WO1998049256A1 - Natural antioxidant - Google Patents

Natural antioxidant Download PDF

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Publication number
WO1998049256A1
WO1998049256A1 PCT/PL1998/000021 PL9800021W WO9849256A1 WO 1998049256 A1 WO1998049256 A1 WO 1998049256A1 PL 9800021 W PL9800021 W PL 9800021W WO 9849256 A1 WO9849256 A1 WO 9849256A1
Authority
WO
WIPO (PCT)
Prior art keywords
food
antioxidant
products
pharmaceutical products
mixture
Prior art date
Application number
PCT/PL1998/000021
Other languages
English (en)
French (fr)
Inventor
Pawe$m(D) GWARDYS
Maria Oszmianska
Hanna Zarawska
Jan Niedworok
Alina Kowalska-Gwardys
Antoni Gwardys
Marzena Krzeminska-Stawiany
Boles$m(D)aw DOMINSKI
Original Assignee
Lamer-Zarawska, Eliza
Oszmianski, Jan
STAWIANY, Pawe$m(D)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lamer-Zarawska, Eliza, Oszmianski, Jan, STAWIANY, Pawe$m(D) filed Critical Lamer-Zarawska, Eliza
Publication of WO1998049256A1 publication Critical patent/WO1998049256A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B5/00—Preserving by using additives, e.g. anti-oxidants
    • C11B5/0085—Substances of natural origin of unknown constitution, f.i. plant extracts
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3472—Compounds of undetermined constitution obtained from animals or plants
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3544—Organic compounds containing hetero rings
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10—Cereal-derived products
    • A23L7/109—Types of pasta, e.g. macaroni or noodles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/52—Stabilizers
    • A61K2800/522—Antioxidants; Radical scavengers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses

Definitions

  • the subject of the invention is an anti - oxidation agent, designed particularly for applications in food and pharmaceutical products, especially products containing vegetable oils and animal fats.
  • Polish - patent No 101 979 - an anti - oxidation agent designed for applications in fats, the main constituents of which are compounds with at least one active phenol group with molecular mass above 110.
  • This antioxidant is extracted from thermal decomposition of wood, crude petroleum and most advantageously from lignite or cellulose materials. It is the object of this invention to provide an safe in use, non - toxic, devoid of smell, stable in the increased temperature (up to 80°) antioxidant of vegetable origin, designed for protection of nutritive or pharmaceutical products containing particularly vegetable oils especially bio-oils and animal fats.
  • Natural antioxidant according to this invention contains as active agent a mixture of flavonoids extracted from skull-cup roots (Scutellaria Bailcalensis Georgi) where the antioxidant is applied to food or pharmaceutical products in amount no less than 0,0001% by weight in relation to mass of said food or pharmaceutical components.
  • the products into which the antioxidant is introduced are being in various shape like liquids, creams, emulsions, paste, powder or jelly and the antioxidant is mixed or homogenised with said food or pharmaceutical components.
  • Admixture of antioxidant according to the invention results in noticeable stability prolongation of food and pharmaceutical products, as well as in durability - mainly - owing to anti-oxidation protective action upon unsaturated fatty acids contained in the main products, as a result of its anti - free radicals property which slows down oxidation processes ( i.e. rancidity).
  • the extract of scutellaria roots contains mixture of biologically active substances where these substances occur in great abundance in relation to other plants.
  • the said active substances are baicalin , baicalein, wogonin, scutellarein , oroxiline and visciduline he application of the agent increases the resistance of food and other products against such degrading factors as temperature, time of storing, light, presence of oxygen and ions of metals in products containing unsaturated fatty acids.
  • Active flavone compounds of scutellaria baicalensis especially their lipofile fraction contained in the extract have many active components.
  • bailcalain being the major part of the mixture, intensively absorbs electromagnetic radiation within the range of 250 - 280 nm and 310 - 350 nm, and as it does not contain any phenol group in ring B is resistant to oxidation and very stable in increased temperature.
  • scvutellaria extract owing to presence of carbonyl group in the heterocyclic ring and a hydroxyl group connected to benzene ring promotes the metal chelation. .
  • Polyphenol compounds mainly those from flavone group present in the extract slow - down the free radicals activity generation, and what is more, they exhibit chelating activity in relation of iron and copper ions present in active enzyme centres , which ions catalyse the fat oxidation process.
  • the natural substances contained in the antioxidant according to the invention do not feature any toxic action as opposed to synthetic equivalents, as well as they are entirely devoid of smell, but they feature many curing abilities instead, especially they are bacteriostatic, anti fungi, anti - allergic and antiphlogistic. This antioxidant and anti free radical action has been observed in human organism.
  • Agent according to the invention when applied to the food products, has manifold action, not only that of antioxidant one but also the extract increases food nutrient value and it enhances food curing abilities, owing to the rich presence of flavone components.
  • the extract imparts a yellow colour to food products to which it has been added because contained in the extract flavone compounds are at the same time a natural yellow dye.
  • the intensity of the colour depends on the amount of the agent applied.
  • This biologically active substance applied in the antioxidant according to invention, extracted from the Scutellaria bailcalensis roots is produced by method own to B.P.F. which assures preservation of all biological properties of extracted compounds.
  • the extract is known in commercial form as ANTOKSYD - S, in the shape of yellow crystalline powder consisting of mixture of many compounds, with the main component being bailcalin, up to 75 % by weight, and many other like bailcalein, scutellarein, wogonin, sculpflawon, oroxiline, visciduline, all extracted from Scutellaria bailcalensis Georgi roots .
  • the effectiveness of the agent can be enhanced by adding a mixture of flavone compounds in particular in application to food products containing water - oil phase like butter, mayonnaise, margarine .and so on.
  • the antioxidant agent ANTOKSYD S is particularly recommended for applications to fatty food products , dairy products, processed vegetable and fruit like jellies and jams along with pharmaceutical and cosmetic products.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Nutrition Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mycology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Biotechnology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Medicines Containing Plant Substances (AREA)
PCT/PL1998/000021 1997-04-29 1998-04-29 Natural antioxidant WO1998049256A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL97319735A PL187310B1 (pl) 1997-04-29 1997-04-29 Naturalny preparat przeciwutleniający
PLP.319735 1997-04-29

