WO2001061057A1 - Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing - Google Patents
Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing Download PDFInfo
- Publication number
- WO2001061057A1 WO2001061057A1 PCT/US2001/001691 US0101691W WO0161057A1 WO 2001061057 A1 WO2001061057 A1 WO 2001061057A1 US 0101691 W US0101691 W US 0101691W WO 0161057 A1 WO0161057 A1 WO 0161057A1
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- WO
- WIPO (PCT)
- Prior art keywords
- bar
- steel
- microalloyed
- bar product
- manufacturing
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0075—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rods of limited length
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2261/00—Machining or cutting being involved
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/28—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for plain shafts
Definitions
- the invention relates to bar product, cylinder rods, hydraulic cylinders, and methods for manufacturing bar product, cylinder rods, and hydraulic piston cylinders. More particularly, the invention relates to bar product prepared from microalloyed bar steel and which can be formed into cylinder rods for use in hydraulic cylinders. The bar product and cylinder rods can be prepared without a step of cold drawing.
- Cylinder rods can be produced from bar steel and processed according to ASTM A 311.
- Bar steel characterized as grade C1045 or grade C1050 according to ASTM A 311 is melted and cast into a preform.
- the preform can typically be considered a billet, bloom, or ingot.
- the preform is reheated to a working temperature of about 2,000°F, and is hot rolled on a multiple stand bar rolling mill to provide a desired round size steel bar.
- the steel bar is cooled to below 1,000°F on a notch-bar cooling bed.
- the cooled bar can be referred to as
- the as-hot rolled bar is typically shipped to a cold finished bar producer for further processing.
- the mill scale is typically removed by shot blasting.
- the as-hot rolled bar is cold drawn to a smaller cross section by pulling it through a lubricated die.
- the standard draft for the cold finished bar industry is 1/16 inch.
- a heavy draft is typically 1/8 inch to 3/32 inch depending on the desired properties and finished cold drawn size. The reduction provided by a heavy draft results in additional strength.
- the cold drawn bars are straightened, and given a stress relief heat treatment to relieve drawing stress and increase the yield strength.
- the stress relief heat treatment is typically provided at about 500°F to about 700°F.
- the resulting bars are typically processed by any or all of the following processing steps including turning, grinding, polishing, surface hardening and chrome plating to achieve a precision size and surface finish.
- Microalloyed steel generally contains of one or more of columbium (niobium), vanadium, titanium, and nitrogen. These elements can be added to a base steel composition such as grade C1045 or grade C1050, and strength can be increased by a combination of grain refinement and precipitation strengthening. Because the microstructure of the steel remains predominantly pearlitic at the carbon levels provided by grade C1045 and grade C1050, ductility at a given strength level is relatively low, and tends to decrease proportionately as tensile strength increases. Yield strengths above 100 ksi can be achieved for microalloyed steel, but the ductility may not meet the requirements of ASTM A 311, Table 2.
- a bar product prepared from microalloyed bar steel is provided according to the invention.
- the bar product is prepared by hot rolling and heat treating a microalloyed bar steel.
- the hot rolled and heat treated microalloyed bar steel is prepared by steps of hot rolling a preform of the microalloyed bar steel at a temperature of between about 1,400° F and about 2,300° F to provide a steel bar having a diameter of between about 3 ⁇ inch and about four inches, cooling the steel bar to provide a surface temperature of below about 1,100° F, and heat treating the steel bar in an environment having a temperature of between about 500° F and about 1,300° F.
- the bar product is preferably prepared without a step of cold drawing.
- the bar product is preferably prepared without a step of drawing to provide a 10% to a 35% reduction.
- the bar product having a diameter of between about 3 A inch and about four inches can be characterized as having a tensile strength of greater than about 105 ksi, a yield strength of greater than about 90 ksi, an elongation in two inches of greater than about 7%, and a reduction of area of greater than about 20%.
- the microalloyed bar steel preferably includes about 0.36 wt.% to about 0.55 wt.% carbon, about 0.60 wt.% to about 1.65 wt.% magnesium, 0 to about 0.050 wt.% phosphorus, 0 to about 0.050 wt.% sulfur, 0 to about 0.40 wt.% silicone, 0 to about 0.06 wt.% tin, 0 to about 0.40 wt.% copper, about 0.01 wt.% to about 0.40 wt.% nickel, about 0.01 wt.% to about 0.30 wt.% chromium, about 0.01 wt.% to about 0.15 wt.% molybdenum, and about 0.005 wt.% to about 0.50 wt.% microalloying additive comprising at least one of columbium (niobium), vanadium, titanium, aluminum and nitrogen.
