WO1999059753A1 - Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants - Google Patents

Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants Download PDF

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Publication number
WO1999059753A1
WO1999059753A1 PCT/SE1998/000925 SE9800925W WO9959753A1 WO 1999059753 A1 WO1999059753 A1 WO 1999059753A1 SE 9800925 W SE9800925 W SE 9800925W WO 9959753 A1 WO9959753 A1 WO 9959753A1
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Prior art keywords
powder
iron
metallurgical
composition
weight
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Application number
PCT/SE1998/000925
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English (en)
Inventor
Sydney Luk
Original Assignee
Höganäs Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Höganäs Ab filed Critical Höganäs Ab
Priority to EP98929953A priority Critical patent/EP1094909B1/fr
Priority to AU79450/98A priority patent/AU7945098A/en
Priority to JP2000549406A priority patent/JP3964135B2/ja
Priority to PCT/SE1998/000925 priority patent/WO1999059753A1/fr
Priority to DE69828315T priority patent/DE69828315T2/de
Priority to AT98929953T priority patent/ATE285306T1/de
Priority to ES98929953T priority patent/ES2230700T3/es
Publication of WO1999059753A1 publication Critical patent/WO1999059753A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/02—Compacting only
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C33/00—Making ferrous alloys
    • C22C33/02—Making ferrous alloys by powder metallurgy
    • C22C33/0207—Using a mixture of prealloyed powders or a master alloy
    • C22C33/0228—Using a mixture of prealloyed powders or a master alloy comprising other non-metallic compounds or more than 5% of graphite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12—Both compacting and sintering
    • B22F3/14—Both compacting and sintering simultaneously
    • B22F2003/145—Both compacting and sintering simultaneously by warm compacting, below debindering temperature

