WO1998008668A1 - Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung - Google Patents
Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung Download PDFInfo
- Publication number
- WO1998008668A1 WO1998008668A1 PCT/DE1997/001842 DE9701842W WO9808668A1 WO 1998008668 A1 WO1998008668 A1 WO 1998008668A1 DE 9701842 W DE9701842 W DE 9701842W WO 9808668 A1 WO9808668 A1 WO 9808668A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- plastic
- container
- ring
- plastic melt
- storage space
- Prior art date
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 46
- 239000004033 plastic Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims description 11
- 238000004519 manufacturing process Methods 0.000 title description 4
- 238000000071 blow moulding Methods 0.000 claims abstract description 3
- 239000000155 melt Substances 0.000 claims description 6
- 238000007664 blowing Methods 0.000 claims description 4
- 239000012815 thermoplastic material Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 238000011144 upstream manufacturing Methods 0.000 claims 2
- 239000000463 material Substances 0.000 abstract description 6
- 230000000007 visual effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract 1
- 229920001169 thermoplastic Polymers 0.000 abstract 1
- 239000004416 thermosoftening plastic Substances 0.000 abstract 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/09—Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/12—Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/19—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their edges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/32—Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/30—Extrusion nozzles or dies
- B29C48/32—Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
- B29C48/335—Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
- B29C48/336—Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/475—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pistons, accumulators or press rams
Definitions
- Barrel-like container made of plastic and method and device for its production
- the invention relates to a barrel-like container made from a discontinuously extruded tubular preform made of thermoplastic material in a blow molding process and having a wall consisting of an inner layer, an outer layer and at least one intermediate layer.
- a method and a device for producing a large-volume hollow body for example a barrel, made of plastic with a multilayer wall are known.
- the device consists of an annular piston which can be axially displaced in a housing and acts as a coextrusion head and which has an approximately radial flow channel bore for each layer of the wall and thus for each plastic melt, each of which flows into a belt distributor.
- the belt distributor then passes into a common flow channel into which the individual plastic melts flow one after the other. Which is about in the middle of the ring piston flow channel is gradually expanded to the cross section of an annular storage space acted upon by the annular piston.
- the outer layer of the wall and therefore also the layer of the preform from which the barrel-like container is produced by a blowing process for example for protection against UV rays or provided with a special color for visual reasons.
- a blowing process for example for protection against UV rays or provided with a special color for visual reasons.
- the wall has an axially extending viewing strip made of translucent plastic.
- a container designed in this way makes it possible, on account of the visible strip, for the filling level of the filling material therein to be regularly monitored or checked.
- FIG. 1 shows a perspective illustration of a container according to the invention
- FIG. 2 shows a section through an inventive device for producing a container from FIG. 1
- FIG. 3 shows an enlarged detail from the device from FIG. 2 in the area of the formation of a viewing strip .
- a barrel-like container 1 is shown, which is made of thermoplastic material from a hose-like preform in the blowing process, the wall of which consists of at least three different layers and in the wall of which a viewing strip 2 extending in the axial direction is incorporated.
- the hose-like preform for forming the barrel-like container 1 is produced by means of a device, of which the Rmgkolben Eat 3 or annular piston accumulation head is shown in Figure 2 of the drawing.
- the Rmgkolben appointment 3 initially consists of a storage jacket 4, which is connected in a conventional manner, not shown, with a housing known per se.
- the storage jacket 4, which is arranged in a stationary manner in the illustrated exemplary embodiment, accommodates an axially displaceable annular piston 5, in which a quill 6 is guided axially displaceably with a nozzle mushroom 7.
- a nozzle gap 8 is formed between the storage jacket 4 and the nozzle mushroom 7 and can be opened and closed by an axial displacement of the sleeve 6.
- the sleeve 6 is associated with a drive, not shown, for example in the form of a piston-cylinder unit.
- the annular piston 10 In its end located outside the tank jacket 4 area of the annular piston 10 has three 5 flow channel bores 9, 11 is connected to the respective melt extruders for the different em ⁇ union producti. Via the flow channel bore 10, for example a clear rela ⁇ hung as translucent plastic melt is fed, which forms the so-called inner layer of the to be produced, and thus the tubular Vorformlmgs subsequent container. 1
- the flow channel bore 9 becomes a plastic melt fed, which consists of a recycled plastic.
- the so-called slug material is used for this recycling plastic, which is obtained when the container 1 is blow molded.
- the plastic melt supplied via the flow channel bore 9 forms the so-called intermediate layer of the preform and thus of the later container 1. This intermediate layer is opaque.
