WO2000050371A3 - Procede et composition pour l'hydroxylation de substrats aromatiques - Google Patents

Procede et composition pour l'hydroxylation de substrats aromatiques Download PDF

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Publication number
WO2000050371A3
WO2000050371A3 PCT/US2000/002440 US0002440W WO0050371A3 WO 2000050371 A3 WO2000050371 A3 WO 2000050371A3 US 0002440 W US0002440 W US 0002440W WO 0050371 A3 WO0050371 A3 WO 0050371A3
Authority
WO
WIPO (PCT)
Prior art keywords
composition
hydroxylation
aromatic substrates
oxygen
catalyst
Prior art date
Application number
PCT/US2000/002440
Other languages
English (en)
Other versions
WO2000050371A2 (fr
Inventor
Terence Michael Barnhart
Original Assignee
Gen Electric
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gen Electric filed Critical Gen Electric
Priority to EP00905873A priority Critical patent/EP1154975B1/fr
Priority to JP2000600956A priority patent/JP2002537368A/ja
Priority to AT00905873T priority patent/ATE267157T1/de
Priority to DE60010867T priority patent/DE60010867T2/de
Publication of WO2000050371A2 publication Critical patent/WO2000050371A2/fr
Publication of WO2000050371A3 publication Critical patent/WO2000050371A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/58—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of molecular oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé et une composition pour l'oxydation de substrats aromatiques en présence d'oxygène, d'un catalyseur, d'une source de protons et d'un réducteur non gazeux. Selon un mode de réalisation préféré de l'invention, on oxyde du benzène en phénol en présence d'oxygène, de vanadyle comme catalyseur, d'acide trifluoroacétique comme source de protons et de ferrocene comme réducteur. Le procédé selon l'invention est économique, sûr et peut faire l'objet d'une mise à l'échelle commerciale.
PCT/US2000/002440 1999-02-26 2000-01-31 Procede et composition pour l'hydroxylation de substrats aromatiques WO2000050371A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP00905873A EP1154975B1 (fr) 1999-02-26 2000-01-31 Procede et composition pour l'hydroxylation de substrats aromatiques
JP2000600956A JP2002537368A (ja) 1999-02-26 2000-01-31 芳香族基質のヒドロキシル化方法及び組成物
AT00905873T ATE267157T1 (de) 1999-02-26 2000-01-31 Verfahren und zusammensetzung zur hydroxylierung von aromatischen verbindungen
DE60010867T DE60010867T2 (de) 1999-02-26 2000-01-31 Verfahren und zusammensetzung zur hydroxylierung von aromatischen verbindungen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/259,653 1999-02-26
US09/259,653 US6232510B1 (en) 1999-02-26 1999-02-26 Method and composition for hydroxylation of aromatic substrates

Publications (2)

Publication Number Publication Date
WO2000050371A2 WO2000050371A2 (fr) 2000-08-31
WO2000050371A3 true WO2000050371A3 (fr) 2000-12-14

Family

ID=22985814

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/002440 WO2000050371A2 (fr) 1999-02-26 2000-01-31 Procede et composition pour l'hydroxylation de substrats aromatiques

Country Status (6)

Country Link
US (2) US6232510B1 (fr)
EP (1) EP1154975B1 (fr)
JP (1) JP2002537368A (fr)
AT (1) ATE267157T1 (fr)
DE (1) DE60010867T2 (fr)
WO (1) WO2000050371A2 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1186125C (zh) * 2002-06-18 2005-01-26 中国科学院成都有机化学研究所 用于氧化偶联萘酚的手性催化剂
RU2333229C2 (ru) * 2003-06-24 2008-09-10 Ниппон Шокубаи Ко., Лтд. Водопоглощающая композиция на основе смол, способ ее изготовления (варианты), поглотитель и поглощающее изделие на ее основе
CN102452901B (zh) * 2010-10-27 2014-01-15 中国科学院大连化学物理研究所 一种苯直接羟基化制苯酚的方法
WO2015177899A1 (fr) * 2014-05-22 2015-11-26 東芝三菱電機産業システム株式会社 Procédé de formation en film de couche tampon et couche tampon

