WO1997018706A1 - Appat toxique pour l'elimination des blattes - Google Patents
Appat toxique pour l'elimination des blattes Download PDFInfo
- Publication number
- WO1997018706A1 WO1997018706A1 PCT/JP1996/003399 JP9603399W WO9718706A1 WO 1997018706 A1 WO1997018706 A1 WO 1997018706A1 JP 9603399 W JP9603399 W JP 9603399W WO 9718706 A1 WO9718706 A1 WO 9718706A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- poison bait
- added
- cockroaches
- mixed
- present
- Prior art date
Links
- 239000002574 poison Substances 0.000 title claims abstract description 30
- 231100000614 poison Toxicity 0.000 title claims abstract description 30
- 241001674044 Blattodea Species 0.000 title claims abstract description 27
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 12
- 230000000749 insecticidal effect Effects 0.000 claims abstract description 9
- -1 fatty acid ester Chemical class 0.000 claims description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- IQVNEKKDSLOHHK-FNCQTZNRSA-N (E,E)-hydramethylnon Chemical group N1CC(C)(C)CNC1=NN=C(/C=C/C=1C=CC(=CC=1)C(F)(F)F)\C=C\C1=CC=C(C(F)(F)F)C=C1 IQVNEKKDSLOHHK-FNCQTZNRSA-N 0.000 claims description 5
- 229930006000 Sucrose Natural products 0.000 claims description 5
- 239000005720 sucrose Substances 0.000 claims description 5
- 230000001665 lethal effect Effects 0.000 abstract description 8
- 239000002917 insecticide Substances 0.000 abstract description 6
- 231100000518 lethal Toxicity 0.000 abstract description 5
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 16
- 235000013312 flour Nutrition 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 239000008213 purified water Substances 0.000 description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 9
- 235000020357 syrup Nutrition 0.000 description 8
- 239000006188 syrup Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000000523 sample Substances 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 240000008042 Zea mays Species 0.000 description 6
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 6
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 6
- 235000005822 corn Nutrition 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000004166 Lanolin Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 229940039717 lanolin Drugs 0.000 description 4
- 235000019388 lanolin Nutrition 0.000 description 4
- 229960003511 macrogol Drugs 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- 229920001214 Polysorbate 60 Polymers 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 3
- 229920000053 polysorbate 80 Polymers 0.000 description 3
- 229940068968 polysorbate 80 Drugs 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- 235000015895 biscuits Nutrition 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 231100000225 lethality Toxicity 0.000 description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 239000005949 Malathion Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 241000382353 Pupa Species 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- 229950001327 dichlorvos Drugs 0.000 description 1
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
- 229940126534 drug product Drugs 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- 235000012631 food intake Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000002949 juvenile hormone Substances 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229960000453 malathion Drugs 0.000 description 1
- 229950003442 methoprene Drugs 0.000 description 1
- 229930002897 methoprene Natural products 0.000 description 1
- 229960001952 metrifonate Drugs 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 210000003254 palate Anatomy 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229940113124 polysorbate 60 Drugs 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
- A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal
Definitions
- the present invention relates to a cockroach poison bait which has increased insecticidal activity and has a faster onset of lethal effect.
- One method of controlling cockroaches is to use a poison bait. This method involves contacting the insecticide with the cockroach and killing the cockroach (ie, killing the insecticide with milk
- An object of the present invention is to increase the insecticidal activity of a poison bait for controlling cockroaches and to increase the rate of onset of lethal effect.
- the present inventors have made intensive studies to achieve the above object, and as a result, by adding a non-ionic surfactant to a cockroach control poison bait containing an insecticide component, a conventional poison bait is obtained.
- the present inventors have also found that the mortality rate of the poison bait is greatly increased, and the present invention has been completed.
- the present invention is a cockroach control poison bait characterized by containing an insecticidal component and a nonionic surfactant.
- examples of the insecticidal component include organophosphorus compounds such as dichlorvos, dinitrothion, propetanphos, malathion, and trichlorfon; Insect growth regulators such as toprene and difluvenzuron, amidinohydrazone compounds such as hydramethylnon, fipronil, boric acid, and borax Can be.
- organophosphorus compounds such as dichlorvos, dinitrothion, propetanphos, malathion, and trichlorfon
- Insect growth regulators such as toprene and difluvenzuron, amidinohydrazone compounds such as hydramethylnon, fipronil, boric acid, and borax Can be.
- compounds known to have a slow onset of insecticidal efficacy for example, hydramethylnon (Silverman et al., J. E. con. Entomol., Vol. 79, pp. 131-166) Page, 1986), the effect of
- nonionic surfactants include lecithin, glycerin fatty acid ester, polyoxyethylene ethylene sorbitan fatty acid ester, polyethylene glycol fatty acid ester, boroxyethylene hydrogenated castor oil, boroxyethylene monoalkyl ether, and polyoxyethylene fatty acid.
