WO2000009943A1 - A light fiber and a method for producing the same - Google Patents
A light fiber and a method for producing the same Download PDFInfo
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- WO2000009943A1 WO2000009943A1 PCT/US1999/014429 US9914429W WO0009943A1 WO 2000009943 A1 WO2000009943 A1 WO 2000009943A1 US 9914429 W US9914429 W US 9914429W WO 0009943 A1 WO0009943 A1 WO 0009943A1
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- Prior art keywords
- light
- clad
- diffusive
- core
- reflective
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/0001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
- G02B6/0005—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being of the fibre type
- G02B6/001—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being of the fibre type the light being emitted along at least a portion of the lateral surface of the fibre
Definitions
- the present invention relates to a light fiber of directional side light extraction type capable of extracting a light from the sidewall and a process for producing the same. More particularly, it relates to a light fiber of directional side light extraction type capable of extracting a light in a specific direction from the sidewall and a production process thereof.
- Discharge tubes such as fluorescent lamp emit a visible light of a particular wavelength region, they are ordinarily used in the application fields for lighting. In the case where the discharge tubes are a neon bulb, they are used to demonstrate an advertisement or decoration or the like in the form of the so-called neon sign.
- the discharge tubes are luminescent with the application of electric voltage. Generally, the discharge tubes generate heat. In such a case, it is necessary to use the discharge tubes with due regard to an electric leakage and the generation of heat. For example, the use of discharge tubes is substantially impossible for under-water lighting or demonstration.
- a light-emitting device comprising a light source located at a distance from the area illuminated therewith has attracted attention to achieve the lighting and demonstration as set forth above.
- a light fiber is installed in the vicinity of an area to be illuminated, away from the light source, so as to give the illumination of a desired light.
- the light fibers comprise a core in the central portion and a clad having a refractive index lower than that of the core on the periphery of the core. A light can be injected into one end and transmitted to the other end of thus configured light fiber.
- a light fiber of directional side light extraction type which can extract a light from the sidewall.
- Those light fibers of directional side light extraction type can extract parts of a light from the sidewall through the clad to the outside, when the light is injected into one end and transmitted to the other.
- a light fiber of directional side light extraction type which is disclosed in JP-A-6-118244 as a light-illuminating plastic optical fiber can leak lights from the whole or a designated part of the sidewall.
- this light fiber is provided with a core and a clad which are made of transparent materials, respectively.
- the core comprises a polymer mainly composed of a polymethyl methacrylate.
- the clad is made of two different parts one of which is composed of a vinylidene fluoride-based copolymer comprising 50 to 90% by mole of vinylidene fluoride and 10 to 50% by mole of tetrafluoroethylene, and another part comprises at least one of the other polymers having a refractive index higher than that of the vinylidene fluoride-based copolymer, preferably a polymer which is the same as or close to the core-forming polymer.
- the clad and core are compatible each other on the interfacial boundary between them. In the interface between the core and the clad which are compatible, the light can not transmit in the core with total reflection, but scatters about within the clad; as a consequence, the light is extracted to the outside.
- JP-A-10-142428 discloses a light-illuminating rod capable of extracting a light from the sidewall to a specific direction.
- This light-illuminating rod is basically provided with a flexible rod member serving as a core in the central portion and a transparent clad layer having a refractive index lower than that of the core and bonded to the outer periphery of the flexible rod member.
- a light diffusive and reflective film comprising a light transmitting polymer in which light diffusive and reflective fine particles are dispersed is present locally therebetween along the longitudinal direction of the rod member.
- This light diffusive and reflective film reflects at least parts of a light injected from one end of the light-illuminating rod member, diffusing and reflecting it to the outside from the radiation surface of the clad in the front of said light diffusive and reflective film.
- JP-B-4-70604, and the like disclose inventions relating to light- illuminating rods comprising the inflexible rod members.
- a hardly flexible material such as quartz glass or optical glass is used as a rod member in those inventions.
- the two different polymers forming the clad are incompatible each other and caused a phase separation. Those two incompatible and phase-separated polymers have as little a refractive index difference as about 0.25 at most. In this light-illuminating plastic optical fiber, therefore, the clad cannot exhibit a light diffusive and reflective effect good enough to extract a highly bright light in a specific direction from the sidewall efficiently if an ordinary light source is used.
- the light diffusive and reflective film disclosed in JP-A-10-142428 is formed by applying a coating material containing a light transmitting polymer and light diffusive and reflective fine particles to a rod member.