Definitions

  • the present invention rel'ates to iron-based metallurgical powder compositions. More particularly, the present invention relates to such compositions containing flow agents to improve the flow characteristics of the powder compositions, particularly at elevated processing temperatures .
  • a metallurgical powder composition is used to produce metal parts in accordance with well established techniques.
  • the metallurgical powder is poured into a compaction die and compacted under high pressure, and in some circumstances elevated temperatures, to form the compacted, or "green", part.
  • This green part is then sintered to form a cohesive metallic part.
  • the sintering operation arso burns off any organic materials, such as the residue of any die lubricant or internal lubricant, from the metallic material.
  • the speed and efficiency at which such parts can be produced is affected by the flow characteristics of the metallurgical powder.
  • the metallurgical powder In most production processing techniques, the metallurgical powder must flow, by gravity, from a storage bin into a container, or "shoe", that transports the powder from the storage site to the die. The powder is then poured from the shoe into the die cavity. The speed at which the powder can flow is a rate determining step for the manufacturing of parts in many instances .
  • metallurgical powder compositions particularly iron-based powder compositions, that can be utilised in compaction operations conducted at "warm” pressing conditions. Improved powder compositions useful in such compaction
  • CONFIRMATION COPY operations are set forth in US Patent No 5 154 881 to Rutz and Luk, which is incorporated herein by reference in its entirety.
  • the powder and/or the die cavity is heated, to a temperature up to about 370°C, for compaction.
  • it has been found that the flow ability of certain iron-based powder compositions is ad- versely affected by those processing temperatures.
  • the present invention provides iron-based metallur- gical powder compositions that are characterised by having superior flow properties, particularly at elevated temperatures associated with warm compaction operations.
  • the invention also provides methods for using the powder compositions to produce compacted parts.
  • a flow agent is incorporated into an iron-based powder composition; the presence of the flow agent enhances the flowability of the powder composition, particularly at elevated temperatures.
  • the flow agent materials are nanoparticles of various metals and their oxides. Typically, the metal and metal oxide powders have average particle sizes below about 500 nanometers.
  • the iron-based powder composition is blended with a silicon oxide flow agent.
  • the silicon oxide flow agents are preferably blended with the iron-based powders in an amount of from about 0.005 to about 2 percent by weight of the resultant powder composition.
  • the preferred silicon oxide having an average particle size below about 40 nanometers.
  • the iron-based powder composition is blended with an iron oxide flow agent.
  • the preferred iron oxide flow agents have an average particle size below about 500 nanometers.
  • the iron oxide flow agents are preferably blended with the iron-based powders in an amount of from about 0.01 to about 2 percent by weight of the resultant powder compo- sition. It is particularly advantageous to blend the iron oxide flow agents with the silicon oxide flow agents.
  • the addition of the flow agents is particularly beneficial for enhancing the flow properties of those iron-based powder compositions used in warm compaction processes.
  • the compositions preferably include a lubricant specifically designed for such warm compaction applications, and where necessary, a binding agent specifically designed for such applications.
  • the present invention provides improved metallurgical powder compositions having superior flow characteristics, particularly at elevated temperatures.
  • the metallurgical powder compositions are generally those containing an iron-based powder, and optionally a lubricant powder and/or a binding agent, and are improved by the further addition of a flow agent powder having a defined particle size distribution.
  • the metal powder compositions that are the subject of the present invention contain iron-based powders of the kind generally used in powder metallurgical methods.
  • iron-based powders are powders of substantially pure iron; particles of iron pre-alloyed with other elements (for example, steel-producing elements) that enhance the strength, hardenability, electromagnetic properties, or other desirable properties of the final product; particles of iron to which such other elements have been diffusion bonded; and particles of iron in admixture with particles of such alloying elements.
  • the iron-based powders generally constitute at least about 85 percent by weight and more commonly at least about 90 percent by weight of the metal powder composition.
  • Substantially pure iron powders that can be used in the invention are powders of iron containing not more than about 1.0% by weight, preferably no more than about 0.5% by weight, of normal impurities.
  • Examples of such highly compressible, metallurgical-grade iron powders are the ANCORSTEEL 1000 series of pure iron powders, e.g. 1000, 1000B and 1000C, available from Hoeganaes Corporation, Riverton, New Jersey and similar powders available from H ⁇ ganas AB, Sweden.
  • ANCORSTEEL 1000 iron powder has a typical screen profile of about 22% by weight of the particles below a No. 325 sieve (U.S. series) and about 10% by weight of the particles larger than a No.
  • the ANCORSTEEL 1000 powder has an apparent density of from about 2.85-3.00 g/cm 3 , typically 2.94 g/cm 3 .
  • Other iron powders that can be used in the invention are typical sponge iron powders, such a Hoeganaes 1 ANCOR MH-100 powder.
  • the iron-based powders can also include iron, preferably substantially pure iron, that has been pre- alloyed, diffusion bonded, or admixed with one or more alloying elements.
  • alloying elements that can be combined with the iron particles include, but are not limited to, molybdenum; manganese; magnesium; chromium; silicon; copper; nickel; gold; vanadium; columbium (niobium) ; graphite; phosphorus; aluminium; binary alloys of copper and tin or phosphorus; Ferro-alloys of manganese, chromium, boron, phosphorus, or silicon; low melting ternary and quaternary eutectics of carbon and two or three of iron, vanadium, manganese, chromium, and molybdenum; carbides of tungsten or silicon; silicon nitride; aluminium oxide; and sulphides of manganese or molybdenum, and combinations thereof.
  • the alloying elements are generally combined with the iron powder, preferably the substantially pure iron powder in an amount of up to about 7% by weight, more preferably from about 0.25% to about 5% by weight, more preferably from about 0.25% to about 4% by weight, although in certain specialised uses the alloying elements may be present in an amount of from about 7% to about 15% by weight, of the iron powder and alloying element.
  • the iron-based powders can thus include iron particles that are in admixture with the alloying elements that are in the form of alloying powders.
  • alloying powder refers to any par ' ticu- late element or compound, as previously mentioned, physically blended with the iron particles, whether or not that element or compound ultimately alloys with the iron powder.
  • the alloying-element particles generally have a weight average particle size below about 100 microns, preferably below about 75 microns, more preferably below about 30 microns.
