WO1997021961A1 - Dispositif favorisant le passage en phase gazeuse pour appareil a gaz possedant une valeur de chauffage elevee - Google Patents
Dispositif favorisant le passage en phase gazeuse pour appareil a gaz possedant une valeur de chauffage elevee Download PDFInfo
- Publication number
- WO1997021961A1 WO1997021961A1 PCT/JP1996/002655 JP9602655W WO9721961A1 WO 1997021961 A1 WO1997021961 A1 WO 1997021961A1 JP 9602655 W JP9602655 W JP 9602655W WO 9721961 A1 WO9721961 A1 WO 9721961A1
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- heat
- gas
- gas cylinder
- heat transfer
- transfer plate
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C7/00—Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
- F17C7/02—Discharging liquefied gases
- F17C7/04—Discharging liquefied gases with change of state, e.g. vaporisation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
- F17C2201/0109—Shape cylindrical with exteriorly curved end-piece
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/01—Shape
- F17C2201/0104—Shape cylindrical
- F17C2201/0119—Shape cylindrical with flat end-piece
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/03—Orientation
- F17C2201/035—Orientation with substantially horizontal main axis
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/05—Size
- F17C2201/058—Size portable (<30 l)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0103—Exterior arrangements
- F17C2205/0107—Frames
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/01—Mounting arrangements
- F17C2205/0103—Exterior arrangements
- F17C2205/0111—Boxes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/035—Propane butane, e.g. LPG, GPL
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0302—Heat exchange with the fluid by heating
- F17C2227/0309—Heat exchange with the fluid by heating using another fluid
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/03—Heat exchange with the fluid
- F17C2227/0367—Localisation of heat exchange
- F17C2227/0369—Localisation of heat exchange in or on a vessel
- F17C2227/0376—Localisation of heat exchange in or on a vessel in wall contact
- F17C2227/0383—Localisation of heat exchange in or on a vessel in wall contact outside the vessel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/02—Improving properties related to fluid or fluid transfer
- F17C2260/025—Reducing transfer time
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/07—Applications for household use
- F17C2270/0709—Camping gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/07—Applications for household use
- F17C2270/0745—Gas bottles
Definitions
- the present invention relates to a vaporization assisting device for a high calorific gas appliance in which a cassette type gas cylinder containing normal butane, isobutane or other liquefied gas can be set, and more particularly to a cassette type gas cylinder.
- the supply of gas from the plant will be continued so that stable thermal power can be obtained, and the gas will be used up so that no liquefied gas remains in the gas cylinder.
- cassette type gas cylinders for example, cassette type stoves
- This cassette type stove needs to have a high heat capacity at the time of cooking, and it is not economically preferable that liquefied gas remains in a used gas cylinder.
- the gas appliance using the cassette type gas cylinder is more widely used in addition to the convenience of the gas appliance.
- the present invention corresponds to this.
- the gas supply from the gas cylinder to the burner can continue burning without any trouble under normal temperature use conditions, and the liquefied gas in the gas cylinder can be maintained. Can easily be used up.
- t liquefied gas supply amount of the gas to the burners one is to increase the vaporization amount of the liquefied gas in the gas cylinder by obtaining ⁇ If the latent heat of vaporization exceeds the heat capacity of the gas cylinder and the liquefied gas in the can and the amount of heat supplied from the surroundings, the temperature of the liquefied gas in the gas cylinder will decrease. However, the equilibrium gas pressure will decrease accordingly.
- a part of the heat transfer plate is placed near the burner, receives the heat, and the other part is placed in contact with the gas cylinder set in the gas appliance, and the liquefied gas in the gas cylinder is liquefied by the latent heat of vaporization.
- the reduction of gas temperature is suppressed by the amount of heat transfer by the heat transfer plate, and vaporization is assisted to secure the supply gas amount and to use up the liquefied gas.
- the method of suppressing the temperature drop of the gas cylinder by supplying a part of the combustion heat of the burner by the heat transfer plate and supplying the heat to the gas cylinder can be achieved only under certain specific conditions. (See FIGS. 14 to 16 below). In other words, there is almost no heat supply to the gas cylinder by the heat transfer plate for a predetermined period after starting the combustion in the gas appliance, and the heat transfer amount can be obtained stably after a predetermined time (for example, 6 to 7 minutes). Yes, in the use of ordinary gas appliances, the main high heat during this initial period: 1 In many cases, the use is terminated.
- a heat conductive plate is disposed in contact with the gas cylinder, and the heat conductive plate is surrounded by a heat conductive plate. It is also considered to absorb heat by exchanging heat with the atmosphere and supply heat to the gas cylinder whose temperature has decreased, thereby suppressing the temperature decrease.
- the amount of heat supplied by the heat conducting plate depends significantly on the ambient temperature, Difficult to supply stable heat of 0 ⁇ during use.
- heat is supplied to the gas cylinder by the heat transfer plate using the combustion heat of the burner, so that the gas cylinder is not overheated even when the operating atmosphere is at its temperature.
- the amount of heat transfer is regulated within a range that does not become excessive. For this reason, it takes about 6 to 7 minutes for the temperature of each part of the heat transfer plate to reach equilibrium after igniting the burner and passing through the heat transfer plate. Supply is scarce (see Figure 20).
- the latent heat material is used to supply heat to the gas cylinder, the sensible heat of the latent heat material and the latent heat of fusion can be supplied to the gas cylinder in the early stage of use, while good heat can be supplied. It was found that heat transfer from the interior of the latent heat material decreased and the temperature of the gas cylinder tended to decrease (see Figs. 14 to 16 described later). It is also considered that the heat exchange member has the same tendency.
- the temperature of the cylinder decreases with the lapse of combustion, and the heating power also decreases. It must be maintained at a temperature of at least 6 ° C, preferably at least 8 ° C, to maintain thermal power. Even if the thermal power is changed, almost the same cylinder temperature is required, but if the thermal power is low, the thermal power can be maintained even if the temperature is slightly lower. From this point, it is necessary that the temperature of the gas cylinder be maintained at or above the above temperature in order to maintain the combustion at a high thermal power with the gas cylinder composed of the current butane gas.
- a high heating power for example, 250 Okcal / hr
- the present invention provides a heat transfer plate that transfers a part of combustion heat to supply heat to a gas cylinder, and a heat supply member or a heat exchange member that contacts a gas cylinder and supplies heat according to a temperature difference. Focusing on this, in both the operating temperature atmosphere and the initial use state, a good heat supply is performed to suppress the gas cylinder temperature from lowering and to assist in the gasification.
- An object of the present invention is to provide a vaporization assisting device for a high-temperature S gas appliance that can easily use up liquefied gas.
- the vaporization assisting device of the present invention is a heat-generating gas appliance equipped with a burner that sets a cassette type gas cylinder to an exchange capacity and burns a vaporized gas.
- a heat transfer plate is provided, one end of which is disposed near the burner and the other end of which is in contact with the gas cylinder to supply a portion of the combustion heat to the gas cylinder and heat it, and a contact position between the heat transfer plate and the gas cylinder.
- the heat storage member may be brought into contact with the heat transfer plate, or a part of the heat storage member may be brought into contact with the gas cylinder simultaneously with the heat transfer plate.
- a contact portion between the heat transfer plate and the heat storage member be provided with a heat conduction member that contacts a surface of the heat storage member other than the surface that contacts the heat transfer plate and that contacts the heat transfer plate.
- the heat storage member includes a liquid heat storage material accommodated in a container, and the liquid heat storage material includes a latent heat storage material having a melting point of 4 to 14 ° C and uses the melting latent heat thereof.
- the liquid heat storage material includes a latent heat storage material having a melting point of 4 to 14 ° C and uses the melting latent heat thereof.
- it is composed of a device that uses water and uses its sensible heat, and a device that uses the sensible heat as a heat storage member as a solid heat storage material.
- the reason for setting the melting point of the latent heat storage material to 4 to 14 ° C. is to maintain the temperature of the gas cylinder and the liquefied gas and maintain the calorific value of the gas appliance as described above. Therefore, it is necessary to set and use the melting point of the latent heat storage material according to the calorific value of the gas appliance.