- the light diffusive and reflective film is a light diffusive, reflective and adhesive film, it is laid directly on the rod member.
- those light diffusive and reflective films have a thickness of from 10 ⁇ m to 110 ⁇ m at most in the case of commercialized products because of various restrictive factors at the time of the production.
- at least parts of light which is injected into the flexible rod member from one end of the light-illuminating rod is leaked through those light diffusive and reflective films to the outside. Therefore, there is a fear that a highly bright light can hardly be extracted in a specific direction from the sidewall in high efficiency.
- a heat-shrinkable type material may hardly be used. If it is used, a rod member having a cross section substantially in the shape of a circle can not be produced since the light diffusive and reflective film portion is partially protruded unlike in the case of the ordinary light-illuminating rods. Furthermore, when they are used, the light-illuminating rods are generally mounted on a commercially available holder-rail having a reflective surface on the internal surface, such as U rail (white) manufactured by Sumitomo-3M, with the intentions to improve the directivity of the lights to be extracted to the outside or the like.
- U rail white
- the holder-rail is made to have the cross section in the shape of a circle which is the most popular cross section among the light-illuminating rods, it appears likely that the light-illuminating rods having a thick and protruded light diffusive and reflective film portion are not housed surely in the said holder-rail.
- an object of the present invention is to provide a light fiber of directional side light extraction type capable of keeping the cross-sectional shape as it is desired, reducing the amount of lights leaked through the light diffusive and reflective portion and extracting a light having a high brightness and a high directivity, and a process for producing the same.
- a light diffusive and reflective portion such as a light diffusive and reflective film from, for example, a material obtained by mixing and dispersing light diffusive and reflective fine particles into a clad-forming resinous material; and said portion is formed at the inner periphery of a clad by co-extruding a resinous material only, and a mixture, for example, obtained by mixing light diffusive and reflective fine particles with a resinous material to disperse said fine particles therein at the time of forming a clad.
- the present invention has been completed on the basis of those findings.
- a light fiber comprising a core and a clad having a refractive index lower than that of the core on the periphery of the core, characterized in that the light fiber has a light diffusive and reflective portion formed by co-extrusion at least on the inner periphery of the clad;
- a light fiber characterized in that the diffusive and reflective portion comes into contact with the core;
- the light diffusive and reflective portion has a thickness extending at least to the vicinity of outer periphery of the clad in a direction perpendicular to the longitudinal direction from the clad
- a light fiber characterized in that the diffusive and reflective portion is formed a linear shape or a band-like shape along the longitudinal direction of the clad; seventhly, there is provided a light fiber, characterized in that the light diffusive and reflective portion is formed along the peripheral direction of the clad, and eighthly, there is provided a method for producing a light fiber which comprises a core, a clad covering said core and a light diffusive and reflective portion, characterized in that a resinous material having a refractive index lower than that of the core-forming, light transmitting material, and a light diffusive and reflective material are co-extruded so as to form a light diffusive and reflective portion at least on the inner periphery of the clad.
- Fig. 1 is a schematic, perspective view of one embodiment of the light fibers according to the present invention.
- Fig. 2 is a schematic, perspective view of another embodiment of the light fibers according to the present invention.
- Fig. 3 is a schematic view of a variation of the clad composing the light fibers according to the present invention.
- Fig. 4 is a cross-sectioned side view of a device used in the measurement of brightness according to the present invention.
- Fig. 1 shows one embodiment of light fibers according to the present invention.
- the light fiber comprises the so-called core in the central portion and a clad having a refractive index lower than that of the core on the periphery thereof.
- the core is formed from a solid mass of light transmitting materials such as quartz glass, optical glass; and polymers and it has a refractive index of 1.4 to 2.0.
- the core is preferably made of a flexible material described in Paragraph 0014 of JP-A-10-142428, for example, such as acrylic resins, ethylene-vinyl acetate copolymers and the like. The relevant descriptions of said laid-open publication are incorporated herein by reference. More preferably, the core is made of an acrylic resin having a refractive index of about 1.5.
- a solid material is generally used as a core material, however, a liquid material is also usable.
- the liquid core material include aqueous solutions of an inorganic salt; polyhydric alcohols such as ethylene glycol, glycerin and the like; silicone oils such as polydimethyl siloxane, polyphenylmethyl siloxane and the like; polyethers; polyesters; hydrocarbons such as liquid paraffin; halo-genated hydrocarbons such as trifluoroethylenechloride oil; phosphoric esters such as tri(chloroethyl)phosphate, trioctyl- phosphate and the like; and polymer solutions prepared by diluting various polymers with appropriate solvents and the like.
