WO1996041911A1 - Textiles tisses et tricotes ignifuges a action desodorisante, et leur procede de fabrication - Google Patents

Textiles tisses et tricotes ignifuges a action desodorisante, et leur procede de fabrication Download PDF

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Publication number
WO1996041911A1
WO1996041911A1 PCT/JP1996/001603 JP9601603W WO9641911A1 WO 1996041911 A1 WO1996041911 A1 WO 1996041911A1 JP 9601603 W JP9601603 W JP 9601603W WO 9641911 A1 WO9641911 A1 WO 9641911A1
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WO
WIPO (PCT)
Prior art keywords
knitted fabric
fiber
woven
mol
knitted
Prior art date
Application number
PCT/JP1996/001603
Other languages
English (en)
Japanese (ja)
Inventor
Hirotake Sugiyama
Original Assignee
Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanegafuchi Kagaku Kogyo Kabushiki Kaisha filed Critical Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
Publication of WO1996041911A1 publication Critical patent/WO1996041911A1/fr

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D06M11/42—Oxides or hydroxides of copper, silver or gold
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/49—Oxides or hydroxides of elements of Groups 8, 9,10 or 18 of the Periodic Table; Ferrates; Cobaltates; Nickelates; Ruthenates; Osmates; Rhodates; Iridates; Palladates; Platinates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Definitions

