WO2002020702A1 - Process for effecting ultra-deep hds of hydrocarbon feedstocks - Google Patents

Process for effecting ultra-deep hds of hydrocarbon feedstocks Download PDF

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Publication number
WO2002020702A1
WO2002020702A1 PCT/EP2001/009641 EP0109641W WO0220702A1 WO 2002020702 A1 WO2002020702 A1 WO 2002020702A1 EP 0109641 W EP0109641 W EP 0109641W WO 0220702 A1 WO0220702 A1 WO 0220702A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
less
ppm
sulfur content
metal component
Prior art date
Application number
PCT/EP2001/009641
Other languages
English (en)
French (fr)
Inventor
Johannes Wilhelmus Maria Sonnemans
Sonja Eijsbouts
Original Assignee
Akzo Nobel N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V. filed Critical Akzo Nobel N.V.
Priority to JP2002525710A priority Critical patent/JP2004508453A/ja
Priority to AU2001284027A priority patent/AU2001284027A1/en
Priority to EP01962959A priority patent/EP1322730A1/en
Publication of WO2002020702A1 publication Critical patent/WO2002020702A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds

Definitions

  • the way in which the additive is incorporated into the catalyst composition is not critical to the process according to the invention.
  • the additive may be incorporated into the catalyst composition prior to, subsequent to, or simultaneously with the incorporation of the hydrogenation metal components.
  • the additive can be incorporated into the catalyst composition prior to the hydrogenation metal components by being added to the carrier before the hydrogenation metal components are. This can be done by mixing the additive with the carrier material before it is shaped, or by impregnating the shaped carrier material with the additive. This embodiment is not preferred at this point in time.
  • the process according to the invention is carried out at elevated temperature and pressure.
  • the temperature generally is about 200 to about 450°C, preferably about 280 to about 430°C.
  • the reactor inlet hydrogen partial pressure generally is about 5 to about 200 bar, preferably about 10 to about 100 bar, more preferably about 15 to about 60 bar.
  • the liquid hourly space velocity preferably is between about 0.1 and about 10 vol./vol.h, more preferably between about 0.5 and about 4 vol. vol.h.
  • the H 2 /oil ratio generally is in the range of about 50 to about 2000 Nl/I, preferably in the range of about 80 to about 1000 Nl/I.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
PCT/EP2001/009641 2000-09-04 2001-08-20 Process for effecting ultra-deep hds of hydrocarbon feedstocks WO2002020702A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2002525710A JP2004508453A (ja) 2000-09-04 2001-08-20 炭化水素供給原料の超高度な水素化脱硫を達成する方法
AU2001284027A AU2001284027A1 (en) 2000-09-04 2001-08-20 Process for effecting ultra-deep hds of hydrocarbon feedstocks
EP01962959A EP1322730A1 (en) 2000-09-04 2001-08-20 Process for effecting ultra-deep hds of hydrocarbon feedstocks

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP00203078 2000-09-04
EP00203078.1 2000-09-04
US23789200P 2000-10-04 2000-10-04
US60/237,892 2000-10-04

Publications (1)

Publication Number Publication Date
WO2002020702A1 true WO2002020702A1 (en) 2002-03-14

Family

ID=56290183

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/009641 WO2002020702A1 (en) 2000-09-04 2001-08-20 Process for effecting ultra-deep hds of hydrocarbon feedstocks

Country Status (5)

Country Link
US (1) US20020070147A1 (ja)
EP (1) EP1322730A1 (ja)
JP (1) JP2004508453A (ja)
AU (1) AU2001284027A1 (ja)
WO (1) WO2002020702A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8722563B2 (en) 2010-06-01 2014-05-13 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
EP2878651B1 (fr) 2013-11-28 2017-07-26 IFP Energies nouvelles Procédé d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs
EP2878370B1 (fr) 2013-11-28 2017-09-27 IFP Energies nouvelles Procédé d'hydrotraitement de gazole mettant en oeuvre un enchainement de catalyseurs

