WO2001098404A3 - Plasticizers derived from vegetable oils - Google Patents

Plasticizers derived from vegetable oils Download PDF

Info

Publication number
WO2001098404A3
WO2001098404A3 PCT/US2001/019751 US0119751W WO0198404A3 WO 2001098404 A3 WO2001098404 A3 WO 2001098404A3 US 0119751 W US0119751 W US 0119751W WO 0198404 A3 WO0198404 A3 WO 0198404A3
Authority
WO
WIPO (PCT)
Prior art keywords
fatty acids
vegetable oils
plasticizers
alcohol
added
Prior art date
Application number
PCT/US2001/019751
Other languages
French (fr)
Other versions
WO2001098404A2 (en
Inventor
Herman P Benecke
Joel D Elhard
Bhima R Vijayendran
Original Assignee
Battelle Memorial Institute
Herman P Benecke
Joel D Elhard
Bhima R Vijayendran
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Battelle Memorial Institute, Herman P Benecke, Joel D Elhard, Bhima R Vijayendran filed Critical Battelle Memorial Institute
Priority to AU2001268618A priority Critical patent/AU2001268618A1/en
Priority to CA2412369A priority patent/CA2412369C/en
Priority to EP01946592A priority patent/EP1294799B1/en
Priority to AT01946592T priority patent/ATE272676T1/en
Priority to MXPA02012822A priority patent/MXPA02012822A/en
Priority to DE60104694T priority patent/DE60104694T2/en
Priority to BRPI0111905-2A priority patent/BR0111905B1/en
Priority to JP2002504358A priority patent/JP5101780B2/en
Publication of WO2001098404A2 publication Critical patent/WO2001098404A2/en
Publication of WO2001098404A3 publication Critical patent/WO2001098404A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1515—Three-membered rings

Abstract

Compositions and method for plasticizing polyvinyl chloride polymers where the plasticizers contain fatty acids derived from vegetable oils and the fatty acids are substantially fully esterfied with an alcohol (monool or polyol), the fatty acids having unsaturated bonds that are substantially fully epoxidized, and wherein the fatty acids are added substantially randomly to one or more hydroxyl sites on the alcohol. The plasticizers may be added in amounts between about 10 to 230 pph of PVC resin.
PCT/US2001/019751 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils WO2001098404A2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AU2001268618A AU2001268618A1 (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils
CA2412369A CA2412369C (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils
EP01946592A EP1294799B1 (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils
AT01946592T ATE272676T1 (en) 2000-06-20 2001-06-20 PLANT OIL-BASED PLANT-OIL-BASED PLASTICIZERS
MXPA02012822A MXPA02012822A (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils.
DE60104694T DE60104694T2 (en) 2000-06-20 2001-06-20 FROM PLANT OIL STIMBING SOFT MAKERS
BRPI0111905-2A BR0111905B1 (en) 2000-06-20 2001-06-20 composition of plasticized vinyl chloride, epoxidized pentaerythritol tetrassoyate, epoxidized propylene and ethylene glycol dissyates, epoxidized methyl soyate, epoxidized sucrose octassoyate, and epoxide product of a first interesterified vegetable oil with a second vegetable.
JP2002504358A JP5101780B2 (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US59697100A 2000-06-20 2000-06-20
US09/596,971 2000-06-20
US09/849,071 US6797753B2 (en) 2000-06-20 2001-05-04 Plasticizers derived from vegetable oils
US09/849,071 2001-05-04

Publications (2)

Publication Number Publication Date
WO2001098404A2 WO2001098404A2 (en) 2001-12-27
WO2001098404A3 true WO2001098404A3 (en) 2002-04-04

Family

ID=27082693

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/019751 WO2001098404A2 (en) 2000-06-20 2001-06-20 Plasticizers derived from vegetable oils

Country Status (11)

