WO1996010495A1 - Generateur de gaz pour coussin gonflable de securite - Google Patents
Generateur de gaz pour coussin gonflable de securite Download PDFInfo
- Publication number
- WO1996010495A1 WO1996010495A1 PCT/JP1995/001927 JP9501927W WO9610495A1 WO 1996010495 A1 WO1996010495 A1 WO 1996010495A1 JP 9501927 W JP9501927 W JP 9501927W WO 9610495 A1 WO9610495 A1 WO 9610495A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas
- generating agent
- gas generating
- container
- gas generator
- Prior art date
Links
- 239000003795 chemical substances by application Substances 0.000 claims description 128
- 239000011810 insulating material Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 12
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical class NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 9
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 8
- 239000010931 gold Substances 0.000 claims description 8
- 229910052737 gold Inorganic materials 0.000 claims description 8
- 239000000919 ceramic Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000011888 foil Substances 0.000 claims description 6
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 4
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 claims description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 4
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 150000003536 tetrazoles Chemical class 0.000 claims description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 2
- MZWDAEVXPZRJTQ-WUXMJOGZSA-N 4-[(e)-(4-fluorophenyl)methylideneamino]-3-methyl-1h-1,2,4-triazole-5-thione Chemical compound CC1=NNC(=S)N1\N=C\C1=CC=C(F)C=C1 MZWDAEVXPZRJTQ-WUXMJOGZSA-N 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 150000002357 guanidines Chemical class 0.000 claims description 2
- 235000010333 potassium nitrate Nutrition 0.000 claims description 2
- 239000004323 potassium nitrate Substances 0.000 claims description 2
- 235000010344 sodium nitrate Nutrition 0.000 claims description 2
- 239000004317 sodium nitrate Substances 0.000 claims description 2
- 239000004020 conductor Substances 0.000 claims 1
- 210000000720 eyelash Anatomy 0.000 claims 1
- 239000003906 humectant Substances 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 25
- 230000004308 accommodation Effects 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 257
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 10
- 238000002309 gasification Methods 0.000 description 9
- 239000004156 Azodicarbonamide Substances 0.000 description 8
- 235000019399 azodicarbonamide Nutrition 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000002826 coolant Substances 0.000 description 8
- UAGLZAPCOXRKPH-UHFFFAOYSA-N nitric acid;1,2,3-triaminoguanidine Chemical compound O[N+]([O-])=O.NNC(NN)=NN UAGLZAPCOXRKPH-UHFFFAOYSA-N 0.000 description 8
- 230000002093 peripheral effect Effects 0.000 description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 150000001540 azides Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- -1 nitrogen-containing compound Chemical class 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 2
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 2
- SWRGUMCEJHQWEE-UHFFFAOYSA-N ethanedihydrazide Chemical compound NNC(=O)C(=O)NN SWRGUMCEJHQWEE-UHFFFAOYSA-N 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 235000019256 formaldehyde Nutrition 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- MDTUWBLTRPRXBX-UHFFFAOYSA-N 1,2,4-triazol-3-one Chemical compound O=C1N=CN=N1 MDTUWBLTRPRXBX-UHFFFAOYSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- MJVIZWIQHKRBPI-UHFFFAOYSA-N 1-(aziridin-1-yl)but-3-en-2-ol Chemical compound C=CC(O)CN1CC1 MJVIZWIQHKRBPI-UHFFFAOYSA-N 0.000 description 1
- ULRPISSMEBPJLN-UHFFFAOYSA-N 2h-tetrazol-5-amine Chemical compound NC1=NN=NN1 ULRPISSMEBPJLN-UHFFFAOYSA-N 0.000 description 1
- NSPMIYGKQJPBQR-UHFFFAOYSA-N 4H-1,2,4-triazole Chemical compound C=1N=CNN=1 NSPMIYGKQJPBQR-UHFFFAOYSA-N 0.000 description 1
- BMTAFVWTTFSTOG-UHFFFAOYSA-N Butylate Chemical compound CCSC(=O)N(CC(C)C)CC(C)C BMTAFVWTTFSTOG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 238000006424 Flood reaction Methods 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- CWRVKFFCRWGWCS-UHFFFAOYSA-N Pentrazole Chemical compound C1CCCCC2=NN=NN21 CWRVKFFCRWGWCS-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 240000008866 Ziziphus nummularia Species 0.000 description 1
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- KMSRVXJGTIRNNK-UHFFFAOYSA-N diaminomethylideneazanium;hydrogen carbonate Chemical compound NC(N)=N.OC(O)=O KMSRVXJGTIRNNK-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 239000011361 granulated particle Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002429 hydrazines Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000009418 renovation Methods 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R21/00—Arrangements or fittings on vehicles for protecting or preventing injuries to occupants or pedestrians in case of accidents or other traffic risks
- B60R21/02—Occupant safety arrangements or fittings, e.g. crash pads
- B60R21/16—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags
- B60R21/26—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow
- B60R21/264—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic
- B60R21/2644—Inflatable occupant restraints or confinements designed to inflate upon impact or impending impact, e.g. air bags characterised by the inflation fluid source or means to control inflation fluid flow using instantaneous generation of gas, e.g. pyrotechnic using only solid reacting substances, e.g. pellets, powder
Definitions
- the present invention relates to a gas generator for an airbag used in a vehicle, and more particularly to a gas generator for an airbag provided with a heat insulating member so that the combustion speed of the gas generating agent is not affected by the surrounding temperature.
