WO2000042163A1 - Detergent pour pulverisateur - Google Patents

Detergent pour pulverisateur Download PDF

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Publication number
WO2000042163A1
WO2000042163A1 PCT/JP1999/001536 JP9901536W WO0042163A1 WO 2000042163 A1 WO2000042163 A1 WO 2000042163A1 JP 9901536 W JP9901536 W JP 9901536W WO 0042163 A1 WO0042163 A1 WO 0042163A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning agent
spray
detergent
cleaner
weight
Prior art date
Application number
PCT/JP1999/001536
Other languages
English (en)
Japanese (ja)
Inventor
Yoshiumi Hamada
Jiro Kakumoto
Original Assignee
Nissin Medico Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissin Medico Co., Ltd. filed Critical Nissin Medico Co., Ltd.
Priority to AU29579/99A priority Critical patent/AU2957999A/en
Publication of WO2000042163A1 publication Critical patent/WO2000042163A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines

Definitions

  • the present invention relates to an improvement in a cleaning agent for spraying which is used by being sprayed on metal fins and cutting blades of an electric shaving machine in an air conditioner such as an air conditioner.
  • the present invention has been proposed in view of the above circumstances. Immediately after spraying, it has a sufficient detergency, and after spraying, there is very little risk of metal corrosion such as metal fins. Provide a spray cleaner that does not require any work. Disclosure of the invention The present invention relates to a water-based spray detergent, wherein the detergent contains a surfactant and a volatile alkaline component, and contains the volatile alkaline component. Is a spray cleaner which is alkaline and becomes neutral due to volatilization of the alkaline component. BEST MODE FOR CARRYING OUT THE INVENTION
  • the cleaning agent of the present invention is a water-based cleaning agent for spraying.
  • the detergent contains a surfactant and a volatile alkaline component, and contains the volatile alkaline component, so that the detergent becomes alkaline and volatilizes the alkaline component. Is neutral.
  • the cleaning agent of the present invention includes an alkaline component having volatility, thereby making the cleaning agent alkaline and evaporating the alkaline component when used.
  • the cleaning agent of the present invention is water-based, contains a surfactant, an oil, a lower alcohol, and a liquefied gas for aerosol, and is a spray sealed in a container with a jet nozzle. It is a formula cleaner.
  • the surfactant concentration in the spray-type cleaning agent is 2% by weight or less, and the cleaning agent is unstable in emulsification and generates foam that is not persistent when sprayed. .
  • the above alkaline component is included in the cleaning agent in a neutral state, so that the cleaning agent is neutralized with volatilization of the alkaline component. Is done.
  • the detergent contains a PH indicator, which allows the color of the detergent to change as the detergent changes from alkaline to neutral.
  • neutral J refers to an alkaline detergent colored with a PH indicator. Means the state in which the color changes.
  • Examples of the volatile alcohol component used in the present invention include ammonia water, morpholine, amino alcohol, and fatty acid amine. These are included in a neutral detergent based on water, so that the pH of the detergent can be increased to 8 or more, and the detergent can be made alkaline. In addition, these substances have good volatility, and when used by spraying in a neutral detergent, volatilize from the detergent in a short time, and the detergent after volatilization becomes neutral. Become. In addition, the amount of these components is such that when the cleaning agent is included in the cleaning agent and sprayed onto the object to be cleaned, the cleaning agent remains in the cleaning agent for a period of time during which the object to be cleaned can be washed, and the cleaning agent can be maintained alkaline.
  • the cleaning agent can be volatilized from the cleaning agent within the time until the sprayed cleaning agent causes metal corrosion. More specifically, the amount of the alkaline component is preferably in the range of about 0.01 to 10% by weight of the entire cleaning agent, and when the amount is less than 0.01% by weight, it is included in the cleaning agent and sprayed. Then, by about 5 seconds, the cleaning agent volatilizes from the cleaning agent and becomes neutral, which makes it difficult to sufficiently clean the cleaning agent and to exert the cleaning effect. on the other hand,
  • cleaning agent of the present invention may also be added to p H indicator as described above 0
  • the PH indicator used in the cleaning agent of the present invention is for visually determining whether or not the cleaning agent has an alkaline property.
  • a neutral detergent By adding this pH indicator together with the above-mentioned alkaline component to a neutral detergent, the detergent that has been rendered alkaline by the alkaline component is brought into a state of exhibiting a unique color, The color of the cleaning agent after the neutral component volatilizes and becomes neutral can be changed, and the neutral can be determined at a glance.