Country Link
US (1) US6797753B2 (en)
EP (1) EP1294799B1 (en)
JP (1) JP5101780B2 (en)
AT (1) ATE272676T1 (en)
AU (1) AU2001268618A1 (en)
BR (1) BR0111905B1 (en)
CA (1) CA2412369C (en)
DE (1) DE60104694T2 (en)
ES (1) ES2225568T3 (en)
MX (1) MXPA02012822A (en)
WO (1) WO2001098404A2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8859654B2 (en) 2009-09-30 2014-10-14 Dow Global Technologies Llc Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
US9181415B2 (en) 2009-09-30 2015-11-10 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
US9228155B2 (en) 2010-07-28 2016-01-05 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same
US9422418B2 (en) 2009-09-30 2016-08-23 Dow Global Technologies Llc Acetylated monoglyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4708706B2 (en) 2002-01-16 2011-06-22 イーストマン ケミカル カンパニー Novel carbohydrate esters and polyol esters as plasticizers for polymers, compositions and products containing such plasticizers and methods for their use
BR0215977C1 (en) * 2002-12-06 2008-06-24 Cognis Imp Acao E Com Oleoquim plasticized poly (vinyl chloride) composition
MY150129A (en) * 2004-04-09 2013-11-29 Archer Daniels Midland Co Method of preparing fatty acid alkyl esters from waste or recycled fatty acid stock
AU2005269945A1 (en) * 2004-07-08 2006-02-09 Archer-Daniels-Midland Company Epoxidized esters of vegetable oil fatty acids as reactive diluents
FR2880892B1 (en) * 2005-01-17 2008-03-21 Gerflor Sa USE OF ESTERIFIED FATTY ACIDS AS PVC PLASTICIZERS
BRPI0609349A2 (en) 2005-03-03 2011-10-18 South Dakota Soybean Processors method for producing a vegetable oil derived polyol, vegetable oil derived polyol, method for decreasing the acid value of a vegetable oil derived polyol, and urethane material
US20070082573A1 (en) * 2005-10-11 2007-04-12 The Procter & Gamble Company Water stable fibers and articles comprising starch, and methods of making the same
IN262459B (en) 2005-11-22 2014-08-29 Segetis Inc
US7538236B2 (en) * 2006-01-04 2009-05-26 Suresh Narine Bioplastics, monomers thereof, and processes for the preparation thereof from agricultural feedstocks
US20070218183A1 (en) * 2006-03-14 2007-09-20 Bunge Oils, Inc. Oil composition of conjugated linoleic acid
US8481622B2 (en) * 2006-09-01 2013-07-09 The Curators Of The University Of Missouri Soybean based epoxy resin and methods of making and use
US20090005583A1 (en) * 2007-06-29 2009-01-01 Benecke Herman P Preparation of Propylene Glycol Fatty Acid Ester or Other Glycol or Polyol Fatty Acid Esters
BRPI0704776A2 (en) * 2007-09-12 2009-05-05 Sgs Polimeros Ltda vegetable oil derivatives
CN101874085B (en) * 2007-09-25 2014-04-16 孟山都技术公司 Use of oils with high concentrations of polyunsaturated fatty acids in plastics and surface coatings
JP2009132846A (en) * 2007-12-03 2009-06-18 Mimaki Engineering Co Ltd Ink for inkjet
BRPI0705276A2 (en) * 2007-12-10 2009-08-11 Nexoleum Bioderivados Ltda pvc primary plasticizers derived from vegetable oils, process for obtaining pvc primary plasticizers derived from vegetable oils and plasticized pvc composition
BRPI0705621B1 (en) 2007-12-10 2019-04-09 Nexoleum Bioderivados Ltda. PVC PLASTIFIC COMPOSITION
CN103788027A (en) * 2008-01-24 2014-05-14 普立万公司 Catalysts for esterification of epoxidized soyates/esters and methods of using same
CN101939307B (en) * 2008-02-12 2015-04-22 普立万公司 Epoxidized soyate diesters and methods of using same
KR20160030328A (en) * 2008-02-15 2016-03-16 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 A replacement plasticizer system for phthalate-plasticized formulations
FR2931830B1 (en) * 2008-05-29 2012-11-30 Arkema France PVC COMPOSITION USED IN AUTOMOBILE INTERIOR DECORATION PREPARED FROM RENEWABLE RAW MATERIALS.
MX341364B (en) * 2008-06-17 2016-08-18 Resinas Y Mat S A De C V Bioplasticizers or primary oleochemical plasticizers with thermal and ultraviolet radiation stabilizing activity for pvc moulding resins and process for obtaining thereof.
BRPI0915488A2 (en) * 2008-07-11 2015-11-10 Polyone Corp sustainable mixing of polyvinyl chloride for flooring products
US8217191B2 (en) 2008-11-05 2012-07-10 Aiken John E Process for integrated co-production of hydrogen peroxide and epoxidized esters
FR2942475B1 (en) * 2009-02-26 2011-04-01 Sika Technology Ag DRY COMPOSITION COMPRISING A BINDER AND MODIFIED VEGETABLE OIL
US8552098B2 (en) * 2009-09-30 2013-10-08 Dow Global Technologies Llc Purified acetylated derivatives of castor oil and compositions including same
