WO2000037735A1 - Agents de traitement pour textiles, leur procede de fabrication et leur utilisation - Google Patents

Agents de traitement pour textiles, leur procede de fabrication et leur utilisation Download PDF

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Publication number
WO2000037735A1
WO2000037735A1 PCT/EP1999/009771 EP9909771W WO0037735A1 WO 2000037735 A1 WO2000037735 A1 WO 2000037735A1 EP 9909771 W EP9909771 W EP 9909771W WO 0037735 A1 WO0037735 A1 WO 0037735A1
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Prior art keywords
weight
component
mixture
already defined
textile treatment
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PCT/EP1999/009771
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German (de)
English (en)
Inventor
Helmut-Martin Meier
Ferdinand Kümmeler
Detlev Kierspe
Jacob-Cornelis Dijks
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Bayer Aktiengesellschaft
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Priority to BR9916435-3A priority Critical patent/BR9916435A/pt
Priority to EP99964541A priority patent/EP1144749A1/fr
Priority to JP2000589780A priority patent/JP2002533581A/ja
Priority to CA002355370A priority patent/CA2355370A1/fr
Priority to AU30370/00A priority patent/AU3037000A/en
Publication of WO2000037735A1 publication Critical patent/WO2000037735A1/fr

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • Textile processing processes such as sewing or tufting, place high demands on the textile material with regard to surface smoothness.
  • High needle speeds lead to thermal and mechanical stresses on the sewing material which, if the surface is not smooth, can lead to thread breaks and stitch detonation damage. This disadvantage can be avoided by providing the textile material with a smoothing finish.
  • DE-OS 30 03 851 also describes dispersions of oxidized waxes
  • DE-OS 25 35 768 uses dispersions of polysiloxanes and hydrocarbons or fluorine-containing polymers to achieve high surface smoothness. It is also known to use fatty acid esters as lubricants together with paraffin hydrocarbons. However, such emulsions or dispersions often have the disadvantage that they are not suitable for use on jet dyeing apparatus, also called “jet systems", which work with short liquors, because the high shear forces caused by the process destroy the emulsions. This leads to creaming and staining, as well as uneven finish distribution on the textile material.
  • plasticizers usually give a pleasantly soft grip.
  • the plasticizers usually contain a long hydrophobic residue, which in turn means that the treated textiles absorb water poorly. This can be particularly annoying for towels, bathrobes and terry towels.
  • Cationic plasticizer compositions with polyhydric alcohols are known from JP 09195167 A2.
  • the use of such compounds for finishing textiles leads to poor sewability.
  • DE-OS 19 629 666 also describes the use of alkyl polyglycosides for the hydrophilic adjustment of polypropylene and polyester fibers. However, the compounds have poor whiteness, which is not acceptable for equipment.
  • DE-OS 31 38 181 also describes mixtures containing fatty acid amides.
  • the use of these substances in the finish leads to a very soft feel, but only to a poor hydrophilicity of the treated textiles.
  • the object of the present invention was therefore to provide a textile treatment agent which at the same time gives the textile material good hydrophilicity, a good soft feel and a high surface smoothness.
  • the textile treatment agent should have such a liquor stability that it can also be used on nozzle dyeing apparatus.
  • the invention relates to textile treatment agents which are characterized in that they are used as components (A) 0-30% by weight of polyalcohols which can be obtained by reacting formaldehyde with ketones which carry at least 4 replaceable hydrogens adjacent to the carbonyl group in the presence of alkaline catalysts,
  • the polyalcohols (A) are obtained by reacting formaldehyde with ketones which carry at least 4 replaceable hydrogen atoms adjacent to the carbonyl group, the reaction being carried out in the presence of alkaline catalysts.
  • the ketones preferably have the general formula (1)
  • R and R 'independently of one another represent straight-chain or branched C 1 -C 4 -alkyl, C 2 -C 2 4-alkenyl, phenyl or naphthyl radicals
  • n 0, 1, 2, 3 or 4.
  • Residues R and R ' are optionally substituted by OH, COOH or SO 3 H.
  • the phenyl or naphthyl radical can also be substituted by OH, COOH or SO 3 H.
  • Preferred radicals R and R ' are those of the formulas -CH 2 -COOH and -CH 2 -C (CH 3 ) 2 (OH).