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6923904B1 (en) * 1999-04-02 2005-08-02 Akso Nobel N.V. Process for effecting ultra-deep HDS of hydrocarbon feedstocks
US20060289340A1 (en) * 2003-12-19 2006-12-28 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
US20070012595A1 (en) * 2003-12-19 2007-01-18 Brownscombe Thomas F Methods for producing a total product in the presence of sulfur
US20050155906A1 (en) * 2003-12-19 2005-07-21 Wellington Scott L. Systems and methods of producing a crude product
CN1894385A (zh) * 2003-12-19 2007-01-10 国际壳牌研究有限公司 生产原油产品的系统,方法和催化剂
BRPI0405723A (pt) * 2003-12-19 2005-10-04 Shell Int Research Métodos de produzir um produto de petróleo bruto e combustìvel de transporte, combustìvel de aquecimento, lubrificantes ou substâncias quìmicas e produto de petróleo bruto
US7988848B2 (en) * 2005-04-15 2011-08-02 Exxonmobil Research And Engineering Company Activating hydroprocessing catalysts using carbon monoxide and use of catalysts for hydroprocessing
CA2655576A1 (en) * 2006-06-22 2007-12-27 Shell Internationale Research Maatschappij B.V. Methods for producing a total product with selective hydrocarbon production
RU2009101916A (ru) * 2006-06-22 2010-07-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способы получения неочищенного продукта из выбранного сырья
JP5032805B2 (ja) * 2006-07-25 2012-09-26 日本ケッチェン株式会社 色相に優れた超低硫黄灯油の製造方法
FR2910351B1 (fr) * 2006-12-22 2009-02-27 Total France Sa Catalyseur d'hydrotraitement, son procede de preparation et son utilisation.
CA2809701C (en) * 2010-09-03 2015-07-07 Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Natural Resources Canada Production of high-cetane diesel product
EP2439253A1 (en) 2010-10-05 2012-04-11 Research Institute of Petroleum Industry (RIPI) Hydrodesulfurization nanocatalyst comprising a support of nanotube / nanorod alumina, method of preparation and application
MX2014007510A (es) 2014-06-20 2015-12-21 Inst Mexicano Del Petróleo Procedimiento de obtencion de una formulacion catalitica para la produccion de diesel de ultrabajo azufre, el producto obtenido y su aplicacion.
JP6802806B2 (ja) * 2015-04-24 2020-12-23 アルベマール・ユーロプ・エスピーアールエル ドープされた担体に金属有機硫化物を含有する水素化処理触媒
US20190233741A1 (en) 2017-02-12 2019-08-01 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
FR3104463B1 (fr) * 2019-12-17 2021-12-17 Ifp Energies Now Catalyseur d’hydrogenolyse obtenu a partir de sels fondus et d’un additif organique

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0300629A1 (en) * 1987-07-02 1989-01-25 Sumitomo Metal Mining Company Limited Catalyst for hydrotreatment of hydrocarbons and method for production thereof
EP0357295A2 (en) * 1988-08-19 1990-03-07 Sumitomo Metal Mining Company Limited Catalysts for hydrotreating of hydrocarbons and methods of preparing the same
EP0870817A1 (en) * 1997-04-11 1998-10-14 Akzo Nobel N.V. Process for effecting deep HDS of hydrocarbon feedstocks
EP1041133A1 (en) * 1999-04-02 2000-10-04 Akzo Nobel N.V. Process for effecting ultra-deep HDS of hydrocarbon feedstocks

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US4028227A (en) * 1974-09-24 1977-06-07 American Cyanamid Company Hydrotreating of petroleum residuum using shaped catalyst particles of small diameter pores
US4636487A (en) * 1985-09-16 1987-01-13 Phillips Petroleum Company Process for the preparation of promoted catalysts
US5139990A (en) * 1988-07-29 1992-08-18 Akzo Nv Process for the preparation of a resulfided catalyst
JP2900771B2 (ja) * 1992-11-18 1999-06-02 住友金属鉱山株式会社 炭化水素油の水素化処理触媒の製造方法
US5935420A (en) * 1996-08-23 1999-08-10 Exxon Research And Engineering Co. Desulfurization process for refractory organosulfur heterocycles
JP3868128B2 (ja) * 1998-10-05 2007-01-17 新日本石油株式会社 軽油の水素化脱硫装置及び方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0300629A1 (en) * 1987-07-02 1989-01-25 Sumitomo Metal Mining Company Limited Catalyst for hydrotreatment of hydrocarbons and method for production thereof
EP0357295A2 (en) * 1988-08-19 1990-03-07 Sumitomo Metal Mining Company Limited Catalysts for hydrotreating of hydrocarbons and methods of preparing the same
EP0870817A1 (en) * 1997-04-11 1998-10-14 Akzo Nobel N.V. Process for effecting deep HDS of hydrocarbon feedstocks
EP1041133A1 (en) * 1999-04-02 2000-10-04 Akzo Nobel N.V. Process for effecting ultra-deep HDS of hydrocarbon feedstocks

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8722563B2 (en) 2010-06-01 2014-05-13 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
US8722564B2 (en) 2010-06-01 2014-05-13 Exxonmobil Research And Engineering Company Hydroprocessing catalysts and their production
EP2878651B1 (fr) 2013-11-28 2017-07-26 IFP Energies nouvelles Procédé d'hydrotraitement de distillat sous vide mettant en oeuvre un enchainement de catalyseurs
EP2878370B1 (fr) 2013-11-28 2017-09-27 IFP Energies nouvelles Procédé d'hydrotraitement de gazole mettant en oeuvre un enchainement de catalyseurs

Also Published As

Publication number Publication date
AU2001284027A1 (en) 2002-03-22
US20020070147A1 (en) 2002-06-13
EP1322730A1 (en) 2003-07-02
JP2004508453A (ja) 2004-03-18

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