- a third plastic melt enters the annular piston 5 via the flow channel bore 11, which is colored and which consists of a UV-stable material. This plastic layer forms the outer layer of the preform and thus of the blown container 1.
- the flow channel bores 9, 10, 11 each first merge into a circumferential ring distributor 12, 13, 14, to each of which an obliquely running ring channel 12a, 13a and 14a connects.
- These ring channels 12a, 13a, 14a open in succession into a common ring channel 15, which gradually widens to the width of an annular storage space 16 in the storage jacket 4.
- the fact that the individual plastic melts are fed in succession to the common ring channel 15 and the same is only gradually expanded to the cross section of the ring storage space 16 ensures that the structure of the individual layers of the multilayer plastic melt is not changed, but is retained. This also applies to the container 1, which is produced from the tubular preform produced in the annular piston accumulator 3.
- a further flow channel bore 17 is provided in the right part of the annular piston 5 and is connected to an extruder. from which a translucent plastic melt is fed to the annular piston 5. If necessary, this flow channel bore 17 can also be connected to the extruder which is connected to the flow channel bore 9. However, it is necessary for the flow channel bore 17 to be preceded by a device by means of which the pressure and the amount of the translucent plastic melt supplied can be precisely controlled.
- the flow channel bore 17 flows radially into the common ring channel 15 at a distance from the obliquely running ring channels 12a, 13a, 14a Layer and the intermediate layer of the multilayer plastic melt split and thus allows the supply of the translucent plastic melt.
- the torpedo 18 extends to the plastic melt forming the inner layer of the preform, which is not colored. Due to the translucent plastic melt supplied via the flow channel bore 17, the outer layer and the intermediate layer em transparent strip is produced in the non-transparent plastic melts, which later forms the visible strip 2 on the blown container 1. It is thus possible to visually check or monitor the fill level of the barrel-like container 1, that is to say without a special measuring device.
- the translucent plastic melt is advantageously not carried out continuously, but rather only the area which later forms the lateral surface of the container 1.
- 1 em viewing strip 2 is required neither in the underbody nor in the upper floor of the container.
- the translucent plastic melt supplied via the flow channel bore 17 must extend to the opposite wall of the common ring channel 15. This means that the torpedo 18 is so long that it can interrupt all three layers of the multilayer plastic melt for supplying the translucent plastic melt for the viewing strip 2.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Packages (AREA)
- Containers Having Bodies Formed In One Piece (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002264196A CA2264196C (en) | 1996-08-31 | 1997-08-23 | Drum-like container of plastic and process and device for its production |
US09/230,903 US6764639B1 (en) | 1996-08-31 | 1997-08-23 | Drum-like container out of plastic and process and device for its production |
EP97941820A EP0923445B1 (de) | 1996-08-31 | 1997-08-23 | Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung |
DE59710927T DE59710927D1 (de) | 1996-08-31 | 1997-08-23 | Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung |
AT97941820T ATE252974T1 (de) | 1996-08-31 | 1997-08-23 | Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung |
JP51116498A JP3935214B2 (ja) | 1996-08-31 | 1997-08-23 | プラスチック製樽形容器及びその製造方法と装置 |
BR9711286-0A BR9711286A (pt) | 1996-08-31 | 1997-08-23 | Recipiente de material sintético em forma de barril, bem como processo e dispositivo para a sua fabricação. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19635334A DE19635334A1 (de) | 1996-08-31 | 1996-08-31 | Faßartiger Behälter aus Kunststoff sowie Verfahren und Vorrichtung zu seiner Herstellung |