- the microalloyed bar steel includes about 0.02 wt.% to about 0.40 wt.% vanadium and between about 0.005 and about 0.025 wt.% nitrogen. More preferably, the microalloyed bar steel includes between about 0.005 wt.% and about 0.10 wt.% columbium (niobium), between about 0.02 and about 0.40 wt.% vanadium, and between about 0.005 wt.% and about 0.025 wt.% nitrogen.
- the microalloyed bar steel can additionally include between about 0.005 wt.% and about 0.05 wt.% titanium and between about 0.020 wt.% and about 0.060 wt.% aluminum.
- the microalloyed bar steel preferably includes between about 95.5 wt.% and about 99.0 wt.% iron.
- the bar product can be further processed to provide a cylinder rod according to the invention.
- Exemplary processing steps can include turning, grinding, and/or polishing to provide a precision size.
- the surface of the bar product can be surface hardened and/or chrome plated.
- a method for manufacturing bar product includes steps of hot rolling the microalloyed bar steel at a temperature of between about 1,400° F and about 2,300° F to provide a steel bar having a diameter of between about 3 / 4 inch and about four inches, cooling the bar steel to provide a surface temperature below about 1,100° F, and heat treating the steel bar at a temperature of between about 500° F and about 1,300° F.
- the bar product can be further processed by steps of turning, grinding, and/or polishing to provide a precision size, and the surface of the bar product can be surface hardened and chrome plated.
- the method can be used to provide a cylinder rod for as a piston in a hydraulic cylinder.
- a hydraulic cylinder is provided according to the invention.
- the hydraulic cylinder includes a housing and a cylinder rod provided within the housing.
- the housing includes an opening through which the cylinder rod extends.
- the cylinder rod includes a first end and a second end. The first end extends out of the housing through the housing opening and is generally attached to a saddle which is then attached to a substrate. The second end generally remains within the housing.
- the housing additionally contains a surface for mounting to another substrate.
- Figure 1 is a cut away view of a hydraulic cylinder according to the invention.
- Figure 2 is a graph illustrating the effect of heat treating on yield strength and reduction of area according to example 1.
- the invention relates to bar product and cylinder rods prepared from microalloyed bar steel. Cylinder rods are commonly used as pistons in hydraulic cylinders. Cylinder rods are generally prepared from bar product.
- the cylinder rods according to the invention preferably include between 0.43 wt.% and 0.55 wt.% carbon, between 0.60 wt.% and 0.90 wt.% magnesium, 0 to 0.050 wt.% phosphorus, and 0 to 0.050 wt.% sulfur.
- cylinder rods according to the invention preferably exhibit properties of tensile strength, yield strength, elongation in two inches, and reduction of area corresponding to those property values identified in Table 2, Class B of ASTM A 311 for grades C1045 and C1050. The property values provided in Table 2. Class B of ASTM A 311 for grades C1045 and C1050 are incorporated herein by reference.
- the tensile strength is preferably at least 115 ksi
- the yield strength is preferably at least 100 ksi
- the elongation in two inches is preferably at least 10%
- the reduction of area is preferably at least 25% .
- the tensile strength is preferably at least 115 ksi, the yield strength is preferably at least 100 ksi, the elongation in two inches is preferably at least 9%, and the reduction of area is preferably at least 25%.
- the tensile strength is preferably at least 105 ksi, the yield strength is preferably at least 90 ksi, the elongation in two inches is preferably at least 7%, and the reduction of area is preferably at least 20%.
- the cylinder rod For cylinder rods prepared from grade C1050 bar steel and having a diameter of up to 2 inches, the cylinder rod preferably exhibits a tensile strength of at least 115 ksi, a yield strength of at least 100 ksi, an elongation in two inches of at least 8%, and a reduction of area of at least 25%.
- the tensile strength is preferably at least 115 ksi
- the yield strength is preferably at least 100 ksi
- the elongation in two inches is preferably at least 8%
- the reduction of area is at least about 20%.
- the cylinder rod For cylinder rods prepared from grade C 1050 bar steel and having a diameter of greater than three inches and up to 4.5 inches, the cylinder rod preferably exhibits a tensile strength of at least 115 ksi, a yield strength of at least 100 ksi, an elongation in 2 inches of at least 7%, and a reduction of area of at least 20%.