  • the PH indicator those generally used widely as alkaline indicators can be used, and examples thereof include phenol phthalate, thymol blue, phenol red, cresol red, tropeolin, and thymol phthalein. Can be mentioned.
  • the color of the detergent becomes reddish purple when the detergent is alkaline, but the color changes to colorless when the detergent becomes neutral.
  • thymol blue when used, when the detergent is alkaline, it exhibits a blue color, but when it becomes neutral, it changes to yellow.
  • the alkaline component in the cleaning agent volatilizes when the cleaning agent is used, and the cleaning agent becomes neutral. Not only can users see at a glance that they have become unsafe, but they can also give users a sense of security and increase their product value.
  • the PH indicator may be included as needed, and may be used even if it is not included.
  • the detergent containing the alcohol component and the PH indicator can be used as long as it is neutral based on water.
  • a detergent containing a surfactant, linemon, alcohol, etc. may be used.
  • the detergent containing the alkaline component and the PH indicator may be composed of only water, or may be composed of only water and include the alkaline component or the PH indicator together with the alkaline component. It can be made to have detergency by the strong power component.
  • the cleaning agent of the present invention containing an alkaline component is preferably enclosed in an aerosol container together with a propellant gas and used as an aerosol.
  • a cleaning agent when a cleaning agent is sprayed alone without being used together with a propellant gas, the alcoholic components in the sprayed cleaning agent volatilize, but the sprayed cleaning agent is not used.
  • the particles are relatively large, it is difficult to volatilize the volatile components inside the particles, and it takes time to volatilize.
  • the cleaning agent is sealed in the aerosol container together with the propellant gas, and the cleaning agent is propelled together with the propellant gas during use, the propellant gas mixed in the cleaning agent volatilizes, resulting in a reduction in the power of the cleaning agent.
  • the volatile components are volatilized with the volatilization of the gas for injection, so that the volatile components can be easily volatilized. Therefore, even when the cleaning agent becomes relatively large particles, the mixed components can be efficiently volatilized when the mixed injection gas is volatilized, and can be volatilized in a short time.
  • liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, carbon dioxide gas, chlorofluorocarbon 134a, etc., or a mixture thereof can be used as the injection gas.
  • the cleaning agent of the present invention combines a cleaning action by a surfactant, alkalinity, and the like, a physical cleaning action by a spraying force of a spray, and a cleaning action by a non-persistent foaming action, so that the surfactant can be used. Even at low concentrations, it is a detergent with sufficient detergency. In the detergent of the present invention, there is no foam remaining after application, and there is no need for a washing operation.
  • the cleaning agent of the present invention is effective for cleaning metal, wood, and plastic surfaces, and is particularly effective for metal surfaces. Furthermore, it is effective for cleaning metal products or metal components that have narrow gaps and are difficult to disassemble. Specifically, cutting of aluminum fins (aluminum heat exchangers) for vacant facilities (especially household air conditioners), cutting blades for electric shaving machines (fin-shaped cutting blades), punches, dies, taps, etc. It is effective for tools, scissors, clippers and other hand tools, brass instruments, watches, and guns.
  • the detergent of the present invention preferably contains oil and is unstable in emulsification. Further, it is preferable that the detergent produce foam that is not persistent when sprayed.
  • the surfactant concentration is less than 2% by weight. In other words, non-persistent foaming can be said to be foaming in which the time until foam break is extremely short. For this reason, even if foaming is temporary, Does not persist and is defoamed, so no foam remains.
  • the concentration of the surfactant in the detergent is preferably 0.5 to 1.5% by weight, and the concentration of the surfactant in the detergent component excluding the liquefied gas for aerosol is 0.5 to 3% by weight. %, Preferably 0.7 to 2% by weight.
  • the surfactant is preferably a nonionic surfactant. Any nonionic surfactant may be used, but polyoxyethylene alkyl phenyl ethers having an alkyl group such as octyl, nonyl, dodecyl, etc., octyl, lauryl, cetyl, stearyl, or oleyl.
  • Fatty acid monoglycerides sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan distearate Ether, sorbitan tristearate, Sorubitanmo Sorbitan fatty acid esters such as oleic acid sorbate and sorbitan trioleate, polyoxyethylene lauric acid amide, polyoxyethylene stearic acid amide, and polyoxyethylene oleic acid amide
