WO2002081188A1 - Conduite pour liquides a plusieurs couches destinee au domaine sanitaire et de chauffage - Google Patents

Conduite pour liquides a plusieurs couches destinee au domaine sanitaire et de chauffage Download PDF

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Publication number
WO2002081188A1
WO2002081188A1 PCT/EP2001/012784 EP0112784W WO02081188A1 WO 2002081188 A1 WO2002081188 A1 WO 2002081188A1 EP 0112784 W EP0112784 W EP 0112784W WO 02081188 A1 WO02081188 A1 WO 02081188A1
Authority
WO
WIPO (PCT)
Prior art keywords
fluid line
pvdf
polyethylene
inner layer
sanitary
Prior art date
Application number
PCT/EP2001/012784
Other languages
German (de)
English (en)
Inventor
Peter Weber
Original Assignee
Geberit Technik Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geberit Technik Ag filed Critical Geberit Technik Ag
Publication of WO2002081188A1 publication Critical patent/WO2002081188A1/fr

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/18Layered products comprising a layer of metal comprising iron or steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L9/00Rigid pipes
    • F16L9/14Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
    • F16L9/147Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups comprising only layers of metal and plastics with or without reinforcement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/033 layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/308Heat stability
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00Polyvinylhalogenides
    • B32B2327/12Polyvinylhalogenides containing fluorine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2597/00Tubular articles, e.g. hoses, pipes

Definitions

  • the present invention relates to a multilayer fluid line and a fluid line system for the sanitary and heating sector.
  • DE 42 38 696 a two-layer fluid line for liquid fuels, the outer layer comprising a thermoplastic material and preferably additionally containing a radiation-crosslinkable plastic.
  • the thermoplastic material of the outer layer can be an elastomer, in particular a polyamide elastomer, a polyester elastomer or a polyolefin elastomer.
  • the inner layer preferably contains ETFE or PVDF.
  • DE 41 32 984 deals with plastic tubes for the guidance of gaseous media and fluids, such as drinking water or waste water.
  • the pipes proposed by DE 41 32 984 consist of a core pipe made of polyethylene, on which a jacket made of polyvinylidene fluoride is arranged.
  • a protective layer made of polyethylene is used to protect the thin jacket made of PVDF.
  • the core tube can have additional protection in the form of an aluminum jacket.
  • DE 197 07 827 discloses a composite pipe which contains an inner layer made of cross-linked polyethylene, an intermediate layer made of aluminum and an outer layer made of polyethylene.
  • PE polyethylene
  • ETFE ethylene-tetrafluoroethylene copolymer
  • PVDF polyvinylidene fluoride
  • PVC polyvinyl chloride
  • PEX cross-linked polyethylene
  • the fluid line according to the invention comprises at least an inner layer, an intermediate layer and an outer layer, the inner layer consisting of a fluoropolymer or a subsequently fluorinated polymer, the intermediate layer consisting of a metal and the outer layer consisting of a thermoplastic.
  • Such a fluid line has a very favorable combination of properties: the inner layer made of a fluoropolymer or a subsequently fluorinated polymer has a very high chemical resistance, the intermediate layer formed from a metal gives shape stability and represents an effective diffusion barrier and the outer layer from one Thermoplastic acts as a protective layer against damage and at the same time prevents the ingress of contaminants.
  • the inner layer of the fluid line consists of a fluoropolymer, namely of a PVDF material.
  • the plastic PVDF has very good properties with regard to the parameters of pressure resistance, pressure shock resistance, long-term stability, temperature resistance and temperature shock resistance and can also be shaped well.
  • PVDF fulfills all hygienic requirements that are set out in the drinking water ordinance. Fluid lines with an inner layer made of PVDF can therefore be used advantageously for hot and cold water supply. Even very small thicknesses of the PVDF layer cause an absolute diffusion barrier for gases and fluids. The smallest possible thickness of the PVDF layer seems desirable in order to enable the least possible consumption of this cost-intensive material and to keep the weight of the fluid line as low as possible.
  • the inner layer consists of a subsequently fluorinated polymer.
  • a large number of processes for fluorinating polymer materials are known from the prior art, all of which can be used in the context of the present invention.
  • a method for producing plastic profiles with a fluorinated layer according to EP-A-0 267 441 may be mentioned here by way of example. With the aid of this method, subsequent fluorination of the inner layer of the fluid line according to the invention can be carried out without any problems.
  • subsequently fluorinated polymers also excellently fulfill the required properties.
  • subsequently fluorinated polymers have good pressure resistance, pressure shock resistance, long-term stability, temperature resistance and temperature shock resistance and can also be shaped well.
  • fluorinated thermoplastic polymers e.g. Polyethylene, polyvinyl chloride, polyamides, PEX, PVDF, polystyrene, polymethacrylic acid esters, polytetrafluoroethylene, polyvinyl acetate, cellulose acetate or linear polyurethanes.
  • the metallic intermediate layer consists of aluminum or stainless steel.
  • the material aluminum has a high flexural strength, is dimensionally stable, compressible and also represents an effective diffusion barrier. Aluminum therefore fulfills the properties advantageous for fluid lines particularly well.
  • thermoplastic material of the outer layer can e.g. are polyethylene, polyvinyl chloride, polyamides, PEX, PVDF, polystyrene, polymethacrylic acid esters, polytetrafluoroethylene, polyvinyl acetate, cellulose acetate or linear polyurethanes.
  • the outer layer of the fluid line consists of polyethylene or PEX.
  • Polyethylene has a number of advantages such as low weight, very good resistance to aggressive soils and good weldability using all currently known methods. When laying the fluid lines in floors, it is also advantageous that polyethylene is insensitive to frost and resistant to microorganisms and has a high resistance to stress cracking. Polyethylene is also an inexpensive material.
  • the present invention further relates to a fluid line system which comprises at least one of the fluid lines described above and at least one connecting part, wherein at least the inside of the connecting part consists of PVDF.
  • the fluid line system consists exclusively of the fluid lines described above and of connecting parts, the inside of which is made of PVDF.
  • This is a line system for e.g. Drinking water in which all parts in contact with the drinking water are made of PVDF plastic.
  • the fluid line system consists of finally from the fluid lines described above and from connecting parts which are made entirely of PVDF.
  • connecting parts which are made entirely of PVDF.