- the clad is made of a resinous material having a refractive index lower than that of the core-forming, light transmitting material such as, for example, tetrafluoroethylene • hexafluoropropylene • copolymer (hereinafter often referred to as FEP), tetrafluoroethylene • ethylene copolymer (hereinafter often referred to as ETFE), or tetrafluoroethylene • hexafluoropropylene • vinylidene fluoride copolymer (hereinafter often referred to as THV) which has a refractive index of about 1.34 to about 1.43.
- FEP tetrafluoroethylene • hexafluoropropylene • copolymer
- ETFE tetrafluoroethylene • ethylene copolymer
- THV tetrafluoroethylene • hexafluoropropylene • vinylidene fluoride copolymer
- the light diffusive and reflective film (light diffusive and reflective portion) for the light fiber according to the present invention is formed in a desired size at a desired portion at least on the inner periphery of the clad by co-extruding a resinous material only for forming the clad, and a mixture obtained by incorporating, for example, light diffusive and reflective fine particles into the same resinous material as said resinous material so as to disperse them therein.
- the maximum thickness of the film is equal to the thickness of the clad. Since the clad has typically a thickness of from 100 to 800 ⁇ m, the light diffusive and reflective film is able to have a thickness of from 100 to 800 ⁇ m.
- the clad of the present invention can be equipped with a light diffusive and reflective film being thicker than that of the conventional ones, thereby the leakage of a light through the light diffusive and reflective film is prevented.
- the light fiber according to the present embodiment can efficiently diffuse and reflect a light which is transmitting within the core in a forward direction of light diffusive and reflective film. As a consequence, a comparatively strong light is extracted only in a specific direction from the sidewall of the light fibers.
- said light diffusive and reflective film can be formed in a predetermined thickness within a range which does not reach the thickness of the clad on the outer periphery or a thickness close thereto at its maximum in a direction perpendicular to the longitudinal direction of the clad, as shown in Fig. 2.
- the light diffusive and reflective film may be formed, conversely in such a manner that said film extends towards the core portion in a direction perpendicular to the longitudinal direction of the clad from the inner periphery surface of said clad.
- the cross-section of the clad is in the shape of a circle having a protrusion that extends into the inner portion of the core.
- said film is formed being extended not only towards the core from the inner periphery surface of the clad, but also being extended into within the core portion. That is, said film can be embedded within the clad.
- its width, thickness, length and shape can optionally be chosen, depending upon the fields of the use.
- the maximum thickness of said film can be the same one as that for the clad itself, and the minimum thickness thereof can be equal to one tenth of the thickness of the clad.
- the width of said film may as well be optionally chosen.
- the clad may have, in the same curvature as that of the clad, a width sufficient to satisfy the needs, and it may be a width good enough to cover 1% to 99% of the whole length of the outer periphery of the clad.
- the length of said film may as well be a length equivalent to the whole or a part of the longitudinally extending length of the light fiber.
- Said film may be a linear shape or, as occasion calls, a band-like shape having a protrusion part.
- the light diffusive and reflective film may not necessarily be used singly but a plurality of light diffusive and reflective films may be provided in parallel along the longitudinal direction of the clad.
- a lighting with a broad coverage is attainable along the longitudinal direction of the light fiber by forming in a linear shape or a band-like shape said light diffusive and reflective film along the longitudinal direction of the clad, desirably as one having a length equivalent to the whole length of the clad.
- the light diffusive and reflective film of the present invention are formed integrally as a part of the clad, thus it does not give any effect on the cross sectional shape of the light fiber. Accordingly, said light fiber shows an essentially circular shape. Therefore, the light fibers of the present invention can easily be used in combination with a commercially available light reflective holder rail such as U rail (white) manufactured by Sumitomo-3M, whereby the light fiber can extract a light with an improved directivity to the outside.
- the light diffusive and reflective film is preferably made to extend along the peripheral direction of the clad. Particularly, if the light diffusive and reflective film covers, along the peripheral direction of the clad, 50% to 99% of the whole length of the peripheral direction of the clad along said direction, the brightness of the light to be extracted in a specific direction is further intensified.