- the bar product and cylinder rods according to the invention preferably satisfy these physical properties. It should be appreciated that the physical properties are measured according to ASTM A 311.
- prior art cylinder rods are prepared by a method which includes a step of cold drawing.
- the step of cold drawing is generally referred to as heavy draft cold drawing which generally refers to providing about 10%) to about 35% reduction.
- the microalloyed bar steel can be processed to provide the desired properties without a step of cold drawing.
- the bar product can be processed into cylinder rods without processing by heavy draft which provides about 10% to about 35% reduction.
- Microalloyed bar steel refers to bar steel containing microalloying elements.
- the microalloyed bar steel according to the invention can be referred to more simply as bar steel.
- the bar steel includes between about 0.36 wt.% and about 0.55 wt.% carbon, between about 0.60 wt.% and about 1.65 wt.% magnesium, 0 to about 0.050 wt.% phosphorous, 0 to about 0.050 wt.% sulfur, 0 to about 0.40 wt.% silicon, 0 to about 0.06 wt.% tin, 0 to about 0.40 wt.% copper, between about 0.01 wt.% and about 0.40 wt.% nickel, between about 0.01 wt.% and about 0.30 wt.% chromium, between about 0.01 wt.% and about 0.15 wt.% molybdenum, and between about 0.005 wt.% and about 0.50 wt.% of a microalloying additive including at least one of columbium (niobium), vanadium, titanium, aluminum, and nitrogen.
- phosphorous, sulfur, silicon, tin, and copper will be present, although the amount of these components can be taken to very low levels.
- phosphorous is present, it is generally provided at a level of greater than about 0.005 wt.%.
- sulfur is present, it is generally provided at a level of greater than about 0.005 wt.%.
- silicon is present, it is generally provided at a level of greater than about 0.01 wt.%.
- tin When tin is present, it is generally provided at a level of greater than about 0.002 wt.%.
- copper it is generally provided at a level of greater than about 0.01 wt.%.
- the microalloying additives are preferably provided at a concentration which provides the cylinder rods according to the invention with the desired physical properties.
- the microalloyed bar steel includes 0 to about 0.10 wt.%) columbium (niobium), about 0.02 wt.% to about 0.40 wt.% vanadium, 0 to about 0.05 wt.% titanium, 0 to about 0.060 wt.% aluminum, and between about 0.005 wt.% and about 0.025 wt.% nitrogen.
- the microalloyed bar steel includes between about 0.02 wt.% and about 0.05 wt.% columbium (niobium), between about 0.25 wt.% and about 0.35 wt.% vanadium, and between about 0.005 wt.% and about 0.025 wt.% nitrogen.
- the microalloyed bar steel can include at least about 0.005 wt.% titanium and preferably between about 0.01 wt.% an about 0.02 wt.% titanium, and at least about 0.020 wt.% aluminum and preferably between about 0.020 wt.% and about 0.040 wt.% aluminum.
- the microalloyed bar steel can be prepared by melting the microalloyed bar steel components to form a liquid metal bath.
- Starting materials for the liquid metal bath can include steel scrap.
- the liquid steel bath is preferably cast into preforms.
- the preforms can be characterized as billets, blooms, or ingots.
- the cast preforms are reheated to between about 1 ,400°F and about 2,300°F and hot rolled to provide a steel bar having a desired diameter.
- the preforms are heated to at least about 2,000°F, and generally to less than about
- the steel bar will be further processed before arriving at the final cylinder rod product. Accordingly, the diameter of the steel bar is slightly larger than the diameter of the cylinder rod because it is expected that the surface will be processed to provide a precision sized cylinder rod.
- the preforms are hot rolled to provide a steel bar having a diameter of between about VA inch and about 4 or 4 Vi inches.
- the steel bar is cooled, and the resulting cooled steel bar can be referred to as "as-hot rolled bar.”
- as-hot rolled bar is cooled at least enough to provide the bar with a black color on its surface. In general, this corresponds to a surface temperature below about 1,100° F.
- the step of cooling can include controlled cooling which is a technique generally recognized in the industry for producing bar steel.
- the as-hot rolled bar is preferably heat treated.
- the heat treatment generally includes heating the as-hot rolled bar to a temperature of between about 500°F and about 1300°F.