- such latent heat storage materials should have a melting point higher than necessary in consideration of the possibility of supercooling during the cooling process.
- the above melting point is required to be at least 4 ° C for the required temperature of 3 to 6 ° C in the case of 180 Okcal / hr, and to be the required temperature of 4 to 7 in the case of 220 Okcal / hr.
- polyethylene glycol When polyethylene glycol is used as the latent heat storage material, it is desirable to contain a mixed solution having a melting point adjusted by blending polyethylene glycol having a different molecule a.
- Heat storage material utilizing the latent heat is a material that performs heat emission in accordance with solidification such primary phase transition in the temperature range, c and the thermal emission is performed without causing a temperature change, the sensible heat
- the heat storage material used releases heat by changing the temperature without changing the state of the substance, such as solidification, as described above.
- sodium sulfate '10 hydrate can be used as inorganic salts.
- Add supercooling inhibitor Used is sodium tetraborate ⁇ 10 hydrate and sodium chloride as a melting point modifier.
- Another vaporization assisting device of the present invention includes:-a heat transfer plate for disposing an end near the burner and contacting the other end with a gas cylinder to supply a part of the combustion heat to the gas cylinder for heating; A heat exchange member for exchanging heat with the outside air is disposed in contact with the heat transfer plate and the gas cylinder in contact with the heat transfer plate.
- the heat exchange member may be arranged so as to be in contact with the heat transfer plate and to be able to contact a part of the gas cylinder at a contact position between the heat transfer plate and the gas cylinder.
- This heat exchange member is formed by bending a metal plate or metal LIN and fixing it to the surface of the heat transfer plate opposite to the surface in contact with the gas cylinder, or a honeycomb sandwich structure, or a fin-shaped It can be configured with a projection.
- a heat exchange member for exchanging heat with air is provided so as to be in contact with the gas cylinder, and one end is disposed near the burner and the other end is connected to the heat exchange member. It is characterized by the provision of a heat transfer plate that supplies a part of the combustion heat by contact.
- the temperature of the liquefied gas is increased by absorbing the latent heat of vaporization.
- the supply of heat from the heat transfer plate is small, and in this initial stage, heat is supplied from the heat storage member whose temperature is higher than the lowered gas cylinder temperature based on the temperature difference, thereby suppressing the gas cylinder temperature from lowering.
- the vaporization assist device equipped with a heat transfer plate and a heat exchange member
- heat absorbed from the outside air is supplied from the heat exchange member to lower the gas cylinder temperature.
- the heat exchange member the heat absorbed according to the temperature difference between the outside air temperature and the gas cylinder is quickly transmitted, and when the temperature difference is reduced, the amount of heat transfer is also reduced, so that the heat is not supplied more than the required amount of heat.
- the heat exchange member is provided on a material or structure that has high thermal conductivity and a large surface area to enhance heat exchange, the heat supply rate will be high, and the latent heat rate of vaporization in high heat combustion can be supported. Necessary and sufficient vaporization assistance in combustion from a state in which the remaining amount of liquefied gas is low can be performed.
- a predetermined amount of heat is supplied through the heat transfer plate to heat the gas cylinder, and in addition, heat is supplied to the gas cylinder from the surrounding atmosphere, and heat from the heat storage member or heat exchange member is supplied to the gas cylinder.
- the heat by the transfer is supplied, the heat supply and the latent heat of vaporization are in an equilibrium state, the stable supply of the vaporized gas is performed, and the combustion by the predetermined thermal power is continued.
- the amount of heat transferred by the heat transfer plate is almost constant, and a stable equilibrium state is maintained.
- the liquefied gas in the gas cylinder is used up.
- a latent heat storage material When a latent heat storage material is used for the heat storage member, it is initially in a liquid state, and the temperature drops according to the specific heat and the amount of the latent heat storage material due to heat absorption accompanying the latent heat of vaporization of the liquefied gas. When this temperature reaches the melting point of the latent heat storage material, the heat storage material starts to solidify and releases heat of solidification, and the heat is released without any change in temperature until the entire heat storage material solidifies.
- the heat transfer plate when the ambient temperature rises, the heat supply from the external atmosphere increases, and the heat transfer plate also reduces the amount of heat dissipated in the middle, increasing the amount of heat transfer to the gas cylinder. Since the end is in contact with the gas cylinder and also with the heat storage member or heat exchange member, the negative part of the heat transfer by the heat transfer plate is absorbed by the heat storage member. Prevent the gas cylinder from overheating.
- still another vaporization assisting device of the present invention is to allow a part of the gas cylinder to be brought into contact with a high calorific gas appliance equipped with a burner for burning a vaporized gas by setting a cassette type gas cylinder in a replaceable manner.
- a heat storage member made of a metal material is provided to supply heat to the gas cylinder from the heat storage member in the initial state of combustion initiation, and one end is disposed near the burner and the other end is in non-contact with the gas cylinder in front. It is characterized in that a heat transfer plate for supplying a part of the combustion heat in contact with the heat storage member is provided.
- Another vaporization assisting device is that a cassette type gas cylinder is set exchangeably and a high calorie gas appliance equipped with a burner for burning a vaporized gas is brought into contact with a part of the gas cylinder and made of a metal material.
- a heat storage member is provided for combustion (in the initial state, heat is supplied from the heat storage member to the gas cylinder, and the heat storage member is disposed at one end near the burner and the other end is in non-contact with the self-heat storage member. It is characterized in that a heat transfer plate for supplying a part of combustion heat by contacting a gas cylinder in a portion not in contact with the member is provided.
- the heat storage member has a circular arc surface in contact with the gas cylinder can along the shape of the can body, and a longitudinal groove is provided in a portion corresponding to a can body weld formed in the longitudinal direction of the can body on the contact surface.
- the welded part is located inside the longitudinal groove, and the other surrounding cylinder walls have a large contact area with the heat storage member, and the heat transfer efficiency from the heat storage member to the gas cylinder is good, and the vaporization assisting effect is obtained as expected.
- the heat storage member is formed by accommodating granular metal or powdery metal in a flexible container, and the heat storage member is installed such that the contact surface with the gas cylinder can has an arc surface along the ffi body shape.
- the contact including the welded portion of the can body ensures a sufficient contact area to obtain a sufficient vaporization assisting effect.
- the gas cylinder is supplied by heat from the heat transfer plate 6 to 7 minutes after ignition as described above.
- the temperature drop is suppressed and vaporization is assisted, in the initial state of ignition of the partner before that, heat is supplied from the heat storage member in contact with the gas cylinder according to the temperature difference between the two to reduce the temperature of the gas cylinder. This will help the liquefied gas evaporate and continue the high calorific combustion.
- the heat storage member it is necessary for the heat storage member to have a large amount of heat storage, but ⁇ Rapid heat supply corresponding to the cooling speed of the gas cylinder from the heat storage member is an important factor.
- the heat storage member is formed by heat conduction, the heat transfer is performed from the inside of the heat storage member immediately in response to the temperature decrease of the gas cylinder. It is possible to effectively suppress the temperature drop of the gas cylinder until the heat supply is sufficiently performed.
- the heat transfer plate does not contact the gas cylinder and the heating member at once, when a part of the combustion heat of the burner is transferred, the heat is directly supplied to the gas cylinder only. Or it is supplied to the gas cylinder via a heat storage member, and the heat to be supplied to the gas cylinder is transmitted to the heat storage member and released from the outer surface to the outside air, which is effectively used for heating the gas cylinder. It is possible to promote Nutrition well.
- the gas cylinder has a can body welded portion protruding on the outer periphery. If the contact area with the heat storage member is reduced by this welded portion, the amount of heat transfer from the heat storage member is also reduced. Although the vaporization assisting function cannot be secured, the welding protrusion is absorbed to secure the contact area with the peripheral surface of the gas cylinder to improve the heat transfer efficiency.
- the heat transfer plate when heat supply by the heat transfer plate in the initial stage of combustion is insufficient, heat is supplied more quickly than the heat storage member or the heat exchange member to suppress a temperature drop, and thereafter, the heat transfer is performed. Heat is supplied by the plate to assist vaporization, and even if the remaining amount of liquefied gas in the gas cylinder is reduced, combustion with a high calorie can be continued, and when the gas cylinder is replaced, all the liquefied gas inside the gas cylinder is used up be able to.
