WO1997002274A1 - Production de nouveaux mono(di)thiophosphates, compositions comprenant ces derniers et procede d'application - Google Patents

Production de nouveaux mono(di)thiophosphates, compositions comprenant ces derniers et procede d'application Download PDF

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Publication number
WO1997002274A1
WO1997002274A1 PCT/RU1996/000174 RU9600174W WO9702274A1 WO 1997002274 A1 WO1997002274 A1 WO 1997002274A1 RU 9600174 W RU9600174 W RU 9600174W WO 9702274 A1 WO9702274 A1 WO 9702274A1
Authority
WO
WIPO (PCT)
Prior art keywords
mixture
group containing
synergistic
methyl
carbons
Prior art date
Application number
PCT/RU1996/000174
Other languages
English (en)
Russian (ru)
Inventor
Anatoly Emmanuilovich Shipov
Martin Izrailevich Kabachnik
Tatyana Alexeevna Mastrjukova
Galina Karpovna Genkina
Svetlana Alexandrovna Roslavtseva
Olga Jurievna Eremina
Elena Ivanovna Bakanova
Galina Ivanovna Sukhoruchenko
Tamara Iliinichna Vasilieva
Original Assignee
Anatoly Emmanuilovich Shipov
Martin Izrailevich Kabachnik
Tatyana Alexeevna Mastrjukova
Galina Karpovna Genkina
Roslavtseva Svetlana Alexandro
Olga Jurievna Eremina
Elena Ivanovna Bakanova
Galina Ivanovna Sukhoruchenko
Tamara Iliinichna Vasilieva
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anatoly Emmanuilovich Shipov, Martin Izrailevich Kabachnik, Tatyana Alexeevna Mastrjukova, Galina Karpovna Genkina, Roslavtseva Svetlana Alexandro, Olga Jurievna Eremina, Elena Ivanovna Bakanova, Galina Ivanovna Sukhoruchenko, Tamara Iliinichna Vasilieva filed Critical Anatoly Emmanuilovich Shipov
Priority to AU65372/96A priority Critical patent/AU6537296A/en
Publication of WO1997002274A1 publication Critical patent/WO1997002274A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/16—Esters of thiophosphoric acids or thiophosphorous acids
    • C07F9/165—Esters of thiophosphoric acids
    • C07F9/1651—Esters of thiophosphoric acids with hydroxyalkyl compounds with further substituents on alkyl

Definitions

  • shi ⁇ is ⁇ lzuem ⁇ g ⁇ in ⁇ e ⁇ a ⁇ a ⁇ ivny ⁇ ⁇ ma ⁇ ⁇ i ⁇ e ⁇ id ⁇ v, ⁇ ednaznachenny ⁇ for b ⁇ by with sinan ⁇ nymi le ⁇ ayuschimi nase ⁇ mymi (mu ⁇ and ⁇ ma ⁇ y) yavlyae ⁇ sya ⁇ i ⁇ e ⁇ nilbu ⁇ sid [I. ⁇ .Le ⁇ n ⁇ va, ⁇ . ⁇ .Slyn ⁇ , ⁇ g ⁇ imiya 1988, ⁇ ° 8, pp. 130-140].
  • the intentional manufacture of pyroxide is carried out by the company Ziba-Gaigi (Switzerland). Similar insecticidal preparations based on mixed mixtures of this synergistic system and part of the process are detected
  • synergistic insecticidal mixture ⁇ P ⁇ 0147064 rion ME2
  • synergistic mixture in general as a general factor:
  • ⁇ is an alkali group containing from 2 to 4 carbons
  • ⁇ 1 is an alkali group containing from 1 to 2 carbons
  • 0,0-diethyl- ⁇ - [( ⁇ -ethyloxycarbonyl- ⁇ -methyloxybenylmethyl) aminomethyl] dietophosphate, 0,0-diethyl- ⁇ - [( ⁇ -ethyloxycyclobenyl, amyl-amyl) 0-diethyl- ⁇ - [( ⁇ -methyl-oxoxylated- Economics ⁇ -isobutyl-oxylbenyl) aminomethyl] dietethyl, ⁇ _0 0,0-diethyl- ⁇ - [( ⁇ -methyl-amyl-nitrous-amyl -dipropyl- ⁇ - [( ⁇ -methyloxybenyl- ⁇ -methyloxybenylmethyl) aminomethy] mono 1 and 2, respectively.
  • the claimed divergent (often) type of device may be used in combination with any environmentally friendly and auxiliary substances.
  • an insecticidal preparation is obtained by dissolving a mixture of a spermethrin and a synergistic agent in an industrial device.
  • ⁇ levy ⁇ is ⁇ y ⁇ aniy is ⁇ lzuyu ⁇ inse ⁇ itsidnuyu ⁇ m ⁇ zitsiyu as v ⁇ dn ⁇ g ⁇ ⁇ ab ⁇ cheg ⁇ ⁇ as ⁇ v ⁇ a
  • ⁇ ig ⁇ vlyaem ⁇ g ⁇ ⁇ b ⁇ az ⁇ m follows: a mixture ⁇ e ⁇ me ⁇ ina and sine ⁇ gis ⁇ a ⁇ as ⁇ v ⁇ yayu ⁇ in ⁇ ganiches ⁇ m ⁇ as ⁇ v ⁇ i ⁇ ele, vv ⁇ dya ⁇ emuls ⁇ gen and ⁇ luchenny ⁇ ntsen ⁇ a ⁇ emulsion ⁇ azbavlyayu ⁇ v ⁇ d ⁇ y d ⁇ zhelaem ⁇ y ⁇ ntsen ⁇ atsii, ⁇ luchaya us ⁇ ychivuyu v ⁇ dnuyu emulsion.
  • Non-hazardous insecticide mixes are applied with the use of the Hamilton sprinkler on the front of the imago of small flakes and 1 volume of tobacco. Taking into account the deaths of insects occurs after 24 hours for small flies and after 48 hours for synanthropic cockroaches.
  • the degree of toxicity separates the average dose (SD 50 , ⁇ g / g), and the data on the death of the insects is processed by the method [P.I. 72-74].
  • the degree of synergistic activity of the claimed compounds determines the value of the coefficient of the combined action (SD) of the synergistic mixture - at a ratio of 10% by weight:
  • test experiments with a test without a system and experiments with a known syngress are put in place - a pyrotechnic test is standard.
  • the invention may also include other variations in the scope of the invention.
  • the invention is described in the paragraphs of the formula below. ⁇ ⁇ 97/02274 ⁇ / ⁇ 6 / 00174
  • the intentional use of the invention provides for the production of new insecticidal preparations containing the claimed new derivatives (often).
  • the invention may be used to combat the creeping and flying insects in the home and agriculture.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Organic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

