WO2000008216A1 - Apparatus and method for the secondary refinement of metals - Google Patents

Apparatus and method for the secondary refinement of metals Download PDF

Info

Publication number
WO2000008216A1
WO2000008216A1 PCT/IB1999/001334 IB9901334W WO0008216A1 WO 2000008216 A1 WO2000008216 A1 WO 2000008216A1 IB 9901334 W IB9901334 W IB 9901334W WO 0008216 A1 WO0008216 A1 WO 0008216A1
Authority
WO
WIPO (PCT)
Prior art keywords
vessel
bath
paddle
metal
slag
Prior art date
Application number
PCT/IB1999/001334
Other languages
English (en)
French (fr)
Inventor
Louis Johannes Fourie
Original Assignee
Ipcor N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ipcor N.V. filed Critical Ipcor N.V.
Priority to CA002305741A priority Critical patent/CA2305741A1/en
Priority to JP2000563838A priority patent/JP2002522634A/ja
Priority to BR9906673-4A priority patent/BR9906673A/pt
Priority to AU46426/99A priority patent/AU4642699A/en
Priority to EP99929649A priority patent/EP1021571A1/en
Priority to SK508-2000A priority patent/SK5082000A3/sk
Priority to PL99339670A priority patent/PL339670A1/xx
Publication of WO2000008216A1 publication Critical patent/WO2000008216A1/en
Priority to BG104298A priority patent/BG104298A/xx