- the light diffusive and reflective film is made of a light diffusive and reflective material obtained by incorporating light scattering fine particles which are explained hereinafter into a resinous material such as an FEP, ETFE resin and the like or polyethylene (PE) having a refractive index of about 1.34 to about 1.51 so as to disperse them uniformly therein.
- Said a light diffusive and reflective film is formed by co-extruding a preparation produced by adding to said resinous material the light scattering fine particles in an amount so as to be contained from 0.3 to 30% by weight.
- a light extracting from the sidewall of the light fiber can be quantitatively adjusted in proportion to the refractive index of resin and the amount of light scattering fine particles incorporated therein.
- the light diffusive and reflective film of the present invention are not meant to be limited to the above-mentioned embodiment.
- the light diffusive and reflective film do not necessarily have a thickness equal to the thickness of the clad, if it can otherwise prevent the light from leaking therethrough.
- the light diffusive and reflective film can be thinner than the clad as shown in Fig. 2, as long as the film can prevent the light from leaking through a part of the film.
- the light diffusive and reflective film should be formed to make a part of the clad integrally in the outer peripheral direction perpendicular to the longitudinal direction of the clad.
- the light diffusive and reflective film can be formed being protruded into the inner portion of the core from the inner periphery surface of the clad, as shown in Fig. 3.
- the light diffusive and reflective film may be colored by incorporating a pigment or a dyestuff thereinto.
- Inorganic fine powder particles having a refractive index greater than that of the core-forming resin by about 0.3 to about 1.3 can suitably be used as the light diffusive and reflective fine particles.
- the improvement in the weatherability and the broadening in the angle of visibility is also expected by incorporating light scattering fine particles such as titanium dioxide in a trace amount such as 0.03% by weight into the light transmitting portion of the clad as well.
- the clad described as above is made, in the following way, by means of co-extrusion molding by extruding two or more materials with two or more extruders.
- a fluorine-based resin for example, Teflon® FEP 100-J pellet manufactured by Du Pont in a predetermined amount
- a fluorine-based resin composition containing the light scattering fine particles previously mixed and dispersed therein for example, Neoflon®FEP NP20WH resin pellet containing 3% by weight of titanium dioxide and manufactured by Daikin Kogyo in a predetermined amount are prepared, respectively.
- each of those pellets is respectively charged into two extruders prepared in advance, and extruded into a die, whereby a tubular clad having a light diffusive and reflective film mentioned above is molded integrally.
- a step of coating an light diffusive and reflective film or adhering an adhesive light diffusive and reflective film both of which are discussed in the section of the prior art is not called for.
- the core can be produced, for example, in the following way. There is prepared firstly a mixed monomer solution containing a predetermined amount of 2- ethylhexyl-methacrylate, a predetermined amount of n-butylmethacrylate and a predetermined amount of triethyleneglycoldimethacrylate. Thereafter, bis (4-t- butylcyclohexyl) peroxydicarbonate is added to the mixed solution as a polymerization initiator to prepare a core precursor. Then, said clad is bent into the shape of U, and the core precursor is injected from one end into within the clad. Thereafter, a solid core is formed so as to provide a light fiber of directional side light extraction type by heating the resultant up to the polymerization initiation temperature.
- the core precursor is heated serially from the bottom to the top of the U- shaped clad.
- the core precursor may come into contact with an inert gas such as nitrogen or argon so as to apply a pressure thereon.
- the core precursor may be heated as a whole, together with the clad, for a predetermined period of time to make the core precursor react completely.
- Teflon® FEP 100-J pellets having a refractive index of about 1.34 and manufactured by Du Pont, and Neoflon® FEP NP20WH resin pellets comprising a binder composed of FEP having a refractive index of about 1.34 and 3% by weight of titanium dioxide and manufactured by Daikin Kogyo are charged, respectively into two extruders previously prepared.
- charged materials were co-extruded into a die so as to give a tubular clad having an outside diameter of about 12 mm and a thickness of about 0.8 mm.
- the clad was found to be provided with a light diffusive and reflective film formed along the longitudinal direction of the clad; said film having a width of about 13 mm and a thickness of about 0.8 mm and containing 3% by weight of titanium dioxide.
- Example 2 A light fiber was prepared by repeating the procedure of Example 1, except that a clad having an outside diameter of about 9 mm and a thickness of about 0.7 mm was produced by co-extrusion molding. In this case, a light diffusive and reflective film was formed in the clad along the longitudinal direction of the clad; said film having a width of about 10 mm and a thickness of about 0.7 mm and containing 3% by weight of titanium dioxide.