- FIG. 1 is a plan view of a gas appliance showing a first embodiment of the present invention
- FIG. 2 is a schematic sectional view of FIG. 1,
- FIG. 3 is a perspective view of the heat transfer plate of FIG. 1,
- FIG. 4 is a schematic cross-sectional view of a gas appliance showing a second embodiment
- FIG. 5 is a schematic sectional view of a gas appliance showing a third embodiment
- FIG. 6 is a schematic cross-sectional view of a gas appliance showing a fourth embodiment
- FIG. 7 is a schematic sectional view of a gas appliance showing a fifth embodiment
- FIG. 8 is a schematic cross-sectional view of only the main portion along the line X--X in FIG. 7,
- FIG. 9 is a schematic cross-sectional view of a main part of a gas appliance showing a sixth embodiment
- FIG. 10 is a schematic cross-sectional view of a main part of a gas appliance showing a seventh embodiment
- FIG. 11 is a schematic cross-sectional view of a main part of a gas appliance showing an eighth embodiment
- FIG. 12 is a schematic cross-sectional view of a main part of a gas appliance according to a ninth embodiment
- FIG. 13 is a schematic cross-sectional view of a main part of a gas appliance showing the tenth embodiment
- FIG. 14 is a diagram showing a case where the amount of liquefied gas at the start of combustion in the first experimental example is 250 g.
- Fig. 15 shows the combustion results in the experimental example of 1!] 3
- a graph showing the measurement results of the change in thermal power with respect to the combustion when the amount of liquefied gas at the start was 125 g
- FIG. 16 is a graph showing the measurement results of the thermal power change with respect to the combustion time when the liquefied gas at the start of combustion in the first experimental example is 6 Og,
- FIG. 17 is a graph showing a measurement result of a change in thermal power with respect to combustion when the liquefied gas S at the start of combustion in the second experimental example is 250 g,
- FIG. 18 is a graph showing the measurement results of the change in thermal power with respect to the combustion time when the liquefied gas S at the start of combustion in the second experimental example was 125 g.
- the 19th graph is a graph showing measurement results of the change in thermal power with respect to the combustion time when the amount of liquefied gas at the start of combustion in the second experimental example is 60 g,
- FIG. 20 is a graph showing the measurement results of the heat transfer plate temperature with respect to the combustion time of the third experimental example.
- FIG. 21 is a graph showing the measurement results of the temperature of each part of the heat transfer plate in the combustion of the third experimental example.
- FIG. 22 is a graph showing the results of calculating the amount of heat passing through each part of the heat transfer plate according to the third experimental example.
- FIG. 23 is a schematic cross-sectional view of a gas appliance showing a first embodiment of the present invention
- FIG. 24 is a side view of a main part of a gas cylinder storage portion of FIG.
- FIG. 25 is a perspective view of the heat storage member of FIG. 23,
- FIG. 26 is a perspective view of the heat transfer plate of FIG. 23,
- FIG. 27 is a schematic cross-sectional view of a gas appliance showing the second embodiment
- Fig. 28 is a side view of the main part of the gas cylinder storage part of Fig. 27,
- FIG. 29 is a perspective view of the heat storage member of FIG.
- FIG. 30 is a perspective view of the heat transfer plate of FIG. 27,
- FIG. 31 is a schematic sectional view of a gas appliance showing a thirteenth embodiment
- FIG. 32 is a perspective view of the heat storage member of FIG. 31,
- FIG. 33 is a perspective view of the heat transfer plate of FIG. 31;
- FIG. 34 is a cross-sectional view of a main part of a gas appliance showing a 14th embodiment
- FIG. 35 is a perspective view of the heat storage member of FIG. 34
- FIG. 36 is a cross-sectional view of a main part of the gas appliance showing the embodiment of FIG. 15,
- FIG. 37 is a perspective view of the heat storage member of FIG.
- FIG. 38 is a cross-sectional view of a main part of a gas appliance showing the sixteenth embodiment
- FIG. 39 is a perspective view of the heat storage member of FIG. 38.
- FIG. 40 is a graph showing measurement results of thermal power change with respect to combustion time in the fourth experimental example.
- FIG. 41 is a graph showing the result of determining the relationship between the gas consumption rate and the initial gas amount in the fourth experimental example.
- FIG. 42 is a graph showing the results of determining the gas cylinder temperature with respect to the combustion time in the fifth experimental example.
- FIG. 43 is a graph showing the results of heating ⁇ ⁇ ⁇ by the heat storage member or the heat transfer plate in the fifth experimental example.
- FIG. 44 is a graph showing the relationship between the total amount of cooling heat and the combustion maintenance characteristics with respect to the combustion time in the fifth experimental example.
- FIG. 45 is a graph showing a relationship between the initial gas g and the thermal power sustaining combustion time in the fifth experimental example.
- FIG. 1 is a plan view showing the gas appliance of this example
- FIG. 2 is a cross-sectional view
- FIG. 3 is a perspective view of a heat transfer plate.
- the appliance body 2 is divided into a combustion section 3 and a cylinder storage section 4 by a partition plate 5, and a burner 7 for burning the central fuel gas in the combustion section 3 is arranged.
- the panner 7 is attached to the bottom surface of the instrument body 2 by a mixing tube 8.
- a cover 11 that can be opened and closed is provided in the cylinder storage section 4 in which the cassette type gas cylinder 9 is set, and a governor device 12 is installed at one end.
- the governor device 12 is connected to the gas supply section of the set gas cylinder 9, pushes in its stem to receive vaporized gas from the gas cylinder 9, and this vaporized gas is
- the pressure adjusted by the pressure mechanism is adjusted to a predetermined pressure, and is supplied at a flow rate according to the opening / closing operation of the cock 13 to the mixing section 8 or less, mixed with air, and ejected from the crater of the burner 7.
- a heat transfer plate 15 as shown in FIG. 3 is provided, and the heat transfer plate 15 is made of a plate member made of a material having a high thermal conductivity such as an aluminum plate.
- the heat transfer plate 15 connects the burner 7 and the cylinder storage section 4.
- a flat intermediate portion 15 b is provided along the bottom surface of the appliance body 2, and one end of the heat transfer plate 15 is connected to the burner 7. And the upper end is bent horizontally, and the end heat receiving portion 15a is fixed to the bottom of the burner-7.
- the heat receiving portion 15a in contact with a part of the burner 7 receives a part of the heat generated by the gas combustion and transfers the heat to the gas cylinder 9 in contact with the heat radiating portion 15c at the other end.
- the heat dissipating part 15c of the heat transfer plate 15 rises from the middle part 15b, passes through the lower part of the partition plate 5, extends into the cylinder storage part 4, and forms a gutter along the cylindrical peripheral surface of the gas cylinder 9. Have been.
- the gas cylinder 9 is placed on the heat radiating portion 15c, and comes into direct contact with the container wall of the gas cylinder 9, and transfers the heat received from the burner 7 to the liquefied gas through the container wall of the gas cylinder 9.
- a pure aluminum plate having a thickness of 0.8 is used as the heat transfer plate 15 and formed to have a width of 80 thighs and a length of 205 thighs.
- the temperature of the burner itself increases with the combustion of the gas in the burner 7, and the heat heats the heat receiving portion 15 a of the heat transfer plate 15. The heat is transmitted to the other end, and the temperature of the heat radiating portion 15c rises to heat the gas cylinder 9.
- the dimension entry from the heat receiving portion 15a on the burner side indicates the heat transfer distance in the measurement in FIGS. 21 and 22 described later.
- a heat storage member 20 is provided below the heat radiating portion 15c of the heat transfer plate 15 at the bottom of the cylinder housing portion 4, and a heat conductive member 24 is provided below the heat storage member 20.
- the heat storage member 20 is formed by housing a liquid heat storage material 21 in a packaging material 22.
- the liquid heat storage material 21 polyethylene glycol # 400 having a freezing point range of 4 to 8 ° C. and a freezing point range
- a latent heat storage material prepared by mixing polyethylene glycol # 600 at a temperature of 15 to 25 ° C with a ratio of 6: 4 and adjusting the melting point to about 10 ° C.