  • Polyoxyethylene fatty acid amides polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, and the like can be used.
  • polyoxyethylene alkylphenyl ethers polyoxyethylene alkyl ethers, polyoxyethylene alkyl ethers, polyoxyethylene sorbitan fatty acid esters, and polyoxyethylene castor oil are preferred, and a mixture thereof is particularly preferred.
  • polyoxyethylene alkylphenyl ethers, polyoxyethylene alkyl ethers, or a mixture of polyoxyethylene castor oil and polyoxyethylene sorbitan fatty acid esters are preferred.
  • a combination of polyoxyethylene nonylphenyl ester and coconut oil fatty acid polyoxyethylene sorbitan, a combination of polyoxyethylene castor oil and polyoxyethylene sorbitan monolaurate, a polyoxyethylene nonylphenyl Combinations of ether and polyoxyethylene sorbitan monolaurate are preferred.
  • the oil component limonene or a hydrocarbon oil is preferable.
  • the concentration of limonene in the detergent component is 1 to 3% by weight, preferably 1 to 2% by weight.
  • the concentration of limonene in the detergent component excluding the liquefied gas for aerosol is 1 to 3% by weight, preferably 1 to 2.5% by weight.
  • any of orange oil (D-limonene), dipentene and the like can be used, but liorogene oil is preferable because it has an aroma for orange peel.
  • isoparaffin-based hydride oil is preferable.
  • concentration of the J-hydrogen oil in the detergent component is 3 to 8% by weight, preferably 4 to 7% by weight, and the cleaning composition excluding the liquefied gas for aerosol.
  • concentration of hydrogen peroxide oil in the mixture is 4 to 10% by weight, preferably 5 to 8% by weight.
  • Hydrogen fluoride oil is used at room temperature. Usually, those having about 7 to 15 carbon atoms are used.
  • Isoparaffinic S-hydrogen oil is a hydrogen peroxide oil produced by polymerizing monoolefin gas having 3 to 5 carbon atoms and hydrogenating unsaturated bonds.
  • Limonene and isoparaffinic hydrocarbon oils are so-called oil components, and have an action of adhering to metal surfaces to float dirt and an action of defoaming bubbles caused by a surfactant.
  • both (particularly isoparaffinic hydrocarbon oils) exert a protective effect on the metal surface after cleaning.
  • lower alcohols may be added to the cleaning agent.
  • lower alcohols methyl alcohol, ethyl alcohol, ethylene glycol, and cellosolve solvents are used.
  • a mixture of ethyl alcohol and ethylene glycol or a mixture of ethyl alcohol and cellosolve is preferred.
  • Ethylene glycol and cellosolve have the effect of increasing the viscosity of the detergent composition to increase the detergency, and the effect of improving the dispersibility of the detergent composition and the liquefied gas for aerosol.
  • cellosolve is effective.
  • ethylene glycol monobutyl ether As cellosolve, ethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol monomethyl ether, and the like can be used, and ethylene glycol monobutyl ether is particularly preferable.
  • the most preferred lower alcohols are mixtures of ethylene glycol and ethylene glycol monobutyl ether. Ethyl alcohol improves the affinity between the oil component limonene, the isoparaffinic hydrogen peroxide oil, and the surfactant.
  • the pH of the detergent composition containing the volatile alkaline moiety is preferably from 8 to 13, and more preferably from 9 to 12.
  • the pH of the cleaning agent excluding the volatile alkaline portion is 6 to 8, preferably 6.5 to 7.5. You.
  • the detergent composition excluding the liquefied gas for aerosol is adjusted by adding a predetermined amount to each of the water to the above-mentioned concentrations. Specifically, with respect to 100 parts by weight of water, 0.5 to 3 parts by weight (preferably, 1 to 2 parts by weight) of a nonionic surfactant, and 0.01 to 3 parts by weight of an alkaline substance. Parts (preferably 0.05 to 0.5 parts by weight), lower alcohols 5 to 30 parts by weight
  • a pH adjuster may be added to the detergent composition.
  • Alkali metal compounds such as sodium and potassium, alkanolamines such as monoethanolamine, diethanolamine and triethanolamine, and alkaline substances such as aqueous ammonia are used as pH adjusters. You.
  • a conventional aerosol container such as a tin can or an aluminum can is used, and a container having a capacity of about 30 OmI is preferable.
  • the detergent composition except for the liquefied gas for aerosol prepared as described above is filled in a container, and a button for aerosol is attached to an opening of the container and sealed. Then, the liquefied gas for nozzle aerosol of the button is injected into the container filled with the cleaning composition.
  • liquefied gas for aerosol liquefied petroleum gas (LPG), dimethyl ether (DME), nitrogen gas, sulfuric acid gas, chlorofluorocarbon 134a or a mixture thereof can be used.
  • LPG liquefied petroleum gas
  • DME dimethyl ether
  • nitrogen gas sulfuric acid gas
  • a mixture a mixture of LPG and DME
  • a mixture of LPG and carbon dioxide can be used.