- Example 3 A light fiber was prepared by repeating the procedure of Example 1, except that a clad having an outside diameter of about 18 mm and a thickness of about 0.8 mm was produced by co-extrusion molding. In this case, a light diffusive and reflective film was formed in the clad along the longitudinal direction of the clad; said film having a width of about 20 mm and a thickness of about 0.8 mm and containing 3% by weight of titanium dioxide.
- Example 4 A light fiber was prepared by repeating the procedure of Example 1, except that Neoflon® FEP NP20WH resin manufactured by Daikin Kogyo was replaced by a mixture of 10 kg of said Teflon® FEP 100-J resin with 1 kg of said Neoflon® FEP NP20WH resin.
- a clad having an outside diameter of about 12 mm and a thickness of about 0.8 mm was produced by subjecting said mixture to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad along the longitudinal direction of the clad; said film having a width of about 13 mm and a thickness of about 0.8 mm and containing 0.3% by weight of titanium dioxide.
- Example 5 A light fiber was prepared by repeating the procedure of Example 1, except that Neoflon® FEP NP20WH resin manufactured by Daikin Kogyo was replaced by a mixture of 2 kg of said Teflon® FEP 100-J resin with 1 kg of said Neoflon® FEP NP20WH resin.
- a clad having an outside diameter of about 12 mm and a thickness of about 0.8 mm was produced by subjecting said mixture to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad along the longitudinal direction of the clad; said film having a width of about 13 mm and a thickness of about 0.8 mm and containing 1% by weight of titanium dioxide.
- Example 6 A clad having an outside diameter of about 12 mm and a thickness of about 0.8 mm was prepared by charging said Teflon® FEP 100-J resin, and TFC SM-413 white resin containing a binder comprised of FEP having a refractive index of about 1.34 and 20% by weight of titanium dioxide and manufactured by Dai-nichi Seika Kogyo into 2 extruders of
- Example 1 respectively.
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.1 mm, running along the longitudinal direction of the clad, having a width of about 13 mm, and containing 20% by weight of titanium dioxide.
- a light fiber was produced, by using glycerin as a substitute for said core made of acrylic resin, by charging into the clad glycerin having a refractive index of about 1.475 that was almost equivalent to that of said core made of an acrylic resin so as to fill up within the clad therewith; and sealing the both ends of the clad with quartz rods.
- Example 7 A light fiber was prepared by repeating the procedure of Example 6, except that said TFC SM-413 white resin manufactured by Dai-nichi Seika Kogyo was replaced by a mixture obtained by mixing 1 kg each of Teflon® FEP 110-J manufactured by Du Pont and TFC SM-413 white resin manufactured by Dai-nichi Seika Kogyo.
- a clad having an outside diameter of about 18 mm and a thickness of about 0.8 mm was produced by subjecting said mixture to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.2 mm, running along the longitudinal direction of the clad, having a width of about 18 mm, and containing 10% by weight of titanium dioxide.
- a light fiber was prepared by repeating the procedure of Example 6, except that a clad having an outside diameter of about 18 mm and a thickness of about 0.8 mm was produced by charging Neoflon® ETFE EP521 resin manufactured by Daikin Kogyo having a refractive index of about 1.43 and AFC SM-412 white resin comprising a binder composed of ETFE having a refractive index of about 1.43 and 30% by weight of titanium dioxide, respectively into 2 extruders and subjecting said materials to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.5 mm, running along the longitudinal direction of the clad, having a width of about 20 mm, and containing 30%) by weight of titanium dioxide.
- Example 9 A light fiber was prepared by repeating the procedure of Example 8, except that said AFC SM-412 white resin manufactured by Dai-nichi Seika Kogyo was replaced by a mixture of 1 kg of same AFC SM-412 white resin and 9 kg of Neoflon® ETFE EP521 resin manufactured by Daikin Kogyo.
- a clad having an outside diameter of about 18 mm and a thickness of about 1.3 mm was produced by subjecting said mixture to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.5 mm, running along the longitudinal direction of the clad, having a width of about 20 mm and containing 3% by weight of titanium dioxide.
- a light fiber was prepared by repeating the procedure of Example 6, except that a clad having an outside diameter of about 18 mm and a thickness of about 0.8 mm was produced by charging fluorine-based polymer THV 500G having a refractive index of about 1.36 and manufactured by Sumitomo-3M, and a mixture comprising 5 kg of low density polyethylene LDPE 1122 manufactured by Chevron and of 1 kg of polyethylene PE-
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.4 mm, running along the longitudinal direction of the clad, having a width of about 20 mm and containing 10% by weight of titanium dioxide in
- LDPE having a refractive index of about 1.51.