  • the present invention relates to a woven or knitted fabric having a deodorizing function, in particular, a deodorizing property against tobacco odor, and having a flameproof property, and a method for producing the same.
  • Knitted fabrics and the like used for curtains and the like are required to have flame resistance.
  • a knitted fabric made of modacrylic fiber made of a polymer obtained by copolymerizing acrylonitrile with a monomer having a halogen atom, particularly vinyl chloride or vinylidene chloride has been known.
  • a knitted fabric having flame resistance and good texture can be obtained. Have been.
  • a deodorizing function particularly a deodorizing function capable of eliminating the evening odor.
  • a deodorizing substance is kneaded into a fiber, or a knitted or woven fabric is knitted or woven, and then the surface thereof is subjected to post-processing by a deodorizing substance.
  • a method of imparting a deodorizing function to a knitted fabric is also known.
  • the present invention provides a flame-retardant knitted fabric which has a deodorizing function without impairing the flame retardancy. Disclosure of the invention
  • the present invention relates to a knitted or woven fabric composed of modacrylic fiber, a mixed or knitted fabric of modacrylic fiber and cellulose fiber, and a woven or knitted fabric selected from a mixed or knitted fabric of modacrylic fiber and polyester fiber, i 0 2 is 5-8 0 molar%, MO "/ 2 (where, M is zinc, copper, silver, cobalt, nickel, iron, titanium, barium, tin, at least one metal selected from zirconium There, n represents the valence of the metal.) power 5-6 5 mol%, the Aruminokei acid salt a 1 2 0 3 consists of 1-6 0 mol%, 1 g Z m with respect knitted fabric It is a flameproof knitted fabric having a deodorizing function and attached so as to be 2 or more.
  • the method for producing a flameproof knitted fabric having a deodorizing function comprises the following knitted fabrics made of modacrylic fiber, mixed knitted fabrics of modacrylic fiber and cellulosic fiber, and modacrylic fiber and polyester fiber.
  • the woven or knitted fabric selected from among interwoven knitted fabric after weaving or knitting of the fabric or the surface of the knitted fabric, S i 0 2 5 to 8 0 mol%, MO n / 2 (where, M is ) It is at least one metal selected from zinc, copper, silver, cobalt, nickel, iron, titanium, titanium, tin, and zirconium, and n is the valence of the metal.) 5 mole%, a 1 2 0 3 force "and Aruminokei salt consisting of 1-6 0 mol%, the deodorant composition consisting of a binder, 1 gZm 2 or the Aruminogei acid salt relative to textiles and It is applied so that it becomes.
  • the knitted fabric composed of the modacrylic fiber includes 30 to 60% by weight of acrylonitrile, 40 to 70% by weight of vinyl chloride and / or vinyldene chloride, and 0 to 70% by weight of other copolymerizable monomers. It is preferable that a fiber made of a polymer consisting of 5% by weight is knitted or woven into a woven or knitted fabric. Examples of the other monomers copolymerizable with acrylonitrile, vinyl chloride and / or vinylidene chloride include styrene sulfonate and methallyl sulfonate.
  • the mixed knitted fabric of modacrylic fiber and cellulosic fiber is a woven or knitted fabric obtained by mixing and modulating modacrylic fiber and cellulosic fiber, or modacrylic fiber and the above cellulosic fiber. Blended Or a knitted fabric obtained by weaving or knitting the resulting spun yarn.
  • the modacrylic fiber 30 to 60% by weight of acrylonitrile, 40 to 70% by weight of vinyl chloride and vinyl chloride or vinyldene chloride
  • a fiber made of a polymer comprising 0 to 5% by weight of a copolymerizable monomer is used.
  • the monomer copolymerizable with acrylonitrile, vinyl chloride and / or vinylidene chloride is styrene sulfone. And methallylsulfonate.
  • the cellulosic fibers include cotton and rayon.
  • the mixing ratio of modacrylic fiber and cellulosic fiber is preferably in the range of 30 to 55% by weight of modacrylic fiber and 45 to 70% by weight of cellulosic fiber.
  • the mixed knitted fabric of modacrylic fiber and polyester fiber in the present invention is a woven or knitted fabric woven or knitted by mixing modacrylic fiber and polyester fiber, or a blend of modacrylic fiber and polyester fiber.
  • the spun yarn is woven or knitted.
  • the modacrylic fiber includes 30 to 60% by weight of acrylonitrile, 40 to 70% by weight of vinyl chloride and / or vinyldene chloride, and 0 to 5% by weight of another copolymerizable monomer.
  • a fiber composed of coalesced fibers is preferable.
  • Examples of the monomer copolymerizable with acrylonitrile, vinyl chloride, Z or vinylidene chloride include styrene sulfonate and methallyl sulfonate.
  • the mixing ratio of the modacrylic fiber and the polyester fiber is preferably in the range of 50 to 90% by weight of the modacrylic fiber and 45 to 70% by weight of the polyester fiber.
  • the aluminoate salt as the deodorant component in the present invention has Sio 2 of 5 to 80 mol%, preferably 5 to 45 mol%, and MOonce/ 2 (where M is zinc, copper, silver, Is at least one metal selected from cobalt, nickel, iron, titanium, barium, tin, and zirconium, and n is the valence of the metal.) Is 5 to 65 mol%, preferably 35 1-6 5 mol%, a 1 2 0 3 consists of 1-6 0 mol%. Examples Micromax metal constituting the ⁇ ⁇ / 2 ⁇ the zinc is most preferred.
  • the Aruminogei salt mixed with a binder, but is deposited with the dispersed knitted fabric surface, the coating amount of Aruminogei salt, 1 111 2 per 8 or more, preferably 2 to 5 g / m 2 .
  • the binder is not particularly limited as long as it functions as a binder that can be applied to a knitted fabric by being mixed with an aluminoate, and a commercially available binder may be used. Examples thereof include urethane-based resins and acrylic-based resins having an acrylate resin as a main component. In general, resin emulsion-type resins are used.
  • Examples of a method for applying the above-described deodorant composition comprising an aluminogate and a binder to the surface of a knitted fabric include immersion and the like.
  • the deodorant composition containing the above aluminoate as a deodorant component is applied to the surface of the knitted fabric.
  • the surface of the knitted fabric refers to both one side or both sides of the knitted fabric.
  • the deodorant composition comprising the aluminogate and the binder is attached to the back surface of the knitted fabric.
  • FIG. 1 is an explanatory view of the apparatus used for the deodorizing test. BEST MODE FOR CARRYING OUT THE INVENTION
  • a woven fabric having a basis weight of 220 g / m 2 was woven by plain weaving using a modacrylic fiber composed of a copolymer consisting of 45% by weight of acrylonitrile, 54% by weight of vinyl chloride, and 1% by weight of sodium methallylsulfonate.
  • Example 2 The same deodorant composition as in Example 1 was added to a cross-woven fabric (with a basis weight of 250 g / m 2 ) of 60 parts by weight of modacrylic fiber and 40 parts by weight of polyester fiber as in Example 1, On the other hand, the mixture was adhered in a mangle tank so that the amount of aluminoate was 3 gZm 2 and the binder (solid content) was 2 gZm 2 , patted with a mangle, and dried with a drier (100 ° C X 3 Min), and baked (130 ° C x 2 min) using a set machine.
  • a cross-woven fabric with a basis weight of 250 g / m 2
  • the binder solid content
  • Example 2 The same deodorant composition as in Example 1 was added to a cross-woven fabric (basic weight: 280 g / m 2 ) of 55 parts by weight of modacrylic fiber and 45 parts by weight of cotton as in Example 1, and the woven fabric was coated with the same deodorant composition. On the other hand, it was adhered in a mangle tank so that the amount of aluminosilicate was 3 g / m 2 and the amount of binder (solid content) was 2 g / m 2 , patted with a mangle, and dried with a drier. After baking at 140 ° C for 2 minutes, it was baked with a setting machine.
  • a woven fabric was prepared in exactly the same manner as in Example i, except that the deodorant composition was not subjected to the attachment processing in the mangle tank.
  • a woven fabric was produced in exactly the same manner as in Example 2, except that the deodorant composition was not subjected to the attachment processing in the mangle tank.
  • a woven fabric was prepared in exactly the same manner as in Example 3, except that the deodorant composition was not attached in the mangle tank.
  • Various odorous components are put into a container as shown in Fig. 1 so as to have a predetermined concentration.
  • a sample cut from each fabric is put into the container, and the concentration of the odorous component in the container is measured with a gas detection tube. The change over time was measured.
  • Example 1 1 0 0 8.0 4.0 4.5
  • Example 2 1 0 0 8.0 4.0 2.5 Before
  • Comparative Example 2 1 0 0 8 0 7 0 5 0 Comparative Example 3 1 0 0 8 0 7 0 6 0 Example 1 1 0 0 1 0. 0 5.5 3.0 Washing Example 2 1 0 0 1 1. 0 6.0 3.00 5 Example 3 1 0 0 1 0 .0 6.5 2.0 times
  • Comparative Example 2 1 0 1 0 1 0 9 Comparative Example 3 1 0 1 0 1 0 1 0 1 0 Example 1 1 0 0 .5 0 .0 5
  • Example 1 1 0 1 0 1 0 1 0 1 0 Comparative example 2 1 0 1 0 1 0 1 0 Comparative example 3 1 0 1 0 1 0 1 0 1 0 1 0
  • Example 2 1 0 3.0 2.0 1.0 ⁇
  • Example 3 1 0 2. 0 1. 0 0. 0 5
  • Example 1 2 5 1 0.0.
  • Example 2 2 5 1 1. 0 1 0. 0 9.
  • a deodorizing function can be provided to a knitted fabric, without impairing the flameproofing performance of the knitted fabric.
  • the flameproof knitted fabric having a deodorizing function according to the present invention can be applied to curtains, car interior materials such as cars and cover sheets, pile toys such as stuffed animals, and other various products. it can .
  • the deodorant composition is applied in the post-processing, so that only care must be taken in the packaging step after the post-processing, and the deodorizing to the fiber can be performed. It is easier to handle at each stage of the manufacturing process than the method of mixing the odorant, and there is no need for troublesome handling control in the process, and there is no problem of fiber discoloration and it is manufactured at low cost. The advantage is that you can do it.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Artificial Filaments (AREA)
  • Woven Fabrics (AREA)