- the solidification temperature characteristics can be set arbitrarily and other By selecting and using latent heat storage materials, it is possible to construct latent heat storage materials with different thermal characteristics.
- the above-mentioned heat storage material 21 is, for example, 10 OmL: inside of a container 22 of a bag-like packaging material formed of a soft vinyl chloride film having a thickness of 0.2 mm, a width of 70 mm, and a good shape of 130. Then, the heat storage member 20 was obtained. The heat transfer member 20 is disposed so as to be in contact with the lower surface of the heat dissipating portion 15c of the heat transfer plate 15 and extend in front of and behind the heat transfer plate 15 so as to directly contact the gas cylinder 9.
- the lower part of the heat storage member 20 and a part of the heat transfer plate 15 are made of aluminum foil with a thickness of 50 ⁇ m, a width of 80 mm, and a length of 100 mm. It is covered with a heat conducting member 24 composed of
- the liquefied gas is supplied with the supply of the vaporized gas from the gas cylinder 9.
- the temperature of the internal liquefied gas drops due to the latent heat of vaporization, but heat is supplied from the heat storage material 21 in accordance with the temperature difference with the heat storage member 20, and when the temperature of the heat storage material 21 decreases and reaches its freezing point, it solidifies.
- the latent heat of fusion is released, and heat is supplied to the gas cylinder 9.
- heat is also transferred from the bottom side of the heat storage member 20 by the heat conduction member 24, and an increase in the heat supply speed is obtained.
- the gas cylinder temperature is maintained at a certain temperature, and the gas pressure of the gas cylinder 9 is increased to this temperature.
- the gas pressure is maintained at a level corresponding to the temperature, and a stable supply of a predetermined amount of gas can be obtained. The effect of preventing lowering is obtained.
- Fig. 14 to Fig. 16 show the results of a combustion experiment (Experimental Example 1 described below) in which the setting was adjusted and the combustion was measured until the gas was exhausted and the natural fire was extinguished. This is indicated by a two-dot chain line ⁇ .
- a latent heat storage material such as polyethylene glycol and sodium sulfate 10-hydrate is used, and a container 22 using a sensible heat storage material such as water and oil.
- a solid sensible heat storage material such as brick, concrete, viscosity, plastic, etc. may be encapsulated and used.
- Short dashed line B The type of the heat storage material used is the same in the second and third embodiments described later.
- FIG. 4 shows the vaporization assisting device of this example, and the heat transfer plate is the same as that of the first embodiment, and shows another example of the heat storage member.
- the heat transfer plate 15 has the same shape as the previous example, and transfers a part of the combustion heat of the burner 7 to supply heat to the gas cylinder 9.
- a heat storage member 25 in which a liquid heat storage material 21 made of polyethylene glycol is sealed in a container 22 made of a bag-like packaging material is brought into contact with the cylinder housing portion 4 on the lower surface of the heat radiating portion 15c of the heat transfer plate 15. At the same time, it is arranged so as to extend before and after the heat transfer plate 15 and directly contact the gas cylinder 9.
- the same structures as those in the previous example are denoted by the same reference numerals, and description thereof is omitted.
- the vaporization assisting device of this example is shown in FIG. 5, and the heat transfer plate 15 is the same as in the first embodiment. This shows another example of the heating member.
- the heat storage member 28 is formed by enclosing a liquid heat storage material 21 in a metal container 29.
- the metal container 29 is made of, for example, aluminum.
- the upper surface is provided in a gutter shape along the peripheral shape of the gas cylinder 9, and a portion corresponding to the heat radiating portion 15c of the heat transfer plate 15 is heated by the heat.
- the heat transfer plate 15 is provided so as to be in close contact with the plate 15, is provided below the heat radiating portion 15 c of the heat transfer plate 15, and is provided so as to hold it.
- Other configurations are the same as those of the first embodiment.
- the heat storage member 28 is formed of the metal container 29, the rigidity is high and the support strength of the gas cylinder 9 is increased, and the vaporization assisting effect is different from that of the first embodiment. Obtained similarly.
- the container 29 may be made of other metals such as copper, iron, and stainless steel, or may be made of a molded plastic container.
- the container 22 made of the packaging material according to the first and second embodiments may be made of a metal foil or a laminated material of a metal foil and a plastic film instead of the plastic film.
- FIG. 6 shows the vaporization assisting device of this example, and the heat transfer plate 15 is the same as that of the first embodiment, and shows another example of the heat storage member.
- the heat storage member 30 is made of a solid heat storage material such as brick, metal lump, paper clay, concrete, molding resin, and the like, and it is preferable to use a material having a large specific heat and a high thermal conductivity.
- the shape of the heat storage member 30 is formed in the same manner as the outer shape of the metal container 29 in the third embodiment, and is disposed below the heat transfer plate 15 in close contact with the heat radiating portion 15c.
- the heat storage member 30 is a sensible heat storage material corresponding to a heat capacity corresponding to the specific heat, and supplies heat according to a temperature difference from the gas cylinder 9 without phase change such as solidification. Therefore, substantially the same effects as in the first embodiment can be obtained.
- FIGS. 7 and 8 show the vaporization assisting device of this example, in which the heat transfer plate 15 is the same as that of the first embodiment, and shows an example in which a heat exchange member is installed instead of the heat storage member. .
- the heat exchange member 40 is made of a plate material having low thermal conductivity such as an aluminum plate.
- a corrugated plate 40a having a bent material is fixed to the back surface of the heat radiating portion 15c, and a large surface area is provided in a honeycomb sandwich structure in which a back plate 40b is joined to the outside of the corrugated plate 40a.
- the heat exchange member is fixed to the f surface of the heat radiating portion 15c of the heat transfer plate 15 and is provided to extend in front of and behind the heat transfer plate 15, and this extended portion is provided on the outer surface of the gas cylinder 9. May be directly contacted.
- the corrugated sheet 40a is formed by processing a 0.2 mm thick aluminum plate into a corrugated shape with a wave number of 8 and a height of 5 mm, which is formed into a width of 55 mm and a length of 130 thighs.
- the back plate 40b is made of a 0.2 mm thick aluminum plate having a width of 55 mm and a length of 130 mm.
- the gas appliance 1 provided with the heat assisting device provided with the heat transfer plate 15 and the heat exchange member 40 as described above, the gas cylinder 9 filled with the liquefied gas is set, and the initial thermal power is reduced to 260,000. After setting to kcal / hr and igniting and burning, use the gas to exhaust The results of a combustion experiment (Experimental Example 2 described later) in which the change in thermal power was measured are shown by short broken lines G in FIGS. 17 to 19 1.
- the heat exchange member is fixed to the heat transfer plate, and the force constituting the vaporization assist device is provided.
- the heat exchange member is provided so as to be in contact with the gas cylinder. May be configured so that heat transfer can be performed by connecting the end portions.
- the heat exchange member is provided in the form of a honeycomb sandwich consisting of a top plate, a corrugated plate and a ⁇ plate, so that the top plate supports the gas cylinder and makes thermal contact with it. What is necessary is just to comprise by connecting the edge part of the heat radiation side thermally. This relationship between the heat transfer plate and the heat exchange member can be similarly configured in sixth to tenth embodiments to be described later.
- FIG. 9 shows another example of the heat exchange member with respect to the previous example.
- the heat exchanging member 43 of this example includes a honeycomb structure having a surface outer shell 43a formed by extruding aluminum (alloy) or the like and a honeycomb portion 43b having a large number of holes therein. It is fixed to the back surface of the heat radiating portion 15c as in the previous example.
- the heat exchange member 43 has a high heat exchange property with the outside air due to a material having a high heat conductivity and a structure having a large area, and supplies the heat absorbed from the outside air to assist in the vaporization. Excess heat is released to the outside to prevent the gas cylinder temperature from rising abnormally.
- the other configuration is the same as that of the fifth embodiment.
- the vaporization assisting device of this example is shown in FIG. 10 and shows another example of the heat exchange member with respect to the fifth embodiment.