  • Formaldehyde can be used in the form of paraformaldehyde, trioxymethylene or a formaldehyde polymer that releases formaldehyde under the reaction conditions.
  • Polyalcohols (A) according to formulas 2 (1) to 2 (8) which can be obtained via the above-mentioned reaction are particularly preferred.
  • Suitable alkaline catalysts are e.g. Oxides or hydroxides of the alkali or alkaline earth metals.
  • Alkaline earth metal hydroxides, in particular calcium hydroxide, are preferably used.
  • the polyalcohols (B) have at least two OH groups and do not fall under the definition of the polyalcohols (A).
  • Suitable polyalcohols (B) are, for example, pentaerythritol, neopentyl glycol, ethylene glycol, diethylene glycol, triethylene glycol, trimethylolpropane, glycerol, polyglycerol, dipentaerythritol, diglycerol, glucose and carbohydrates with more than 2 OH groups.
  • the ethylene oxide adducts (C) are adducts of C 2 -C 2 fatty acids or Cg-Cig fatty alcohols or C 2 -C 36 alkyl or di (C 12 -C 36 ) - alkyl amines or C 9 -C 2 4-alkylphenols with 2-100 mol ethylene oxide (see, for example, Tensid-Taschenbuch by W. Stache, 2nd edition, 1981, pp. 617-662).
  • Particularly preferred ethylene oxide adducts (C) are e.g. Adducts of stearyl alcohol with 19, 56 or 95 mol ethylene oxide, from oleyl alcohol with 19, 56 or 95 mol ethylene oxide, from stearic acid with 6.5, 8.5 and 10 mol ethylene oxide, from oleic acid with 6.5, 8.5 or 10 mol ethylene oxide, or Adducts of tallow fatty amine with 2, 4.5, 10, 22 or 25 mol ethylene oxide.
  • aqueous plasticizer formulation (D) The components contained in the aqueous plasticizer formulation (D) are described in detail, for example, in DE-OS 31 38 181, to which reference is hereby expressly made. These are, for example, aqueous mixtures containing Ml
  • component (I) which are acylated alkanolamines which are obtainable by reacting saturated or unsaturated C 2 -C 2 2 -carboxylic acids with alkanolamines which have 1 or 2 nitrogen atoms, 1 - Contain 3 OH groups and 2 - 6 C atoms, in a molar ratio (1 -3): 1,
  • component (II) which is water-soluble, quaternary ammonium salts of the general formula (3)
  • R 1 is a C 14 -C 2 5 -alkyl or alkenyl radical which is interrupted by an amide and / or ester group,
  • R2 is a radical with the meaning of R 1 or one
  • R 3 and R 4 independently of one another a C j -C 4 alkyl radical, a hydroxyethyl, a hydroxypropyl or a benzyl radical and
  • X t_ is a t-negatively charged anion, where t is 1, 2 or 3,
  • component (III) which are fatty acid esters of saturated or unsaturated C 12 -C 22 fatty acids or saturated or unsaturated C 4 -C ] o-dicarboxylic acids and mono- to tetravalent C 3 -C 2 Q alcohols
  • component (IV) which are ethylene oxide adducts of
  • component (V) which are diorganopolysiloxanes with a viscosity of 1,000 to 100,000 mm 2 / s, wherein all of the above-mentioned percentages by weight are based in each case on the entire mixture Ml and the sum of components (I) to (V) in the mixture Ml is 10 to 90% by weight.
  • acylated alkanolamines (I) which are described, for example, by K. Lindner, "Tenside-Textilstoff -kar-Waschrohstoffe", 2nd edition, volume 1, pages 904 and 993, and by Schwartz-Perry "Surface Active Agents” 1949, vol. 1, p. 173, contain amide and / or ester groups, depending on the alkanolamines used.
  • Carboxylic acids of natural or synthetic origin are used to manufacture them
  • Lauric acid e.g. Lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid or their mixtures, as described e.g. made from coconut oil, palm kernel oil or tallow, or branched chain acids from oxosynthesis, e.g. Isostearic acid, or the acid chlorides of these carboxylic acids.
  • Technical quality stearic acid and behenic acid are preferably used.
  • Suitable alkanolamines containing 1-3 OH groups and having 2-6 carbon atoms include monoethanolamine, diethanolamine, triethanolamine, N-methyldiethanolamine, N- (2-aminoethyl) ethanolamine, 1-aminopropanol and bis- (2-hydroxy- propyl) - amine.
  • N- (2-Aminoethyl) ethanolamine, monoethanolamine and diethanolamine are preferably used.
  • the water-soluble quaternary ammonium salts (II) contain at least one Cj 4 -C 5 alkyl or alkenyl chain which is interrupted by an amide and / or ester group as the hydrophobic radical. For their production are known
  • R 1 is preferably the radical R 5 -CO-YR 6 -, where R 5 is an alkyl or alkenyl radical having 12 to 22 carbon atoms, R 6 is an ethylene or propylene radical and Y is NH or O. .
  • anion X t_ is preferably chloride, bromide, sulfate,
  • Phosphate methosulfate or dimethyl phosphite.
  • Suitable amines for the preparation of (II) are e.g. 3-amino-1-dimethylamino-propane, 3-amino-1-diethylamino-propane, methyl-bis- (3-amino-propyl) -amine, bis- (2-methylamino-ethyl) -methylamine, 2-dimethylamino- ethanol, methyl bis (2-hydroxyethyl) amine or 3-dimethylamino-l-propanol.