  • liquefied petroleum gas liquefied propane gas, liquefied butane gas, liquefied pentane gas and the like are used.
  • a mixture of liquefied propane gas and liquefied butane gas is preferable because a high internal pressure can be formed.
  • the liquefied gas for aerosol is added so that the amount of the detergent containing the liquefied gas for aerosol is 10 to 40% by weight, preferably 20 to 35% by weight, and the water temperature is 35 ° C. of the internal pressure in the container in HitaKiyoshi the state the bath is, 6 kg Roh cm 2 or more (6 ⁇ 8 kg / cm 2) , preferably, 6. 5 kg / cm 2 or more (6. 5 ⁇ 8 kgcm 2 ).
  • An injection nozzle is attached to the nozzle of the button of the container into which the liquefied gas for aerosol has been injected as described above.
  • An injection nozzle having a low-diffusion nozzle tip is used.
  • the low-diffusion nozzle tip is provided with an injection channel that extends to the tip with almost the same inner diameter (in other words, hardly increases in diameter toward the tip).
  • "Quick sprayer" manufactured by the Precision Valve Co., Ltd. can be suitably used.
  • the principle of the cleaning action of the cleaning agent of the present invention is considered as follows. Since the detergent of the present invention has a low surfactant content, it does not become emulsifiable even if it contains an oil component, and can be temporarily and to some extent dispersed by stirring. The so-called emulsification is unstable. Therefore, the cleaning agent sprayed from the spray nozzle separates in the air before adhering to the object to be cleaned, the surfactant is in a foam state, and the oil adheres to the object without foaming . The oil reaches the oil earlier than the air resistance, and forms an oil film on the surface of the object to be cleaned. To reach it, the dirt is physically pushed to some extent by the force of the collision.
  • the foam that arrives at the point where the oil has adhered to the surface and the contact angle is high cannot be kneaded, and almost all bubbles disappear in a few seconds to several tens of seconds. Due to the vibration generated when the bubbles disappear, dirt on the surface to be cleaned is easily peeled off. The oil-soluble dirt on the surface of the object to be cleaned, which has become easy to peel off due to the vibration when the bubbles disappear, is re-swelled by the oil adhering to the surface and floats up. The surface of the object to be cleaned is cleaned by being blown off by the sprayed cleaning agent. Therefore, the surface of the object to be cleaned can be cleaned by spraying the cleaning agent of the present invention for a certain period of time. As described above, since the bubbles disappear in about several tens of seconds, there is no need to wash away the bubbles, and since the concentration of the surfactant is sufficiently low, washing with water is unnecessary.
  • a surfactant (0.9% by weight of polyoxyethylene nonylphenyl ether, 0.1% by weight of polyoxyethylene sorbitan monolaurate), 1% by weight of limonene, 20% by weight of ethanol, and water
  • a water-based neutral detergent with a pH of 6.5 was manufactured, and this was used as an alkaline component.
  • Aqueous ammonia 0.1% S% was added.
  • the pH of the detergent after adding 28% ammonia water was 10.3. Further, a few drops of phenolphthalein as a PH indicator were added thereto to obtain a red-purple cleaning agent of the present invention.
  • the obtained cleaning agent was filled into an aerosol container equipped with a low-diffusion nozzle tip together with liquefied petroleum gas as a propellant gas to form an aerosol.
  • this cleaning agent was sprayed onto the metal fins of the air conditioning equipment, it initially turned red-purple, but after 5 to 10 seconds it became colorless and the cleaning agent became neutral. At a glance, I understood. (Example 2)
  • 1% by weight of surfactant (0.9% by weight of polyoxyethylene nonylphenyl ether, 0.1% by weight of polyoxyethylene sorbitan monolaurate), 1% by weight of limonene and 20% by weight of ethanol
  • 1% by weight of morpholine as an alkaline component was added to a neutral detergent having a pH of 6.5 based on water.
  • the pH of the detergent after the addition of morpholine was 10.5.
  • several drops of thymol blue as a pH indicator were added thereto, and a blue-colored cleaning agent of the present invention was obtained.
  • the obtained cleaning agent was filled into an aerosol container equipped with a low-diffusion nozzle tip together with liquefied petroleum gas as a jetting gas to obtain an aerosol.
  • this cleaning agent was sprayed on the metal fins of the air conditioner, it initially turned blue, but turned yellow 30 to 40 seconds later, and the cleaning agent became neutral. At a glance, I understood.
  • a water-based PH 6.5 containing 1% by weight of a surfactant, 1% by weight of limonene, 20% by weight of ethanol, and water as neutral detergents was used.
  • the cleaning agent of the present invention was prepared by using a neutral cleaning agent having a pH of 6.5 based on the water and adding 0.1% by weight of 28% ammonia water. These were filled into an aerosol container, half of each was sprayed on the metal fins of a dirty air conditioner, and the color of the liquid flowing out was visually compared to observe the stain removal.