- the heat exchanging member 45 of this example is formed by extruding aluminum (alloy) or the like, and has an arc-shaped surface plate 45a fixed to the heat transfer plate 15 and a plate-shaped member formed in parallel to the lower surface.
- the fin structure formed by the fin portion 45b is similarly fixed to the back surface of the heat transfer plate.
- Others are configured similarly to the fifth embodiment and have similar functions.
- FIG. 11 The vaporization assisting device of this example is shown in FIG. 11 and shows another example of the fin structure of the heat exchange member with respect to the fifth embodiment.
- the fin structure of the heat exchange member 47 of the present embodiment includes an arc-shaped top plate 47a fixed to the back surface of the heat transfer plate 15 and a fin portion 47b having a T-shaped cross section projecting downward. It is formed.
- the other configuration is the same as that of the fifth embodiment and has the same operation.
- the vaporization assisting device of this example is shown in FIG. 12 and shows another example of the heat exchange member with respect to the fifth embodiment.
- the heat exchange member 49 of the present example is formed by bonding a corrugated body 49a having a large surface area by bending a gold foil such as an aluminum foil into a triangular wave shape and fixing the corrugated body 49a to the back surface of the heat transfer plate 15. is there.
- Other configurations are the same as those of the fifth embodiment and have the same functions.
- the vaporization assisting device of this example is shown in Fig. 13 and shows another example in which the shape of the heat exchange member is different from the ninth embodiment.
- the heat exchange member 51 of the present embodiment is formed by fixing a corrugated body 51a having a large surface area by bending a metal foil such as an aluminum foil into a pulse wave shape, on the back surface of the heat transfer plate.
- Other configurations are the same as those of the fifth embodiment and have the same functions.
- FIGS. 14 to 16 show the results of the comparative examples in which only the heat transfer plate was used, only the heat storage material was used, and the heat transfer plate and the heating member were not used.
- Fig. 14 shows the amount of liquefied gas filled in the gas cylinder at the start of combustion is 250 g (full amount).
- Fig. 15 shows the case where the filling amount is 125 g. In this case, the amount is 60 g.
- the present invention 3 is indicated by a dashed-dotted line C representing a heat member.
- a comparative example 1 indicated by a solid line D using only a heat transfer plate
- a comparative example 2 indicated by a dotted line E using only a heating member made of polyethylene glycol
- a long broken line F including neither a heat transfer plate nor a heat storage member.
- the flame is shortened on the way as described above, and if the combustion is interrupted, the liquefied gas will remain in the gas cylinder. Furthermore, as shown in Fig. 16, when the charge a in the initial stage of combustion decreases, thermal equilibrium cannot be obtained with the heat transfer plate alone, and the thermal power rapidly decreases.
- the heat storage member In the characteristics of the heat storage member, heat is supplied from the heat storage material promptly to the temperature drop of the gas cylinder and liquefied gas at the beginning of combustion, but the heat transfer is close to the contact surface of the heat storage member with the gas cylinder. The heat is transferred from the heat storage member to the contact area. The heat transfer due to heat conduction and convection from inside the heat storage member cannot follow the cooling of the gas cylinder and is delayed, and the temperature of the gas cylinder gradually decreases. Compared with the heat transfer plate of Comparative Example 1, the decrease in thermal power at the beginning of combustion is greater in the heat transfer plate of Comparative Example 1, and after a certain amount of combustion time has elapsed, it reverses and the heat power of the heat material decreases. I do. When sodium sulfate 10 hydrate was used as the heat storage material, although not shown, the tendency of the decrease in thermal power was similar to that of polyethylene glycol in Comparative Example 2. Shows the property that it is smaller than polyethylene glycol.
- the liquid heat storage material is polyethylene glycol as a latent heat storage material, water as a sensible heat storage material, and water. Almost the same results were obtained with paper clay as a solid heat storage material.
- the amount of water used is small because it is used in combination with the heat transfer plate, but when water is reduced to 25 mL.
- the starting charge of combustion is reduced to 60 g, the decrease in thermal power in the initial stage of combustion increases slightly, In another experiment, it was confirmed that the liquefied gas could maintain a sufficient heating power.
- the gas appliance 1 was burned in a normal temperature atmosphere, and when the environmental temperature was low, for example, 1 ° C or less, polyethylene glycol as a latent heat storage material solidified. In this case, the latent heat cannot be used, and the supply of heat using sensible heat suppresses the temperature drop of the gas cylinder.
- the heat transfer plate and the heat storage member are used in combination, if the ambient temperature is high and the heat transfer plate excessively supplies heat to the gas cylinder, the heat transfer from the heat transfer plate will be By contacting both, it is performed by both, preventing the gas cylinder from overheating. From this point, even in the design of the heat transfer plate, the heat transfer amount can be increased as compared with the case of the heat transfer plate alone, and the performance guarantee at the low temperature side becomes easier.
- FIGS. 17 to 19 show the results of the comparative example without the heat transfer plate and the heat exchange member when only the plate is used.
- Fig. 17 shows the amount of liquefied gas filled in the gas cylinder at the start of combustion is 250 g (full amount).
- Fig. 18 shows the case where the amount is 125 g. In this case, the amount is 60 g.
- the product of the present invention is the present invention 4 indicated by a short broken line G provided with the heat transfer plate and the heat exchange member in the fifth embodiment.
- Comparative examples are Comparative Example 1 indicated by a solid line D using only a heat transfer plate, and Comparative Example 3 indicated by a long broken line F having neither a heat transfer plate nor a heat exchange member.
- Comparative Example 1 (Curve D) using only the heat transfer plate and Comparative Example 3 (Curve F) having nothing were compared with the results of Experimental Example 1 (FIGS. 14 to 16).
- the time required to extinguish the fire is shortened due to the high heat setting, and the initial decrease in the thermal power is sharply accompanied by the dog with the latent heat of vaporization, but the overall tendency is similar. Is shown.
- Experimental Example 1 the configuration of the present invention 1, in a state of mounting only removed heat transfer plate heat storage member, the front 0 performs combustion under the same conditions as himself first 4 figures, the heat transfer plate burner It dissipates heat during the heat transfer process, has a temperature gradient to the heat radiating section, and requires about 6 to 7 minutes to reach the equilibrium temperature.
- FIG. 20 shows the progress of the combustion time since the start of combustion and the temperature change of the heat transfer plate.
- the measurement point of the heat transfer plate temperature is transmitted from the heat receiving unit 15a in Fig. 3 ⁇ . This is the position where the heat distance is 140, which is slightly before the heat radiating part 15c.
- FIG. 21 shows the heat transfer plate temperature at each point when the combustion time has elapsed for 45 minutes. According to this, the temperature of the heat transfer plate suddenly rises from the start of combustion and stabilizes after 7 minutes, and the temperature of each part of the heat transfer plate is radiated to the outside during the heat transfer process from the heat receiving part and varies according to the distance. It is falling.
- Fig. 22 shows the amount of heat transferred to each part of the heat transfer plate based on the temperature measurement as described above.c From the results of Fig. 14 above, the actual amount of combustion heat is about 200 Okcal / hr. The amount of latent heat of vaporization of the liquefied gas required for this combustion is about 14.5 kcal / hr, whereas according to FIG. 22, according to FIG. 22, the radiating portion 15c of the heat transfer plate (heat transfer distance 1 The amount of heat passing through (50 to 200 mm), that is, the amount of heat released, is 3.5 to 4 kcal / hr, and the supply ratio is about 24 to 28%.
- the problem with the heat supply by the heat transfer plate is that, as shown in Fig. 20, the time from the start of combustion until the temperature of the heat transfer plate reaches an equilibrium state (about 7 minutes). If there is no heat supply to the gas cylinder during this time, the temperature of the liquefied gas will drop sharply. However, in this region, heat is supplied by the heat storage member or heat exchange member and the temperature drops sharply. Suppress.
- the amount of heat supplied by the heat storage member is determined by setting the heat capacity by the material of the heat storage material and ⁇ , the size of the contact area with the gas cylinder, and the heat transfer characteristics of the contact part It is provided so that a required amount of heat can be supplied in the initial stage until the heat transfer from the heat transfer plate becomes sufficient.