- the gas generating system has a structure in which a gas generating agent and an igniting agent for igniting the gas generating agent and a squib for igniting the igniting agent are housed in a container. There is also an ignition means that combines the explosive and the squib.
- reference numeral 27 denotes a lower container made of an aluminum alloy, which has an inner AS 27a and an outer shell 27b.
- Reference numeral 28 denotes an aluminum alloy upper container, which has an inner cylinder 28a and an outer cylinder 28b. Then, the inner cylinders 27a, 28a and the outer f 727b, 28b are joined together and joined by friction welding to form a short cylindrical container (casin 21. In addition, the container 21 is divided into an annular outer chamber 35 and a central chamber 34 by the inner cylinders 27a and 28a of the lower container 27 and the upper container 28.
- a bag-shaped protrusion 27 c protruding toward the central chamber 34 is integrally formed at the center portion.
- Eve (ignition means) 10 is stored.
- the projecting portion 27c is provided with a quick communication hole 27d for communicating the space inside the projecting portion 27c with the central chamber 34 at the center thereof.
- an orifice 33 for communicating the outer chamber 35 and the central chamber 34 is opened in the inner cylinder 28 a of the upper container 28, and a gas discharge hole is formed in the outer cylinder 28 b of the upper container 28. 3 6 are open.
- an ignition agent tube 40 is housed above the projecting portion 27 c of the central chamber 34.
- the outer chamber 35 is defined by an inner wall 31 having an orifice 32. And, inside the inner wall 31, a gas generating agent power tap 50 is housed. Outside the inner wall 31, a first coolant 25, a second coolant 26, and a filter 30 in front of a gas discharge hole 36, which are located at the outlet of the orifice 32, are housed. .
- the filter 30 is sealed with a filter push bar 29.
- the operation of the gas generator 1 will be described.
- a predetermined flow through the lead wire 7 flows to the S bridge (not shown) of the squib 10
- the explosive in the squib is ignited, the tip of the squib is broken, and high-temperature, high-pressure gas is released. Is done.
- This high-temperature gas breaks the igniting agent cap 40 and ignites the stored igniting agent (ignition hand S) 41.
- the high-temperature gas generated by the burning of the igniting agent 41 passes through the orifice 33, breaks the gas generating agent power 50, and ignites the stored gas generating agent 51.
- a large amount of gas is generated by the combustion of the gas generating agent 51, and the generated gas passes through the first coolant 25 and the second coolant 26 via the orifice 32, and is cooled and burned.
- the slag is removed through the filter 30 and then from the discharge hole 36 to the inside of the bag (not shown).
- This gas generator 1 is built in the airbag module. Furthermore, the air bag module incorporating the gas generator 1 is a steering wheel. Attached to the device.
- Such an airbag module considers the case where the vehicle starts immediately after being hidden in the scorching sun and the case where the vehicle starts immediately after the vehicle is left under severe cold. It must be specified that it can be used even if it is exposed to an ambient temperature of at least 40 ° C to ft ⁇ temperature + 85 ° C.
- the container 21 of the gas generator 1 is formed of a gold (S) material such as aluminum so as to have sufficient strength to withstand the internal pressure due to the generated gas.
- This metal material such as aluminum generally has good heat conduction, and is easily heated or cooled under the influence of the ambient temperature. Therefore, there is a good possibility that the temperature of the container 21 has a wide temperature distribution from 140 to + 85'C.
- the weight of the container 21 accounts for a large part of the weight of the gas generator 1, and the maturity S of the container 21 is also large.
