WO2002064668A1 - Superfinition antimicrobienne et procede de fabrication - Google Patents

Superfinition antimicrobienne et procede de fabrication Download PDF

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Publication number
WO2002064668A1
WO2002064668A1 PCT/US2002/003485 US0203485W WO02064668A1 WO 2002064668 A1 WO2002064668 A1 WO 2002064668A1 US 0203485 W US0203485 W US 0203485W WO 02064668 A1 WO02064668 A1 WO 02064668A1
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Prior art keywords
composition
textile
antimicrobial
polyurethane
weight
Prior art date
Application number
PCT/US2002/003485
Other languages
English (en)
Inventor
Stephen A. Payne
Original Assignee
Microban Products Company
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Filing date
Publication date
Application filed by Microban Products Company filed Critical Microban Products Company
Priority to US10/467,356 priority Critical patent/US20040077747A1/en
Publication of WO2002064668A1 publication Critical patent/WO2002064668A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16—Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/015—Biocides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D06M13/156—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring containing halogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D06M15/572—Reaction products of isocyanates with polyesters or polyesteramides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes

Definitions

  • the present invention concerns a durable textile coating having antimicrobial properties such that the colorfastness, hand, and absorbency of the textile is not significantly changed from a textile having no such coating thereon.
  • the coating when applied to cotton or cotton blend towels, for example, drastically reduce or eliminate mold, mildew, fungus and bacteria on the cotton towels.
  • the microemulsion coating comprises polyurethane, a plasticizer, and an antimicrobial agent.
  • a antimicrobial effective composition effective to at least 50 home launderings which is stable (does not settle quickly) has good colorfastness, good hand, and good absorbency when compared with a control having no antimicrobial composition.
  • the present comprises a coating composition which includes three materials, namely: 1) a polyurethane (or copolyurethane), 2) a plasticizer, and 3) an antimicrobial agent.
  • This composition is generally created and then 3 to 7 parts are then mixed with water for a total of 100 parts, and coated on a textile article. Then textile article is cotton or cotton blends such as polycotton.
  • the polyurethane or copolyurethane be self-crosslinking and is preferably based on a copolymer of ethylene oxide and propylene oxide, reacted with a diisocyanate.
  • Suitable plasticizers are those that are compatible with polyurethane and preferably comprise triacetin.
  • Suitable antimicrobial agents are those that are effective after 50 laundries according to AATCC Test 147-1993, and preferably is triclosan.
  • a method of making the antimicrobial composition, coating it on a textile article, and drying the article is also disclosed.
  • the present application comprises a composition coated on a textile comprising polyurethane, plasticizer, and an antimicrobial agent.
  • the present invention also concerns a method of producing a coated textile article comprising producing a textile article, coating said article, and drying said article wherein the dried coating comprises polyurethane resin, plasticizer, and an antimicrobial agent.
  • the present invention additionally comprises an aqueous coated composition comprising from about 3 to about 7 parts of antimicrobial composition and from 93 to 97 parts water such that the total aqueous composition comprises 100 parts, wherein said anti-microbial composition comprises polyurethane, plasticizer, and an antimicrobial agent.
  • the present invention employs a self-crosslinking polyurethane or polyurethane copolymer that does not crosslink or otherwise react with the natural or synthetic fibers (i.e. cotton or polycotton blends) of the textile. Because the polyurethane is self- crosslinking, preferably no catalyst is needed nor desired.
  • the polyurethane is durable to the typical industry standard of fifty home launderings, it reduces pilling of the textile (the pulling apart and balling of individual fiber filaments), and it improves abrasion resistance.
  • the plasticizer is generally a liquid having a low vapor pressure at room temperature and is used to: 1) modify flow properties of synthetic resins, 2) reduce evaporation rate, and 3) input flexibility and toughness to the polyurethane or polyurethane copolymer.
  • the antimicrobial agent is also compatible with the polyurethane or polyurethane copolymer. Therefore no separation of the components occurs.
  • a particularly preferred self-crosslinking polyurethane resin is sold by Bayer Co. under the trademark BAYPRETTM. Under the BAYPRET products, BAYPRET USV is particularly preferred. This product appears to be polyurethane made from a block ethylene oxide/polypropylene oxide copolymer reacted with a diisocyanate such as hexamethylene diisocyanate with acetic acid salt and an antioxidant.
  • suitable polyurethane resins can comprise a one or two component polyurethane resin coatings sold under the trademark IMPRANIL or IMPRAPERM which are solvent free and permeable to water vapor. These products are both aliphatic and aromatic urethane resins and are also sold by Bayer Co..
  • Other suitable polyurethanes are sold by Merquinst of Spain which has a full line of thermoplastic polyurethanes.
  • plasticizer compatible with polyurethane or polyurethane copolymer, and compatible with the antimicrobial agent are suitable for the present invention.
  • a preferred plasticizer is triacetin or glycerol triacetate, also known as 1 , 2, 3 -propanetriol triacetate. It is commercially available, for example, under the trade name Triacetin by Eastman Chemical Company.