DE19635334.3 | 1996-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1998008668A1 true WO1998008668A1 (de) | 1998-03-05 |
Family
ID=7804256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE1997/001842 WO1998008668A1 (de) | 1996-08-31 | 1997-08-23 | Fassartiger behälter aus kunststoff sowie verfahren und vorrichtung zu seiner herstellung |
Country Status (11)
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1459866A1 (de) | 2003-03-20 | 2004-09-22 | SIG Technology Ltd. | Extrusionskopf sowie Extrusionsverfahren |
RU2258003C2 (ru) * | 2002-09-17 | 2005-08-10 | Шютц Гмбх Унд Ко. Кгаа | Пластиковая бочка и способ изготовления бочки |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE29915975U1 (de) | 1999-09-10 | 1999-12-23 | Sussmann, Erich, 85551 Kirchheim | Thermobehälter |
US6652699B1 (en) | 2000-02-17 | 2003-11-25 | Salflex Polymers Ltd. | Flanged member with barrier layer |
DE102004015551A1 (de) * | 2004-03-30 | 2005-10-20 | Guenter Richter | Vorrichtung zur Herstellung schlauchartiger Vorformlinge mit asymmetrischem Ringkolben |
DE202007013318U1 (de) * | 2007-09-21 | 2008-01-03 | Mauser-Werke Gmbh | Vorrichtung und deren Verwendung zur Herstellung von Kunststoff-Behältern mit Sichtstreifen |
CN102615802B (zh) * | 2012-04-11 | 2014-04-30 | 大连交通大学 | 可视化超高分子量聚乙烯连续挤压实验装置 |
JP6065266B2 (ja) | 2012-11-30 | 2017-01-25 | 株式会社吉野工業所 | 合成樹脂製窓付き容器、プリフォーム及びプリフォームの射出成形装置 |
JP6115853B2 (ja) | 2012-11-30 | 2017-04-19 | 株式会社吉野工業所 | 2軸延伸ブロー成形容器、その容器用プリフォーム及びそのプリフォームの射出成形装置 |
JP6061250B2 (ja) * | 2013-06-28 | 2017-01-18 | 株式会社吉野工業所 | 合成樹脂製窓付き容器、プリフォーム及びプリフォームの射出成形方法 |
CN103909641B (zh) * | 2014-03-10 | 2016-05-25 | 苏州金纬机械制造有限公司 | 实壁管及制管模具 |
DE202019105681U1 (de) * | 2019-10-15 | 2021-01-19 | Kautex Maschinenbau Gmbh | Extrusionstechnik zur Bildung von Kunststoff-Vorformlingen und Schlauchbildungstechnik |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0321946A2 (en) * | 1987-12-21 | 1989-06-28 | E.I. Du Pont De Nemours And Company | Improved coextrusion blowmolding process |
DE9107812U1 (de) * | 1991-06-25 | 1991-10-24 | Richter, Günter, Dipl.-Ing., 5230 Altenkirchen | Vorrichtung zur diskontinuierlichen Herstellung eines Vorformlings für das Blasformen |
EP0491093A1 (en) * | 1990-12-11 | 1992-06-24 | Hoover Universal,Inc. | Die head for multiple resin tubular plastic body |
US5204120A (en) * | 1989-10-31 | 1993-04-20 | Hoover Universal, Inc. | Intermittent multi-layer multi-parison extrusion head |
US5464107A (en) * | 1993-06-25 | 1995-11-07 | Owens-Illinois Plastic Products Inc. | Hollow plastic container with viewing stripe and method of making |
WO1996018500A1 (fr) * | 1994-12-14 | 1996-06-20 | Elf Atochem S.A. | Liant d'adhesion de polyolefines et de polymeres fluores, procede de fabrication de materiau composite le mettant en ×uvre et materiau composite ainsi obtenu |
JPH09193303A (ja) * | 1996-01-24 | 1997-07-29 | Shiseido Co Ltd | 樹脂容器 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2227682A (en) * | 1939-01-25 | 1941-01-07 | Sylvania Ind Corp | Method of making striped pellicles |
US3889839A (en) * | 1974-05-30 | 1975-06-17 | Advanced Chem Tech | Blow-molded drum |
DE2743543C2 (de) * | 1977-09-28 | 1984-05-10 | Häfner & Krullmann GmbH, 4817 Leopoldshöhe | Versandbehälter für Kunststoffspulen o.dgl. |
US4297092A (en) * | 1980-06-30 | 1981-10-27 | Midland-Ross Corporation | Accumulator head used in the formation of a multi-layer parison |
US4399265A (en) * | 1983-01-19 | 1983-08-16 | Garware Plastics & Polyester Ltd. | Process of products UV-stabilized polyester materials |
DE3635334C3 (de) * | 1986-10-17 | 1997-04-03 | Guenter Richter | Vorrichtung zur diskontinuierlichen Herstellung mehrschichtiger, coextrudierter, schlauchartiger Vorformlinge aus thermoplastischem Kunststoff für das Blasformen |
