Classifications

• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
  • C01B13/10—Preparation of ozone
  • C01B13/11—Preparation of ozone by electric discharge
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B2201/00—Preparation of ozone by electrical discharge
  • C01B2201/30—Dielectrics used in the electrical dischargers
  • C01B2201/32—Constructional details of the dielectrics
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
  • C01B2201/00—Preparation of ozone by electrical discharge
  • C01B2201/30—Dielectrics used in the electrical dischargers
  • C01B2201/34—Composition of the dielectrics
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F24—HEATING; RANGES; VENTILATING
  • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
  • F24F8/00—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying
  • F24F8/40—Treatment, e.g. purification, of air supplied to human living or working spaces otherwise than by heating, cooling, humidifying or drying by ozonisation
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S422/00—Chemical apparatus and process disinfecting, deodorizing, preserving, or sterilizing
  • Y10S422/906—Plasma or ion generation means

Definitions

• This invention relates to an air purification device, and particularly but not exclusively to an air purification device which generates ozone.
• air purification device is meant a device which may be used to improve the quality of air, by removal of at least a portion of pollutants, odours, airborne particles, bacteria and/or the like from the air.
• a device may be used to clean exhaust gases from motor vehicles and other polluting processes, for sterilization purposes in "clean" manufacturing facilities, hospitals, food storage and preparation areas, etc.
• Ozone is poisonous to bacteria and microorganisms, and also oxidises many organic compounds that may be present in odours, however as ozone is also toxic to humans, its use as an air purifier has had limited application.
• ozone generators are operated using the "silent discharge” or "dielectric barrier principle” to convert oxygen into ozone.
• the feedstock is typically oxygen gas because the use of air in a conventional device can lead to the production of undesirable end products such as oxides of nitrogen (e.g. NO x ).
• the use of air as a feedstock can however be achieved using generators of the dielectric barrier type provided that they are operated at a high frequency.
• Such high frequency devices comprise two electrodes having a gap between them, air being passed through the gap so that electrical discharge across the electrodes causes the oxygen in the air to be converted to ozone.
• These devices generally have very narrow gaps between the electrodes and thus offer considerable resistance to the flow of air through the device, requiring a pump to provide airflow.
• GB-A-2296172 discloses an ozone generator having dielectric spacers between the electrodes.
• the spacers maintain the spacing between the electrodes, which is important as the pressure between the electrodes can become raised above atmospheric pressure, causing the electrodes to bow or warp.
• the gap between the electrodes is of the order of a few millimetres or less, to help reduce the voltage required to establish a corona discharge.
• an open dielectric foam, a dielectric filament material or irregularly spaced dielectric particles are placed in the electrode gap around the spacers, to provide an impedance to the flow of gas through the electrode gap so that gas flow between the electrodes and hence corona discharge is uniform.
• the air flow through the device is not high enough to enable the apparatus to be used as an air purification device.
• the known devices are also often prone to overheating which reduces the efficiency of ozone production as ozone thermally degrades above about 50°C and can cause failure of the discharge electrode arrangement due to distortion such as bowing or warping.
• an apparatus for purifying air comprising two electrodes having a dielectric material therebetween and means for applying a potential difference across the electrodes, wherein the electrodes are air permeable and the dielectric material is in the form of an air permeable, fixed bed and wherein means are provided to provide air flow through one electrode, across the fixed bed of dielectric material and through the other electrode.
• a method of purifying air comprising passing the air through an air permeable electrode, an air permeable fixed bed of dielectric material and a second air permeable electrode whilst applying a potential difference across the bed to convert oxygen in the air to ozone.
• fixed bed is intended to describe a material that extends between the electrodes so that it does not move in normal usage of the device but which is air permeable so that air may flow through gaps present therein.
• the term is intended to cover inter alia a bed of discrete particles, a foam, a sponge-like structure, and a bed of elongate elements such as filaments arranged in a contacting relationship with air gaps therebetween.
• the invention causes air to flow through the air permeable electrodes and dielectric material, preferably in a direction parallel to the applied electric field, thus substantially increasing airflow through the device.
• the air purification device of the present invention thus generates ozone with a high volume of airflow, but in low concentrations, eliminating problems of exceeding toxicity levels in "populated" areas.
• Cooling of the device which increases the efficiency of ozone generation, is achieved by the use of a high air flow through the device, which is not possible with a solid, impermeable dielectric material, and without the need to fluidize a particle bed as described in the prior art. Cooling is thus achieved without expensive and bulky fluidization apparatus or air pumps or cooling water.
• the use of the fixed bed also allows discharge to take at the points of contact of the dielectric (if the dielectric is in the form of discrete particles) so that the discharge across the electrodes is uniform. As a result, the spacing between the electrodes may be increased compared to the prior art devices, allowing greater airflow through the device.
• the fixed bed reduces level of airborne pollutants (especially particulates such as smoke, dust, soot, etc; aerosols; and bacteria) by electrostatic dust precipitation and by the chemical processes of ozonolysis, oxidation and sterilisation, and by the particles being burnt off due to electrical discharge at the points of contact of the dielectric.
• the electrodes may be formed of a metal gauze or mesh. Suitable metals include steel and nickel.
• the dielectric material may be any suitable material, but preferably has a dielectric constant less than 100, and more preferably less than 20.
• the dielectric material is preferably glass.
• Silica, alumina or another suitable dielectric zirconia, sapphire, etc. could be used in place of glass.
• materials such as barium titanate, which has a dielectric constant of 1000 may be used as the dielectric material, as it may be obtained at a relatively low cost.