  • the cleaning agent containing no alkaline component turned into a light brown liquid
  • the cleaning agent of the present invention turned into a dark brown liquid.
  • the alkaline cleaning agent containing an alkaline component of the present invention is more effective in neutral cleaning containing no alkaline component. It was confirmed that the detergency was high compared to the comparative example.
  • Surfactant 0.5% by weight polyoxyethylene castor oil 0.45% by weight; polyoxyethylene sorbitan monolaurate 0.05 part by weight
  • isoparaffinic hydrocarbon oil manufactured by Idemitsu Petrochemical Co., Ltd.
  • IP 1620 isoparaffinic hydrocarbon oil 1% by weight, 20% by weight of ethanol, 0.1% by weight of sodium nitrite and water with a water-based neutral detergent PH 6.5 It was manufactured, and 0.1% by weight of 28% ammonia water as an alkaline component was added thereto.
  • the pH of the cleaning agent after adding 28% aqueous ammonia was 10.3. Furthermore, 0.003 parts by weight of phenolphthalein as a pH indicator was added thereto to obtain a red-purple cleaning agent of the present invention.
  • the obtained cleaning agent was charged into an aerosol container equipped with a low-diffusion nozzle tip together with liquefied petroleum gas as a jetting gas to obtain an aerosol.
  • this cleaning agent was sprayed onto the metal fins of the air conditioning equipment, it initially turned red-purple, but became colorless after 5 to 10 seconds, and the cleaning agent became neutral. I saw it.
  • a surfactant (0.4% by weight of polyoxyethylene nonylphenyl ether, 0.05% by weight of polyoxyethylene sorbitan monolaurate) and an isoparaffin hydrocarbon oil (Idemitsu Petrochemical Co., Ltd.) IP 1620) 1% by weight, ethanol 20% by weight, sodium nitrite 0.1% S%, and water-based neutralized PH 6.5
  • IP 1620 isoparaffin hydrocarbon oil
  • phenolphthalein as a PH indicator was added thereto to obtain a cleaning agent of the present invention exhibiting a reddish purple color.
  • the obtained cleaning agent was filled into an aerosol container equipped with a low-diffusion nozzle tip together with liquefied petroleum gas as a propellant gas to obtain an aerosol.
  • this detergent was sprayed onto the metal fins of the air conditioner, it initially turned red-purple, but became colorless after 5 to 10 seconds, indicating that the detergent became neutral. At a glance I understood.
  • surfactant (0.4% by weight of polyoxyethylene nonylphenyl ether, 0.05% by weight of polyoxyethylene sorbitan monolaurate) and isoparaffinic hydrocarbon oil (Idemitsu Petrochemical IP 1620) 1% by weight, 20% by weight of ethanol, 0.1% by weight of sodium nitrite and water, neutral cleaning of PH 6.5 based on water An agent was prepared, and 0.1% by weight of 28% aqueous ammonia as an alkaline component was added thereto. The pH of the cleaning agent after adding 28% aqueous ammonia was 10.3. Further, a few drops of thymol blue as a PH indicator were added thereto to obtain a blue-colored cleaning agent of the present invention.
  • the obtained detergent together with liquefied petroleum gas as a jetting gas was filled into an aerosol container equipped with a low-diffusion nozzle tip to form an aerosol.
  • this cleaning agent was sprayed onto the metal fins of the air conditioner, it initially turned blue, but turned yellow after 30 to 40 seconds, indicating that the cleaning agent became neutral. At a glance I understood.
  • each cleaning agent was spray-coated on aluminum fins of one household air conditioner that had not been cleaned for one year or more, and properties were observed.
  • foaming occurred at the time of application, but the foam immediately disappeared, and no foam was present after about 20 seconds.
  • the detergent of the present invention is alkaline immediately after spraying, it has a higher detergency than conventional neutral detergents and can instantly remove dirt.
  • the alkaline components contained in the cleaning agent can be volatilized. This reduces the danger of metal corrosion even when sprayed on metal fins of air conditioning equipment, and eliminates the need for washing after spraying.
  • the concentration of the surfactant in the detergent is set to 2% by weight or less, and the detergent contains oil and is emulsified unstable, and furthermore, when spray-applied, foaming without kneading property is generated. You may. To do this Therefore, since the detergent has a low-grade surfactant and contains an oil, there is no residual foam after application and there is no need for a washing operation. Furthermore, even when the concentration of the surfactant is low, the cleaning action by the surfactant, oil, etc., the physical cleaning action by the spraying force of the spray, and the non-sustainable foaming action, especially by the vibration when the foam disappears, It has a sufficient cleaning power because it has a composite cleaning function consisting of a cleaning function.