- the as-hot rolled bar is heated to a temperature of between about 550°F and about 1250°F, and more preferably between about 1000°F and about 1100°F.
- the length of time provided at this temperature generally depends on the diameter of the as-hot rolled bar and the furnace type.
- Conventional furnaces include gas fired furnaces and induction furnaces. For a conventional gas fired furnace, it is generally desirable to expose the as-hot rolled bar to an environment having the temperature identified above for 40 minutes per inch of diameter.
- the as-hot rolled bar having a diameter of between about 3 / inch and about 4 inches
- the length of time for heat treating can be as low as two minutes. Accordingly, the step of heat treating can take place for between about two minutes and about 12 hours depending upon the temperature of the environment, the type of furnace, and the diameter of the as-hot rolled bar.
- the amount of heat treatment is conducted for a length of time and at a temperature to provide desired elongation and reduction of area properties while maintaining desired tensile strength and yield strength properties.
- the heat treated, as-hot rolled bar can be referred to as bar product.
- the bar product can be further processed to provide cylinder rods which can be used in hydraulic cylinders. Exemplary processing steps include turning, grinding, and polishing to provide a precision size.
- the surface is preferably finished, surface hardened, and chrome plated.
- An exemplary surface hardening technique which can be practiced includes nitriding or nitrogen surface-hardening.
- the invention can be practiced without the cold drawing operation provided by the prior art. By eliminating the cold drawing operation, a significant reduction in the cost of manufacturing the cylinder rod can be provided.
- the hydraulic piston cylinder 10 includes a cylinder housing 12 and a cylinder rod or piston 14.
- the cylinder housing 12 provides an internal area 13.
- the cylinder rod or piston 14 is constructed for sliding within the opening 16 of the cylinder housing 12.
- the cylinder rod 14 is shown having a first end 20 and a second end 22.
- the first end 20 slides within the opening 16.
- the first end 20 includes threads 26 for attachment to a saddle.
- the saddle can be welded to the first end 20.
- the second end 22 generally slides within the cylinder housing 12.
- a piston 30 can be provided with seals 32 at the second end 22.
- the housing 12 preferably includes head securing screws 34 or some other mechanism for attachment to a substrate.
- microalloyed bar steel A was prepared according to the chemistry shown in Table 1. The amounts of each component identified in Table 1 is provided on a weight percent basis.
- the chemistry of the microalloyed bar steel A satisfies the requirements of grade C1045 according to ASTM A 311, and includes the addition of microalloying elements columbium (niobium) and vanadium. Nitrogen was also added above typical Electric Arc Furnace levels to enhance the strengthening effect of the vanadium addition.
- the balance of microalloyed bar steel A is iron.
- Microalloyed bar steel A was continuously cast to form 5-1/2" square billets, and hot rolled to a number of bar sizes to determine the hot rolled mechanical properties prior to heat treating.
- the bars were cooled separately on a moveable notch hotbed until they were below the coarsening temperature of the microalloy constituents.
- Figure 2 illustrates the effect of heat treating on yield strength and reduction of area.
- the as-hot rolled bars rolled to 1-9/16" round sections had yield strengths of 109 ksi, which is well above the 100 ksi minimum required by ASTM A 311, Class B.
- the reduction in area (RA) was 19% which is well below the 25% minimum required by ASTM A 311 , Class B.
- Heat treating curves in the small furnace were used for reference. North Star Saint Paul has a 60 ft., reciprocating hearth furnace with a 60,000 ton capacity. An evaluation lot of 1 9/16 rd. produced in the furnace was initially heat treated at 1050° F based on the heat treating curves obtained in the lab. The reduction in area at that temperature was below the 25% minimum required by ASTM A 311, Class B. 1100° F was provided to bring the reduction of area to 27%, with minimal loss in yield strength. Additional heat treating may have further increased the reduction of area (RA), but it is expected that strength would have dropped as Figure 2 suggests.
- RA reduction of area
- microalloyed steels according to the invention achieve their mechanical property characteristics from the interaction of the chemical composition and thermo-mechanical processing.
- the microalloyed steel bars according to the invention exhibit higher strength in the as rolled condition in comparison to standard plain carbon or many low alloy steel bars.