  • Other suitable plasticizers are propylene glycol, triacetate. It is commercially available, for example, under the trade name Triacetin by Eastman Chemical Company.
  • suitable plasticizers are propylene glycol, propylene glycol benzoate, DINP - Diisononyl Phthalate and DIDP - Diisodecyl Phthalate.
  • Suitable antimicrobial agents suitable with the present invention may be 2,4,4 trichloro-2 -hydroxydiphenyl ether (also known as triclosan); 2-phenylphenol; diiodomethyl-4-tolylsulfone; zinc-2-mercaptopyridine-N-oxide; and N-alkyl-N, N- dimethyl-N-benzylammonium chloride. Of these antimicrobial agents, triclosan is preferred.
  • the polyurethane or copolyurethane, plasticizer and antimicrobial agent When blended together, it tends to have a light blue or bluish-gray color.
  • This mixture (the antimicrobial composition) is then blended with water. About 93 -97 parts of water are thoroughly blended with about 3-7 parts of the light blue or blue-gray color mixture, and then the aqueous blend is applied to the textile article, and dried. Drying crosslinks the coating with itself, but the coating does not interact with the textile article.
  • the light blue or blue-gray mixture comprises from about 90- 95% by wt. polyurethane or polyurethane copolymer resin (Baypret USV, for example); from about 1-5% by wt. plasticizer; and from 1-5% by wt. antimicrobial agent, with the total being 100%.
  • the plasticizer and antimicrobial agent are typically blended together in a 50-50 wt. percent blend and 5-10% by wt. is added to the polyurethane or copolyurethane resin (totaling 100%) by weight) with the mixer running at a medium speed during the addition.
  • Most preferably, 94 parts of the resin is blended with 6 parts of the 50-50 blend (plasticizer and antimicrobial agent).
  • the light blue or blue-gray mixture (3-7 parts) is mixed with water to 100 parts total, producing the coating formulation.
  • the aqueous antimicrobial resin finish is permitted to settle, to allow the bubbles of air to separate from the coating formulation.
  • the coating formulation is applied to the textile product by any conventionally known method such as spraying, dipping, rollbrush application, etc.
  • the (gained) between 20 and 100% wt. over the dry wt. of the textile article, depending on whether the article is made from synthetic (polycotton) or natural fibers, as well the construction of the textile (non-woven, woven or knitted).
  • the amount of coating formulation is applied such that it equates to 3 - 5 grams of dried coating per 100 grams of textile article.
  • the coating must be cured at about 130°C for at least about 1 minute so that all of the water is evaporated and bonding occurs without the use of a catalyst.
  • the amount of antimicrobial agent in the dried residue on the examples is about 0.09-0.15%) by wt.
  • Various active concentrations of the antimicrobial agent within the formulation were compared at the 1%, 2%, 3%, and 4% by wt. level.
  • a more durable finish can be produced when the concentration of the antimicrobial agent is lessened or reduced within the formulation. Accordingly, one skilled in the art would use sufficient amount to accomplish the antimicrobial effect but for economic reason and durability reasons would use no more than what is necessary. Generally this is between 2 and 4% by wt. of the antimicrobial agent in the wet coating on the textile.
  • AATCC Test Method 147-1993 is the industry test for antimicrobial effectiveness with the staphylococcus aureus (gram negative) being ATCC 6538 and the klebsiella pneumoniae (gram positive) being ATCC 4352 where the textile sample size was 25 millimeters by 50 millimeters and the nutrient broth was incubated at 37°C +/- 2°C for eighteen to twenty four hours.
  • the antimicrobial effectiveness was determined on unwashed textile articles, textile articles after 50 washes and the textile articles after 100 washes.
  • the test (AATCC Test Method 147-1993) determines if the antimicrobial agent effectively inhibits the growth of staphylococcus aureus (ATCC 6538 Gram-negative bacteria) and klebsiella pneumoniae (ATCC 4352 Gram-positive bacteria). The results are set forth in Table 1.
  • the antimicrobial agent is incorporated into a polymer (polyurethane) it has antimicrobial efficacy, especially against stain and odor causing bacteria. It was observed that the colorfastness, fiber retention, and softness of hand of an antimicrobial treated textile article are superior to that of an uncoated textile article.
  • the coated textile has minimum loss of absorbency compared to an uncoated textile article. Lastly, the coating composition is transparent and does not yellow.
  • Example 2 the burgundy towels were tested for antimicrobial effectiveness using the same procedures in Example 1, except the antimicrobial concentration was present on the dried textile article in Example 1 at about 3 weight %. In this Example, the amount of antimicrobial material was cut in half, i.e., 1.5 weight %. The results were noted after 0 launderings, 25 launderings, 50 launderings, 75 launderings, and 100 launderings. In addition to the good colorfastness, it was observed that these towels had good hand and good absorbency when compared with the control (0 launderings). The results of the antimicrobial effectiveness are set forth in Table 2.
  • Example 2 a 50/50 polycotton blend textile was tested for both colorfastness and antimicrobial effectiveness employing the same test set forth above with respect to Example 1.
  • the amount of antimicrobial material tested ranged from 0 (the control) to 0.06%) and to 0.09%) by weight, based on the weight of the textile.
  • the amount of launderings for the control was 25 and 100 launderings.
  • the test for colorfastness and antimicrobial effectiveness were after 25 launderings, and 100 launderings.
  • For the 0.09% by weight antimicrobial agent present in the finish 75 launderings and 100 launderings were the plateau for testing. In this Example all of the colorfastness results were good.
  • the antimicrobial test results are set forth in Table 3.
  • mm Zone of Inhibition Reported in Millimeters

