WO2002026665A3 - Verfahren zur herstellung von arylverbindungen - Google Patents

Verfahren zur herstellung von arylverbindungen Download PDF

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Publication number
WO2002026665A3
WO2002026665A3 PCT/EP2001/010558 EP0110558W WO0226665A3 WO 2002026665 A3 WO2002026665 A3 WO 2002026665A3 EP 0110558 W EP0110558 W EP 0110558W WO 0226665 A3 WO0226665 A3 WO 0226665A3
Authority
WO
WIPO (PCT)
Prior art keywords
aryl compounds
grignard reagent
substituted aryl
producing aryl
compounds
Prior art date
Application number
PCT/EP2001/010558
Other languages
English (en)
French (fr)
Other versions
WO2002026665A2 (de
Inventor
Markus Eckert
Guido Giffels
Hans-Christian Militzer
Thomas Prinz
Original Assignee
Bayer Ag
Markus Eckert
Guido Giffels
Hans-Christian Militzer
Thomas Prinz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE2000147484 external-priority patent/DE10047484A1/de
Priority claimed from DE2001121105 external-priority patent/DE10121105A1/de
Application filed by Bayer Ag, Markus Eckert, Guido Giffels, Hans-Christian Militzer, Thomas Prinz filed Critical Bayer Ag
Priority to AU2002218171A priority Critical patent/AU2002218171A1/en
Priority to EP01985697A priority patent/EP1324964A2/de
Publication of WO2002026665A2 publication Critical patent/WO2002026665A2/de
Publication of WO2002026665A3 publication Critical patent/WO2002026665A3/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B37/00—Reactions without formation or introduction of functional groups containing hetero atoms, involving either the formation of a carbon-to-carbon bond between two carbon atoms not directly linked already or the disconnection of two directly linked carbon atoms
    • C07B37/04—Substitution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Arylverbindungen werden in vorteilhafter Weise durch Kreuzkupplungsreaktion einer substituierten Arylverbindung mit einem Grignard-Reagenz unter Nickelkatalyse hergestellt, wenn man substituierte Arylverbindungen und einen neuartigen Nickelkatalysator vorlegt und bei Reaktionstemperatur das Grignard-Reagenz zudosiert.
PCT/EP2001/010558 2000-09-26 2001-09-13 Verfahren zur herstellung von arylverbindungen WO2002026665A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU2002218171A AU2002218171A1 (en) 2000-09-26 2001-09-13 Method for producing aryl compounds
EP01985697A EP1324964A2 (de) 2000-09-26 2001-09-13 Verfahren zur herstellung von arylverbindungen

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE10047484.5 2000-09-26
DE2000147484 DE10047484A1 (de) 2000-09-26 2000-09-26 Verfahren zur Herstellung von Arylverbindungen
DE2001121105 DE10121105A1 (de) 2001-04-27 2001-04-27 Verfahren zur Herstellung von Arylverbindungen
DE10121105.8 2001-04-27

Publications (2)

Publication Number Publication Date
WO2002026665A2 WO2002026665A2 (de) 2002-04-04
WO2002026665A3 true WO2002026665A3 (de) 2002-11-07

Family

ID=26007157

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/010558 WO2002026665A2 (de) 2000-09-26 2001-09-13 Verfahren zur herstellung von arylverbindungen

Country Status (5)

Country Link
US (1) US20020077250A1 (de)
EP (1) EP1324964A2 (de)
CN (1) CN1289190C (de)
AU (1) AU2002218171A1 (de)
WO (1) WO2002026665A2 (de)

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* Cited by examiner, † Cited by third party
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CA2620223A1 (en) 2005-09-02 2007-03-08 Abbott Laboratories Novel imidazo based heterocycles
CN103877995B (zh) * 2014-03-31 2016-02-17 陕西师范大学 蒙脱土负载纳米Pd/Cu催化剂及其原位一锅法制备和应用
CN106146454B (zh) * 2016-07-01 2018-08-24 陕西师范大学 Negishi偶联制备多氟联芳烃类化合物的方法
CN106187656B (zh) * 2016-07-01 2018-10-23 陕西师范大学 镁辅助镍催化多氟芳烃单芳基化的方法
CN106243018B (zh) * 2016-07-26 2018-09-21 陕西师范大学 一种多氟苯基吡啶类化合物的合成方法
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
CN107266282B (zh) * 2017-07-25 2020-06-30 利尔化学股份有限公司 一种1,4-二甲基萘的制备方法
CN109053359B (zh) * 2018-06-29 2021-09-07 万华化学集团股份有限公司 一种四烃基取代联苯的制备方法
CN112675850A (zh) * 2020-12-23 2021-04-20 江苏广域化学有限公司 镍催化剂、其制备方法及嘧啶类衍生物的合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0262389A1 (de) * 1986-08-30 1988-04-06 BASF Aktiengesellschaft Verfahren zur Herstellung von medizinischen Weissölen und medizinischen Paraffinen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0262389A1 (de) * 1986-08-30 1988-04-06 BASF Aktiengesellschaft Verfahren zur Herstellung von medizinischen Weissölen und medizinischen Paraffinen

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
GANDIA L.M., MONTES M.: "Effect of Thermal Treatments on the Properties of Nickel and Cobalt Activated-Charcoal-Supported Catalysts", J. CATAL., vol. 145, 1994, pages 276 - 288, XP002194527 *
IKOMA Y ET AL.: "Non-ligated Nickel Chloride-Catalyzed Cross-Coupling of Aromatic Grignard Reagents with Aryl Halides", SYNTHESIS, 1990, pages 147 - 8, XP002194436 *
LIPSHUTZ B.H.: "Development of Nickel-on-Charcoal as a "dirt-Cheap" Heterogeneous Catalyst: A Personal Account", ADV. SYNTH. CATAL., vol. 343, no. 4, 8 June 2001 (2001-06-08), XP002194454 *
LIPSHUTZ ET AL-: "Kumada couplings catalyzed by nickel on charcoal (Ni/C)", INORG. CHIM. ACTA, vol. 296, 1999, pages 164 - 9, XP002194453 *
TAMAO K ET AL: "NICKEL-PHOSPHINE COMPLEX-CATALYZED GRIGNARD COUPLING. I. CROSS-COUPLING OF ALKYL, ARYL, AND ALKENYL GRIGNARD REAGENTS WITH ARYL AND ALKENYL HALIDES: GENERAL SCOPE AND LIMITATIONS", BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, JAPAN PUBLICATIONS TRADING CO. TOKYO, JP, vol. 49, no. 7, July 1976 (1976-07-01), pages 1958 - 1969, XP000996380, ISSN: 0009-2673 *

Also Published As

Publication number Publication date
CN1289190C (zh) 2006-12-13
WO2002026665A2 (de) 2002-04-04
US20020077250A1 (en) 2002-06-20
CN1466487A (zh) 2004-01-07
AU2002218171A1 (en) 2002-04-08
EP1324964A2 (de) 2003-07-09

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