Abstract

L'invention se rapporte à des textiles ignifuges tissés ou tricotés auxquels on confère des propriétés désodorisantes sans diminuer leur résistance au feu. On obtient ce résultat en appliquant une composition désodorisante qui comprend un silicate d'aluminium constitué, en pourcentage, de 5 à 80 moles de SiO2, de 5 à 65 moles de MOn/2 (où M est au moins un métal choisi parmi: zinc, cuivre, argent, cobalt, nickel, fer, titane, baryum, étain et zirconium; et n est la valence du métal) ainsi que de 1 à 60 moles de Al2O3, et un liant, sur la surface d'un textile tissé ou tricoté fabriqué en fibres modacryliques, d'un fil jaspé tissé ou tricoté ou d'un tissu métisse à base de fibres modacryliques et cellulosiques, ou encore d'un fil jaspé ou d'un tissu métisse tissé ou tricoté en fibres modacryliques et en fibres de polyester ou autres, selon un poids au revêtement de 1 g/m2 ou plus en ce qui concerne le silicate d'aluminium.
PCT/JP1996/001603 1995-06-13 1996-06-12 Textiles tisses et tricotes ignifuges a action desodorisante, et leur procede de fabrication WO1996041911A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP7/145913 1995-06-13
JP7145913A JPH08337964A (ja) 1995-06-13 1995-06-13 消臭機能を有する防炎性編織物及びその製造法

Publications (1)

Publication Number Publication Date
WO1996041911A1 true WO1996041911A1 (fr) 1996-12-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1996/001603 WO1996041911A1 (fr) 1995-06-13 1996-06-12 Textiles tisses et tricotes ignifuges a action desodorisante, et leur procede de fabrication

Country Status (2)

Country Link
JP (1) JPH08337964A (fr)
WO (1) WO1996041911A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0340878A (ja) * 1989-07-04 1991-02-21 Jinichi Kishi 防臭呼吸機能性繊維構造物、およびその製造法
JPH03213562A (ja) * 1990-01-12 1991-09-18 Mitsubishi Rayon Co Ltd 消臭繊維及びその製法
JPH05156510A (ja) * 1991-11-29 1993-06-22 Sumitomo Cement Co Ltd 繊維及び繊維製品の加工方法及び繊維及び繊維製品
JPH06313213A (ja) * 1993-04-29 1994-11-08 Bergmann Gmbh & Co Kg ポリエステルを主成分とする単繊維のかつらと代用毛髪及びそれらの製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0340878A (ja) * 1989-07-04 1991-02-21 Jinichi Kishi 防臭呼吸機能性繊維構造物、およびその製造法
JPH03213562A (ja) * 1990-01-12 1991-09-18 Mitsubishi Rayon Co Ltd 消臭繊維及びその製法
JPH05156510A (ja) * 1991-11-29 1993-06-22 Sumitomo Cement Co Ltd 繊維及び繊維製品の加工方法及び繊維及び繊維製品
JPH06313213A (ja) * 1993-04-29 1994-11-08 Bergmann Gmbh & Co Kg ポリエステルを主成分とする単繊維のかつらと代用毛髪及びそれらの製造方法

Also Published As

Publication number Publication date
JPH08337964A (ja) 1996-12-24

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