  • Binding agents are preferably included in admixtures of iron particles and alloying powders to prevent dusting and segregation of the alloying powder from the iron powder. Examples of commonly used binding agents include those set forth in U.S. Patent Nos .
  • Binding agents can be blended into the metal powder compositions in amounts of from about 0.005-3% wt., preferably about 0.05-1.5% wt., and more preferably about 0.1-1% wt . , based on the weight of the iron and alloying powders.
  • the iron-based powder can further be in the form of iron that has been pre-alloyed with one or more of the alloying elements.
  • the pre-alloyed powders can be prepared by making a melt of iron and the desired alloying elements, and then atomising the melt, whereby the atomised droplets form the powder upon solidification.
  • the amount of the alloying element or elements incorporated depends upon the properties desired in the final metal part.
  • Pre-alloyed iron powders that incorporate such alloying elements are available from Hoeganaes Corp. as part of its ANCORSTEEL line of powders.
  • iron-based powders is diffusion-bonded iron-based powder
  • example is a powder which are particles of substantially pure iron that have a layer or coating of one or more other metals, such as steel-producing elements and the alloying elements set forth above, diffused into their outer surfaces.
  • Such commercially available powders include DISTALOY 4600A diffusion bonded powder from Hoeganaes Corporation', which contains about 1.8% nickel, about 0.55% molybdenum, and about 1.6% copper, and DISTALOY 4800A diffusion bonded powder from Hoeganaes Corporation, which contains about 4.05% nickel, about 0.55% molybdenum, and about 1.6% copper. Similar grade powders are also available from H ⁇ ganas AB, Sweden.
  • a preferred iron-based powder is of iron pre-alloyed with molybdenum (Mo) .
  • the powder is produced by atomising a melt of substantially pure iron containing from about 0.5 to about 2.5 weight percent Mo.
  • An example of such a powder is Hoeganaes ANCORSTEEL 85HP steel powder, which contains about 0.85 weight percent Mo, less than about 0.4 weight percent, in total, of such other materials as manganese, chromium, silicon, copper, nickel, molybdenum or aluminium, and less than about 0.02 weight percent carbon.
  • Another example of such a powder is Hoeganaes
  • ANCORSTEEL 4600V steel powder which contains about 0.5- 0.6 weight percent molybdenum, about 1.5-2.0 weight per- cent nickel, and about 0.1-0.25 weight percent manganese, and less than about 0.02 weight percent carbon.
  • This steel powder composition is an admixture of two different pre-alloyed iron-based powders, one being a pre-alloy of iron with 0.5-2.5 weight percent molybdenum, the other being a pre- alloy of iron with carbon and with at least about 25 weight percent of a transition element component, wherein this component comprises at least one element selected from the group consisting of chromium, manganese, vana- dium, and columbium.
  • the admixture is in proportions that provide at least about 0.05 weight percent of the transition element component to the steel powder composition.
  • Such a powder is commercially available as Hoeganaes ANCORSTEEL 41 AB steel powder, which contains about 0.85 weight percent molybdenum, about 1 weight percent nickel, about 0.9 weight percent manganese, about 0.75 weight percent chromium, and about 0.5 weight percent carbon.
  • iron-based powders that are useful in the practice of the invention are ferromagnetic powders.
  • An example is a composition of substantially pure iron powders in admixture with powder of iron that has been pre- alloyed with small amounts of phosphorus.
  • each particle has a substantially uniform circumferential coating about the iron core particle.
  • Sufficient thermoplastic material issued to provide a coating of about 0.001-15% by weight of the iron particles as coated.
  • the thermoplastic material is present in an amount of at least 0.2% by weight, preferably about 0.4- 2% by weight, and more preferably about 0.6-0.9% by weight of the coated particles ' .
  • thermoplastics such as poplyethersulfones, polyetherimides, polycarbonates, or polyphenylene ethers, having a weight average molecular weight in the range of about 10 000 to 50 000.
  • Other polymeric coated iron-based powders include those containing an inner coating of iron phosphate as set forth in U.S. Patent No. 5 063 011 to Rutz et al . , which is incorporated herein in its entirety.
  • the particles of pure iron, pre-alloyed iron, diffusion bonded iron, or thermoplastic coated iron can have a weight average particle size as small as one micron or below, or up to about 850-1000 microns, but generally the particles will have a weight average particle size in the range of about 10-500 microns. Preferred are those having a maximum number average particle size up to about ' 350 microns, preferably 50-150 microns.
  • the flow behaviour of composition of iron-based powders is an important physical characteristic for it directly affects the rate at which parts can be manufactured by using conventional powder metallurgy techniques.
  • the present invention provides for the improvement of the flow of the generally known and used iron-based powders by incorporating a particulate flow agent. It has been found that the presence of the flow agent, having a defined particle size distribution, enhances the flow characteristics of the metal powder composition, particularly at elevated temperatures.
  • the flow agent should not adversely effect the compactability of the powder composition, nor should it adversely effect the compacted (green) or sintered properties of the resulting parts.
  • the flow agents of the present invention can be referred to as "nanoparticles" in that they are particulate materials wherein a majority of the powder has a particle diameter below 1 micron.
  • the particle size distribution of the flow agents can be determined by various means.
  • the term "average particle size” as used with respect to the present invention is determined, on a weight basis, in accordance with formula (I) :
  • the density of the powder is determined using standard procedures such as those set forth in testing stan- dard ASTM D70.
  • the surface area is the BET (Brunauer, Emmett, Teller) surface area determined using standard procedures such as those set forth in ASTM D4820.
  • the particle size distribution can be verified by means of electron microscopy, which can be used to visually exa- mine the particle size of the powder.
  • the flow agents can be selected from those metals and metal oxides having average particle sizes below about 500 nm, preferably below about 250 nm, and more preferably below about 100 nm, and are thus referred to as nanoparticle materials.
  • Representative metals that can be used as the nanoparticle materials in either their metal or metal oxide forms include silicon, aluminium, copper, iron, nickel, titanium, gold, silver, platinum, palladium, bismuth, cobalt, manganese, magnesium, lead, tin, vanadium, yttrium, niobium, tungsten, and zirconium. Such materials are commercially available from ULTRAM International.
  • nanoparticle materials are present in the metallurgical compositions in an amount of from about 0.005 to about 2 percent by weight, preferably from about 0.01 to about 1 percent by weight, and more preferably from about 0.025 to about 0.5 percent by weight, based on the total weight of the metallurgical composi- tion.
  • Preferred flow agents are oxides of silicon, and the other nanoparticle materials can be beneficially admixed with the silicon oxides to further enhance the flow of the metallurgical powder composition.