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0097551A1 (fr) * 1982-06-21 1984-01-04 Institut Français du Pétrole Utilisation de complexes péroxydiques du vanadium, du niobium et du tantale comme réactifs et comme catalyseurs d'hydroxylation des hydrocarbures aromatiques
US4982015A (en) * 1989-09-26 1991-01-01 Shell Oil Company Process for the oxidation of benzene to phenol
JPH06256242A (ja) * 1993-03-10 1994-09-13 Tosoh Corp 芳香族化合物の水酸化方法
EP0638536A1 (fr) * 1993-08-10 1995-02-15 Tosoh Corporation Procédé de préparation de phénols
US5952532A (en) * 1997-07-31 1999-09-14 Sunoco, Inc. Hydroxylation of aromatics using molecular oxygen as the terminal oxidant without coreductant

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3441617A (en) * 1966-03-15 1969-04-29 Lummus Co Oxidation of aromatic compounds
US3804906A (en) 1966-07-25 1974-04-16 Ici Ltd Oxidation of organic compounds
US3453332A (en) 1967-11-29 1969-07-01 Universal Oil Prod Co Hydroxylation of aromatic compounds
US3699175A (en) * 1970-01-09 1972-10-17 Shell Oil Co Hydroxylation of aromatics
US4078918A (en) * 1976-11-26 1978-03-14 Perman Craig A Method for precious metal recovery
US4692546A (en) * 1984-07-24 1987-09-08 Celanese Corporation Process for producing acyloxy aromatic carboxylic acids
US4861911A (en) * 1985-07-01 1989-08-29 The Standard Oil Company Process for oxidation of benzene to phenol precursor
US5180871A (en) 1987-11-11 1993-01-19 Mitsui Petrochemical Industries, Ltd. Process for producing phenols
FR2630733B1 (fr) 1988-05-02 1990-07-20 Rhone Poulenc Chimie Procede de preparations du phenol
US5110995A (en) 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives
US5233097A (en) 1992-10-15 1993-08-03 Uop Oxidation of aromatics to hydroxyaromatics using aluminosilicates containing framework titanium
JPH07223984A (ja) * 1994-02-09 1995-08-22 Kemipuro Kasei Kk フェノール類の製造方法
JP3549234B2 (ja) * 1994-03-18 2004-08-04 三井化学株式会社 キノン類、フェノール類およびそのカルボン酸エステル類の製造方法
RU2058286C1 (ru) 1994-04-12 1996-04-20 Институт катализа им.Г.К.Борескова СО РАН Способ получения фенола или его производных
US5591270A (en) * 1995-07-31 1997-01-07 Corpex Technologies, Inc. Lead oxide removal method
US5912391A (en) * 1997-11-17 1999-06-15 General Electric Company Method for hydroxylating aromatic compounds

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0097551A1 (fr) * 1982-06-21 1984-01-04 Institut Français du Pétrole Utilisation de complexes péroxydiques du vanadium, du niobium et du tantale comme réactifs et comme catalyseurs d'hydroxylation des hydrocarbures aromatiques
US4982015A (en) * 1989-09-26 1991-01-01 Shell Oil Company Process for the oxidation of benzene to phenol
JPH06256242A (ja) * 1993-03-10 1994-09-13 Tosoh Corp 芳香族化合物の水酸化方法
EP0638536A1 (fr) * 1993-08-10 1995-02-15 Tosoh Corporation Procédé de préparation de phénols
US5952532A (en) * 1997-07-31 1999-09-14 Sunoco, Inc. Hydroxylation of aromatics using molecular oxygen as the terminal oxidant without coreductant

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 129, no. 15, 12 October 1998, Columbus, Ohio, US; abstract no. 188970a, YAMANAKA I ET AL: "Oxidation of methane and benzene with oxygen catalyzed by reduced vanadium species at 40°C" page 630; column 1; XP002901199 *
J. MOL. CATAL. A: CHEM., vol. 133, no. 3, 1998, pages 251 - 254 *
PATENT ABSTRACTS OF JAPAN vol. 018, no. 656 (C - 1286) 13 December 1994 (1994-12-13) *

Also Published As

Publication number Publication date
DE60010867T2 (de) 2006-09-07
JP2002537368A (ja) 2002-11-05
US20010003139A1 (en) 2001-06-07
DE60010867D1 (de) 2004-06-24
EP1154975B1 (fr) 2004-05-19
ATE267157T1 (de) 2004-06-15
US6232510B1 (en) 2001-05-15
WO2000050371A2 (fr) 2000-08-31
US6323378B2 (en) 2001-11-27
EP1154975A2 (fr) 2001-11-21

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