WO2011046736A2 (en) * 2009-10-13 2011-04-21 Polyone Corporation Use of epoxidized alkyl soyates to plasticize cellulose alkanoates
BR112012017956B1 (en) * 2010-01-22 2020-04-07 Archer Daniels Midland Co poly (vinyl halide) composition
DE102010000259A1 (en) 2010-01-29 2011-08-04 Benecke-Kaliko AG, 30419 Multilayer sheet
EP2357276B2 (en) 2010-02-01 2016-01-27 Benecke-Kaliko AG Multi-layer textile sheet and method for its production
US9096773B2 (en) * 2010-02-06 2015-08-04 Ndsu Research Foundation Highly functional epoxidized resins and coatings
WO2014043720A1 (en) 2012-09-17 2014-03-20 Ndsu Research Foundation Blocked bio-based carboxylic acids and their use in thermosetting materials
WO2015070018A1 (en) 2013-11-07 2015-05-14 Ndsu Research Foundation Bio-based resins with high content of ethylenically unsaturated functional groups and thermosets thereof
US7951766B1 (en) * 2010-02-12 2011-05-31 Galata Chemicals, Llc Bio-based solvents and methods for using same
WO2011143028A1 (en) * 2010-05-10 2011-11-17 Dow Global Technologies Llc Flexible pvc compositions made with plasticizers derived from renewable sources
US9034965B2 (en) * 2010-08-06 2015-05-19 Arkema Inc. Epoxidized composition and methods for making the same
WO2012036913A2 (en) * 2010-09-13 2012-03-22 Regents Of The University Of Minnesota Bio-renewable plasticizers derived from vegetable oil
WO2012102952A1 (en) 2011-01-24 2012-08-02 Arkema Inc. Epoxidized fatty acid alkyl esters as flexibilizers for poly(lactic acid)
US8507596B2 (en) 2011-02-18 2013-08-13 Galata Chemicals Llc Bio-based plasticizer
BRPI1102427B1 (en) 2011-05-26 2021-03-30 Oxiteno S.A. Indústria E Comércio COMPOSITION OF WATER BASED COATING UNDERSTANDING GREEN COALESCENTS, AND, USE OF THE COMPOSITION
BRPI1102456B1 (en) 2011-05-26 2021-03-30 Oxiteno S/a Industria E Comércio COMPOSITION OF COALESCENCE AGENTS, AND, USE OF THE COMPOSITION OF COALESCENCE AGENTS
CN103703068A (en) * 2011-06-15 2014-04-02 麦兰特公司 Environmentally friendly coalescing agents
EP2702123A1 (en) 2011-06-17 2014-03-05 Biosynthetic Technologies, LLC Epoxidized estolides, sulfurized estolides, and methods of making the same
IN2014DN00197A (en) 2011-06-27 2015-06-05 Archer Daniels Midland Co
US9382415B2 (en) * 2011-07-27 2016-07-05 Polyone Corporation Crosslinkable bioplasticizers
US8829216B2 (en) 2011-08-31 2014-09-09 Biosynthetic Technologies, Llc Hydroxy estolides, poly-capped estolides, and methods of making the same
MX341216B (en) * 2011-09-30 2016-08-11 Dow Global Technologies Llc Process for mixing polyvinyl chloride with a bio-based plasticizer.
CA2850429C (en) 2011-09-30 2020-06-02 Dow Global Technologies Llc Plasticizer for low temperature unwind with weight retention during heat aging
US10262767B2 (en) 2011-09-30 2019-04-16 Dow Global Technologies Llc Plasticizer for color retention during heat aging
SG10201508216WA (en) 2011-10-14 2015-11-27 Galata Chemicals Llc Plasticizers derived from renewable feedstock
KR101288437B1 (en) 2011-11-29 2013-07-26 동구산업(주) Environment-friendly plasticizers prepared with vegetable oil and preparation method thereof
MX357165B (en) 2012-02-08 2018-06-28 Dow Global Technologies Llc Plasticizer compositions and methods for making plasticizer compositions.
KR102088075B1 (en) 2012-06-22 2020-03-11 다우 글로벌 테크놀로지스 엘엘씨 Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions
BR112014027891B1 (en) 2012-06-26 2021-03-23 Dow Global Technologies Llc COMPOSITION OF PLASTIFIED POLYMERIC VINYL CHLORIDE AND COATED CONDUCTOR
DE102013011882A1 (en) * 2012-08-21 2013-09-26 UNIKOPF Innovations GmbH Polyvinyl chloride glove with soap fragrance useful for depilating, where soap fragrance is incorporated into the polyvinyl chloride, and the fragrance is an integral part of the polyvinyl chloride glove
DE102012217199A1 (en) 2012-09-24 2014-03-27 Evonik Industries Ag Ester with epoxide group and carbonate group
KR101993956B1 (en) * 2012-10-18 2019-06-27 다우 글로벌 테크놀로지스 엘엘씨 Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
BR112015010689B1 (en) 2012-11-12 2022-01-25 Dow Global Technologies Llc Process for producing epoxidized fatty acid alkyl esters, plasticizer and polymer composition
EP2917191B1 (en) 2012-11-12 2018-12-26 Dow Global Technologies LLC Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers
KR101352236B1 (en) 2012-12-26 2014-01-15 이종선 Product and producing method of eco-friendly plasticizer