  • the silicon oxides particularly useful in the practice of the present invention are those that have a surface area of between about 75 and about 600 m 2 /g, preferably between about 100 and about 500 m 2 /g, and more preferably between about 150 and about 500 m 2 /g.
  • the den- sity of the silicon oxides is preferably between about
  • the silicon oxides have an average particle size, determined in accordance with formula (I) above (and generally a number average particle size determined by electron microscopy visual examination) below about 40 nanometers (nm) , advantageously between about 1 to about 35 nm, preferably between about 1 and about 25 nm, more preferably between about 5 and about 20 nm.
  • the particle size distribution of the silicon oxide is preferably such that about 90 percent, on a number basis of the particles are below about 100 nm, preferably below 75 nm, and more preferably below about 50 nm.
  • the silicon oxides are present in the metallurgical compositions in an amount of from about 0.005 to about 2 percent by weight, preferably from about 0.01 to about 1 percent by weight, and more, preferably from about 0.025 to about 0.5 percent by weight, based on the total weight of the metallurgical composition.
  • Preferred silicon oxides are the silicon dioxide materials, both hydro- philic and hydrophobic forms, commercially available as the Aerosil line of silicon dioxides, such as the Aerosil 200 and R812 products, from Degussa Corporation.
  • the iron oxides useful in the practice of the present invention are those that have a surface area of between about 2 and about 150 m 2 /g, preferably between about 5 and about 50 m 2 /g, and more preferably between about 5 and about 20 m 2 /g.
  • the density of the silicon oxides is generally between about 3 and about 5 g/cm 3 , preferably between about 4 and about 5 g/cm 3 , more pre- ferably between about 4.4 and about 4.7 g/cm 3 .
  • the iron oxides will preferably have an average particle size, determined in accordance with formula (I) above (and generally a number average particle size determined by electron microscopy visual examination) of below about 500 nm, advantageously between about 10 to about 400 nm, preferably between about 25 and about 300 nm, more preferably between about 40 and about 200 nm.
  • the particle size distribution of the iron oxide is preferably such that about 90 percent, on a number basis, of the par- tides are below about 1 micron, preferably below 750 nm, and more preferably below 500 nm.
  • the iron oxides are present in the metallurgical compositions in an amount of from about 0.01 to about 2 percent by weight, preferably from about 0.05 to about 1 percent by weight, and more preferably from about 0.05 to about 0.5 percent by weight, based on the total metallurgical composition.
  • Preferred iron oxides are the Fe 3 0 4 materials.
  • useful iron oxides are those commercially available as the Bayferrox line of iron oxides, such as the Bayferrox 318M and 330 pigment products, from Miles Inc. It is preferred to use the iron oxide materials in conjunction with the silicon oxide materials to provide synergistic flow enhancement properties to the metal powder compositions.
  • the metal powder composition of the present invention can further contain a lubricant to reduce the ejection force required to remove the compacted part from the die cavity.
  • a lubricant to reduce the ejection force required to remove the compacted part from the die cavity.
  • typical powder metallurgy lubricants include the stearates, commonly zinc stearate and lithium stearate; synthetic waxes, such as ethylene bis- stearamide, along with such lubricants as molybdenum sulphides, boron nitride, and boric acid.
  • the lubricant is generally present in the metal powder composition in an amount up to about 15 weight percent, preferably from about 0.1 to about 10 weight percent, more preferably about 0.1-2 weight percent, and most preferably about 0.2-1 weight percent, of the metal powder composition.
  • the metal powder compositions of the present invention are compacted in a die according to standard metallurgical techniques.
  • Typical compaction pressures range between about 5 and 200 tons per square inch (tsi) (69- 2760 MPa) , preferably from about 20-100 tsi (276-1379 MPa) , and more preferably from about 25-60 tsi (345-828 PMa) .
  • the part can be sintered, according to standard metallurgical techniques, at temperatures and other conditions appropriate to the compo- sition of the iron-based powder.
  • Those metal powder compositions containing a thermoplastic coating are generally not sintered following compaction, but are rather subjected to a post-compaction heat treatment, such as that described in U.S. Pat. No. 5,225,459 to Oliver and Clisby, which is hereby incorporated by reference in its entirety.
  • the oxide flow agents of the present invention have been found to advantageously improve the flow characteristics of those metal powder compositions designed for compaction at "warm" temperature conditions.
  • Compaction in accordance with warm temperature techniques generally required that the metal powder composition is compressed at a compaction temperature - measured as the temperature of the composition as it is being compacted - up to about 370°C (700°F) .
  • the compaction is generally conducted at a temperate above 100°C (212°F) and commonly above about 125°C (260°F) , preferably at a temperature of from about 150°C (300°F) to about 370°C (700°F) , more preferably from about 175°C (350°F) to about 260°C (500°F) .
  • the metal pow- der compositions designed for use at warm compaction conditions preferably contain a lubricant adopted for high temperature compaction.
  • the composition usually contains a binder to prevent segregation and dusting.
  • a useful high temperature lubricant and various binding agents that perform well in such compositions intended for warm compaction are set forth in U.S. Pat. No. 5,368,630 to Luk, which is incorporated herein by reference in its entirety.
  • the high temperature lubricant described U.S. Pat. No. 5,368,630 is a polyamide lubricant that is, in essence, a high melting-point wax.
  • the lubricants formed by the condensation reaction are polyamides characterised as having a melting range rather that a melting point.
  • the reaction product is generally a mixture of moieties whose molecular weights, and therefore properties dependent on such, will vary.
  • the polyamide lubricant begins to melt at a temperature between about 150°C (300°F) and 260°C (500°F) , preferably about 200°C (400°F) to about 260°C (500°F) .
  • the polyamide will generally be fully melted at a temperature about 250 degrees centigrade above this initial melting temperature, although it is preferred that the polyamide reaction product melt over a range of no more than about 100 degrees centigrade.
  • a preferred lubricant is commercially available as ADVAWAX 450, or PROMOLD 450, polyamide sold by Morton International of Cincinnati, Ohio, which is an ethylene bis-stearamide having an initial melting point between about 200°C and 300°C.
  • the high temperature lubri- cant will generally be added to the composition in the form of solid particles.
  • the particle size of the lubricant can vary, but is preferably below about 100 microns. Most preferably the lubricant particles have a weight average particle size of about 10-50 microns.
  • the binding agents described in U.S. Pat. No. 5,368,630 are polymeric resin materials that can be either soluble or insoluble in water, although it is pre- ferred that the resin is insoluble in water.