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D27/00Stirring devices for molten material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • B22D1/002Treatment with gases
    • B22D1/005Injection assemblies therefor
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/003General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals by induction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27BFURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B14/00Crucible or pot furnaces
    • F27B14/06Crucible or pot furnaces heated electrically, e.g. induction crucible furnaces with or without any other source of heat
    • F27B14/061Induction furnaces
    • F27B14/065Channel type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/18Charging particulate material using a fluid carrier
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/16Introducing a fluid jet or current into the charge
    • F27D2003/161Introducing a fluid jet or current into the charge through a porous element
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00Subject matter not provided for in other groups of this subclass
    • F27D99/0001Heating elements or systems
    • F27D99/0006Electric heating elements or system
    • F27D2099/0021Arc heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D99/00Subject matter not provided for in other groups of this subclass
    • F27D99/0001Heating elements or systems
    • F27D99/0006Electric heating elements or system
    • F27D2099/0031Plasma-torch heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/14Charging or discharging liquid or molten material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/15Tapping equipment; Equipment for removing or retaining slag
    • F27D3/1545Equipment for removing or retaining slag
    • F27D3/1554Equipment for removing or retaining slag for removing the slag from the surface of the melt
    • F27D3/1563Equipment for removing or retaining slag for removing the slag from the surface of the melt by the use of scrapers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D7/00Forming, maintaining, or circulating atmospheres in heating chambers
    • F27D7/02Supplying steam, vapour, gases, or liquids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • This invention relates to an apparatus and a method for the secondary refinement of metals, particularly steel.
  • ladle furnaces are used extensively for controlling the temperature of the steel coming from a steel furnace and for refining it prior to casting through continuous casting machines.
  • a steel casting ladle is positioned under a hood, and electric arc heating applied to the upper surface of the steel in the ladle while argon gas is bubbled through the steel to distribute the heat throughout the contents of the ladle.
  • the aforesaid bubbling of argon gas is usually effected by introducing such gas through one or more porous elements located on the bottom of the ladle.
  • Such argon gas bubbling is indispensable for ensuring good mass and heat transfer conditions between the steel and the slag.
  • electromagnetic stirring may be used for obtaining additional benefits.
  • Steel ladles are vertically disposed cylindrical vessels, of which the depth to diameter ratio is normally larger than 1 , and smaller than 2. It will be appreciated that one of the main reasons for having such vessels so vertically disposed, is to maintain the surface area of the bath as small as possible and hence retain the energy of the metal bath inside it.
  • a further disadvantage found with such a vertically disposed vessel is that the surface to volume ratio of the metal bath in the vessel is relatively small.
  • the metal-slag surface area is increased, thereby reducing the thickness of the slag layer.
  • the substantially circular configuration of the surface of the slag layer puts a restriction on the width of such a paddle in the sense that a paddle which is wide enough to extend over the whole width of the slag layer near such lip, is too narrow in a position further away from such lip, thus allowing slag to escape around its ends.
  • apparatus for use in the secondary refinement of a metal, particularly steel includes an elongated vessel of which the length to width ratio is greater than two, the vessel being provided with at least one channel type inductor adapted for heating the vessel, and the vessel being adapted in operation to be located with its long side substantially horizontally disposed.
  • the aspect ratio of a metal/slag bath inside the vessel i.e. the ratio of the length of its surface to the width of its surface, will be larger than two. It will further be appreciated that the surface area of such a metal/slag bath will be much larger than what the case is with the conventional vertically disposed vessel so that a much larger contact area is available for reaction with chemicals added to the bath for the secondary refining of the metal and/or for the removal of sulphur from such bath and/or for the interaction between the metal bath and its overlying slag layer.
  • the at least one inductor is disposed substantially along the centre of the bottom side of the vessel when it is so horizontally disposed.
  • Applicant has found that the fact that the bath in such a vessel is heated from below, coupled to the fact that a relatively low metallo static head is present, together with the resulting convection streams, ensure that a sufficiently strong stirring action is created in the vicinity of the inductor(s) to cause effective slag/metal interaction and homogeneous distribution of the refined metal and impurity saturated slag.
  • the fluxes and alloys which are required in the refining process can be added in an at least semi-continuous stream to the surface of the metal bath directly above the inductor(s), i.e. where the most active stirring motion is achieved. It will be appreciated that any such fluxes etc which are required in the metal bath can also in conventional manner be introduced to the bath through one or more lances passing from above into the bath.
  • additional stirring of the metal bath may be effected by introducing argon and/or nitrogen gas into the bath by means of one or more lances or porous element stirring devices located in the vessel.
  • any additional heating which may be required may be effected in conventional manner by means of one or more plasma torches and/or three phase electric arc electrodes.
  • the vessel is of round cylindrical configuration in cross section.
  • the vessel is provided towards at least one of its shorter ends with an opening through which a paddle or the like can be inserted for scraping the spent slag layer from the metal bath in the vessel.
  • a paddle can be used which substantially spans the whole width of the slag layer over substantially the whole length of the slag layer. By pushing or pulling such a paddle along the slag layer, the spent slag can be removed from the top of the metal bath in a very effective manner.
  • At least one of the said shorter ends of the vessel may be provided with a recessed outlet.
  • the width of the paddle is slightly less than the width of the vessel, the narrow gaps so left between the ends of the paddle and the walls of the vessel ensuring free movement of the paddle in the vessel.
  • air or nitrogen may be blown into such gaps to prevent the slag from escaping through the gaps when the paddle is moved along the slag layer.
  • the invention also includes within its scope a method for the secondary refining of a metal using the apparatus disclosed above.
  • Figure 1 is a diagrammatic side view of apparatus according to the invention
  • Figure 2 is a diagrammatic cross sectional view of the apparatus of figure 2, as seen on line I : I in figure 1 ;
  • Figure 3 is a diagrammatic plan view of the apparatus of figure 1 as seen in the direction arrow A in figure 1.
  • apparatus for carrying out the secondary refinement of a metal comprises a horizontally disposed refractory lined cylindrical vessel 10 of which the length to diameter ratio is greater than 2.
  • the length of vessel 10 may, for example, be in the order of 8m and its diameter in the order of 2m, the intention being that it will be filled with liquid metal 11 to a depth in the order of 1 m.
  • vessel 10 is shown in the drawings as being of circular configuration in cross section, it can be of any other suitable configuration in cross section such as, for example, substantially square, triangular, etc.
  • Vessel 10 is provided along its upper wall with an inlet 12 through which fluxes or the like may be charged to it. Vessel 10 is also provided along the centre of its bottom wall with at least one channel type inductor 13 of 3MW capacity. The upper wall of vessel 10 is also provided along each of its opposite ends with an opening 14 through which an elongated slag paddle 15 may be inserted which is operated by means of a handle 16, the width of paddle 15 being slightly less than the diameter of vessel 10.
  • Openings 14 are provided with lids (not shown).
  • Vessel 10 is also provided with a lance 17 which passes from above into metal bath 11 and through which argon and/or nitrogen may be passed into bath 11 for stirring purposes.
  • vessel 10 may also be provided with one or more porous stirring elements which can be fed with argon and/or nitrogen in order to assist in the stirring of bath 11. Only one of these is shown in dotted lines at 18 in figure 1 of the drawings.
  • the molten metal to be refined is charged to vessel 10 through one of the openings 14 to form a bath with a depth in the order of 1m, and the required fluxes introduced through inlet 12.
  • lnductor(s) 13 when switched on, not only serve(s) to heat up bath 11 , but through convection and electromagnetic forces also cause(s) the stirring of bath 11.
  • stirring may be supplemented by passing argon and/or nitrogen through lance 17 (or element(s) 18) into bath 11.
  • paddle 15 is inserted through one of the openings 14, and the slag in layer 19 raked or pushed out through recessed outlets (not shown) provided in the said outer ends of vessel 10.
  • the width of paddle 15 is slightly less than the cross sectional diameter of vessel 10 so that when paddle 15 engages slag layer 19, narrow gaps 20 are left between the outer ends of paddle 15 and the inside wall of vessel 10 to allow paddle 15 relatively free to-and-fro movement in vessel 10.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Manufacture And Refinement Of Metals (AREA)
PCT/IB1999/001334 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals WO2000008216A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CA002305741A CA2305741A1 (en) 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals
JP2000563838A JP2002522634A (ja) 1998-08-07 1999-07-28 金属を2次精錬する装置および方法
BR9906673-4A BR9906673A (pt) 1998-08-07 1999-07-28 Aparelho e processo para o refino secundário de metais
AU46426/99A AU4642699A (en) 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals
EP99929649A EP1021571A1 (en) 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals
SK508-2000A SK5082000A3 (en) 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals
PL99339670A PL339670A1 (en) 1998-08-07 1999-07-28 Apparatus for and method of secondary refining metals
BG104298A BG104298A (en) 1998-08-07 2000-04-04 Apparatus and method for secondary metal refinement