- Example 2 Microalloyed bar steel B-F were prepared having the chemistry identified in Table 2. The components are provided on a weight percent basis, and the balance of the microalloyed bar steel is iron. The microalloyed bar steel was hot rolled to provide a steel bar having a diameter of 1-9/16 inches. The resulting properties of yield strength, tensile strength, percent elongation and percent reduction of area for the steel bars are reported in Table 2. The properties reported in Table 2 are for the steel bars prior to heat treatment according to the invention.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Heat Treatment Of Steel (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2001229609A AU2001229609A1 (en) | 2000-02-15 | 2001-01-18 | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
CA002400286A CA2400286A1 (en) | 2000-02-15 | 2001-01-18 | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
EP01953019A EP1261748A4 (en) | 2000-02-15 | 2001-01-18 | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
JP2001559893A JP2003522836A (en) | 2000-02-15 | 2001-01-18 | Bar-shaped product, cylinder rod, hydraulic cylinder, and method of manufacturing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/504,287 US6395109B1 (en) | 2000-02-15 | 2000-02-15 | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
US09/504,287 | 2000-02-15 |
Publications (1)
Publication Number | Publication Date |
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WO2001061057A1 true WO2001061057A1 (en) | 2001-08-23 |
Family
ID=24005622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US2001/001691 WO2001061057A1 (en) | 2000-02-15 | 2001-01-18 | Bar product, cylinder rods, hydraulic cylinders, and method for manufacturing |
Country Status (6)
Country | Link |
---|---|
US (1) | US6395109B1 (en) |
EP (1) | EP1261748A4 (en) |
JP (1) | JP2003522836A (en) |
AU (1) | AU2001229609A1 (en) |
CA (1) | CA2400286A1 (en) |
WO (1) | WO2001061057A1 (en) |
Cited By (2)
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DE102007021101A1 (en) * | 2007-05-03 | 2008-11-06 | Mahle International Gmbh | Alloy steel and its use |
EP2634279A1 (en) * | 2010-10-27 | 2013-09-04 | Nippon Steel & Sumitomo Metal Corporation | Steel for surface hardening for machine structural use, and steel component for machine structural use and process for producing same |
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JP2002363770A (en) * | 2001-06-06 | 2002-12-18 | Exedy Corp | Surface treatment method for fulcrum portion of diaphragm spring and metal plate to be slid therewith |
JP3748425B2 (en) * | 2002-09-04 | 2006-02-22 | パーカー熱処理工業株式会社 | Salt bath nitriding method for metal members with enhanced corrosion resistance |
JP4332003B2 (en) * | 2003-09-22 | 2009-09-16 | トヨタ自動車株式会社 | Oil-tight chain tensioner |
DE102004022248B4 (en) * | 2004-05-04 | 2007-06-14 | Zf Friedrichshafen Ag | Process for the production of balls or ball segments, as well as subsequently manufactured ball element for two-part ball studs |
US8182617B2 (en) | 2010-10-04 | 2012-05-22 | Moyer Kenneth A | Nitrogen alloyed stainless steel and process |
KR102319985B1 (en) * | 2019-08-23 | 2021-11-02 | 일진제강(주) | Method for Manufacturing Cylinder Tube for Hydraulic Cylinder |
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- 2001-01-18 JP JP2001559893A patent/JP2003522836A/en not_active Withdrawn
- 2001-01-18 EP EP01953019A patent/EP1261748A4/en not_active Withdrawn
- 2001-01-18 WO PCT/US2001/001691 patent/WO2001061057A1/en not_active Application Discontinuation
- 2001-01-18 AU AU2001229609A patent/AU2001229609A1/en not_active Abandoned
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007021101A1 (en) * | 2007-05-03 | 2008-11-06 | Mahle International Gmbh | Alloy steel and its use |
EP2634279A1 (en) * | 2010-10-27 | 2013-09-04 | Nippon Steel & Sumitomo Metal Corporation | Steel for surface hardening for machine structural use, and steel component for machine structural use and process for producing same |
EP2634279A4 (en) * | 2010-10-27 | 2015-03-25 | Nippon Steel & Sumitomo Metal Corp | Steel for surface hardening for machine structural use, and steel component for machine structural use and process for producing same |
Also Published As
Publication number | Publication date |
---|---|
EP1261748A4 (en) | 2004-12-15 |
EP1261748A1 (en) | 2002-12-04 |
CA2400286A1 (en) | 2001-08-23 |
US6395109B1 (en) | 2002-05-28 |
AU2001229609A1 (en) | 2001-08-27 |
JP2003522836A (en) | 2003-07-29 |
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