• the dielectric material is formed of a bed of discrete bodies in a contacting relationship.
• the discrete bodies are preferably particles, preferably regularly shaped particles and more preferably beads.
• the diameter of the beads is preferably about 1mm to 6mm. Glass wool, chips, or extruded foam could be used in place of beads provided that air permeability is retained and that elements of the dielectric material are in a contacting relationship, although regularly spaced beads give an advantage in that better airflow is allowed through the dielectric bed.
• the potential difference applied across the electrodes may be V pk .
• pk 10-20 kV and 10-15 kHz, although voltage such as mains at 50Hz or 60Hz could be used.
• Figure 1 is an expanded, schematic cross-sectional view of an air purifier according to the present invention
• Figure 2 is a schematic perspective view of a packed bed electrode according to the present invention.
• an air purifier 1 comprising a fan 2 in a housing 3, downstream of which is a spacer 4, and retaining grids 5 and 6.
• a pellet bed 7 is arranged between the retaining grids such that grid 5 is upstream and grid 6 is downstream of the pellet bed 7.
• Electrodes 8, 9 are also provided with electrode 8 situated between retaining grid 5 and pellet bed 7, with electrode 9 situated between retaining grid 6 and the pellet bed 7.
• the fan 2 and housing 3 may be of any suitable type. In experiments a 240- volt fan in a square cross-section housing 3 having dimensions of 120mm x 120mm was used.
• the spacer 4 may be of Perspex and should preferably have the same cross- sectional dimensions as the fan housing 3. A spacer having 120mm x 120mm external dimensions with a 95mm x 95mm internal cut-out and having a thickness of 1.8cm was successfully used in experiments.
• Retaining grids 5 and 6 are of a plastics material having the same cross- sectional dimensions as the fan housing 3 and spacer 4.
• the retaining grids are to provide reinforcement to the pellet bed 7 and so must have as many holes as possible to provide a good air flow through the device but must also retain enough rigidity to provide the required strengthening to the pellet bed 7.
• Pellet bed 7 comprises two gauze electrodes 8, 9 separated by a Perspex spacer 10.
• the spacer 10 is of a similar shape to spacer 4, to create a housing for pellet bed 7. Glass beads 11 are packed into the space between the electrodes 8, 9 created by the spacer 10.
• Gauze electrode 8 is of high voltage steel high transmittance gauze, although may be formed of nickel, such gauzes being available as radio frequency interference screens. The electrode is made using a basic size gauze of 120mm x 120mm, which is trimmed by 5mm around each edge, the edges then being sealed with epoxy. The gauze is sealed between retaining grid 5 and the Perspex spacer 10 with silicone rubber compound.
• a high voltage cable (not shown) is attached to the gauze by solder and epoxy overlayer.
• Gauze electrode 9 is similar to gauze electrode 8 except that epoxy edging need not be applied to the gauze.
• a standard earth lead (not shown) is attached to the electrode instead of the high voltage cable.
• the glass beads 11 are packed into the interior of pellet bed 7 formed between the electrodes 8, 9 and Perspex spacer 10.
• the beads 11 may be 6mm diameter and are preferably packed in at least two layers. The spacing between the beads allows air to flow through the bed 7.
• the ozone generator 1 would in use be su ⁇ ounded by a housing having an air inlet and an air outlet, and would have a power supply and operating switches. These additional features are not shown in the drawings, as they are comprised of standard components. A timer mechanism may also be incorporated in the device.
• the size of glass particle used in the device is not crucial, and particles between 1mm and 6mm diameter can be used successfully. With particles of a small size, however, the airflow through the device is restricted.
• the use of glass rather than a material having a high dielectric constant does reduce the efficiency at which ozone is generated, but in an air quality improvement device high rates of production of ozone could be extremely dangerous if someone were to enter the area being cleaned before the ozone had degraded or dissipated. Efficiency of ozone production is therefore not required to be very high. Glass is also a cheap substance, which gives a significant cost advantage.
• a chamber could be attached to the device downstream of the packed bed in which the reaction of ozone with airborne contaminants could be allowed to take place.
• a further metallic gauze or grid downstream of the reaction chamber is used to break down the ozone before the air is returned to the room. This gauze could also be coated with a suitable material for deactivating ozone.
• a coarse filter could be added to the device upstream of the fan, to remove large particles from the air.
• the apparatus In use, the apparatus is placed in a room or other location where the air is to be cleaned, either for the elimination of odours or to remove pollutants, bacteria or other contaminants.
• the fan 2 is switched on together with the voltage supply to the pellet bed 7.
• the fan causes air to be pushed through the bed 7 whilst the electrodes 8,9 and the glass particles 11 cause ozone to be generated from the air by discharge due to a high frequency electric field being generated across bed 7, in accordance with the known discharge principles.
• the voltage applied to the device is typically V pk .
• pk 10-20 kV and 10-15 kHz.
• High voltage such as mains at 50Hz or 60Hz could also be used.
• the apparatus is left running for a sufficient length of time for the ozone generated to have purified the air.
• air purification is meant an improvement in the quality of the air due to the removal of at least some of the airborne particulate matter, pollutants and odours that was initially present in the air.
• the electric discharge created in the packed bed will also destroy some particulate matter that may be present in the air either by burning it off or by means of electrostatic precipitation onto the dielectric particles, which will further improve the air quality.
• the packed bed of dielectric means that electric discharge takes place at the points of contact between the dielectric particles, making the discharge very uniform and allowing the spacing between the electrodes to be increased.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Combustion & Propulsion (AREA)
• Mechanical Engineering (AREA)
• General Engineering & Computer Science (AREA)
• Oxygen, Ozone, And Oxides In General (AREA)
• Physical Or Chemical Processes And Apparatus (AREA)
• Electrostatic Separation (AREA)
• Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
• Percussion Or Vibration Massage (AREA)
• Vertical, Hearth, Or Arc Furnaces (AREA)
• Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
• Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
• Filtering Of Dispersed Particles In Gases (AREA)