US4802833A (en) * | 1988-03-21 | 1989-02-07 | Hoover Universal, Inc. | Accumulator head for producing a storage drum with view stripe |
US4890994A (en) * | 1988-09-30 | 1990-01-02 | Hoover University, Inc. | Apparatus for forming a parison with a view stripe |
US5301840A (en) * | 1991-04-08 | 1994-04-12 | Colgate-Palmolive Company | Tube dispenser capable of creating a suckback effect in the nozzle |
US5221540A (en) * | 1992-06-17 | 1993-06-22 | Hoover Universal, Inc. | Extrusion head with adjustable view stripe positioning |
US5238148A (en) * | 1992-08-10 | 1993-08-24 | Courtaulds Packaging Inc. | Thermoplastic composite layered squeeze tube and method of making same |
-
1996
- 1996-08-31 DE DE19635334A patent/DE19635334A1/de not_active Withdrawn
-
1997
- 1997-07-29 IN IN455BO1997 patent/IN189558B/en unknown
- 1997-08-23 CA CA002264196A patent/CA2264196C/en not_active Expired - Fee Related
- 1997-08-23 ES ES97941820T patent/ES2210574T3/es not_active Expired - Lifetime
- 1997-08-23 BR BR9711286-0A patent/BR9711286A/pt not_active Application Discontinuation
- 1997-08-23 AT AT97941820T patent/ATE252974T1/de not_active IP Right Cessation
- 1997-08-23 JP JP51116498A patent/JP3935214B2/ja not_active Expired - Fee Related
- 1997-08-23 CN CNB971971765A patent/CN1160179C/zh not_active Expired - Fee Related
- 1997-08-23 US US09/230,903 patent/US6764639B1/en not_active Expired - Lifetime
- 1997-08-23 EP EP97941820A patent/EP0923445B1/de not_active Expired - Lifetime
- 1997-08-23 WO PCT/DE1997/001842 patent/WO1998008668A1/de active IP Right Grant
- 1997-08-23 DE DE59710927T patent/DE59710927D1/de not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0321946A2 (en) * | 1987-12-21 | 1989-06-28 | E.I. Du Pont De Nemours And Company | Improved coextrusion blowmolding process |
US5204120A (en) * | 1989-10-31 | 1993-04-20 | Hoover Universal, Inc. | Intermittent multi-layer multi-parison extrusion head |
EP0491093A1 (en) * | 1990-12-11 | 1992-06-24 | Hoover Universal,Inc. | Die head for multiple resin tubular plastic body |
DE9107812U1 (de) * | 1991-06-25 | 1991-10-24 | Richter, Günter, Dipl.-Ing., 5230 Altenkirchen | Vorrichtung zur diskontinuierlichen Herstellung eines Vorformlings für das Blasformen |
US5464107A (en) * | 1993-06-25 | 1995-11-07 | Owens-Illinois Plastic Products Inc. | Hollow plastic container with viewing stripe and method of making |
WO1996018500A1 (fr) * | 1994-12-14 | 1996-06-20 | Elf Atochem S.A. | Liant d'adhesion de polyolefines et de polymeres fluores, procede de fabrication de materiau composite le mettant en ×uvre et materiau composite ainsi obtenu |
JPH09193303A (ja) * | 1996-01-24 | 1997-07-29 | Shiseido Co Ltd | 樹脂容器 |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch Week 9740, Derwent World Patents Index; Class A17, AN 97-430462, XP002051836 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2258003C2 (ru) * | 2002-09-17 | 2005-08-10 | Шютц Гмбх Унд Ко. Кгаа | Пластиковая бочка и способ изготовления бочки |
EP1459866A1 (de) | 2003-03-20 | 2004-09-22 | SIG Technology Ltd. | Extrusionskopf sowie Extrusionsverfahren |
DE10312522B3 (de) * | 2003-03-20 | 2004-09-23 | Sig Technology Ltd. | Extrusionskopf sowie Extrusionsverfahren |
US7374412B2 (en) | 2003-03-20 | 2008-05-20 | Kautex Maschinenbau Gmbh | Extrusion head |
Also Published As
Publication number | Publication date |
---|---|
US6764639B1 (en) | 2004-07-20 |
CA2264196A1 (en) | 1998-03-05 |
DE19635334A1 (de) | 1998-03-05 |
JP3935214B2 (ja) | 2007-06-20 |
IN189558B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2003-03-29 |
CN1160179C (zh) | 2004-08-04 |
JP2000516895A (ja) | 2000-12-19 |
CN1227522A (zh) | 1999-09-01 |
ES2210574T3 (es) | 2004-07-01 |
CA2264196C (en) | 2005-04-26 |
DE59710927D1 (de) | 2003-12-04 |
BR9711286A (pt) | 2000-01-18 |
EP0923445A1 (de) | 1999-06-23 |
ATE252974T1 (de) | 2003-11-15 |
EP0923445B1 (de) | 2003-10-29 |
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