunctional and organofunctional polysiloxanes including dimethylpolysiloxanes, methylhydrogen polysiloxanes, methylalkyl polysiloxanes methylaryl polysiloxanes, methylfluoroalkyl polysiloxanes, and organofunctional methylpolysiloxanes such as aminoalkylmethyl polysiloxane, cyanoalkylmethyl polysiloxane, haloalkylmethyl polysiloxane, and vinylmethyl polysiloxane.
  • monomeric or oligomeric siloxanes include MeOSi(Me) 2 -OMe, Me 3 SiOMe, Me 3 Si(OMe) 2 ,
  • cyclic siloxane oligomers include octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane.
  • the anti-crocking nonionic dispersant is CROCKFAST 2 (TM) available from Ami Technology, Oxford, NY.
  • the graft polymer chains are formed from monomers and prepolymers containing appropriate polymerizable functionality, e.g., groups such as hydroxyl, carboxyl, epoxy, amide, amine, a hydride and so forth.
  • appropriate polymerizable functionality e.g., groups such as hydroxyl, carboxyl, epoxy, amide, amine, a hydride and so forth.
  • the quantity of triacrylates is kept low to reduce unwanted crosslinking.
  • the polymerizable material in the treatment composition will form grafts onto the substrate fiber.
  • at least about 20%, more preferably at least about 50%, of the polymerizable material is grafted to the substrate fibers.
  • Evidence of grafting is found when the fibers do not lose more than 50% of the treatment after at least 15 washes with normal detergent.
  • the treatment compositions is a stable single-contact formulation, wherein the activators and catalysts co-exist in the stable formulation with the prepolymers.
  • the formulation can be stored and used at normal ambient temperature without congealing or polymerizing.
  • the stable concentrated composition in one embodiment includes: between about 16% and about 30% of acrylic prepolymer; between about 1%> and about 4% of an elastomeric latex prepolymer; between about 38% and about 60% of an organopolysiloxane emulsion; between about 1% and about 4% of a urethane prepolymer emulsion; between about 0.02% and about 0.2% of a catalyst; between about 0.02% and about 0.2% of a graft initiator.
  • the concentrate may also contain between about 0.02% and about 0.2% of a polyethylene glycol diacrylate and between about 0.02% and about 0.2%> of a surfactant monomer.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paper (AREA)
PCT/US2002/009438 2001-04-04 2002-03-27 Improved polymer-grafted cotton fibers and products WO2002081811A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP02723634.8A EP1377709B1 (en) 2001-04-04 2002-03-27 Improved polymer-grafted cotton fibers and products
CA2442836A CA2442836C (en) 2001-04-04 2002-03-27 Improved polymer-grafted cotton fibers and products
MXPA03009005A MXPA03009005A (es) 2001-04-04 2002-03-27 Fibras y de algodon mejoradas injertadas con polimeros y productos elaborados con ellas.
JP2002579563A JP4647188B2 (ja) 2001-04-04 2002-03-27 改善されたポリマーグラフト綿繊維および製品
HK05100085A HK1068155A1 (en) 2001-04-04 2005-01-06 Improved polymer-grafted cotton fibers and products

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US09/824,732 US6645255B2 (en) 2001-04-04 2001-04-04 Polymer-grafted stretchable cotton
US09/824,732 2001-04-04
US09/825,287 US6638319B2 (en) 2001-04-04 2001-04-04 Polymer for printed cotton
US09/825,287 2001-04-04
US09/825,283 2001-04-04
US09/825,283 US6645256B2 (en) 2001-04-04 2001-04-04 Polymer grafted cotton

Publications (1)

Publication Number Publication Date
WO2002081811A1 true WO2002081811A1 (en) 2002-10-17

Family

ID=27420168

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/009438 WO2002081811A1 (en) 2001-04-04 2002-03-27 Improved polymer-grafted cotton fibers and products

Country Status (11)

Country Link
EP (1) EP1377709B1 (ko)
JP (1) JP4647188B2 (ko)
CN (1) CN1266330C (ko)
CA (1) CA2442836C (ko)
CR (1) CR7133A (ko)
DO (1) DOP2002000374A (ko)
EG (1) EG23282A (ko)
HK (1) HK1068155A1 (ko)
MX (1) MXPA03009005A (ko)
TW (1) TWI299068B (ko)
WO (1) WO2002081811A1 (ko)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021170A (zh) * 2017-06-09 2018-12-18 天津科技大学 一种抗盐性纳米/微米纤丝纤维素凝胶的制备方法
CN112813685A (zh) * 2020-06-30 2021-05-18 应急管理部四川消防研究所 一种耐久性阻燃后整理织物及其制备方法
CN114889239A (zh) * 2020-11-16 2022-08-12 刘雷 一种吸湿排汗纤维面料的制备方法
CN115947923A (zh) * 2023-02-17 2023-04-11 广州山木新材料科技有限公司 一种水性聚氨酯树脂及包含其的数码烫画墨水
US11976414B2 (en) 2021-06-15 2024-05-07 Dow Silicones Corporation Polysiloxane-based water repellants for textiles