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA987125 1998-08-07
ZA98/7125 1998-08-07

Publications (1)

Publication Number Publication Date
WO2000008216A1 true WO2000008216A1 (en) 2000-02-17

Family

ID=25587196

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB1999/001334 WO2000008216A1 (en) 1998-08-07 1999-07-28 Apparatus and method for the secondary refinement of metals

Country Status (12)

Country Link
EP (1) EP1021571A1 (tr)
JP (1) JP2002522634A (tr)
CN (1) CN1274390A (tr)
AU (1) AU4642699A (tr)
BG (1) BG104298A (tr)
BR (1) BR9906673A (tr)
CA (1) CA2305741A1 (tr)
PL (1) PL339670A1 (tr)
SK (1) SK5082000A3 (tr)
TR (1) TR200000919T1 (tr)
TW (1) TW446753B (tr)
WO (1) WO2000008216A1 (tr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971547A (en) * 1973-08-23 1976-07-27 Allmanna Svenska Elektriska Aktiebolaget Apparatus and method for refining metal
US4395281A (en) * 1980-12-23 1983-07-26 Asea Ab Treating molten pig iron in a torpedo
EP0252308A1 (de) * 1986-06-12 1988-01-13 Centrem S.A. Verfahren zum Behandeln von Metallschmelzen und Vorrichtung zum Durchführen des Verfahrens
JPH08269517A (ja) * 1995-03-28 1996-10-15 Kobe Steel Ltd 混銑車の溶銑予備処理方法及びその溶銑予備処理装置