Cette invention concerne la production de nouveaux mono(di)thiophosphates correspondant à la formule générale (I) où R représente un groupe alkyle comportant de 2 à 4 atomes de carbone; R1 représente un groupe alkyle comportant de 1 à 2 atomes de carbone, un groupe aryle ou un groupe aryle substitué; R2 représente un groupe alkyle comportant de 1 à 4 atomes de carbone; X représente soufre ou oxygène. Cette invention concerne également la production de nouvelles préparations insecticides contenant ces nouveaux composés, et peut être utilisée dans la lutte contre les insectes volants et rampants, que ce soit dans les applications domestiques ou dans le domaine agricole.
PCT/RU1996/000174 1995-06-30 1996-06-28 Production de nouveaux mono(di)thiophosphates, compositions comprenant ces derniers et procede d'application WO1997002274A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU65372/96A AU6537296A (en) 1995-06-30 1996-06-28 Novel derivatives of di(mono)thiophosphates, a composition containing them and a method of using them

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU95111335/04A RU2087477C1 (ru) 1995-06-30 1995-06-30 0,0-диалкил-s-[(n-алкокси(арокси)карбонил-n-алкоксикарбонилалкил)аминометил]ди(моно)тиофосфаты, проявляющие синергистическое действие к периметру в отношении комнатных мух и синатропных тараканов
RU95111335 1995-06-30

Publications (1)

Publication Number Publication Date
WO1997002274A1 true WO1997002274A1 (fr) 1997-01-23

Family

ID=20169633

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU1996/000174 WO1997002274A1 (fr) 1995-06-30 1996-06-28 Production de nouveaux mono(di)thiophosphates, compositions comprenant ces derniers et procede d'application

Country Status (3)

Country Link
AU (1) AU6537296A (fr)
RU (1) RU2087477C1 (fr)
WO (1) WO1997002274A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1424705A (en) * 1972-04-27 1976-02-11 Ciba Geigy Ag Pesticidal dithiophoshphoric acid esters
GB2039487A (en) * 1978-12-14 1980-08-13 Philagro Sa New fungicidal derivatives of N- phenyl-N-(alkoxycarbonylalkyl) -acetamide phosphorodithioates
US4231782A (en) * 1978-11-03 1980-11-04 Monsanto Company N-Carbobenzoxy-N-phosphonomethylglycine thioesters
EP0064670A1 (fr) * 1981-05-02 1982-11-17 Hoechst Aktiengesellschaft Agents pesticides
US4362722A (en) * 1979-05-11 1982-12-07 Ici Australia Limited Synergistic tickicidal compositions containing organophosphorus compounds and cyclopropane carboxylates

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1424705A (en) * 1972-04-27 1976-02-11 Ciba Geigy Ag Pesticidal dithiophoshphoric acid esters
US4231782A (en) * 1978-11-03 1980-11-04 Monsanto Company N-Carbobenzoxy-N-phosphonomethylglycine thioesters
GB2039487A (en) * 1978-12-14 1980-08-13 Philagro Sa New fungicidal derivatives of N- phenyl-N-(alkoxycarbonylalkyl) -acetamide phosphorodithioates
US4362722A (en) * 1979-05-11 1982-12-07 Ici Australia Limited Synergistic tickicidal compositions containing organophosphorus compounds and cyclopropane carboxylates
EP0064670A1 (fr) * 1981-05-02 1982-11-17 Hoechst Aktiengesellschaft Agents pesticides

Also Published As

Publication number Publication date
RU95111335A (ru) 1996-11-20
AU6537296A (en) 1997-02-05
RU2087477C1 (ru) 1997-08-20

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