- the setting of the amount of heat supplied by the heat exchange member is performed by setting the heat conductivity of the material and the heat exchange characteristics according to the shape and dimensions.
- the vaporization assisting device in this example is shown in Fig. 23 to Fig. 26, and is an example in which a metal heat storage member is brought into direct contact with a gas cylinder.
- the vaporization assisting device is provided with a metal heat storage member 55 as shown in FIG.
- the heat storage member 55 is provided at the bottom of the cylinder storage section 4 and is die-cast with, for example, a zinc alloy (ZDC 2).
- the contact surface 9a on the upper surface extends along the peripheral surface of the can body 9a of the gas cylinder 9.
- the bottom surface 9b is a flat surface, and the length in the front-rear direction is slightly shorter than the length of the can body 9a of the gas cylinder 9.
- the heat storage member 55 has an upper contact surface 9a in contact with the gas cylinder 9 to perform heat transfer, and a lower surface in contact with a heat transfer plate 56 described later.
- the heat storage member 55 is formed to have a width of 50 mm, a length of 130, and a thickness of the thinnest portion at the center of 8. At this time, the volume is about 100 cm 3 and has a heat capacity of 100 O cal for a temperature change of 15 ° C.
- the heat transfer plate 56 is shown in FIG. 26.
- the heat transfer plate 56 is made of a plate member made of a material having high thermal conductivity such as an aluminum plate.
- the heat transfer plate 56 connects the parner 7 and the heat storage member 55.
- a flat middle portion 56b is provided along the bottom surface of the appliance body 2, and one end of the heat transfer plate 56 is connected to the burner 7. It stands upright and its upper end is bent horizontally, and the end heat receiving portion 56a is fixed to the bottom of the burner 7.
- the heat receiving portion 56a in contact with a part of the burner 7 receives a part of the heat generated by the gas combustion, and transfers the heat to the heat storage member 55 in contact with the heat transfer portion 56c at the other end.
- the heat transfer portion 56c of the heat transfer plate 56 extends flatly from the intermediate portion 55b to the bottom of the cylinder storage portion 4 through the lower portion of the partition plate 5, and is fixed to the bottom surface 55b of the heat storage member 55.
- the heat transfer plate 56 As a specific example of the heat transfer plate 56, a pure aluminum plate having a thickness of 1.0 ram is used, and is formed in a width of 80 mm and a length of 200 band.
- the temperature of the burner itself increases with the combustion of the gas in the burner 17, and the heat heats the heat receiving portion 56 a of the heat transfer plate 56, and this heat is transferred to the heat transfer plate 56.
- the plate 56 is transmitted to the other end, and the temperature of the heat transfer section 56c rises Then, the gas cylinder 9 is heated via the heat storage member 55.
- the gas cylinder 9 (gas cylinder can) is provided with a stem 9b of a valve mechanism at one end of a cylindrical can body 9a. By pushing the stem 9b, vaporized fuel gas can be supplied from the inside. 9 is set in the gas appliance 1 by engaging the notch 9d formed in the mounting force tub 9c with the claw (not shown) of the appliance main body 1 so that it is normally positioned upward. Things.
- the liquefied gas is supplied with the supply of the vaporized gas from the gas cylinder 9.
- the temperature of the internal liquefied gas decreases due to the latent heat of vaporization, but heat is supplied from the heat storage member 55 to the gas cylinder 9 in accordance with the temperature difference with the heat storage member 55.
- the heat transfer from the heat storage member 55 to the gas cylinder 9 is made of a metal having high heat conductivity, so that the internal heat is also supplied quickly and well, and the gas temperature in the early stage of ignition is sharp.
- the remaining amount of liquefied gas is small, the temperature is prevented from dropping rapidly, and the vaporization of liquefied gas is promoted to continue burning at a high calorific value.
- the heat storage member 55c is transferred from the heat transfer section 56c. Heat is supplied to the gas cylinder 9 via the liquefied gas, and a decrease in the temperature of the liquefied gas is suppressed. That is, in the initial stage of ignition, heat is mainly supplied from the heat storage member 55, and heat is supplied from the heat transfer plate 56 after a certain period of combustion ⁇ has elapsed.
- the gas cylinder temperature is maintained at a certain temperature, and the gas pressure of the gas cylinder 9 is reduced.
- a predetermined amount of gas can be supplied stably, and a rapid decrease in gas pressure and a decrease in the gas supply amount can be prevented.
- the vaporization assisting device of this embodiment is shown in FIGS. 27 to 30 and is an example in which the end of the heat transfer plate is brought into direct contact with the gas cylinder 9.
- the heat storage member 58 is a metal die similar to that of the first embodiment. It is a cast molded product, the bottom surface 58b is a flat surface, the upper half is composed of an arc-shaped contact surface 58a that can contact the can body 9a of the gas cylinder 9, and the other front half is formed concavely low and has a gas cylinder. 9 and a portion 58c that is not in contact with the heat transfer plate 59 described later.
- a heat transfer plate 59 is shown in FIG. 30.
- One end of the heat transfer plate 59 is formed in a heat receiving portion 59a similar to that of the first embodiment, and is fixed to the burner 7, and the heat transfer plate 59 is bonded from the intermediate portion 59b.
- the heat transfer portion 59c at the other end extending to the storage compartment 4 is formed on an arc surface along the can body 9a of the gas cylinder 9, and is configured to be able to contact the gas cylinder 9.
- the heat transfer portion 59c is provided at a position corresponding to the concave portion 58c of the heat storage member 58, and is installed in non-contact with the heat storage member 58.
- the heat storage member 58 and the heat transfer plate 59 are simultaneously in contact with the peripheral surface of the gas cylinder 9 to directly supply heat, and the initial ignition is performed.
- the temperature of the gas cylinder 9 decreases, heat is quickly supplied from the heat storage member 58 through the contact surface 58a, and the heat conductivity is high.
- the gas cylinder 9 is heated by the movement.
- the heat receiving portion 59a of the heat transfer plate 59 is heated by the combustion heat of the burner 7, and is directly transferred to the gas cylinder 9 in contact with the heat transfer portion 59c at the other end.
- the heat transfer portion 59 c of the heat transfer plate 59 reduces the amount of heat transmitted from the burner portion without being in contact with the heat storage member 58 and being supplied to the heat storage member 58 and radiated to the atmosphere as it is. Used efficiently for heating. Also in this example, in a normal use environment, the vaporization assisting effect in the continuous combustion by the burner 7 can be obtained almost in the same manner as in the eleventh embodiment.
- the vaporization assisting device of this example is shown in FIGS. 31 to 33, and is an example in which the end of the heat transfer plate is brought into direct contact with the gas cylinder 9.
- the heat storage member 61 is a gold-bend die-cast molded product similar to that of the first embodiment, the bottom surface 61b is a flat surface, and the upper half is a gas cylinder 9 in the lateral half and a gas cylinder 9 described later. It is formed in a concave portion 61 c that does not contact the heat transfer plate 62, and the other half is formed as an arc-shaped contact surface 61 a that can contact the can body 9 a of the gas cylinder 9.
- the heat transfer plate 62 is shown in FIG. 33.
- the heat transfer plate 62 has a negative end similar to that of the first embodiment.
- the heat transfer portion 62c is formed on the heat receiving portion 62a of the gas cylinder 9 and fixed to the burner 7, and the heat transfer portion 62c at the other end extending from the intermediate portion 62b to the cylinder storage portion 4 is formed on an arc surface along the can body 9a of the gas cylinder 9.
- its shape is formed in the front-rear direction, but its length in the arc direction is short, and it is cut off at the substantially end, and the area in contact with the gas cylinder 9 is the transfer in the first and second projection forms.
- the area is almost the same as the area of the heating part 59c.
- the heat transfer section 62c is provided at a position corresponding to the recess 6k of the heat storage member 61, and is installed in a non-contact manner with the heat storage member 61.
- the heat storage member 61 and the heat transfer plate 62 simultaneously contact the peripheral surface of the gas cylinder 9 so that heat is directly supplied, and the heat is supplied directly in the early stage of ignition.
- the temperature of the gas cylinder 9 drops, heat is quickly supplied from the heat storage member 61 via the contact surface 61a, and the heat conductivity is high, so that heat is transferred even from the part not in contact with the gas cylinder 9.