- the container 21 If the container 21 is cooled down to ⁇ 40 ° C., the amount of heat generated by the combustion reaction of the gas generating agent will be absorbed by the heating of the container 21, and the amount of heat generated will decrease. The burning speed of the gas becomes extremely slow. Conversely, when the container 21 is heated to 85'C, the amount of heat generated by the combustion reaction of the gas generating agent is less likely to be absorbed by the container 21, so that the calorific value increases. The burning rate of the gas generating agent is too fast.
- the difference between the calorific value between the low temperature and the high temperature was changed by changing the type of the oxidizing agent of the gas generating agent.
- a gas generant that allows the box to be used may be used. Then, regardless of whether the ambient temperature is low or low, there is no large difference in the calorific value due to the combustion of the gas generating agent, and the reaction rate does not largely change.
- the gas generating agent to the oxidizing agent to reduce the difference in Hatsujuku amount at low temperature and high temperature composed mainly of sodium azide, for example F e 2 0 3 and A l a
- SOJ ⁇ the gas generating agent to the oxidizing agent to reduce the difference in Hatsujuku amount at low temperature and high temperature
- these components are slag components, so their addition will reduce the gasification rate of the gas generating agent to 50% or less. Therefore, in order to obtain the same amount of gas, a larger amount of gas generating agent was required, which hindered downsizing of the gas generator and the shift to S.
- the present invention has been made in view of such a problem g of the conventional technology, and its main purpose is to provide a gas generating agent storage space which is received from the ambient temperature.
- An object of the present invention is to provide a gas generator which has a small effect on (emptiness in which a gas generating agent is substantially present).
- the object of the present invention is to provide a gas generator which makes it possible to use a gas generating agent having a high gasification rate and which can achieve downsizing and lightening of the gas generator.
- Another object of the present invention is to provide a gas generator which allows the use of a gas generating agent having a small calorific value during combustion. Disclosure of the invention
- the gas generator for a pair of bags that solves the above-mentioned BI principle has a central chamber, an annular outer chamber having a communicating portion with the central chamber and surrounding the tongue central chamber, and a gas bag for inflating the bag.
- a short cylindrical container having a discharge hole for discharging gas from the outer chamber, a gas generating agent stored in the S-shaped outer chamber, and a gas generating agent stored in the central chamber for burning the gas generating agent.
- a heat insulating material provided at least above and / or below the outer chamber is provided. I have.
- the temperature at the start of combustion must be within the specified range, and after the start of combustion, the heat exchange between the generated high crude gas and its surroundings must be reduced. is important. Thus, self-contained combustion can be achieved by burning with less transfer of heat from the surroundings. Therefore
- the present invention has been made in view of the fact that the gas generator container has a large heat capacity as a whole of the gas generator, and furthermore, the burning speed of the gas generating agent is easily affected by the container temperature *.
- the gas generating agent contained in the outer chamber of the gas generator container is provided with a cutout material at least above the outer chamber, which is the portion closest to the outermost wall of the container, and Z or below. This is the gas generator of the present invention.
- the heat insulating member When the heat insulating member is provided in this way, the combustion state of the gas generating agent is less affected by the container temperature than in the conventional gas generator without the heat insulating member. As a result, even when the container temperature is as low as 140 ° C to as high as 85 ° C, there is little change in the combustion rate of the gas generating agent, and safe and reliable airbag operation is possible. become.
- Some gas generators include a cup in the outer chamber for storing the gas generating agent.
- the upper and / or lower jujube material in the outer chamber is placed inside the cup.
- the gas generating agent storage space and its surroundings are reliably disconnected. heat.
- an upper and / or lower heat insulating member in the outer chamber may be provided outside the cup. it can.
- the heat insulating material When the heat insulating material is put on the outside of the front K cup, it is preferable that the heat insulating material is disposed so as to be in direct contact with the outside of the upper surface and / or the lower surface of the cup.
- the gas generator is provided with an inner wall for partitioning the space inside the container, and depending on the shape of the inner wall, the inner wall is arranged so as to be in direct contact with the upper surface of the cup and the outside of the Z or lower surface. S can be difficult to do.
- a heat insulating material is provided at least between the upper surface of the forceps and the inner surface node of the container and / or between the lower surface of the cup and the inner surface portion of the container.
- the heat insulating material a material that is inert to the gas generating agent, nonflammable, and withstands high temperatures is used.
- a material that satisfies this condition one or more of graphite sheet, ceramic fiber, ceramic molded product, heat-resistant polymer, and foamed gold) s, and gold-coated foil product are preferable.