  • Preferred compounds (II) are reaction products of technical stearic acid or behenic acid with 3-amino-l-dimethylamino-propane or 3-amino-l-di-ethylamino-propane, which are quaternized with dimethyl sulfate or dimethyl phosphite.
  • acylated alkanolamines (I) can also serve as solvents in molten form, provided that they do not contain a tertiary nitrogen atom.
  • Suitable quaternizing agents are, for example, methyl chloride, dimethyl sulfate, dimethyl phosphite or ethylene oxide, the reaction in the latter case being carried out in sulfuric acid or phosphoric acid solution.
  • the substances of the two groups of substances (I) and (II) can also be prepared in a one-pot process by reacting mixtures of the amines mentioned for both groups with fatty acids and then quaternizing the proportion of tertiary amino groups accordingly.
  • Mono- to tetravalent C 3 -C 20 alcohols are used to prepare the carboxylic acid esters (III).
  • the alkyl chain of these alcohols can also be interrupted by oxygen.
  • carboxylic acid esters (III) examples include butyl stearate, 2-ethylhexyl stearate, octa-decyl stearate, isotridecyl stearate, 2-ethylhexyl oleate, di-2-ethylhexyl sebacate, pentaethylene glycol dilaurate, trimethylolpropane trilaurate and pentaerythritol tetrapelargonate.
  • Components (I), (II) and (III) are plasticizer compounds.
  • ethylene oxide adducts of C 12 -C 22 fatty acids, C 8 -C ] 8 fatty alcohols, C 2 -C 36 alkyl or di (C 2 -C 36 ) alkylamines or C 9 -C 2 alkyl phenols used.
  • These components (IV) also have plasticizer properties due to the long alkyl residues.
  • the optimal degree of alkoxyhering varies from case to case and can be from 2-100 mol ethylene oxide per mol starting substance.
  • diorganopolysiloxanes (V) with viscosities of 1000 to 100,000 nm 2 / s can be added to the mixtures of the plasticizer compounds by emulsion polymerization. These diorganopolysiloxanes are usually used as aqueous emulsions and also have plasticizer properties. Polydimethylsiloxanes are preferred.
  • the aqueous mixture Ml additionally contains 1-30% by weight of a component (VI), which is an oxidized polyethylene wax emulsion, wherein this weight percent of component (VI) is also based on the entire mixture Ml and the sum of components (I) to (VI) in the mixture Ml is 10-90% by weight.
  • a component (VI) which is an oxidized polyethylene wax emulsion
  • oxidized polyethylene wax emulsions (VI) usually have one
  • Acid number of 10 to 60 mg KOH / g and are described for example in DE-OS 30 03 851 and DE-OS 28 30 173.
  • a mixture M2 can also be used as the aqueous plasticizer formulation (D)
  • a mixture M3 can also be used as the aqueous plasticizer formulation (D)
  • component (IV) already defined for the mixture Ml
  • component (VI) already defined for the mixture Ml
  • a component (VII), which is a cationic emulsifier 1-20 wt .-% of a component (VII), which is a cationic emulsifier, the addition of 2-20 mol of ethylene oxide and / or propylene oxide to a C 10 -C 22 alkylamine in the presence of an organic or inorganic acid is obtained
  • the cationic emulsifier (VII) contained in the mixture M3 is obtained by addition of 2-20 mol ethylene oxide and / or propylene oxide onto a C 10 -C 22 alkylamine in the presence of an organic or inorganic acid.
  • an organic or inorganic acid for example, formic acid, acetic acid, phosphoric acid, phosphorous acid, hydrochloric acid, sulfuric acid or sulfurous acid can be used as the organic or inorganic acid.
  • a mixture M4 can also be used as the aqueous plasticizer formulation (D)
  • a mixture M5 can also be used as the aqueous plasticizer formulation (D)
  • VIII a component (VIII), which is a branched polysiloxane / polyether copolymer
  • component (IX) which is an organic phosphoric acid salt
  • Component (VIII) is a branched polysiloxane / polyether copolymer.
  • Suitable is, for example, a branched polysiloxane / polyether copolymer which is obtainable by reacting octamethyltetrasiloxane, methyltrichlorosilane and polyglycols started from ethylene oxide and / or propylene oxide with a hydroxyl number of on alkanols, preferably butanol
  • Component (IX) is, for example, organic phosphoric acid salts from mono- or di- (C, -C lg- alkyl) phosphates and hydroxy- (C, -C 4 ) -alkylamines. Alkali or alkaline earth phosphates can also be used. A mixture M6 can also be used as the aqueous plasticizer formulation (D)
  • component (XI) which is polydimethylsiloxane with a viscosity of less than 40 mPas at 23 ° C
  • Mix M6 are related and the sum of components (I), (II), (III), (IV) and (XI) in the mixture M6 is 10 - 90 wt .-%.