Abstract

L'invention concerne un détergent pour pulvérisateur, comprenant un agent tensio-actif et un composant alcalin volatil, ledit détergent étant rendu alcalin par le composant alcalin et étant rendu neutre par vaporisation de l'agent alcalin volatil. L'utilisation dudit détergent est avantageuse en ce que non seulement le détergent présente une détergence supérieure à celle d'un détergent neutre classique, immédiatement après sa pulvérisation, mais également en ce que, après un bref délai après la pulvérisation, il devient neutre par vaporisation de l'agent alcalin qu'il contient, de sorte que, lorsque ledit détergent est pulvérisé sur les ailettes métalliques d'un conditionneur d'air, il n'est pas nécessaire de procéder à un lavage à l'eau après pulvérisation car le risque de corrosion est faible.
PCT/JP1999/001536 1999-01-13 1999-03-25 Detergent pour pulverisateur WO2000042163A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU29579/99A AU2957999A (en) 1999-01-13 1999-03-25 Detergent for spray

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP11/6621 1999-01-13
JP00662199A JP2002226898A (ja) 1999-01-13 1999-01-13 スプレー用洗浄剤

Publications (1)

Publication Number Publication Date
WO2000042163A1 true WO2000042163A1 (fr) 2000-07-20

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JP (1) JP2002226898A (fr)
AU (1) AU2957999A (fr)
WO (1) WO2000042163A1 (fr)

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* Cited by examiner, † Cited by third party
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JP2014080476A (ja) * 2012-10-15 2014-05-08 Dainippon Jochugiku Co Ltd 発泡性洗剤組成物
JP2020169257A (ja) * 2019-04-03 2020-10-15 西村　直人 産業用空調機アルミフィンの洗浄剤及びその使用方法

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Publication number Priority date Publication date Assignee Title
CA2742835C (fr) * 2008-11-11 2014-07-08 Colgate-Palmolive Company Composition avec une couleur pour indiquer la surface couverte
BRPI0823277A2 (pt) 2008-11-11 2015-06-23 Colgate Palmolive Co Composição, e , método