- Ester, polyoxyethylene phytosterol, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl phenyl ether, polyoxyethylene lanolin, polyoxyethylene lanolin alcohol, Polyoxyethylene lanolin sorbitol milow, sorbitan fatty acid ester, sucrose fatty acid ester, etc. can be used. They can be used in combination.
- the nonionic surfactant varies depending on the nonionic surfactant used, but is preferably 0.1 to 30% by weight based on the whole preparation.
- the poison bait for controlling cockroaches includes cockroaches such as insecticides, baits (flour, starches, corn syrup, rice bran, brown sugar, boiled, sorbit, gelatin, pupa flour, oat flour flour, starch syrup, biscuit flour, etc.). (Preferred), non-ionic surfactant and other components as required, and mixed, molded into a suitable size, and formed into solid preparations such as dumplings and tablets. If the poison bait has high viscosity and fluidity, it can be filled into a tube, syringe, etc., and squeezed out before use.
- the other components include purified water, fatty acids such as oleic acid and linoleic acid, glycerin, macrogol and the like. Industrial applicability
- Sample 1 Poison bait obtained in the same manner as in Example 1 except that 42 g of corn syrup was added instead of 37 g in Example 1.
- Sample 2 Poison bait prepared in the same manner as Sample 1 except that the amount of polysorbate 80 in Sample 1 was changed to 6 g instead of 2 g.
- Control sample Sample 1 was the same as Sample 1 except that polysorbate 80 was not used. Poison bait prepared similarly.
- the prepared poison bait was given to each test insect, the cumulative food consumption of the palate after the start of the test was measured, and the lethality of male adults over time was observed.
- One adult male group of 10 animals] was used as an example, and the 50% lethal rate of each one animal was analyzed by the Probit method. 50% lethal rate (LT S0 ) for control samples and LT 5 for samples 1-3. The results are shown in the following table.
- the bait containing polysorbate 80 or sucrose sugar ester had a lethal rate (LT,) value of about ⁇ Z2 compared to the control, and the onset of the lethal effect was faster.
- LT lethal rate
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Food Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Insects & Arthropods (AREA)
- Plant Pathology (AREA)
- Toxicology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
L'invention concerne un appât toxique pour l'élimination des blattes, caractérisé en ce qu'il contient un insecticide et un tensioactif non ionique et en ce qu'il offre un pouvoir insecticide amélioré et un effet mortel plus rapide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU75890/96A AU7589096A (en) | 1995-11-21 | 1996-11-20 | Poison bait for getting rid of cockroaches |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7/301840 | 1995-11-21 | ||
JP30184095 | 1995-11-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997018706A1 true WO1997018706A1 (fr) | 1997-05-29 |
Family
ID=17901798
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1996/003399 WO1997018706A1 (fr) | 1995-11-21 | 1996-11-20 | Appat toxique pour l'elimination des blattes |
Country Status (2)
Country | Link |
---|---|
AU (1) | AU7589096A (fr) |
WO (1) | WO1997018706A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2168062A1 (es) * | 1999-04-22 | 2002-05-16 | Sumitomo Chemical Co | Composiciones para control de cucarachas |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03176401A (ja) * | 1989-11-27 | 1991-07-31 | Clorox Co | ゲル状殺虫組成物 |
JPH03176402A (ja) * | 1989-11-27 | 1991-07-31 | Clorox Co | 泡状殺虫組成物 |
JPH04335851A (ja) * | 1991-05-10 | 1992-11-24 | Yuukou Yakuhin Kogyo Kk | 害虫捕獲器 |
-
1996
- 1996-11-20 AU AU75890/96A patent/AU7589096A/en not_active Abandoned
- 1996-11-20 WO PCT/JP1996/003399 patent/WO1997018706A1/fr active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03176401A (ja) * | 1989-11-27 | 1991-07-31 | Clorox Co | ゲル状殺虫組成物 |
JPH03176402A (ja) * | 1989-11-27 | 1991-07-31 | Clorox Co | 泡状殺虫組成物 |
JPH04335851A (ja) * | 1991-05-10 | 1992-11-24 | Yuukou Yakuhin Kogyo Kk | 害虫捕獲器 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2168062A1 (es) * | 1999-04-22 | 2002-05-16 | Sumitomo Chemical Co | Composiciones para control de cucarachas |
Also Published As
Publication number | Publication date |
---|---|
AU7589096A (en) | 1997-06-11 |
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