- Example 11 A light fiber was prepared by repeating the procedure of Example 6, except that a clad having an outside diameter of about 18 mm and a thickness of about 0.9 mm was produced by charging a mixture of 10 kg of Teflon FEP 100-J resin and 0.1 kg of Neoflon FEP NP20WH resin manufactured by Daikin Kogyo, and the above-mentioned Neoflon FEP NP20WH manufactured by Daikin Kogyo, respectively into 2 extruders; and subjecting said materials to co-extrusion molding.
- a light diffusive and reflective film was formed in the clad; said film being as thin as about 0.5 mm, running along the longitudinal direction of the clad, having a width of about 22 mm and containing 3%) by weight of titanium dioxide.
- Example 12 A light fiber was prepared by repeating the procedure of Example 6, except that a clad having an outside diameter of about 9 mm and a thickness of about 0.7 mm was obtained by charging Teflon FEP 100-J resin and Neoflon FEP NP20WH resin, respectively, into 2 extruders, and subjecting said materials to co-extrusion molding. In this step, a light diffusive and reflective film was formed in the clad; said film running along the longitudinal direction of the clad, having a width of about 21 mm and a thickness of about 0.7 mm and containing 3% by weight of titanium dioxide.
- Example 13 A light fiber was prepared by repeating the procedure of Example 12, except that AFC SM-415 white resin containing a binder comprised of FEP having a refractive index of about 1.34 and 10% by weight of titanium dioxide, and manufactured by Dai-nichi Seika
- Neoflon FEP NP20WH resin was used as a substitute for Neoflon FEP NP20WH resin to form a clad having an outside diameter of about 12 mm and a thickness of about 0.8 mm by means of co- extrusion molding.
- a light diffusive and reflective film was formed along the longitudinal direction from in the clad thus obtained clad; said film having a width of about 1 mm and a thickness of about 0.8 mm and containing 10% by weight of titanium dioxide.
- a dispersion was prepared by adding 3g of Tipaque® CR-90 titanium dioxide manufactured by Ishihara Techno to a solution of 97 g of said fluorine-based polymer THV200P having a refractive index of about 1.36 and manufactured by Sumitomo-3M in
- an ethyl acetate solution(a solid content of 30%) of a copolymer made of 2-ethylhexylacrylate and acrylic acid in a weight ratio of 90:10 and having a refractive index of about 1.472 was coated onto Purex® GIW release liner to form a 5 ⁇ m thick adhesive layer. Then, thus formed adhesive layer was laminated on said light diffusive and reflective film.
- the light fibers obtained as above were evaluated.
- the evaluation was carried out as to the brightness and illuminance of a light extracted from the sidewall of the light fibers.
- the brightness was measured in the way as shown in Fig. 4.
- One end of the respective light fibers according to said Examples and Comparative Example was respectively connected with a metal halide lamp LBM130H manufactured by Sumitomo- 3M as the light source.
- a Minolta brightness meter CS-100 (not depicted) was disposed at a predetermined distance of 0.1 to 10 m from the light source to measure the brightness. Thereupon, the brightness meter was positioned at the site 60 cm away from the light fiber.
- the light leaked from the sidewall opposite to the site of sticking the light diffusive and reflective film to the core was also measured by using same measuring method at the predetermined distance.
- the performance of the clad tube according to the present invention can be evaluated by using a light fiber produced, without passing through the polymerization step, as in the case, especially the ones like Examples 6 to 13 in which glycerin was used as a core.
- Example 1 Extraction 21300 15100 12300 11900 9680 5120 2310 1150 416 118 Leakage 600 671 290 361 237
- the results of the brightness measurement was shown in Tables 1 and 2. According to Tables 1 and 2, it was found that the light fiber of Comparative Example leaked, through the light diffusive and reflective portion, light in an extent similar to that extracted when the light fiber extracted light in the forward direction by means of the light diffusive and reflective portion. On the contrary, in all the light fibers of said Examples, the brightness of the light leaked through the light diffusive and reflective portion was found to be, at most, 25% or lower of the brightness of the total light when the light fiber extracted it in the forward direction from the light diffusive and reflective portion.