CA2902488C (en) * 2013-02-25 2020-03-10 Arkema Inc. Unsaturated fatty acid ester-based plastic additives
DE102013203972A1 (en) * 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl esters based on fatty acids or fatty acid mixtures of tall oil or linseed oil
DE102013203973A1 (en) 2013-03-08 2014-09-11 Evonik Industries Ag Isononyl ester based on fatty acid mixtures of vegetable oils
WO2014197327A1 (en) 2013-06-03 2014-12-11 Regents Of The University Of Minnesota Epoxy estolide fatty acid alkyl esters useful as biorenewable plasticizers
US9346939B2 (en) 2013-11-01 2016-05-24 Galata Chemicals Llc Flexible PVC compounds having a low metals content
DE102015206645A1 (en) 2014-04-16 2015-10-22 Basf Se Use of modified fatty acid esters as plasticizer
BR112016026541B1 (en) 2014-05-13 2022-01-25 Magink Comércio De Imagem Gráfica Ltda. - Me PROCESS FOR PREPARING THE DISPERSION OF HOMOPOLYMER OF VINYL CHLORIDE WITH HIGH CONTENT OF FREE HYDROXYL AS ADHESIVE
WO2015185963A1 (en) * 2014-06-05 2015-12-10 Sion Nanotec Procedure for obtaining plasticizer polymers and plasticizing polymers based on agents of plant origin for use in polymers
EP2990470A1 (en) 2014-08-26 2016-03-02 Evonik Degussa GmbH Mixed epoxidised fatty acid esters
WO2016033603A1 (en) 2014-08-29 2016-03-03 Iowa State University Research Foundation, Inc. Improved asphalt products and materials and methods of producing them
US9856366B2 (en) * 2015-04-10 2018-01-02 Georgia-Pacific Chemicals Llc Plastic compositions that include plasticizers containing an acylated phenolated fatty acid ester
US9765233B2 (en) * 2015-04-21 2017-09-19 Ndsu Research Foundation Biobased highly functional oligomers and thermosets therefrom
US10144812B2 (en) 2015-10-05 2018-12-04 Regents Of The University Of Minnesota Multi-functional fatty acid ester derivatives useful as biorenewable plasticizers
US20170233956A1 (en) 2016-02-17 2017-08-17 The Hanson Group Llc Cooling infill for synthetic turf applications
US10961395B2 (en) 2016-02-29 2021-03-30 Iowa State University Research Foundation, Inc. Rejuvenation of vacuum tower bottoms through bio-derived materials
US10570286B2 (en) 2016-08-30 2020-02-25 Iowa State University Research Foundation, Inc. Asphalt products and methods of producing them for rejuvenation and softening of asphalt
BE1025186B1 (en) 2017-09-27 2018-11-26 Proviron Holding N.V. Plasticizer composition
EP3710495A4 (en) 2017-11-14 2021-11-17 Avery Dennison Corporation Pvc compositions, films, laminates and related methods
BE1026295B9 (en) * 2018-05-22 2020-01-14 Proviron Holding N V Use of an epoxidized fatty acid ester as a plasticizer in halogenated resins
WO2020229416A1 (en) 2019-05-14 2020-11-19 Nouryon Chemicals International B.V. Pvc foams
US11773265B2 (en) 2019-09-18 2023-10-03 Iowa State University Research Foundation, Inc. Biosolvents useful for improved asphalt products utilizing recycled asphalt pavement or other brittle asphalt binders such as vacuum tower bottom
CN111777510B (en) * 2020-07-10 2021-04-02 江南大学 Preparation method and application of plant oil-based environment-friendly plasticizer with high thermal stability
CN113402891A (en) * 2021-04-08 2021-09-17 华南理工大学 Migration-resistant micro-crosslinked structure environment-friendly plasticizer and preparation method thereof
WO2023199260A1 (en) * 2022-04-14 2023-10-19 Tmg Tecidos Plastificados E Outros Revestimentos Para A Industria Automovel Sa Multi-layered pvc material, method of obtaining and uses thereof
EP4261030A1 (en) * 2022-04-14 2023-10-18 TMG Tecidos Plastificados e Outros Revestimentos Para A Industria Automovel SA Multi-layered pvc material, method of obtaining and uses thereof
CN115710323B (en) * 2022-08-23 2023-08-15 中国林业科学研究院林产化学工业研究所 Castor oil modified internal plasticization polyvinyl chloride material and preparation method thereof
CN115677547A (en) * 2022-10-27 2023-02-03 中国林业科学研究院林产化学工业研究所 Tung oil-based plasticizer and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2029851A (en) * 1932-04-08 1936-02-04 Du Pont Product and process of preparing same
EP0358181A2 (en) * 1988-09-09 1990-03-14 The Geon Company Polyvinyl chloride blends having improved physical properties
EP0510521A2 (en) * 1991-04-26 1992-10-28 Nippon Zeon Co., Ltd. A method of preparation of foamed articles of polyvinyl chloride resins
US5643501A (en) * 1992-05-27 1997-07-01 Baxter International Inc. Additives for polymer compositions