- non-azide soda gas generating agent having a high gasification rate a nitrogen-containing compound is used as a gas generating component, and an oxidizing agent mainly containing nitrate is combined. There is something.
- nitrogen-containing compound examples include one or more selected from the group consisting of a tetrazole derivative, a guanidine derivative, an azodicarbonamide derivative, a hydrazine derivative, and a triazole derivative.
- ADCA azodicarbonamide
- guadin triamino guanidine nitrate
- TAGN triamino guanidine nitrate
- guanidine diacid guanidine carbonate
- tetrazole 5-aminonotetrazole
- 5 , 5'-Ib-IH-tetrazole 5-oxo-1,2,4-triazole
- hexamethylenetetramidine dicyandiamide
- biuret hydrazine.
- Lipohydrazide oxalic acid dihydrazide. And so on.
- reaction products are preferred examples o
- a gas generating agent obtained by reacting a compound having one NH, group or one NH- in the structural formula with an organic compound having one CH 0 group in the structural formula is a preferable gas from the viewpoint of handling safety. It is a generator.
- Specific examples of the organic compound having one CH 0 group in the above structural formula include formaldehyde (methanal, hereinafter the formal name in parentheses). Ataldehyde (ethanal), p13bionaldehyde (propanal).
- organic compound capable of forming one CH 0 group examples include paraformaldehyde H 0 (CH a 0) n H. Trioxane (CH a 0) s , hexamethylene tetraamine (CH,) ⁇ These are used alone or in combination of two or more.
- oxidizing agent examples include sodium nitrate, potassium nitrate, barium nitrate, ammonium nitrate and strontium nitrate.
- FIG. 1 is a cross-sectional view of a gas generator of the present invention
- FIG. 2 is a cross-sectional view of another gas generator of the present invention
- FIG. 30 is a cross-sectional view of still another gas generator of the present invention.
- FIG. 4 is a cross-sectional view
- FIG. 4 is a graph showing characteristics of gas pressure and temperature of the gas generator according to Example 1
- FIG. 5 is a gas pressure of the gas generator according to Comparative Example 1.
- FIG. 6S is a graph showing characteristics of gas pressure and temperature of the gas generator according to Comparative Example 2
- FIG. 7 is a graph showing characteristics of other gases of the present invention.
- FIG. 8 is a sectional view of a generator
- FIG. 8 is a sectional view of still another gas generator according to the present invention
- FIG. 9 is a sectional view of a conventional gas generator.
- FIG. 1 is a cross-sectional view of the gas generating system 4 of the present invention.
- the same portions as those in the conventional example in FIG. 9 are denoted by the same reference numerals, and description thereof will be omitted.
- the difference from FIG. 9 is that the heat insulating members 22 and 23 are provided on the upper surface and the lower surface of the annular forceps 50.
- the other different parts are that the coolants 25 and 26 are removed, the bottom of the inner wall 31 extends to the bottom of the container 21, and the gas generating agent storage space is enlarged, and The orifice 32 is provided on the side surface.
- the heat insulating material 22, 23 is an outer chamber 3 in which the gas generating agent 51 stored in the outer chamber 35 of the gas generator container is the node closest to the outermost wall of the vessel 21. It is crotched up and down inside 5.
- the heat insulating material 22 since the gas generating agent 51 is housed in the three-way forceps 50 provided in the outer chamber 35, the heat insulating material 22. Side and upper and lower surfaces.
- the heat insulating material 23 is disposed inside the upper surface side of the power bar 50 and is in contact with the gas generating agent 51.
- the heat insulating material 22 is arranged inside the lower surface side of the power tube 50 and is in contact with the gas generating agent 51. In this manner, since no other node material is interposed between the heat insulating members 22 and 23 and the gas generating agent 51, the gas generating agent storage space and its surroundings are reliably insulated. In addition, if the material is capable of bursting when gas is generated, it is desirable to provide a heat insulating member also on the surface with respect to the orifices 33, 32.
- the heat insulating member 22.23 a material which is inert to the gas generating agent 51, is nonflammable, and can withstand high temperatures is used. Products that meet this condition include lead sheets, ceramic fibers, ceramic molded products, One or more of heat-resistant polymers, foamed gold JS, and gold JS foil seed layer products are preferred.
- the main body and the throat body of the gas generant power tap 50 are formed of aluminum foil. ttThe bottom of the cup 50 is placed on the inner wall 31.