- the light fibers of the present invention could reduce the light leakage through the light diffusive and reflective portion, extracting a comparatively strong light only in a specific direction from the sidewall.
- Those light fibers can be used for the application fields wherein a light having a high brightness is required, such as for example, as a substitute for neon sign.
- the ones wherein the illuminance in an area illuminated therewith are important, other than those wherein the brightness thereof is important as a yardstick for the performance of the light fiber, like the case with neon sign to take a look at directly with eyes.
- the illuminance on a floor space (30cm below) just under a point 50 cm away from the light source in the lengthwise direction of the light fiber was measured by using Minolta illuminometer T-1H, with lighting the light fibers of directional side light extraction type which had been cut 1 m long in Example 3 and Comparative Example 1 on one of whose end a reflecting mirror was pasted and on the other end of which was connected with a light source LBM130H and disposed horizontally on the height of 30 cm from the floor, respectively.
- the results are shown in Table 3.
- the leakage of light through the light diffusive and reflective film is reduced since the light fiber according to the present invention has a comparatively thick light diffusive and reflective film that is formed by co-extrusion molding at least on the inner periphery of the clad, whereby a comparatively strong light can be extracted in a specific direction from the sidewall of the light fibers.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Light Guides In General And Applications Therefor (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Non-Portable Lighting Devices Or Systems Thereof (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU48328/99A AU762580B2 (en) | 1998-08-10 | 1999-06-25 | A light fiber and a method for producing the same |
| JP2000565347A JP2002525643A (ja) | 1998-08-10 | 1999-06-25 | ライトファイバおよびその製造方法 |
| DE69916462T DE69916462T2 (de) | 1998-08-10 | 1999-06-25 | Lichtfaser und verfahren zur herstellung |
| BR9912880-2A BR9912880A (pt) | 1998-08-10 | 1999-06-25 | Fibra de luz, e, processo para produzir a mesma |
| EP99931917A EP1105673B1 (en) | 1998-08-10 | 1999-06-25 | A light fiber and a method for producing the same |
| KR1020017001708A KR20010072361A (ko) | 1998-08-10 | 1999-06-25 | 광섬유 및 그 제조 방법 |
| US09/762,912 US6563993B1 (en) | 1998-08-10 | 1999-06-25 | Light fiber and a method for producing the same |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10226212A JP2000056136A (ja) | 1998-08-10 | 1998-08-10 | ライトファイバおよびその製造方法 |
| JP10/226212 | 1998-08-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000009943A1 true WO2000009943A1 (en) | 2000-02-24 |
Family
ID=16841662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1999/014429 Ceased WO2000009943A1 (en) | 1998-08-10 | 1999-06-25 | A light fiber and a method for producing the same |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP1105673B1 (enExample) |
| JP (2) | JP2000056136A (enExample) |
| KR (1) | KR20010072361A (enExample) |
| AU (1) | AU762580B2 (enExample) |
| BR (1) | BR9912880A (enExample) |
| DE (1) | DE69916462T2 (enExample) |
| WO (1) | WO2000009943A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1336875A1 (de) * | 2002-02-16 | 2003-08-20 | Preh-Werke GmbH & Co. KG | Lichtleiter |
| ITRM20120387A1 (it) * | 2012-08-03 | 2014-02-04 | Headway Srl | "guida di luce" |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070258085A1 (en) * | 2006-05-02 | 2007-11-08 | Robbins Michael D | Substrate illumination and inspection system |