- the heat receiving portion 62a of the heat transfer plate 62 is heated by the combustion heat of the burner 7, and is directly transferred to the gas cylinder 9 which contacts the heat transfer portion 62c at the other end.
- the heat transfer portion 62 c of the heat transfer plate 62 reduces heat that is transmitted from the wrench portion without being in contact with the heat storage member 61 and supplied to the heat storage member 61 and radiated to the atmosphere as it is. Used efficiently. Also in this example, in a normal use environment, the vaporization assisting effect in the continuous combustion in the burner 7 can be obtained substantially in the same manner as in the first and second embodiments.
- FIG. 34 shows a cutaway view of a main part of a gas cylinder storage unit
- FIG. 35 shows a perspective view of a heat storage member.
- the basic structure of the heat storage member 55 and the heat transfer plate 56 is the same as that of the first embodiment, and the heat storage member 55 has a vertical groove 55c formed on a contact surface 55a on the upper surface thereof.
- the vertical length 55c is concealed corresponding to the position of the vertical welded portion 9e on the can body 9a of the gas cylinder 9.
- the shape and position of the welded portion 9e of the can body 9a in the gas cylinder 9 are not specified, but the gas cylinder 9 of each company at present has a protrusion of 1.0 mm wide and 0.2 mm in length.
- the position is located within a range of ⁇ 10 images around a position 17 ° from the diagonal of the notch 9d of the mounting cup 9c.
- the vertical length 55c has a width of 20 mm and a depth of 0.5 mm centering on a position 17 ° from the contact center of the gas cylinder 9.
- the can body welding portion 9e of the gas cylinder 9 is located in the vertical groove 55c of the contact hole 55a of the heat storage member 55.
- the protrusion creates a gap around it, but escapes into the vertical groove 55c, the peripheral surface of the can body 9a comes into close contact with the contact surface 61a of the heat storage member 61, and the amount of heat transfer can be secured .
- the area of the contact surface 55a of the heat storage member 55 is smaller than that of the first embodiment, but the heat transfer can be performed efficiently due to the low lift of the welded portion 9e, and the good vaporization can be achieved. An assisting effect is obtained.
- the vaporization assisting device of this example is shown in FIGS. 36 and 37 and has a structure related to the 14th embodiment.
- the basic structure of the heat storage member 55 and the heat transfer plate 56 of the present example is the same as that of the first embodiment, and a plurality of vertical lengths 55d are formed on the contact surface 55a of the heat storage member 55.
- the vertical grooves 55d are, for example, 1.5 recitals in width, 0.5 mm in depth, and formed every 3.5 recitations.
- the welding portion 9e is located in the vertical groove 55d even for the gas cylinder 9 in which the welding portion 9e of the can body 9a is provided at a position different from the normal position, and the heat storage member 55
- the contact between the contact surface 55a of the gas cylinder 9 and the peripheral surface of the can 9a of the gas cylinder 9 is enhanced to improve the heat transfer effect.
- the vaporization assisting device of this example is shown in FIGS. 38 and 39, and is another example of the welding portion 9e of the gas cylinder 9.
- the heat storage member 65 of this example is made of a metal flexible container 65a, for example, a mesh mesh of stainless steel (mesh 350), a granular metal bag 65b (eg, granules of mesh 144 to 280). (Bronze).
- the heat transfer plate 56 is formed in the same manner as in the previous example.
- the heat storage member 65 is configured by filling 74 g of granular bronze in a stainless mesh bag having a width of 50 thighs, a length of 170 mm, and a height of 10 strokes. .
- the heat storage member 65 is deformable, and when the gas cylinder 9 is set on the heat storage member 65, the protruding welded portion 9e is moved by the internal granular metal 65b and becomes flexible.
- the container 65a deforms and escapes, and the surrounding can body 9a and the contact member of the heating member 65 come into close contact with each other.
- a metal foil or the like can be used in addition to the reticulated metal, and a granular metal or a powdered metal can be filled inside.
- a gas cylinder filled with liquefied butane gas (normal butane 70%, isobutane 30%) is used by using a gas appliance 1 having a heat storage member 55 and a heat transfer plate 56 as shown in the first embodiment.
- Set 9 Flu types of 250 g, 125 g, 60 g, and 30 g
- the initial heating power to 250 Okcal / hr
- the results of a combustion experiment (outside air temperature: 16 to 17 ° C) in which the change in thermal power until the natural fire was extinguished using all of the gas are shown by the solid line in Fig. 40 and the filling fi of each.
- the measurement results using only the heat transfer plate are also indicated by broken lines.
- This heat transfer plate like the heat transfer plate in the first and second embodiments, has a curved end at the other end and directly contacts the gas cylinder 9 to transfer a part of the combustion heat to heat the gas cylinder. Structure.
- Fig. 41 shows the result of determining the gas consumption rate by the ratio. Since the measurement is based on the theoretical value, the measurement consumption rate does not reach 100%, but practically it is possible to use up gas if it is 75% or more, and if it is less than 75%, it is possible to use up gas.
- Fig. 41 shows that if only the heat transfer plate is used and the initial gas II is about 190 g or less, the above consumption rate will drop to 75% or less and gas will not be used up.
- the gas consumption can be achieved regardless of the initial gas ⁇ without the consumption rate being less than 75%.
- a gas cylinder 9 filled with 60 g of liquefied gas was set, and an initial state was set.
- Fig. 42 shows the results of measuring the temperature change (outside air temperature of 22 ° C) at the bottom of the can body 9a of the gas cylinder 9 by setting the thermal power to 250 O kcal / hr and performing ignition combustion.
- the first embodiment, the first comparative example in which only the above-described heat transfer plate is provided, and the second comparative example of the heat transfer plate contact portion of the gas cylinder are shown.
- the temperature change during combustion was measured in the same way on a lower surface of a 0.2-mm-thick vinyl chloride bag with water as a heat storage material attached by hand.
- Fig. 42 when only the heat transfer plate is used, there is no heat supply at the beginning of combustion, so the liquefied gas charge S in the gas cylinder 9 is as small as 60 g, so the heat of the liquefied gas is small.
- the capacity is small, the temperature rapidly decreases in response to the vaporization of the liquefied gas accompanying the high calorific value combustion, and the heat supply by the heat transfer increases to reach an equilibrium state after 6-7 minutes. The temperature is low and the thermal power decreases.
- the use of the metal heat storage member allows the heat storage member to rapidly heat from the gas cylinder and the heat storage member according to the temperature difference between the gas cylinder and the heat storage member due to the temperature decrease of the gas cylinder from the start of combustion.
- the gas is supplied, and the temperature of the gas cylinder decreases slowly, which increases the amount of heat of combustion and increases the heat transfer ⁇ by the heat transfer plate. Temperature is low and is maintained at a high temperature.
- the latent heat of vaporization of the liquefied gas in the gas cylinder is 300 cal per minute.
- the thermal power By supplying heat to the gas cylinder from the outside, the combustion is maintained by the thermal power.However, at the time of the collision, the necessary heat M cannot be completely supplied by the heat storage member and the ripening plate.
- the gas temperature decreases, and the gas- ⁇ equilibrium pressure also decreases.
- Fig. 43 shows the change in the amount of heating heat of the metal heat storage member, the heat storage material by water, and the heat transfer plate with respect to the combustion time in the above experiment.
- Fig. 44 shows the heating of these materials from the latent heat of vaporization.
- Fig. 45 shows the change in the amount of cooling heat of the gas cylinder with the calorific value subtracted.
- Fig. 45 shows the combustion time for maintaining the thermal power in the above high calorific value combustion with respect to the initial gas amount of the gas cylinder. The combustion time when liquefied gas is burned is also shown as the thermal power maintenance limit line.
- the liquefied gas in the gas cylinder has thermal stars, and the heat capacity differs depending on the amount of residual gas. Therefore, when the remaining gas is small, the heat capacity is small and cooling by vaporization latent heat is rapid. From this, according to Fig. 44, for example, when the gas remaining amount is 60 g, the thermal power maintenance time of 250 O kcal / hr only for the heat transfer plate is 4 minutes, and 1 25 g Is 18 minutes for, and 90 minutes for 250 g. Furthermore, according to Fig. 45, in the case of only the heat transfer plate, when the initial gas 3 ⁇ 4 is 250 g, there is no problem because the combustion time is longer than the thermal power maintenance limit line.