- the inner peripheral side surface of the »-shaped cup 50 has a gap with the inner wall 28a, and the annular force is The outer peripheral side surface of the bush 50 also has a space between the upright wall 8P of the inner wall 31 and the asperity.
- the squib 10 is ignited, and the hot gas generated by burning the igniting agent 41 blows out through the orifice 33.
- This high-temperature gas penetrates the gas generating agent cup 50 and ignites the gas generating agent 51.
- a large amount of gas generated by the combustion of the gas generating agent 51 passes through the orifice 32 of the inner wall 31 and reaches the filter 30. Further, the slag contained in the gas is removed by the filter 30 as necessary, and the slag is discharged into the airbag (not shown) from the discharge hole 36.
- the gas generator 4 as described above is composed of the upper and lower surfaces of the container 21 and the force tube 50 closest to the container 21 which are greatly affected by the temperature from the outside of the gas generator 4, and the outside.
- the gas generating agent 51 stored in the chamber 35 is insulated by the thermal insulation materials 22, 23. Therefore, the range in which the temperature of the gas generating agent storage space fluctuates is narrower than the range in which the temperature of the container 21 fluctuates, and the temperature of the gas generating agent storage space at the start of combustion may be within a predetermined range. it can. After the start of combustion, the heat exchange between the high-temperature gas generated by the heat insulating material 22.23 and its surroundings, or the heat exchange between the gas generating agent itself and the vessel wall is reduced, and the self-contained operation is completed. Enables combustion. As a result, a predetermined range of burning speed is obtained.
- the gas generator 4 described above has a small change in the combustion rate of the gas generating agent 51 even when the ambient temperature is as low as 140 ° C. to the S temperature of + 85 ° C. It enables safe and reliable operation of the air bag.
- gas generators that have little effect on the gas generating agent storage space from the ambient temperature must use the gas generating agent in consideration of the effect from the ambient temperature.
- the heat insulating member 22.23 so as to surround the entire space in which the gas generating agent 51 is housed, since the transfer of heat to the surroundings is minimized.
- the heat-insulating members 22 and 23 disposed above and below the outer chamber 35 are provided with the container 21 and the heat-receiving member 21 which receive a large amount of temperature shadow from the outside of the gas generator 4 as described above. Since the upper and lower surfaces of the forceps 50 closest to the container ⁇ ⁇ are insulated from the gas generating agent 51 stored in the outer chamber 35, a heat insulating node is provided. In comparison with a conventional gas generator that does not have the above, the influence of the ambient temperature of the container 21 and the like on the gas generating agent storage space is sufficiently reduced.
- the heat insulating members 22 and 23 of the gas generator 4 of the above embodiment are provided with a heat insulating member 22.23 and a gas insulating material in order to surely insulate the gas generating agent 51 and its surroundings. It is placed inside the force switch 50 so that no other member is interposed in the ffl with the generator 51. However, if at least a portion of the cup 24 is formed of a low heat capacity S member such as a wire mesh, the maturing member 38.3, as in the gas generator shown in FIG. 2 or FIG. 7 can be provided outside the forceps 24.
- the gas generator 5 shown in FIG. 2 is an example in which the heat insulating nodes 38 and 37 are provided so as to directly contact the upper and lower surfaces of the power tube 24 outside the power window 24. Is shown.
- the inner wall orifice 32 is crotched below the gas generating agent storage power tube 24 as in the conventional case, and the inner wall orifice 32 extends outside the lower surface of the power tube 24.
- a heat insulating member 3 is provided between the upper surface of the forceps 24 and the inner surface of the container 21 and between the lower surface of the forceps 24 and the inner surface of the container 21. 7 and 38 are provided.
- the heat insulating material 38 is attached to the ceiling of the upper container 28 located on the upper side of the inner surface of the container S 21, and is in contact with the gas generating agent tube 24.
- the cutout member 37 is attached to the bottom of the lower container 27 located on the lower side of the inner surface of the container 21.
- the lower surface of the gas generating agent cap 24 faces the heat insulating material 37 via the inner wall 31 having the opening of the smart press 32.
- the heat insulating member 37 at the bottom has a bent portion 37 a that is in contact with the lower inner peripheral surface of the container 21.
- the body of the gas generant tub 24 is formed of a wire mesh, and the lid is formed of aluminum foil.
- the bottom of the wire mesh rests on the inner wall 31.
- the inner peripheral side surface of the »-shaped forceps 24 formed of a wire mesh has a gap with the inner cylinder 28a, and the outer peripheral side surface of the cup 24 also has an inner wall 3 1 standing wall 3 It has a gap with 1a.