  • a mixture M7 can also be used as the aqueous plasticizer formulation (D)
  • a mixture M8 can also be used as the aqueous plasticizer formulation (D) 0.1-20% by weight of component (IV) already defined for the mixture Ml
  • aminosilicones which are liquid at room temperature can be used as aminosilicones (XII), preference being given to N-modified, particularly preferably N-acylated and in particular N-formylated aminosilicones.
  • amphoteric surfactants can be used as amphoteric surfactants (XIV). Those from the class of the C 8 -C 24 alkylamine oxides are preferably used.
  • the straight-chain or branched monohydric C r C 18 alcohols (XIV) can be, for example, aliphatic, cycloaliphatic, araliphatic alcohols or ether alcohols. For example, ethanol, propanol, butanol, isobutanol, cyclohexanol, butyl diglycol or benzyl alcohol are suitable.
  • a mixture M9 can also be used in the aqueous plasticizer formulation (D)
  • component (II) already defined for the mixture Ml 0-30% by weight, preferably 10-30% by weight, of component (II) already defined for the mixture Ml,
  • a component (XV) which is the reaction product of a saturated or unsaturated C 18 -C 22 carboxylic acid with amines selected from the group consisting of diethylenetriamine, triethylenetetramine and dimethylamino-propylamine,
  • XVI a component which is a paraffin with a melting point of 50-120 ° C
  • a component (XVII) which is a vegetable oil, preferably refined rapeseed oil, 0 - 30% by weight stearyl sarcoside (XVIII),
  • XX paraffin sulfonic acid or its alkali metal or alkaline earth metal salts
  • the mixture M9 can contain the acylated alkanolamines (I) which, as already described, by reacting saturated or unsaturated C 12 -C 22 -carboxylic acids with alkanolamines, the 1 or 2 nitrogen atoms, 1 - 3 OH groups and 2 - 6 C atoms contain, are available in a molar ratio (1-3): 1, also be quaternized or protonated.
  • Suitable quaternizing agents are, for example, methyl chloride, dimethyl sulfate, dimethyl phosphite or ethylene oxide, in which case the reaction is carried out in sulfuric acid or phosphoric acid solution.
  • component (XV) can also be quaternized, protonated or with C 4 -C 18 diisocyanates, preferably hexamethylene diisocyanate (HDI), 4-methyl-m-phenylene diisocyanate (TDI) or 4,4'-methylene-bis- (phenyl isocyanate) (MDI).
  • HDI hexamethylene diisocyanate
  • TDI 4-methyl-m-phenylene diisocyanate
  • MDI 4,4'-methylene-bis- (phenyl isocyanate)
  • Component (XVII) is a vegetable oil; refined rapeseed oil, which essentially consists of erucic acid, is used as the triglyceride with oleic, linoleic and linolenic acid.
  • Component (XVIII) is the reaction product of stearic acid chloride and sarcosine, optionally also in the form of an alkali metal, in particular sodium, salt.
  • Component (XIX) is based on beef tallow as animal fat, which contains various proportions of myristic acid, palmitic acid, stearic acid, oleic acid and linoleic acid in the form of the respective triglycerides. This beef tallow is e.g. sulfonated using oleum and neutralized with alkali.
  • Component (XX) is a paraffin sulfonic acid or its
  • Suitable paraffin sulfonic acids or salts include straight-chain, branched, saturated or unsaturated hydrocarbons with 12-20 C atoms which have sulfonic acid groups and / or sulfonate groups.
  • Component (XX) has a surface-active effect.
  • aqueous mixtures Ml to M9 are prepared by heating the respective components of these mixtures above the melting point, if necessary, and stirring them homogeneously with the addition of a corresponding amount of warm water. After cooling to room temperature, aqueous plasticizer formulations (D) are obtained in the form of stable liquid solutions or emulsions which contain 10-90% by weight, preferably 10-80% by weight, of plasticizer compounds, based on the aqueous plasticizer formulation.
  • the aqueous mixtures M1 to M9 thus obtained are added to the textile treatment agents according to the invention.
  • the textile treatment agents according to the invention are produced by mixing the respective ones
  • the textile treatment agents according to the invention can also contain other constituents which are customary for textile auxiliaries. These include protective colloids, perfumes, fungicides or bactericides,
  • Preferred textile treatment agents are 0-20% by weight of polyalcohols (A), 0-20% by weight of polyalcohols (B), 0.1-8% by weight of ethylene oxide adducts (C) and 80-95% by weight .-% of the plasticizer formulation (D) contain, the sum of (A) and (B)> 0.1 wt .-%, based on the sum of components (A) to (D).