Publications (1)

Publication Number Publication Date
WO1998049256A1 true WO1998049256A1 (en) 1998-11-05

Family

ID=20069768

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL1998/000021 WO1998049256A1 (en) 1997-04-29 1998-04-29 Natural antioxidant

Country Status (2)

Country Link
PL (1) PL187310B1 (pl)
WO (1) WO1998049256A1 (pl)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10139793A1 (de) * 2001-08-14 2003-02-27 Beiersdorf Ag Verwendung von Wogonin zur Herstellung kosmetischer oder dermatologischer Zubereitungen zur Prophylaxe und Behandlung von entzündlichen Hautzuständen und/oder zum Hautschutz bei empfindlich determinierter und trockener Haut
DE10139791A1 (de) * 2001-08-14 2003-02-27 Beiersdorf Ag Verwendung von Oroxylin A zur Herstellung kosmetischer oder dermatologischer Zubereitungen zur Prophylaxe und Behandlung von entzündlichen Hautzuständen und/oder zum Hautschutz bei empfindlich determinierter und trockener Haut
EP2108370A1 (en) 2002-04-30 2009-10-14 Unigen Pharmaceuticals, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans as a therapeutic agent
US7695743B2 (en) 2002-04-30 2010-04-13 Unigen Pharmaceuticals, Inc. Formulation of a mixture of Free-B-Ring flavonoids and flavans for use in the prevention and treatment of cognitive decline and age-related memory impairments
US8535735B2 (en) 2002-03-01 2013-09-17 Unigen, Inc. Identification of free-B-ring flavonoids as potent COX-2 inhibitors
US8568799B2 (en) 2002-03-22 2013-10-29 Unigen, Inc. Isolation of a dual COX-2 and 5-lipoxygenase inhibitor from acacia
US8771761B2 (en) 2006-10-12 2014-07-08 Unigen, Inc. Composition for treating atopic dermatitis comprising extracts of bamboo and scutellaria
US8790724B2 (en) 2003-04-04 2014-07-29 Unigen, Inc. Formulation of dual cycloxygenase (COX) and lipoxygenase (LOX) inhibitors for mammal skin care
US8945518B2 (en) 2002-04-30 2015-02-03 Unigen, Inc. Formulation of dual eicosanoid system and cytokine system inhibitors for use in the prevention and treatment of oral diseases and conditions

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986003969A1 (en) * 1985-01-03 1986-07-17 David Rubin Anti-asthmatic composition and method using 8,11,14,17-eicosatetraenoic acid
JPS62155210A (ja) * 1985-12-27 1987-07-10 Lion Corp 口腔用組成物
JPS6450877A (en) * 1987-08-20 1989-02-27 Ichimaru Pharcos Inc Oxygen radical catching and removing agent
JPS6450822A (en) * 1987-08-20 1989-02-27 Ichimaru Pharcos Inc Production of 'ougon' extract
WO1989008447A1 (fr) * 1988-03-09 1989-09-21 Lvmh Recherche Liposomes contenant des extraits de scutellaria
FR2651132A1 (fr) * 1989-08-30 1991-03-01 Pacific Chem Co Ltd Agents de protection des cellules contre les especes chimiques a oxygene actif et leur preparation.
JPH03163025A (ja) * 1989-08-03 1991-07-15 Takeda Chem Ind Ltd 黄▲ごん▼含有液剤

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1986003969A1 (en) * 1985-01-03 1986-07-17 David Rubin Anti-asthmatic composition and method using 8,11,14,17-eicosatetraenoic acid
JPS62155210A (ja) * 1985-12-27 1987-07-10 Lion Corp 口腔用組成物
JPS6450877A (en) * 1987-08-20 1989-02-27 Ichimaru Pharcos Inc Oxygen radical catching and removing agent
JPS6450822A (en) * 1987-08-20 1989-02-27 Ichimaru Pharcos Inc Production of 'ougon' extract
WO1989008447A1 (fr) * 1988-03-09 1989-09-21 Lvmh Recherche Liposomes contenant des extraits de scutellaria
JPH03163025A (ja) * 1989-08-03 1991-07-15 Takeda Chem Ind Ltd 黄▲ごん▼含有液剤
FR2651132A1 (fr) * 1989-08-30 1991-03-01 Pacific Chem Co Ltd Agents de protection des cellules contre les especes chimiques a oxygene actif et leur preparation.