- the lid is pressed down by a heat insulating member 38.
- the squib 10 is ignited, and the hot gas generated by burning the igniting agent 41 blows out through the orifice 33. This hot gas strikes the wire mesh of the gas generant tube 24.
- Gas generator 51 is ignited.
- the heavy gas generated by the burning of the gas generating agent 51 floods the orifice 32 and hits the heat insulating member 37 attached to the bottom of the lower container 27 as shown by the arrow 1 .
- this gas reaches the filter 30 via the passage 31 b around the inner wall 31.
- the slag contained in the gas is removed by the filter 30 as required, and is discharged from the discharge hole 36 into the airbag (not shown).
- the groom portion of the gas generating agent tube 24 is formed of gold 8
- the heat capacity is smaller than that of a metal plate. Therefore, the temperature of the empty ffl containing the gas generating agent 51 is hardly affected by the temperature of the gas generating agent 24, and the generated gas or the gas generating agent itself is The degree of cooling by the generator cup 24 is also reduced, and the degree of change in the combustion rate of the gas generator 51 is further reduced.
- a cup made of a carbon fiber woven nep in addition to a wire mesh forcep.
- wire mesh As the wire mesh that fulfills the above-mentioned functions, a wire mesh made of stainless steel and having a coarse mesh is preferable, but an iron wire or a mesh may be used.
- FIGS. 4, 5, and 6 are gas pressure and temperature characteristic diagrams of the gas generator, and show the results of a test using a 60 liter tank. The solid line indicates the rise in pressure in tank ⁇ , and the dashed line indicates the rise in gas temperature in the tank.
- FIG. 4 corresponds to Experimental Example 1
- FIG. 5 corresponds to Comparative Example 1
- FIG. 6 corresponds to Comparative Column 2.
- a gas generator in which a heat insulating material is arranged on the upper surface and the lower surface outside the gas generating agent cap and the main part of the gas generating agent cup is formed by a wire mesh,
- the degree of increase in gas temperature and gas pressure has been greatly improved, and the burning rate of the gas generating agent has been increased, thus achieving the desired gas generator characteristics.
- a gas generating agent containing an oxidizing agent containing a non-oxohalogenate as a main component which has been considered to be unusable in the past, can be used in a gas generator and replaces sodium azide. Enables the use of various drugs. Expanding the range of selection of gas generating agents makes it possible to significantly reduce the size and weight of gas generators.
- a gas generator capable of miniaturization and ⁇ -quantification is in addition, there are gas generators that use ADCA, TAGN (triamino guanidine nitrate), and 51-aminotetrazole to store gas generating agents with a high gasification rate.
- ADCA deoxyribonate
- TAGN triamino guanidine nitrate
- 51-aminotetrazole to store gas generating agents with a high gasification rate.
- a gas generating agent having a high gasification rate using ADCA, TAGN, 5-aminotetrazole or the like there is no need to use a coolant for removing the residue, and the structure is discarded.
- a gas generator 6.3 using such a gas generating agent is shown in FIGS. 7S and 8.
- the gas generators 6 and 3 have a structure in which the lower container 101 and the upper container 102 are fixed with bolts 103 to form the container 21.
- a bag-shaped protrusion 101a is formed, and the squib 10 is housed in the protrusion 1D1a, and the retainer 104 is screwed in and fixed. It has become.
- An ffi body 105 is fitted around the protruding ffi 101 a, and an ignition agent tube 40 is housed in the cylindrical body 105.
- a cushion material 106 is provided between the body 105 and the upper container 102. The cushioning material 106 presses the ignition agent power supply 40 and the gas generating agent power supplies 50 and 24 described below against the container 21 so that there is no play. .
- An orifice 109 is opened obliquely downward in the body 105, and a number of small-diameter discharge holes 36 are opened in the outer periphery of the upper container 102.
- An annular gas generant tube 24.50 is housed in the gas generant container 21 so as to surround the cylindrical body 105. Further, a gas retention space 111 having neither a coolant nor a filter is formed between the outer peripheral side surface of the gas generating agent tube 24.50 and the inner surface portion of the side surface of the container 21.
- the gas retention space 111 is a space for equally dividing the gas from the gas generating agent ports 24, 50 toward the discharge holes 36 by E.
- a ripening member 108 serving also as a rupture sheet is provided on the inner side of the container 21 so as to close the discharge hole 36.