  • aqueous plasticizer formulation (D) contains, all of the above% by weight being based in each case on the entire textile treatment composition according to the invention and one or more of the mixtures Ml to M9 described above being used as the aqueous plasticizer formulation (D).
  • Trimethylolpropane, pentaerythritol, glucose or mixtures of these compounds are used in particular as component (B).
  • Textile treatment agents according to the invention are also particularly preferred
  • aqueous plasticizer formulation (D) contains, all of the above% by weight being based in each case on the entire textile treatment composition according to the invention and one or more of the mixtures Ml to M9 described above being used as the aqueous plasticizer formulation (D).
  • aqueous preparations from the textile treatment agents according to the invention.
  • These aqueous preparations contain 10-90% by weight, preferably 30-70% by weight, of the textile treatment agents according to the invention.
  • the invention further relates to a process for finishing natural and synthetic textile materials, in which these textile materials are treated with the text treatment agents according to the invention or their aqueous preparations.
  • this process is carried out by treating the textile materials with the textile treatment agents or the aqueous preparations in the exhaust process (reel runners, nozzle-dyeing unit) or in the dipping, spraying or padding process.
  • the textile treatment agents according to the invention are preferably used in an amount of 1-3% by weight in the exhaust process or with 10-30 g / 1 liquor in the padding process, based on a 100% liquor absorption.
  • the liquor ratios can vary between 1: 1 and 1: 30 depending on the type of application.
  • the invention thus also relates to natural and synthetic textile materials which have been treated with the textile treatment agents according to the invention or their aqueous preparations.
  • the textile materials that can be used can consist of natural and / or synthetic fiber materials.
  • Suitable natural fiber materials are, for example, cellulose fibers such as cotton, viscose or rayon wool, as well as wool or silk.
  • synthetic fibers e.g. Polyamide, polyester or polyacrylonitrile can be used.
  • the textile treatment agents according to the invention considerably improve the hydrophilicity of the treated textile materials, while maintaining the soft feel and the high surface smoothness.
  • Another advantage of the textile treatment agents according to the invention is their behavior when stored at low temperatures.
  • conventional plasticizer compositions with paraffins and waxes the active ingredients precipitate out in solid form at low temperatures and can no longer be brought into emulsion by heating.
  • the textile treatment agents according to the invention it is possible at any time without problems to get usable emulsions again by heating.
  • inventive and comparative textile treatment agents are applied by the padding process with 100% liquor absorption.
  • a quantity of 20 g of textile treatment agent per 1 liquor is used in each case.
  • the handle on the treated substrates is assessed and the properties of the sewability, the degree of whiteness and the hydrophilicity are determined in accordance with the following test conditions:
  • Sewability Tested on 4-layer material with 5200 stitches min over a sewing distance of 80 cm and using the needle shape LBALL / SES.
  • Hydrophilicity the water drop test is used to check the time within which a water drop is absorbed by the substrate.
  • Handle assessment carried out on terry goods by 6 people each by awarding a ranking, the mean value of which is given. A grip of 3 is still acceptable.
  • plasticizer formulations 1-8 are produced as component (D):
  • Textile treatment agent 1 (according to the invention)
  • Textile treatment agent 2 (according to the invention)
  • Textile treatment agent V 5 (mixture according to DE-OS 196 29 666) (comparison 5)
  • a plasticizer formulation according to DE-OS-196 29 666 consisting of a 20% aqueous dispersion of a mixture of (in% by weight) 70% [(C 17 H 35 COOCH 2 CH 2 ) 2 (HOCH 2 CH 2 ) N (CH 3 )] 3% O-SO 2 (OCH 3 ) 20% alkyl polyglucoside of the formula
  • the textile treatment agents 6 and V8 are subsequently used to treat 100% polyester 2).
  • the textile treatment agents according to the invention are stored at -4 ° C. for 10 hours. After thawing, it is checked whether there are any solid parts in the thawed formulations.
  • the textile treatment agents are applied to cotton jersey 1).
  • the textile treatment agents are also stored at -4 ° C for 10 hours and checked for solid proportions as described.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