  • the resin will have the capacity to form a film, in either its natural liquid state or as dissolved in a solvent, around the iron-based powder and the alloying powder. It is important that the binding agent resin is selected such that it will not adversely affect the elevated temperature compaction process.
  • Preferred binding agents include cellulose ester resins such as cellulose acetates having a number average molecular weight (MW) of from about 30,000-70,000, cellulose acetate butyrates having a MW of from about 10,000- 100,000, cellulose acetate propionates having a MW of from about 10,000-100,000, and mixtures thereof. Also useful are high molecular weight thermoplastic phenoloic resins having a MW of from about 10,000-80,000, and hydroxyalkylcellulose resins wherein the alkyl moiety has from 1-4 carbon atoms having a MW of from about 50,000-1,200,000, and mixtures thereof.
  • cellulose ester resins such as cellulose acetates having a number average molecular weight (MW) of from about 30,000-70,000, cellulose acetate butyrates having a MW of from about 10,000- 100,000, cellulose acetate propionates having a MW of from about 10,000-100,000, and mixtures thereof.
  • polyvinylpyrrolidone that is preferably used in combination with the plastizicers such as PEG, glycerol and its esters, esters of organic diacids, sorbitol, phosphate esters, cellusose esters, arylsufonamide-formaldehyde resins and long chain alcohols as disclosed in the US patent 5 432 223.
  • the plastizicers such as PEG, glycerol and its esters, esters of organic diacids, sorbitol, phosphate esters, cellusose esters, arylsufonamide-formaldehyde resins and long chain alcohols as disclosed in the US patent 5 432 223.
  • the flow agents of this invention can be blended with the iron-based powder to from the metallurgical composition by conventional blending techniques.
  • the iron-based powder including the alloying powder if present, is blended with any of the lubricants, binding agents, and the flow agents of the present invention in any order.
  • the metal powder mixture can be prepared in accordance with the procedures set forth in U.S. Pat. No.
  • the binding agent is admixed, preferably in liquid form, with the powders for a time sufficient to achieve good wetting of the powders.
  • the binding agent is preferably dissolved or dispersed in an organic solvent to provide better dispersion of the binding agent in the powder mixture, thus providing a substantially homogeneous distribution of the binding agent throughout the mixture.
  • the lubricant can be added, generally in its dry particulate form either before or after the addition of the binding agent.
  • the lubricant, along with the iron-based powder are first dry blended, after which the binding agent is applied to the metal powder composition and any solvent removed, followed by the addition, by dry blending, of the flow agent.
  • the sequence of addition of the binding agent and lubricant can be varied to alter the final characteristics of the powder composition.
  • Two other blending methods can be used in addition to the blending method described in which the binding agent is added after the lubricant has been mixed with the iron-based powder.
  • a portion of the lubricant from about 50 to about 99 weight percent, preferably from about 75 to about 95 weight percent, is added to the iron-based powder, then the binding agent is added, followed by removal of the solvent, and subsequently the rest of the lubricant is added to the metal powder composition.
  • the other method is to add the binding agent first to the iron-based powder, remove the solvent, and subsequently add the entire amount of the lubricant.
  • the flow agent is then admixed to the thus formed metal powder compositions .
  • the flow agents of this invention provide an additional benefit during the compac- tion process in that they reduce both the peak ejection force and the peak ejection pressure required to remove the compacted part from the die cavity.
  • the flow agents also can function as internal lubricants during the compaction process.
  • Example 1 The improvement to the flow characteristics of a metal powder composition from the incorporated of a silicon dioxide powder as a flow agent were studied. The flow was determined according to standard testing procedure ASTM B213-77, where the flow apparatus was maintained within a temperature controlled enclosure.
  • a metal powder composition was made having a composition as set forth in Table 1.1. This powder was prepared by blending the ANCORSTEEL 1000B powder, the graphite powder, and about 90% wt . of the lubricant powder in standard laboratory bottle-mixing equipment for about
  • the metal powder composition set forth in Table 1.1 functioned as the control powder.
  • a small amount of two different silicon dioxide powders was then blended into the control powder in the amount shown in Table 1.2 as a weight percentage of the control powder composition.
  • the results of the flow characteristics are set forth in Table 1.2, where it is shown that the flow characteristics of the metal powder are extended beyond 200°F (95°C) by the addition of both flow agents.
  • Example 2 The improvement in the flow characteristics of the powder composition containing a ferrophosphorus alloying powder by the addition of a flow agent according to the present invention was studied.
  • a base powder composition as set forth in Table 2.1 was used as the reference pow- der, where the lubricant and binder were the same as in
  • Example 1 This powder was prepared by dry blending the
  • Example 3 The flow characteristics of the metal powder compositions containing a silicon dioxide flow agent were enhanced further by the addition of an iron oxide, Fe 3 0 4 , flow agent.
  • the powder compositions were prepared by blending the Fe 3 0 4 powders with the Mix C from Example 2 using bottle mixing techniques.
  • Mixes F and H contained 0.08% wt .
  • iron oxide and Mix G contained 0.12% wt. iron oxide, based on the weight of Mix C.
  • the flow properties of these Mixes are set forth in Table 3.1.
  • the peak ejection force is defined as the maximum force per unit cross-sectional area of the die cavity registered during the ejection of the compacted part from the die - this is a measure of the maximum force applied to the punch to push the compacted part out of the die cavity.
  • the peak ejection pressure is calculated as the quotient of the maximum load during ejection divided by the total cross-sectional area of the part in contact with the die surface - this is a measure of the maximum friction force between the surfaces of the compacted part and the die that must be overcome to finish the ejection process.
  • a reference composition mix was prepared as set forth in Table 4.1 using the same FeP powder, lubricant, and binder as used in Example 2.
  • Experimental mixes Cl, Dl, El and FI were prepared containing similar amounts of the flow agent (s) as mixes C-F in Examples 2-3. That is, 0.04% wt., 0.08% wt., and 0.12% wt .
  • Aerosil 200 sili- con dioxide powder was added to the reference mix to form mixes Cl, Dl and El, respectively, and 0.04% wt . Aerosil 200 powder and 0.08% wt . Bayferrox 318M Fe 3 0 4 powder were added to the reference mix to form mix FI .
  • Hoeganaes 85HP powder and the composition of the control powder is set forth in Table 5.1.
  • the graphite, lubricant, and binding agent were the same materials as in Example 1.
  • To this control powder was added 0.04% wt . of the Aerosil 200 silicon dioxide powder to prepare test Mix I.
  • FD max Filling density (g/cm 3 ) of the larger cavity
  • FD m i n Filling density (g/cm 3 ) of the smaller cavity