Abstract

La présente invention concerne une conduite pour liquides destinée au domaine sanitaire et de chauffage. Cette conduite comprend une couche interne, une couche intermédiaire et une couche externe. La couche interne est constituée d'un fluoropolymère ou d'un polymère ultérieurement fluoré, la couche intermédiaire est constituée d'un métal et la couche externe est constituée d'une matière thermoplastique.
PCT/EP2001/012784 2001-04-03 2001-11-05 Conduite pour liquides a plusieurs couches destinee au domaine sanitaire et de chauffage WO2002081188A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10116731 2001-04-03
DE10116731.8 2001-04-03

Publications (1)

Publication Number Publication Date
WO2002081188A1 true WO2002081188A1 (fr) 2002-10-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/012784 WO2002081188A1 (fr) 2001-04-03 2001-11-05 Conduite pour liquides a plusieurs couches destinee au domaine sanitaire et de chauffage

Country Status (1)

Country Link
WO (1) WO2002081188A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009058595A1 (fr) * 2007-11-02 2009-05-07 Illinois Tool Works Inc. Gainage à tôle résistant à la corrosion
WO2009126421A1 (fr) * 2008-04-07 2009-10-15 Illinois Tool Works Inc. Gainage métallique de feuille résistant à la corrosion
DE102008038039A1 (de) * 2008-08-16 2010-03-04 Henco Industries Nv Mehrschicht-Verbundrohr mit einer Polyvinylidenfluorid-Innenschicht

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0111169A2 (fr) * 1982-11-15 1984-06-20 Adolf Rundel Tube multicouche
US4999903A (en) * 1984-03-16 1991-03-19 Pabreco S.A. Process of manufacturing composite tube by rolling and welding without elongating the same
NL9002601A (nl) * 1990-11-28 1992-06-16 Nkf Kabel Bv Fluidum-doorstromingselement.
JPH04229246A (ja) * 1990-10-08 1992-08-18 Nippon Carbide Ind Co Inc 新規な含フッ素樹脂フィルム積層金属板
DE9218141U1 (de) * 1992-06-06 1993-11-04 Rasmussen Gmbh Mehrschichtrohr
DE19707827A1 (de) * 1997-02-25 1998-08-27 Geberit Technik Ag Pressverbindung
WO1999061833A1 (fr) * 1998-05-22 1999-12-02 The B.F. Goodrich Company Tuyau en materiau composite multicouche, son utilisation dans un circuit de conduits et son procede de fabrication
DE20018188U1 (de) * 2000-10-25 2001-01-11 Unicor Rohrsysteme Gmbh Mehrschichtverbundrohr
DE20014466U1 (de) * 1999-11-03 2001-03-22 Hewing Gmbh Kunststoff-Metall-Verbundrohr

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0111169A2 (fr) * 1982-11-15 1984-06-20 Adolf Rundel Tube multicouche
US4999903A (en) * 1984-03-16 1991-03-19 Pabreco S.A. Process of manufacturing composite tube by rolling and welding without elongating the same
JPH04229246A (ja) * 1990-10-08 1992-08-18 Nippon Carbide Ind Co Inc 新規な含フッ素樹脂フィルム積層金属板
NL9002601A (nl) * 1990-11-28 1992-06-16 Nkf Kabel Bv Fluidum-doorstromingselement.
DE9218141U1 (de) * 1992-06-06 1993-11-04 Rasmussen Gmbh Mehrschichtrohr
DE19707827A1 (de) * 1997-02-25 1998-08-27 Geberit Technik Ag Pressverbindung
WO1999061833A1 (fr) * 1998-05-22 1999-12-02 The B.F. Goodrich Company Tuyau en materiau composite multicouche, son utilisation dans un circuit de conduits et son procede de fabrication
DE20014466U1 (de) * 1999-11-03 2001-03-22 Hewing Gmbh Kunststoff-Metall-Verbundrohr
DE20018188U1 (de) * 2000-10-25 2001-01-11 Unicor Rohrsysteme Gmbh Mehrschichtverbundrohr

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199239, Derwent World Patents Index; Class A14, AN 1992-321205, XP002200908 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009058595A1 (fr) * 2007-11-02 2009-05-07 Illinois Tool Works Inc. Gainage à tôle résistant à la corrosion
WO2009126421A1 (fr) * 2008-04-07 2009-10-15 Illinois Tool Works Inc. Gainage métallique de feuille résistant à la corrosion
US10208885B2 (en) 2008-04-07 2019-02-19 Illinois Tool Works Inc. Corrosion resistant sheet metal jacketing
DE102008038039A1 (de) * 2008-08-16 2010-03-04 Henco Industries Nv Mehrschicht-Verbundrohr mit einer Polyvinylidenfluorid-Innenschicht
DE102008038039B4 (de) * 2008-08-16 2011-02-17 Henco Industries Nv Mehrschicht-Verbundrohr mit einer Polyvinylidenfluorid-Innenschicht

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