Priority Applications (8)

Applications Claiming Priority (2)

Publications (1)

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Family Applications (1)

Country Status (11)

Cited By (1)

Families Citing this family (16)

Citations (5)

Family Cites Families (7)

• 1998
  • 1998-09-09 GB GBGB9819540.7A patent/GB9819540D0/en not_active Ceased
• 1999
  • 1999-09-09 US US09/786,795 patent/US6635153B1/en not_active Expired - Fee Related
  • 1999-09-09 AT AT99946303T patent/ATE284836T1/de not_active IP Right Cessation
  • 1999-09-09 DE DE69922665T patent/DE69922665T2/de not_active Expired - Lifetime
  • 1999-09-09 JP JP2000568776A patent/JP2002524168A/ja active Pending
  • 1999-09-09 EP EP99946303A patent/EP1109737B1/en not_active Expired - Lifetime
  • 1999-09-09 CA CA002343723A patent/CA2343723C/en not_active Expired - Fee Related
  • 1999-09-09 ES ES99946303T patent/ES2235512T3/es not_active Expired - Lifetime
  • 1999-09-09 AU AU58722/99A patent/AU759432C/en not_active Ceased
  • 1999-09-09 PT PT99946303T patent/PT1109737E/pt unknown
  • 1999-09-09 WO PCT/GB1999/003006 patent/WO2000014010A1/en not_active Ceased

Patent Citations (5)

Non-Patent Citations (3)

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