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4736241B1 (fr) * 1968-09-30 1972-09-12
JPS4976903A (fr) * 1972-11-27 1974-07-24
JPS5358506A (en) * 1976-11-09 1978-05-26 Dainichi Seika Kogyo Kk Detergent composition
JPS62116697A (ja) * 1985-11-15 1987-05-28 ゴスペル化工株式会社 中性洗浄剤
JPH0341200A (ja) * 1989-04-21 1991-02-21 Procter & Gamble Co:The 硬質表面浄化組成物
JPH03139600A (ja) * 1989-10-25 1991-06-13 Taiho Ind Co Ltd 塗装面用の洗浄剤
JPH03199297A (ja) * 1989-11-23 1991-08-30 Procter & Gamble Co:The 硬質表面クリーニング組成物
JPH05239500A (ja) * 1991-12-11 1993-09-17 Unilever Nv 硬質表面洗浄剤の改良
JPH07258694A (ja) * 1993-10-14 1995-10-09 Kao Corp 硬質表面洗浄剤組成物
JPH08157899A (ja) * 1994-12-01 1996-06-18 Showa Kk フィン洗浄剤
JPH08259997A (ja) * 1995-03-23 1996-10-08 Lion Corp 液体洗浄剤組成物
JPH08337793A (ja) * 1995-06-13 1996-12-24 Lion Corp レンジ用洗浄剤組成物
JPH09157692A (ja) * 1995-10-04 1997-06-17 Mitsubishi Chem Corp 表面処理組成物及び基体表面処理方法
JPH10123128A (ja) * 1996-10-17 1998-05-15 Hokko Chem Ind Co Ltd 水洗トイレでの尿蛋白検査・洗浄用固形製剤およびその使用方法
JPH10152694A (ja) * 1996-11-26 1998-06-09 Taiho Ind Co Ltd 車両に起因する汚染面の洗浄剤
JPH10330792A (ja) * 1997-05-28 1998-12-15 T Paul Kk 殺菌洗浄剤組成物およびその使用方法

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4736241B1 (fr) * 1968-09-30 1972-09-12
JPS4976903A (fr) * 1972-11-27 1974-07-24
JPS5358506A (en) * 1976-11-09 1978-05-26 Dainichi Seika Kogyo Kk Detergent composition
JPS62116697A (ja) * 1985-11-15 1987-05-28 ゴスペル化工株式会社 中性洗浄剤
JPH0341200A (ja) * 1989-04-21 1991-02-21 Procter & Gamble Co:The 硬質表面浄化組成物
JPH03139600A (ja) * 1989-10-25 1991-06-13 Taiho Ind Co Ltd 塗装面用の洗浄剤
JPH03199297A (ja) * 1989-11-23 1991-08-30 Procter & Gamble Co:The 硬質表面クリーニング組成物
JPH05239500A (ja) * 1991-12-11 1993-09-17 Unilever Nv 硬質表面洗浄剤の改良
JPH07258694A (ja) * 1993-10-14 1995-10-09 Kao Corp 硬質表面洗浄剤組成物
JPH08157899A (ja) * 1994-12-01 1996-06-18 Showa Kk フィン洗浄剤
JPH08259997A (ja) * 1995-03-23 1996-10-08 Lion Corp 液体洗浄剤組成物
JPH08337793A (ja) * 1995-06-13 1996-12-24 Lion Corp レンジ用洗浄剤組成物
JPH09157692A (ja) * 1995-10-04 1997-06-17 Mitsubishi Chem Corp 表面処理組成物及び基体表面処理方法
JPH10123128A (ja) * 1996-10-17 1998-05-15 Hokko Chem Ind Co Ltd 水洗トイレでの尿蛋白検査・洗浄用固形製剤およびその使用方法
JPH10152694A (ja) * 1996-11-26 1998-06-09 Taiho Ind Co Ltd 車両に起因する汚染面の洗浄剤
JPH10330792A (ja) * 1997-05-28 1998-12-15 T Paul Kk 殺菌洗浄剤組成物およびその使用方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014080476A (ja) * 2012-10-15 2014-05-08 Dainippon Jochugiku Co Ltd 発泡性洗剤組成物
JP2020169257A (ja) * 2019-04-03 2020-10-15 西村　直人 産業用空調機アルミフィンの洗浄剤及びその使用方法

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