- a heat insulating member sheet 108 having flexibility, such as a black sheet is used for a rapture, the sheet is sequentially broken according to the internal pressure and the opening area is increased. Therefore, the internal pressure can be adjusted by adjusting the thickness of the ripened member 108 that closes the discharge hole 36.
- the gas generator 6 shown in FIG. 70 is provided with a heat insulating member 22.23 on the upper surface and the lower surface inside the annular forcep 50 made of aluminum foil.
- the insulating material 22 and 23 are composed of the upper and lower surfaces of the container 21 and the cup 50 closest to the container 21 and the container 21 which are most affected by temperature from the outside of the gas generator 6, and the gas generation. It insulates the space where the agent is stored.
- the heat insulating members 22 and 23 are stiffened so that no other members are interposed between the heat insulating member and the gas generating agent, in order to reliably insulate the gas generating agent and its surroundings.
- 50 fi is arranged inside.
- the heat insulating materials 22 and 23 are formed of a graphite sheet.
- the gas generator 3 shown in FIG. 8 has an annular force ring 24 formed of a wire mesh.
- the heat insulating members 37 and 38 are attached to the inside and the upper and lower surfaces of the container 21.
- the gas generating agent tube 24 entirely formed of a wire mesh is housed in a space surrounded by the heat insulating members 37, 38, and a heat insulating member 108 also serving as a rupture sheave. Have been.
- the squib 10 ignites, the igniting agent 41 burns, and the hot gas blows out of the orifice 1D9.
- the gas generating agent 51 is burned through the cup 50.24.
- the gas from the gas generating agent cups 50 and 24 is equally divided into E toward the discharge hole 36 in the gas retaining space 11 1.
- the heat insulating material 108 blocking the discharge hole 36 is sequentially broken and opened.
- the number of open discharge holes 36 increases and the opening area increases. Therefore, in container 2 1
- the pressure rise is kept to a certain limit and maintained at a predetermined pressure within 100 bar for a certain time.
- the gas generators 6 and 3 have a minimum size of ignition means 40 and 10 and gas generators 50 and 24 in the enclosure 21 and can be miniaturized. It is. Availability in industrial draft
- the gas generator according to the present invention is provided with a heat insulating material at least in the vicinity of the gas generating agent storage space, that is, at least above, and Z or below, in the outer chamber of the gas generator container.
- the shadow W on the gas generator storage space received from the engine is reduced, and it is possible to obtain a combustion speed in a predetermined range. Therefore, there is no need to select a gas generating agent in consideration of the shadow W from the ambient temperature, and there are various alternatives to a gas generating agent with a high gasification rate, a gas generating agent with low heat generation during combustion, and sodium azide. It is most suitable as a gas generator that makes use of chemicals etc. fool. Further, since the amount of the gas generating agent used and the extra members of the gas generator can be eliminated by removing the gas generating agent, the gas generating device is optimal as a gas generator capable of achieving downsizing and improvement.
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Air Bags (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6/261727 | 1994-09-30 | ||
JP26172794 | 1994-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996010495A1 true WO1996010495A1 (fr) | 1996-04-11 |
Family
ID=17365876
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1995/001927 WO1996010495A1 (fr) | 1994-09-30 | 1995-09-25 | Generateur de gaz pour coussin gonflable de securite |
Country Status (2)
Country | Link |
---|---|
TW (1) | TW284727B (enrdf_load_html_response) |
WO (1) | WO1996010495A1 (enrdf_load_html_response) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2989788B2 (ja) | 1996-10-31 | 1999-12-13 | ダイセル化学工業株式会社 | エアバッグ用ガス発生器及びエアバッグ装置 |