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Organic Chemistry (AREA)
  • Toxicology (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Materials Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne un revêtement textile durable à propriétés antimicrobiennes, tel que la solidité de la couleur, le toucher et la capacité d'absorption du textile ne sont pas modifiées de manière significative par rapport à un textile dépourvu de ce revêtement. En particulier, ce revêtement appliqué sur des serviettes en coton ou en coton mélangé, par exemple, permet de réduire fortement ou d'éliminer les moisissures, champignons et bactéries présents sur celles-ci ; ce qui permet de réduire efficacement les taches et les odeurs de ces serviettes. Plus particulièrement, ce revêtement à base de micro-émulsion comporte un polyuréthanne, un plastifiant et un agent antimicrobien. Le revêtement à base de micro-émulsion (composition antimicrobienne) renferme d'environ 90 à environ 95 % en poids de polyuréthanne ou de co-polyuréthanne ; d'environ 1 à environ 5 % en poids de plastifiant ; et d'environ 1 à 5 % en poids d'agent antimicrobien, le total atteignant 100 pour cent. On obtient ensuite une composition de revêtement pour textiles à l'aide de cette composition de micro-émulsion en mélangeant de 3 à 7 parties de la composition antimicrobienne avec 93 à 97 parties d'eau (pour un total de 100 parties). Cette composition aqueuse est ensuite appliquée sur un textile et séchée. Le textile revêtu antimicrobien garde son efficacité pendant au moins 50 lavages, conformément à la méthode d'essai AATCC 147-1993.
PCT/US2002/003485 2001-02-09 2002-02-05 Superfinition antimicrobienne et procede de fabrication WO2002064668A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US10/467,356 US20040077747A1 (en) 2002-02-05 2002-02-05 Antimicrobial superfinish and method of making