Les procédés de traitement des textiles, tels que la couture ou le capitonnage, sont très exigeants pour le matériau textile du point de vue du lustre. La vitesse élevée des aiguilles génère pour le matériau à coudre des charges thermiques et mécaniques qui risquent de provoquer, si la surface n'est pas suffisamment lisse, des cassures de fil et des sauts de maille. On peut éviter cet inconvénient en recouvrant le matériau textile d'un avivage lustrant.
PCT/EP1999/009771 1998-12-22 1999-12-10 Agents de traitement pour textiles, leur procede de fabrication et leur utilisation WO2000037735A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR9916435-3A BR9916435A (pt) 1998-12-22 1999-12-10 Agente de tratamento têxtil, processos para a sua preparação, bem como seu emprego
EP99964541A EP1144749A1 (fr) 1998-12-22 1999-12-10 Agents de traitement pour textiles, leur procede de fabrication et leur utilisation
JP2000589780A JP2002533581A (ja) 1998-12-22 1999-12-10 織物処理剤、その製造法および使用
CA002355370A CA2355370A1 (fr) 1998-12-22 1999-12-10 Agents de traitement pour textiles, leur procede de fabrication et leur utilisation
AU30370/00A AU3037000A (en) 1998-12-22 1999-12-10 Agents for treating textiles, method for producing them and their use