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Powder Metallurgy (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

L'invention concerne une composition pulvérulente métallurgique améliorée comprenant une importante quantité de poudre métallique à base de fer et une faible quantité d'un oxyde inorganique particulaire dont la taille moyenne des particules est à inférieure à 500 nm.
PCT/SE1998/000925 1998-05-15 1998-05-15 Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants WO1999059753A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP98929953A EP1094909B1 (fr) 1998-05-15 1998-05-15 Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants
AU79450/98A AU7945098A (en) 1998-05-15 1998-05-15 Iron-based metallurgical compositions containing flow agents and methods for using same
JP2000549406A JP3964135B2 (ja) 1998-05-15 1998-05-15 流動剤含有冶金用鉄基組成物及びその使用方法
PCT/SE1998/000925 WO1999059753A1 (fr) 1998-05-15 1998-05-15 Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants
DE69828315T DE69828315T2 (de) 1998-05-15 1998-05-15 Metallurgische zusammensetzungen auf eisenbasis, die flussmittel enthalten und verfahren zu deren verwendung
AT98929953T ATE285306T1 (de) 1998-05-15 1998-05-15 Metallurgische zusammensetzungen auf eisenbasis, die flussmittel enthalten und verfahren zu deren verwendung
ES98929953T ES2230700T3 (es) 1998-05-15 1998-05-15 Composiciones metalurgicas a base de hierro que contienen agentes de flujo y metodos para utilizarlas.