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300408C (zh) * 2005-01-17 2007-02-14 西南农业大学 天然绿茧丝微波接枝固色方法
CN101070676B (zh) * 2007-05-18 2013-03-20 广东德美精细化工股份有限公司 一种纤维材料改质的方法及其染色工艺
CN104404647B (zh) * 2014-10-15 2016-08-17 浙江恒逸高新材料有限公司 一种纤维素纳米晶改性的亲水聚酯纤维及其制备方法
US20170022314A1 (en) * 2015-07-24 2017-01-26 Weyerhaeuser Nr Company Grafted crosslinked cellulose
CN109023992B (zh) * 2018-08-24 2020-08-25 江门市卓益纺织布业有限公司 一种提高纤维素纤维靛蓝染色湿摩擦色牢度的方法
CN113089321A (zh) * 2021-04-07 2021-07-09 罗莱生活科技股份有限公司 乙烯基单体接枝改性的抗菌纤维及其制备方法和在抗菌袜中的用途

Citations (4)

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Publication number Priority date Publication date Assignee Title
US4052158A (en) * 1973-11-12 1977-10-04 Stauffer Chemical Company Textile finishing process
EP0492649A2 (de) * 1990-12-27 1992-07-01 Amann & Söhne GmbH & Co. Verfahren zur Veränderung der Eigenschaften eines textilen Substrates
US5741548A (en) * 1996-09-24 1998-04-21 Sanduja; Mohan L. Coating composition for reemay and satin acetate fabrics for laser printability
US6165919A (en) 1997-01-14 2000-12-26 University Of Georgia Research Foundation, Inc. Crosslinking agents of cellulosic fabrics

Family Cites Families (6)

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US2952892A (en) * 1956-07-19 1960-09-20 Bancroft & Sons Co J Cellulosic fabric finishing
JPS491279B1 (ko) * 1969-09-13 1974-01-12
JPS5653278A (en) * 1979-09-28 1981-05-12 Wakayama Prefecture Wrinkleproof * shrinkproof and fireproof process of cellulose fiber
JPH0299668A (ja) * 1988-10-04 1990-04-11 Unitika Ltd 繊維構造物の深色加工法
JP3233224B2 (ja) * 1992-01-30 2001-11-26 東洋紡績株式会社 セルロース繊維含有繊維構造物及びその製造方法
JP2002146680A (ja) * 2000-11-09 2002-05-22 Dai Ichi Kogyo Seiyaku Co Ltd セルロース系繊維布帛の反撥風合い加工処理剤及び加工方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4052158A (en) * 1973-11-12 1977-10-04 Stauffer Chemical Company Textile finishing process
EP0492649A2 (de) * 1990-12-27 1992-07-01 Amann & Söhne GmbH & Co. Verfahren zur Veränderung der Eigenschaften eines textilen Substrates
US5741548A (en) * 1996-09-24 1998-04-21 Sanduja; Mohan L. Coating composition for reemay and satin acetate fabrics for laser printability
US6165919A (en) 1997-01-14 2000-12-26 University Of Georgia Research Foundation, Inc. Crosslinking agents of cellulosic fabrics

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109021170A (zh) * 2017-06-09 2018-12-18 天津科技大学 一种抗盐性纳米/微米纤丝纤维素凝胶的制备方法
CN112813685A (zh) * 2020-06-30 2021-05-18 应急管理部四川消防研究所 一种耐久性阻燃后整理织物及其制备方法
CN114889239A (zh) * 2020-11-16 2022-08-12 刘雷 一种吸湿排汗纤维面料的制备方法
CN114889239B (zh) * 2020-11-16 2024-03-01 湖南永霏特种防护用品有限公司 一种吸湿排汗纤维面料的制备方法
US11976414B2 (en) 2021-06-15 2024-05-07 Dow Silicones Corporation Polysiloxane-based water repellants for textiles
CN115947923A (zh) * 2023-02-17 2023-04-11 广州山木新材料科技有限公司 一种水性聚氨酯树脂及包含其的数码烫画墨水

Also Published As

Publication number Publication date
MXPA03009005A (es) 2004-02-12
EG23282A (en) 2004-10-31
JP2005503492A (ja) 2005-02-03
TWI299068B (ko) 2008-07-21
JP4647188B2 (ja) 2011-03-09
CN1513072A (zh) 2004-07-14
CA2442836A1 (en) 2002-10-17
CA2442836C (en) 2012-01-03
EP1377709A1 (en) 2004-01-07
EP1377709B1 (en) 2013-09-11
CR7133A (es) 2004-04-15
DOP2002000374A (es) 2002-12-15
HK1068155A1 (en) 2005-04-22
CN1266330C (zh) 2006-07-26

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