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE1998159294 DE19859294A1 (de) 1998-12-22 1998-12-22 Textilbehandlungsmittel, Verfahren zu deren Herstellung sowie deren Verwendung
DE19859294.9 1998-12-22

Publications (1)

Publication Number Publication Date
WO2000037735A1 true WO2000037735A1 (fr) 2000-06-29

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PCT/EP1999/009771 WO2000037735A1 (fr) 1998-12-22 1999-12-10 Agents de traitement pour textiles, leur procede de fabrication et leur utilisation

Country Status (8)

Country Link
EP (1) EP1144749A1 (fr)
JP (1) JP2002533581A (fr)
AU (1) AU3037000A (fr)
BR (1) BR9916435A (fr)
CA (1) CA2355370A1 (fr)
DE (1) DE19859294A1 (fr)
MX (1) MXPA01006396A (fr)
WO (1) WO2000037735A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7662745B2 (en) 2003-12-18 2010-02-16 Kimberly-Clark Corporation Stretchable absorbent composites having high permeability
US7772456B2 (en) 2004-06-30 2010-08-10 Kimberly-Clark Worldwide, Inc. Stretchable absorbent composite with low superaborbent shake-out
US7938813B2 (en) 2004-06-30 2011-05-10 Kimberly-Clark Worldwide, Inc. Absorbent article having shaped absorbent core formed on a substrate

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10300980A1 (de) 2003-01-14 2004-07-22 Cht R. Beitlich Gmbh ph-Wert unabhängiges Avivieren von Nähgarnen im Ausziehverfahren

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0075770A2 (fr) * 1981-09-25 1983-04-06 Bayer Ag Composition de traitement pour textile et son utilisation pour le finissage de matériaux textiles
FR2603623A1 (fr) * 1986-09-09 1988-03-11 Beghin Say Sa Composition et procede pour le traitement de complexes cellulosiques non tisses
EP0641833A1 (fr) * 1993-08-31 1995-03-08 Sandoz Ltd. Dispersions aqueuses de cires et de silicones, leur fabrication et leur utilisation
EP0691396A2 (fr) * 1994-06-09 1996-01-10 Hoechst Aktiengesellschaft Adoucissant concentré pour le linge
EP0696661A1 (fr) * 1994-08-11 1996-02-14 Ciba-Geigy Ag Compositions d'agents de finition multi-fonctionnels
JPH09195167A (ja) * 1996-01-11 1997-07-29 Kao Corp 液体柔軟仕上剤組成物
WO1999005246A1 (fr) * 1997-07-28 1999-02-04 Cognis Deutschland Gmbh Dispersion de faible viscosite destinee au traitement du papier et du textile

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0075770A2 (fr) * 1981-09-25 1983-04-06 Bayer Ag Composition de traitement pour textile et son utilisation pour le finissage de matériaux textiles
FR2603623A1 (fr) * 1986-09-09 1988-03-11 Beghin Say Sa Composition et procede pour le traitement de complexes cellulosiques non tisses
EP0641833A1 (fr) * 1993-08-31 1995-03-08 Sandoz Ltd. Dispersions aqueuses de cires et de silicones, leur fabrication et leur utilisation
EP0691396A2 (fr) * 1994-06-09 1996-01-10 Hoechst Aktiengesellschaft Adoucissant concentré pour le linge
EP0696661A1 (fr) * 1994-08-11 1996-02-14 Ciba-Geigy Ag Compositions d'agents de finition multi-fonctionnels
JPH09195167A (ja) * 1996-01-11 1997-07-29 Kao Corp 液体柔軟仕上剤組成物
WO1999005246A1 (fr) * 1997-07-28 1999-02-04 Cognis Deutschland Gmbh Dispersion de faible viscosite destinee au traitement du papier et du textile

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
HARDT, P.: "Umweltfreundliche Textilweichmacher", MELLIAND TEXTILBERICHTE, INTERNATIONAL TEXTILE REPORTS,DE,MELLIAND TEXTILBERICHTE K.G. HEIDELBERG, vol. 71, no. 9, 1990, pages 699 - 706, XP002135429 *
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 11 28 November 1997 (1997-11-28) *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7662745B2 (en) 2003-12-18 2010-02-16 Kimberly-Clark Corporation Stretchable absorbent composites having high permeability
US7772456B2 (en) 2004-06-30 2010-08-10 Kimberly-Clark Worldwide, Inc. Stretchable absorbent composite with low superaborbent shake-out
US7938813B2 (en) 2004-06-30 2011-05-10 Kimberly-Clark Worldwide, Inc. Absorbent article having shaped absorbent core formed on a substrate

Also Published As

Publication number Publication date
JP2002533581A (ja) 2002-10-08
BR9916435A (pt) 2001-09-04
MXPA01006396A (es) 2002-02-01
DE19859294A1 (de) 2000-06-29
AU3037000A (en) 2000-07-12
CA2355370A1 (fr) 2000-06-29
EP1144749A1 (fr) 2001-10-17

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