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
"THE HERBS", XP002077736, Retrieved from the Internet <URL:HTTP://WWW.JKFA.COM/ALPUB/DIABETES/HERBS.HTM> [retrieved on 19980915] *
DATABASE FOODLINE DIALOG; 1994, KIM H. ET AL.: "Development of functional new materials from Koren medicinal plants", XP002077737 *
DATABASE FOODLINE DIALOG; 1996, PACKER L. ET AL.: "Antioxidant effect of TJ-960 ...", XP002077738 *
DATABASE FSTA / IFIS 1996, CRIADO S. ET AL.: "Medium and substitution pattern effects on the action of hydroxyflavones as photoprotectors ...", XP002077739 *
PATENT ABSTRACTS OF JAPAN vol. 011, no. 394 (C - 465) 23 December 1987 (1987-12-23) *
PATENT ABSTRACTS OF JAPAN vol. 013, no. 238 (C - 603) 5 June 1989 (1989-06-05) *
PATENT ABSTRACTS OF JAPAN vol. 015, no. 398 (C - 0874) 9 October 1991 (1991-10-09) *

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10139791A1 (de) * 2001-08-14 2003-02-27 Beiersdorf Ag Verwendung von Oroxylin A zur Herstellung kosmetischer oder dermatologischer Zubereitungen zur Prophylaxe und Behandlung von entzündlichen Hautzuständen und/oder zum Hautschutz bei empfindlich determinierter und trockener Haut
DE10139793A1 (de) * 2001-08-14 2003-02-27 Beiersdorf Ag Verwendung von Wogonin zur Herstellung kosmetischer oder dermatologischer Zubereitungen zur Prophylaxe und Behandlung von entzündlichen Hautzuständen und/oder zum Hautschutz bei empfindlich determinierter und trockener Haut
US9061039B2 (en) 2002-03-01 2015-06-23 Unigen, Inc. Identification of Free-B-Ring flavonoids as potent COX-2 inhibitors
US8535735B2 (en) 2002-03-01 2013-09-17 Unigen, Inc. Identification of free-B-ring flavonoids as potent COX-2 inhibitors
US8568799B2 (en) 2002-03-22 2013-10-29 Unigen, Inc. Isolation of a dual COX-2 and 5-lipoxygenase inhibitor from acacia
US9168242B2 (en) 2002-03-22 2015-10-27 Unigen, Inc. Isolation of a dual COX-2 and 5-lipdxygenase inhibitor from Acacia
US8034387B2 (en) 2002-04-30 2011-10-11 Unigen, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans for use in the prevention and treatment of cognitive decline and age-related memory impairments
US8652535B2 (en) 2002-04-30 2014-02-18 Unigen, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans for use in the prevention and treatment of cognitive decline and age-related memory impairments
US8945518B2 (en) 2002-04-30 2015-02-03 Unigen, Inc. Formulation of dual eicosanoid system and cytokine system inhibitors for use in the prevention and treatment of oral diseases and conditions
US7695743B2 (en) 2002-04-30 2010-04-13 Unigen Pharmaceuticals, Inc. Formulation of a mixture of Free-B-Ring flavonoids and flavans for use in the prevention and treatment of cognitive decline and age-related memory impairments
EP2108370A1 (en) 2002-04-30 2009-10-14 Unigen Pharmaceuticals, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans as a therapeutic agent
US9370544B2 (en) 2002-04-30 2016-06-21 Unigen, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans as a therapeutic agent
US9655940B2 (en) 2002-04-30 2017-05-23 Unigen, Inc. Formulation of a mixture of free-B-ring flavonoids and flavans as a therapeutic agent
US9849152B2 (en) 2002-04-30 2017-12-26 Unigen, Inc. Formulation of a mixture of Free-B-ring flavonoids and flavans as a therapeutic agent
US8790724B2 (en) 2003-04-04 2014-07-29 Unigen, Inc. Formulation of dual cycloxygenase (COX) and lipoxygenase (LOX) inhibitors for mammal skin care
US9622964B2 (en) 2003-04-04 2017-04-18 Unigen, Inc. Formulation of dual cycloxygenase (COX) and lipoxygenase (LOX) inhibitors for mammal skin care
US8771761B2 (en) 2006-10-12 2014-07-08 Unigen, Inc. Composition for treating atopic dermatitis comprising extracts of bamboo and scutellaria
US9623068B2 (en) 2006-10-12 2017-04-18 Unigen, Inc. Composition for treating atopic dermatitis comprising extracts of bamboo and scutellaria

Also Published As

Publication number Publication date
PL319735A1 (en) 1998-11-09
PL187310B1 (pl) 2004-06-30

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