Applications Claiming Priority (2)

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US26795301P 2001-02-09 2001-02-09
US60/267,953 2001-02-09

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WO2002064668A1 true WO2002064668A1 (fr) 2002-08-22

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006077049A2 (fr) * 2005-01-21 2006-07-27 Henkel Kommanditgesellschaft Auf Aktien Polymeres anti-adhesifs permettant d'empecher l'adhesion de micro-organismes sur des textiles et ainsi l'odeur du linge
EP1718788A2 (fr) * 2004-02-25 2006-11-08 Supreme Elastic Corporation Procede pour la fourniture de fils composites amtimicrobiens, tissus composites et articles realises a partir de ceux-ci
EP1724392A3 (fr) * 2005-05-04 2007-12-19 Fritz Blanke Gmbh & Co. Kg Procédé d'apprêtage anti-microbien de surfaces textiles
WO2022144827A1 (fr) * 2020-12-30 2022-07-07 Calcutta Immo Nv Textile à effet inhibiteur de virus

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5660178A (en) * 1992-12-01 1997-08-26 Minnesota Mining And Manufacturing Company Hydrophilic pressure sensitive adhesives

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5660178A (en) * 1992-12-01 1997-08-26 Minnesota Mining And Manufacturing Company Hydrophilic pressure sensitive adhesives

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1718788A2 (fr) * 2004-02-25 2006-11-08 Supreme Elastic Corporation Procede pour la fourniture de fils composites amtimicrobiens, tissus composites et articles realises a partir de ceux-ci
EP1718788A4 (fr) * 2004-02-25 2009-12-02 Supreme Elastic Corp Procede pour la fourniture de fils composites amtimicrobiens, tissus composites et articles realises a partir de ceux-ci
US7939686B2 (en) 2004-02-25 2011-05-10 Supreme Corporation Method for providing antimicrobial composite yarns, composite fabrics and articles made therefrom
WO2006077049A2 (fr) * 2005-01-21 2006-07-27 Henkel Kommanditgesellschaft Auf Aktien Polymeres anti-adhesifs permettant d'empecher l'adhesion de micro-organismes sur des textiles et ainsi l'odeur du linge
WO2006077049A3 (fr) * 2005-01-21 2006-10-26 Henkel Kgaa Polymeres anti-adhesifs permettant d'empecher l'adhesion de micro-organismes sur des textiles et ainsi l'odeur du linge
JP2008528815A (ja) * 2005-01-21 2008-07-31 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 繊維製品への微生物の付着を防止および洗濯物臭気を防止するための抗付着性ポリマー
EP1724392A3 (fr) * 2005-05-04 2007-12-19 Fritz Blanke Gmbh & Co. Kg Procédé d'apprêtage anti-microbien de surfaces textiles
WO2022144827A1 (fr) * 2020-12-30 2022-07-07 Calcutta Immo Nv Textile à effet inhibiteur de virus
BE1028981B1 (nl) * 2020-12-30 2022-08-03 Calcutta Immo Nv Textiel met virusremmende werking

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