US6378901B1 (en) | 1998-06-26 | 2002-04-30 | Daicel Chemical Industries, Ltd. | Gas generator for an air bag and air bag system |
EP1346886A4 (en) * | 2000-12-27 | 2005-03-30 | Daicel Chem | AIRBAG AND GAS GENERATOR FOR AIR BAG |
WO2006016632A1 (ja) * | 2004-08-10 | 2006-02-16 | Daicel Chemical Industries, Ltd. | エアバッグ用ガス発生器 |
JP2007062461A (ja) * | 2005-08-30 | 2007-03-15 | Daicel Chem Ind Ltd | ガス発生器 |
US7648163B2 (en) | 2004-08-10 | 2010-01-19 | Daicel Chemical Industries, Ltd. | Gas generator for air bag |
US10960846B2 (en) | 2008-09-30 | 2021-03-30 | Zf Airbag Germany Gmbh | Inflator, method of manufacturing the same and module including said inflator |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02225389A (ja) * | 1989-02-28 | 1990-09-07 | Daicel Chem Ind Ltd | 清浄ガス発生剤 |
JPH05178153A (ja) * | 1991-12-27 | 1993-07-20 | Daicel Chem Ind Ltd | エアバッグ用ガス発生器 |
-
1995
- 1995-09-25 WO PCT/JP1995/001927 patent/WO1996010495A1/ja active Application Filing
- 1995-11-20 TW TW084112330A patent/TW284727B/zh active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH02225389A (ja) * | 1989-02-28 | 1990-09-07 | Daicel Chem Ind Ltd | 清浄ガス発生剤 |
JPH05178153A (ja) * | 1991-12-27 | 1993-07-20 | Daicel Chem Ind Ltd | エアバッグ用ガス発生器 |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2989788B2 (ja) | 1996-10-31 | 1999-12-13 | ダイセル化学工業株式会社 | エアバッグ用ガス発生器及びエアバッグ装置 |
US6378901B1 (en) | 1998-06-26 | 2002-04-30 | Daicel Chemical Industries, Ltd. | Gas generator for an air bag and air bag system |
US6511081B2 (en) | 1998-06-26 | 2003-01-28 | Daicel Chemical Industries, Ltd. | Gas generator for an air bag and air system |
US6679521B2 (en) | 1998-06-26 | 2004-01-20 | Daicel Chemical Industries, Ltd. | Gas generator for an air bag and air bag system |
DE19929279B4 (de) * | 1998-06-26 | 2016-12-01 | Daicel Chemical Industries, Ltd. | Gasgenerator für Airbag und Airbag-System |
US7114746B2 (en) | 2000-12-27 | 2006-10-03 | Daicel Chemical Industries, Ltd. | Air bag-use gas generator and air bag device |
EP1346886A4 (en) * | 2000-12-27 | 2005-03-30 | Daicel Chem | AIRBAG AND GAS GENERATOR FOR AIR BAG |
JP2006076558A (ja) * | 2004-08-10 | 2006-03-23 | Daicel Chem Ind Ltd | エアバッグ用ガス発生器 |
US7648163B2 (en) | 2004-08-10 | 2010-01-19 | Daicel Chemical Industries, Ltd. | Gas generator for air bag |
CN1989030B (zh) * | 2004-08-10 | 2010-05-26 | 大赛璐化学工业株式会社 | 气囊气体发生器 |
WO2006016632A1 (ja) * | 2004-08-10 | 2006-02-16 | Daicel Chemical Industries, Ltd. | エアバッグ用ガス発生器 |
JP2007062461A (ja) * | 2005-08-30 | 2007-03-15 | Daicel Chem Ind Ltd | ガス発生器 |
US10960846B2 (en) | 2008-09-30 | 2021-03-30 | Zf Airbag Germany Gmbh | Inflator, method of manufacturing the same and module including said inflator |
Also Published As
Publication number | Publication date |
---|---|
TW284727B (enrdf_load_html_response) | 1996-09-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6095559A (en) | Chemical cooling of airbag inflation gases | |
JP2926040B2 (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
US7134689B2 (en) | Inflator | |
US7237801B2 (en) | Gas generating system | |
US7343862B2 (en) | Gas generating system | |
US20050263994A1 (en) | Inflator | |
US7398996B2 (en) | Gas producer | |
JPH11334517A (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
JPH1159314A (ja) | エアバッグ用ガス発生器 | |
WO2005014344A1 (ja) | ガス発生器 | |
EP2380786B1 (en) | Gas generator for airbag device | |
US6808204B1 (en) | Hybrid inflator | |
WO1996010494A1 (fr) | Generateur de gaz | |
US8123878B1 (en) | Gas generating system | |
WO1996010495A1 (fr) | Generateur de gaz pour coussin gonflable de securite | |
JP4271570B2 (ja) | エアバッグ用インフレータ | |
JP3218213B2 (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
JPH10181516A (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
US20060202455A1 (en) | Gas generator | |
US7275760B2 (en) | Multi-chamber gas generating system | |
JP3229840B2 (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
CN100540513C (zh) | 充气器和气囊系统 | |
JPH11189126A (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
JP2001206189A (ja) | エアバッグ用ガス発生器及びエアバッグ装置 | |
JPH0995202A (ja) | エアバッグ用ガス発生器 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): JP KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
122 | Ep: pct application non-entry in european phase |