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL235270A (en) * 1958-01-20
US3236795A (en) * 1961-03-02 1966-02-22 Archer Daniels Midland Co Coating compositions comprising carboxyl interpolymers and epoxidized fatty acid esters
US3218296A (en) * 1962-07-30 1965-11-16 Tenneco Chem Initiators for the polymerization of formaldehyde
US3493414A (en) * 1967-10-12 1970-02-03 Ashland Oil Inc Epoxy/polyester compositions
US4486561A (en) * 1981-08-21 1984-12-04 Ethyl Corporation Injection-moldable thermoplastic polyester composition
DE3246618A1 (en) * 1982-12-16 1984-07-05 Henkel KGaA, 4000 Düsseldorf ALKYD RESIN CONTAINING RING OPENING PRODUCTS EPOXY FATTY ALCOHOLS OR FATTY ACID DERIVATIVES AS HYDROXYL COMPOUNDS
JPS61140589A (en) * 1984-12-10 1986-06-27 ア−ガス・ケミカル・コ−ポレ−シヨン Hydrolytic resistance-improved pentaerythritol-spiro-bis-phosphite composition and composition containing same
US4782170A (en) * 1986-05-13 1988-11-01 Argus Chemical Corporation Liquid polyvinyl chloride resin stabilizer systems based on complexes of organic triphosphites with zinc chloride
US5030511A (en) * 1989-06-09 1991-07-09 W. R. Grace & Co.-Conn. Extruded vinylidene chloride copolymer flexible packaging film
US5324846A (en) * 1992-01-30 1994-06-28 Elf Atochem North America, Inc. Partial esters of epoxy containing compounds
AU682287B2 (en) * 1995-05-10 1997-09-25 Morton International, Inc. Latent mercaptans as multi-functional additives for halogen-containing polymer compositions
JP4007656B2 (en) * 1997-11-27 2007-11-14 株式会社Ａｄｅｋａ Epoxidized animal and vegetable oil composition
JP2000319468A (en) * 1999-05-07 2000-11-21 Asahi Denka Kogyo Kk Stabilizer composition for vinyl chloride-based resin