Applications Claiming Priority (1)

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PCT/SE1998/000925 WO1999059753A1 (fr) 1998-05-15 1998-05-15 Compositions metallurgiques a base de fer et contenant des agents fluidifiant et procedes d'utilisation correspondants

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JP (1) JP3964135B2 (fr)
AT (1) ATE285306T1 (fr)
AU (1) AU7945098A (fr)
DE (1) DE69828315T2 (fr)
ES (1) ES2230700T3 (fr)
WO (1) WO1999059753A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
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WO2001017716A1 (fr) * 1999-09-09 2001-03-15 Höganäs Ab Composition pulverulente comprenant des granules de poudre de fer et d'additifs et un agent fluidifiant, et procede de preparation
JP2003535215A (ja) * 2000-05-31 2003-11-25 ヘガネス・コーポレーシヨン 金属に基づく圧密構成成分及び冷圧密化に適した金属に基づく粉末組成物の製造法
EP1387730B1 (fr) * 2001-04-17 2005-08-17 Höganäs Ab Composition de poudre de fer contenant un lubrifiant de type amide et procede pour preparer cette composition
WO2011029759A1 (fr) 2009-09-08 2011-03-17 Höganäs Ab Composition de poudre métallique
CN103361578A (zh) * 2013-06-21 2013-10-23 马鞍山市恒毅机械制造有限公司 一种合金含铬粉末冶金钢及其制备方法
EP2343142A3 (fr) * 2009-09-08 2014-05-14 György Dutkay Composition métallurgique en poudre et procédé pour la fabrication d'un produit à base de métallurgie de poudre renforcé de nanofibres
US9352393B2 (en) 2012-12-28 2016-05-31 Jfe Steel Corporation Iron-based powder for powder metallurgy
RU2645857C1 (ru) * 2016-10-21 2018-02-28 Владислав Валентинович Берент Способ изготовления фрикционного материала для тормозных колодок и тормозная колодка
RU2690127C1 (ru) * 2018-12-18 2019-05-30 Публичное акционерное общество "Северсталь" Способ получения порошковой смеси, готовой для прессования металлургических деталей
RU2692002C1 (ru) * 2018-12-19 2019-06-19 Публичное акционерное общество "Северсталь" Способ получения комплексно-легированной порошковой смеси, готовой для формования
CN112719262A (zh) * 2020-12-29 2021-04-30 上海富驰高科技股份有限公司 一种高速压制用钨合金造粒料及其制备方法
US11534824B2 (en) 2018-03-15 2022-12-27 Hewlett-Packard Development Company, L.P. Composition
US11998977B2 (en) 2018-03-15 2024-06-04 Hewlett-Packard Development Company, L.P. Build material composition with metal powder and freeze-dried heteropolymer

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CA2699033C (fr) 2007-09-14 2013-05-28 Jfe Steel Corporation Poudre a base de fer pour la metallurgie des poudres
EP2221130B1 (fr) 2007-12-13 2019-04-24 JFE Steel Corporation Poudre à base de fer pour métallurgie des poudres et son procédé de fabrication
ES2620444T3 (es) * 2008-11-26 2017-06-28 Höganäs Ab (Publ) Lubricante para composiciones metalúrgicas en polvo
JP5604981B2 (ja) 2009-05-28 2014-10-15 Ｊｆｅスチール株式会社 粉末冶金用鉄基混合粉末
JP2010285633A (ja) * 2009-06-09 2010-12-24 Kobe Steel Ltd 粉末冶金用混合粉末の製造方法、及び焼結体の製造方法
JP5663974B2 (ja) 2009-06-26 2015-02-04 Ｊｆｅスチール株式会社 粉末冶金用鉄基混合粉末
JP6232610B2 (ja) * 2013-06-16 2017-11-22 エクトム株式会社 金属焼結体の製造方法及び金属焼結体
CN105344992A (zh) * 2015-11-19 2016-02-24 苏州紫光伟业激光科技有限公司 一种冶金粉末组合物
JP6619039B2 (ja) * 2018-03-14 2019-12-11 株式会社ＥｘＯｎｅ バインダジェット法に用いる積層造形用粉末材料
CN110871269B (zh) * 2018-08-31 2022-11-08 大同特殊钢株式会社 合金粉末组合物
JP7400218B2 (ja) 2018-08-31 2023-12-19 大同特殊鋼株式会社 合金粉末組成物
JP7204793B2 (ja) * 2021-02-05 2023-01-16 株式会社ExOne 積層造形用粉末材料