- the heat storage material using water has a small amount of heat per unit time, but continues during the time of agriculture.
- the heat storage material made of metal has a large amount of heat per unit time, and the heating time is short.
- the heating amount in FIG. The invention according to the invention has a stable heating amount from the beginning of combustion, and the combination of the heat storage member made of water of the comparative example shown by the broken line shows that the peak value is high but the heating amount in the initial state is low. I have.
- the temperature drop immediately after the start of combustion can be reduced, thereby increasing the continuous combustion maintaining time.
- the cylinder temperature in the process of reaching the equilibrium state is less reduced, the amount of combustion heat is increased, and a high-level equilibrium state is obtained. Those show good characteristics.
- the thermal power maintenance time in Fig. 45 exceeds the thermal power maintenance limit line, and it is possible to use up gas while maintaining high calorific value combustion even in the state where the initial gas amount is small. .
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Feeding And Controlling Fuel (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/091,201 US6089218A (en) | 1995-12-13 | 1996-09-17 | Vaporization acceleration device for high-calorie gas appliance |
EP96930420A EP0866276A4 (en) | 1995-12-13 | 1996-09-17 | DEVICE FOR PROMOTING THE GASEOUS PHASE FOR A GAS APPLIANCE HAVING A HIGH HEATING VALUE |
KR1019980704469A KR19990072138A (ko) | 1995-12-13 | 1996-09-17 | 고열량 가스 기구용 기화 촉진 장치 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7324470A JP2787154B2 (ja) | 1995-12-13 | 1995-12-13 | 高熱量ガス器具における気化助勢装置 |
JP7/324470 | 1995-12-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997021961A1 true WO1997021961A1 (fr) | 1997-06-19 |
Family
ID=18166172
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1996/002655 WO1997021961A1 (fr) | 1995-12-13 | 1996-09-17 | Dispositif favorisant le passage en phase gazeuse pour appareil a gaz possedant une valeur de chauffage elevee |
Country Status (7)
Country | Link |
---|---|
US (1) | US6089218A (ja) |
EP (1) | EP0866276A4 (ja) |
JP (1) | JP2787154B2 (ja) |
KR (1) | KR19990072138A (ja) |
CN (1) | CN1106534C (ja) |
CA (1) | CA2240187A1 (ja) |
WO (1) | WO1997021961A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0907054A1 (fr) * | 1997-10-03 | 1999-04-07 | Giovanni Santilli | Appareil portatif à gaz G.P.L. fixé directement sur cartouches jetables ou réservoirs rechargeables, applicable à un utilisateur thermique |
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US8091106B1 (en) | 2000-06-26 | 2012-01-03 | Thomson Licensing | Method and apparatus for using DVD subpicture information in a television receiver |
DE10053679A1 (de) * | 2000-10-28 | 2002-05-08 | Volkswagen Ag | Gaskocher, insbesondere für Campingfahrzeuge |
AU2003216701A1 (en) * | 2002-03-28 | 2003-10-13 | Bs Manufacturing Limited | A Compact Stove. |
JP4534667B2 (ja) * | 2004-08-24 | 2010-09-01 | 日立工機株式会社 | 燃焼式動力工具 |
JP2009530532A (ja) * | 2006-03-21 | 2009-08-27 | ディクソン,マイケル,パトリック | 液体又は液化ガス気化システム |
US20070277801A1 (en) * | 2006-05-09 | 2007-12-06 | Tong Han Enterprise Co., Ltd | Cooking device |
US20080072891A1 (en) * | 2006-09-22 | 2008-03-27 | Iwatani International Corporation Of America | Heat panel system |
CN102062419B (zh) * | 2010-04-07 | 2013-01-09 | 徐克� | 气化炉搅推调整和复合式取气方法及其装置 |
CN102042481B (zh) * | 2010-12-13 | 2013-05-08 | 刘新 | 一种瓶装液化石油气全自动强制气化机 |
KR101356776B1 (ko) * | 2013-05-16 | 2014-01-27 | 주식회사 코베아 | 휴대용 버너 |
TWD174006S (zh) * | 2014-10-28 | 2016-03-01 | 高飛亞有限公司 | 瓦斯爐之部分 |
CN204880256U (zh) * | 2015-07-15 | 2015-12-16 | 脉鲜金属(大连)有限公司 | 便携式燃气灶具 |
CN108980906A (zh) * | 2018-08-17 | 2018-12-11 | 安徽信息工程学院 | 燃气灶 |
US11262079B2 (en) * | 2019-05-15 | 2022-03-01 | Gsi Outdoors, Inc | Collapsible camp stove |
USD972359S1 (en) * | 2020-06-02 | 2022-12-13 | Dr. Hows Co., Ltd. | Portable gas range |
KR102431576B1 (ko) * | 2022-01-19 | 2022-08-10 | 김주학 | 설치안정성 및 파지성이 증대된 충전식 가스버너 |
CN114909679A (zh) * | 2022-04-11 | 2022-08-16 | 山东大学 | 一种防止卡式炉气罐结霜的装置及卡式炉 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS54100880U (ja) * | 1977-12-26 | 1979-07-16 | ||
JPS54100880A (en) | 1977-11-23 | 1979-08-08 | Harwell Packaging Ltd | Preparation of largeesized bag with valve |
JPS54123726A (en) * | 1978-03-18 | 1979-09-26 | Tiger Vacuum Bottle Ind | Method of preventing reduction of vaporization action of liquefied gas in gas bomb for cassette system gas heater and gas bomb and gas heater for said method |
JPS5525757A (en) * | 1978-08-14 | 1980-02-23 | Keiji Aoyanagi | Method of promoting liquidified gas gasification for small- sized desk heater |
-
1995
- 1995-12-13 JP JP7324470A patent/JP2787154B2/ja not_active Expired - Fee Related
-
1996
- 1996-09-17 WO PCT/JP1996/002655 patent/WO1997021961A1/ja not_active Application Discontinuation
- 1996-09-17 US US09/091,201 patent/US6089218A/en not_active Expired - Fee Related
- 1996-09-17 CA CA002240187A patent/CA2240187A1/en not_active Abandoned
- 1996-09-17 CN CN96199845A patent/CN1106534C/zh not_active Expired - Fee Related
- 1996-09-17 EP EP96930420A patent/EP0866276A4/en not_active Withdrawn
- 1996-09-17 KR KR1019980704469A patent/KR19990072138A/ko not_active Application Discontinuation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS54100880A (en) | 1977-11-23 | 1979-08-08 | Harwell Packaging Ltd | Preparation of largeesized bag with valve |
JPS54100880U (ja) * | 1977-12-26 | 1979-07-16 | ||
JPS54123726A (en) * | 1978-03-18 | 1979-09-26 | Tiger Vacuum Bottle Ind | Method of preventing reduction of vaporization action of liquefied gas in gas bomb for cassette system gas heater and gas bomb and gas heater for said method |
JPS5525757A (en) * | 1978-08-14 | 1980-02-23 | Keiji Aoyanagi | Method of promoting liquidified gas gasification for small- sized desk heater |
Non-Patent Citations (1)
Title |
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See also references of EP0866276A4 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0907054A1 (fr) * | 1997-10-03 | 1999-04-07 | Giovanni Santilli | Appareil portatif à gaz G.P.L. fixé directement sur cartouches jetables ou réservoirs rechargeables, applicable à un utilisateur thermique |
Also Published As
Publication number | Publication date |
---|---|
CN1208454A (zh) | 1999-02-17 |
KR19990072138A (ko) | 1999-09-27 |
CN1106534C (zh) | 2003-04-23 |
CA2240187A1 (en) | 1997-06-19 |
EP0866276A1 (en) | 1998-09-23 |
JP2787154B2 (ja) | 1998-08-13 |
JPH09159175A (ja) | 1997-06-20 |
US6089218A (en) | 2000-07-18 |
EP0866276A4 (en) | 1999-06-02 |
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