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2029851A (en) * 1932-04-08 1936-02-04 Du Pont Product and process of preparing same
EP0358181A2 (en) * 1988-09-09 1990-03-14 The Geon Company Polyvinyl chloride blends having improved physical properties
EP0510521A2 (en) * 1991-04-26 1992-10-28 Nippon Zeon Co., Ltd. A method of preparation of foamed articles of polyvinyl chloride resins
US5643501A (en) * 1992-05-27 1997-07-01 Baxter International Inc. Additives for polymer compositions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8859654B2 (en) 2009-09-30 2014-10-14 Dow Global Technologies Llc Heat stabilized polymeric composition with epoxidized fatty acid ester plasticizer
US9181415B2 (en) 2009-09-30 2015-11-10 Dow Global Technologies Llc Acetylated derivatives of castor oil and their blends with epoxidized fatty acid esters
US9422418B2 (en) 2009-09-30 2016-08-23 Dow Global Technologies Llc Acetylated monoglyceride of 12-hydroxystearic acid and blends with epoxidized fatty acid esters
US9228155B2 (en) 2010-07-28 2016-01-05 Dow Global Technologies Llc Plasticizers made from oil extracted from microorganisms and polar polymeric compositions comprising the same

Also Published As

Publication number Publication date
US20020013396A1 (en) 2002-01-31
WO2001098404A2 (en) 2001-12-27
DE60104694T2 (en) 2005-07-14
DE60104694D1 (en) 2004-09-09
ATE272676T1 (en) 2004-08-15
EP1294799A2 (en) 2003-03-26
EP1294799B1 (en) 2004-08-04
BR0111905B1 (en) 2010-12-28
ES2225568T3 (en) 2005-03-16
JP5101780B2 (en) 2012-12-19
US6797753B2 (en) 2004-09-28
CA2412369C (en) 2011-04-26
CA2412369A1 (en) 2001-12-27
JP2004501257A (en) 2004-01-15
MXPA02012822A (en) 2003-10-06
BR0111905A (en) 2003-05-13
AU2001268618A1 (en) 2002-01-02

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