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3357818A (en) * 1964-09-02 1967-12-12 Mannesmann Ag Metallurgical powder mixtures and mixing methods therefor
DE3232245A1 (de) * 1982-08-30 1984-03-01 Hermann C. Starck Berlin, 1000 Berlin Verbesserung der fliessfaehigkeit und erhoehung der schuettdichte von hochkapazitiven ventilmetallpulvern
JPH01298101A (ja) * 1988-05-27 1989-12-01 Nippon Telegr & Teleph Corp <Ntt> 磁気遮蔽用金属粉末の焼鈍法
US4927461A (en) * 1988-11-02 1990-05-22 Quebec Metal Powders, Ltd. Machinable-grade, ferrous powder blend containing boron nitride and method thereof
US5782954A (en) * 1995-06-07 1998-07-21 Hoeganaes Corporation Iron-based metallurgical compositions containing flow agents and methods for using same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE438275B (sv) * 1983-09-09 1985-04-15 Hoeganaes Ab Avblandningsfri jernbaserad pulverblandning
US4834800A (en) * 1986-10-15 1989-05-30 Hoeganaes Corporation Iron-based powder mixtures
JPH03189461A (ja) * 1989-12-18 1991-08-19 Mazda Motor Corp 無段変速機の変速比制御装置

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3357818A (en) * 1964-09-02 1967-12-12 Mannesmann Ag Metallurgical powder mixtures and mixing methods therefor
DE3232245A1 (de) * 1982-08-30 1984-03-01 Hermann C. Starck Berlin, 1000 Berlin Verbesserung der fliessfaehigkeit und erhoehung der schuettdichte von hochkapazitiven ventilmetallpulvern
JPH01298101A (ja) * 1988-05-27 1989-12-01 Nippon Telegr & Teleph Corp <Ntt> 磁気遮蔽用金属粉末の焼鈍法
US4927461A (en) * 1988-11-02 1990-05-22 Quebec Metal Powders, Ltd. Machinable-grade, ferrous powder blend containing boron nitride and method thereof
US5782954A (en) * 1995-06-07 1998-07-21 Hoeganaes Corporation Iron-based metallurgical compositions containing flow agents and methods for using same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI WORLD PATENT INF 1 January 1900 (1900-01-01), "Annealing magnetic shielding metal powder - by mixing flaky metal powders e.g. iron nickel alloy powder with heat resisting oxide powd", XP002940774, Database accession no. 1990-018650 *

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001017716A1 (fr) * 1999-09-09 2001-03-15 Höganäs Ab Composition pulverulente comprenant des granules de poudre de fer et d'additifs et un agent fluidifiant, et procede de preparation
US6436166B2 (en) 1999-09-09 2002-08-20 Höganäs Ab Powder composition
JP2003535215A (ja) * 2000-05-31 2003-11-25 ヘガネス・コーポレーシヨン 金属に基づく圧密構成成分及び冷圧密化に適した金属に基づく粉末組成物の製造法
EP1387730B1 (fr) * 2001-04-17 2005-08-17 Höganäs Ab Composition de poudre de fer contenant un lubrifiant de type amide et procede pour preparer cette composition
EP2343142A3 (fr) * 2009-09-08 2014-05-14 György Dutkay Composition métallurgique en poudre et procédé pour la fabrication d'un produit à base de métallurgie de poudre renforcé de nanofibres
WO2011029759A1 (fr) 2009-09-08 2011-03-17 Höganäs Ab Composition de poudre métallique
US9352393B2 (en) 2012-12-28 2016-05-31 Jfe Steel Corporation Iron-based powder for powder metallurgy
CN103361578A (zh) * 2013-06-21 2013-10-23 马鞍山市恒毅机械制造有限公司 一种合金含铬粉末冶金钢及其制备方法
RU2645857C1 (ru) * 2016-10-21 2018-02-28 Владислав Валентинович Берент Способ изготовления фрикционного материала для тормозных колодок и тормозная колодка
US11534824B2 (en) 2018-03-15 2022-12-27 Hewlett-Packard Development Company, L.P. Composition
US11684978B2 (en) 2018-03-15 2023-06-27 Hewlett-Packard Development Company, L.P. Build material composition
US11998977B2 (en) 2018-03-15 2024-06-04 Hewlett-Packard Development Company, L.P. Build material composition with metal powder and freeze-dried heteropolymer
RU2690127C1 (ru) * 2018-12-18 2019-05-30 Публичное акционерное общество "Северсталь" Способ получения порошковой смеси, готовой для прессования металлургических деталей
RU2692002C1 (ru) * 2018-12-19 2019-06-19 Публичное акционерное общество "Северсталь" Способ получения комплексно-легированной порошковой смеси, готовой для формования
CN112719262A (zh) * 2020-12-29 2021-04-30 上海富驰高科技股份有限公司 一种高速压制用钨合金造粒料及其制备方法

Also Published As

Publication number Publication date
DE69828315T2 (de) 2005-06-09
ATE285306T1 (de) 2005-01-15
ES2230700T3 (es) 2005-05-01
AU7945098A (en) 1999-12-06
JP2002515542A (ja) 2002-05-28
DE69828315D1 (de) 2005-01-27
EP1094909A1 (fr) 2001-05-02
EP1094909B1 (fr) 2004-12-22
JP3964135B2 (ja) 2007-08-22

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