| KR20040049572A (ko) * | 2002-12-06 | 2004-06-12 | 삼성전자주식회사 | 발산형 플라스틱 광섬유를 이용한 액정표시장치용백라이트 유닛 |
| JP2006317844A (ja) * | 2005-05-16 | 2006-11-24 | Three M Innovative Properties Co | 側面発光型光ファイバー及び発光装置 |
| DE102008034791B4 (de) | 2008-07-25 | 2022-01-20 | Schott Ag | Preformen und Verfahren zur Herstellung von seitenemittierenden Stufenindexfasern |
| DE102008009139B4 (de) * | 2008-02-14 | 2021-09-23 | Schott Ag | Seitenemittierende Stufenindexfaser, Faserbündel und Flächengebilde und deren Verwendungen sowie Preformen und Verfahren zu deren Herstellung |
| DE102008009137B4 (de) * | 2008-02-14 | 2017-09-21 | Schott Ag | Seitenemittierende Stufenindexfaser |
| JP5480822B2 (ja) | 2008-02-14 | 2014-04-23 | ショット アクチエンゲゼルシャフト | 側面光放射ステップ・インデックス型ファイバ |
| JP5885196B2 (ja) * | 2011-08-18 | 2016-03-15 | フクビ化学工業株式会社 | 光ファイバ型線状発光体の製造方法、及び光ファイバ型線状発光体 |
| KR101971692B1 (ko) * | 2012-12-17 | 2019-04-25 | 엘지이노텍 주식회사 | 차량용 조명유닛 |
| JP6287421B2 (ja) * | 2014-03-24 | 2018-03-07 | 株式会社デンソー | ライトガイド部材、ライトガイド部材用のアタッチメント、イルミネーション装置 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0470604A (ja) * | 1990-07-06 | 1992-03-05 | Hitachi Cable Ltd | 合成樹脂光伝送体の製造方法 |
| JPH06118244A (ja) * | 1992-10-02 | 1994-04-28 | Mitsubishi Rayon Co Ltd | 照光プラスチック光ファイバ |
| WO1998020279A1 (en) * | 1996-11-07 | 1998-05-14 | Minnesota Mining And Manufacturing Company | Light-illuminating rods |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60118806A (ja) * | 1983-11-30 | 1985-06-26 | Agency Of Ind Science & Technol | 照明具 |
| JPH01109303A (ja) * | 1987-10-23 | 1989-04-26 | Hitachi Ltd | 表示用光フアイバ |
| JPH0514619A (ja) * | 1991-07-04 | 1993-01-22 | Minolta Camera Co Ltd | 画像読取装置 |
| JP2000039520A (ja) * | 1998-07-24 | 2000-02-08 | Bridgestone Corp | 光伝送チューブ及びその製造方法 |
| JP2000039517A (ja) * | 1998-07-24 | 2000-02-08 | Bridgestone Corp | 光伝送チューブ及びその製造方法 |
| JP2000039521A (ja) * | 1998-07-24 | 2000-02-08 | Bridgestone Corp | 光伝送チューブ及びその製造方法 |
-
1998
- 1998-08-10 JP JP10226212A patent/JP2000056136A/ja active Pending
-
1999
- 1999-06-25 WO PCT/US1999/014429 patent/WO2000009943A1/en not_active Ceased
- 1999-06-25 DE DE69916462T patent/DE69916462T2/de not_active Expired - Fee Related
- 1999-06-25 AU AU48328/99A patent/AU762580B2/en not_active Ceased
- 1999-06-25 EP EP99931917A patent/EP1105673B1/en not_active Expired - Lifetime
- 1999-06-25 JP JP2000565347A patent/JP2002525643A/ja active Pending
- 1999-06-25 BR BR9912880-2A patent/BR9912880A/pt active Search and Examination
- 1999-06-25 KR KR1020017001708A patent/KR20010072361A/ko not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0470604A (ja) * | 1990-07-06 | 1992-03-05 | Hitachi Cable Ltd | 合成樹脂光伝送体の製造方法 |
| JPH06118244A (ja) * | 1992-10-02 | 1994-04-28 | Mitsubishi Rayon Co Ltd | 照光プラスチック光ファイバ |
| WO1998020279A1 (en) * | 1996-11-07 | 1998-05-14 | Minnesota Mining And Manufacturing Company | Light-illuminating rods |
Non-Patent Citations (2)
| Title |
|---|
| PATENT ABSTRACTS OF JAPAN vol. 16, no. 272 (P - 1373) 18 June 1992 (1992-06-18) * |
| PATENT ABSTRACTS OF JAPAN vol. 18, no. 402 (P - 1777) 27 July 1994 (1994-07-27) * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1336875A1 (de) * | 2002-02-16 | 2003-08-20 | Preh-Werke GmbH & Co. KG | Lichtleiter |
| ITRM20120387A1 (it) * | 2012-08-03 | 2014-02-04 | Headway Srl | "guida di luce" |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002525643A (ja) | 2002-08-13 |
| AU4832899A (en) | 2000-03-06 |
| AU762580B2 (en) | 2003-06-26 |
| KR20010072361A (ko) | 2001-07-31 |
| DE69916462T2 (de) | 2005-03-24 |
| DE69916462D1 (de) | 2004-05-19 |
| EP1105673A1 (en) | 2001-06-13 |
| BR9912880A (pt) | 2001-05-08 |
| JP2000056136A (ja) | 2000-02-25 |
| EP1105673B1 (en) | 2004-04-14 |
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