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3971547A (en) * 1973-08-23 1976-07-27 Allmanna Svenska Elektriska Aktiebolaget Apparatus and method for refining metal
US4395281A (en) * 1980-12-23 1983-07-26 Asea Ab Treating molten pig iron in a torpedo
EP0252308A1 (de) * 1986-06-12 1988-01-13 Centrem S.A. Verfahren zum Behandeln von Metallschmelzen und Vorrichtung zum Durchführen des Verfahrens
JPH08269517A (ja) * 1995-03-28 1996-10-15 Kobe Steel Ltd 混銑車の溶銑予備処理方法及びその溶銑予備処理装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 199, no. 702 28 February 1997 (1997-02-28) *

Also Published As

Publication number Publication date
AU4642699A (en) 2000-02-28
BR9906673A (pt) 2000-08-29
JP2002522634A (ja) 2002-07-23
PL339670A1 (en) 2001-01-02
EP1021571A1 (en) 2000-07-26
SK5082000A3 (en) 2000-10-09
CA2305741A1 (en) 2000-02-17
TW446753B (en) 2001-07-21
TR200000919T1 (tr) 2000-11-21
CN1274390A (zh) 2000-11-22
BG104298A (en) 2000-08-31

Similar Documents

Publication Publication Date Title
CA1300898C (en) Melting furnace and method for melting metal
RU2285052C2 (ru) Рафинирование стали в ковше
JP3972266B2 (ja) 二重容器アーク炉を運転する方法及び装置
EP0030220A2 (en) Method for adding solids to molten metal
US3918692A (en) Apparatus for refining molten metals and molten metal refining process
WO2000008216A1 (en) Apparatus and method for the secondary refinement of metals
US6490312B1 (en) Direct-current arc furnace comprising a centric charging shaft for producing steel and a method therefor
US4588170A (en) Side mounted lance for ladles
CA1323494C (en) Process for heating molten steel contained in a ladle
US3934863A (en) Apparatus for refining molten metal and molten metal refining process
US5738823A (en) Meltdown apparatus
US3556502A (en) Reaction vessel for reacting together two liquids of different specific gravities
MXPA00002867A (en) Apparatus and method for the secondary refinement of metals
DE3373014D1 (en) Process for operating a metallurgical melting-furnace, and metallurgical melting-furnace
JP2889901B2 (ja) 液状鋼浴再加熱方法
KR100328035B1 (ko) 진공순환탈가스설비의용강승온방법및그장치
KR20180040587A (ko) 채널형 유도로
JPH0596266A (ja) フイルターダストの溶融方法
JPH0254715A (ja) 溶鋼の脱ガス処理方法
CZ20001275A3 (cs) Zařízení a způsob k provádění sekundární rafinace kovů
US3554519A (en) Furnace for producing steel continuously
US4681625A (en) Methods for simultaneously desulfurizing and degassing steels
RU2151805C1 (ru) Способ обработки кипящей стали в ковше
JPH08143943A (ja) 溶湯の精錬方法
JPH0478690B2 (tr)

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 99801308.0

Country of ref document: CN

AK Designated states

Kind code of ref document: A1

Designated state(s): AE AL AM AT AU AZ BA BB BG BR BY CA CH CN CU CZ DE DK EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW SD SL SZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 46426/99

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: IN/PCT/2000/30/CHE

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 1020007003011

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 1999929649

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: PA/a/2000/002867

Country of ref document: MX

ENP Entry into the national phase

Ref document number: 2305741

Country of ref document: CA

Ref document number: 2305741

Country of ref document: CA

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2000/00919

Country of ref document: TR

WWE Wipo information: entry into national phase

Ref document number: 5082000

Country of ref document: SK

Ref document number: PV2000-1275

Country of ref document: CZ

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 09508141

Country of ref document: US

WWP Wipo information: published in national office

Ref document number: 1999929649

Country of ref document: EP

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WWP Wipo information: published in national office

Ref document number: 1020007003011

Country of ref document: KR

WWP Wipo information: published in national office

Ref document number: PV2000-1275

Country of ref document: CZ

WWW Wipo information: withdrawn in national office

Ref document number: 1999929649

Country of ref document: EP

WWR Wipo information: refused in national office

Ref document number: PV2000-1275

Country of ref document: CZ

WWW Wipo information: withdrawn in national office

Ref document number: 1020007003011

Country of ref document: KR