WO1995024449A1 - Colle thermofusible a base de polypropylene - Google Patents
Colle thermofusible a base de polypropylene Download PDFInfo
- Publication number
- WO1995024449A1 WO1995024449A1 PCT/CA1995/000132 CA9500132W WO9524449A1 WO 1995024449 A1 WO1995024449 A1 WO 1995024449A1 CA 9500132 W CA9500132 W CA 9500132W WO 9524449 A1 WO9524449 A1 WO 9524449A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- ethylene
- grafted
- composition
- copolymer
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/24—Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Definitions
- the present invention relates to a polypropylene-based hot-melt adhesive composition which is capable of bonding a polypropylene substrate to another substrate.
- the present invention relates to a polypropylene-based hot-melt adhesive composition that is capable of being applied so as to bond two polypropylene-based substrates together and also be capable of being subjected to recycling processes for polypropylene.
- Structures may be bonded together using a variety of adhesives.
- One adhesive that is relatively easy to apply while still providing good bonding properties is an isocyanate-containing polyurethane adhesive, which may be sprayed onto a substrate and then subsequently cured to provide a strong bond strength.
- an isocyanate-containing polyurethane adhesive which may be sprayed onto a substrate and then subsequently cured to provide a strong bond strength.
- use of water- based polyurethane adhesives is known for the bonding of polypropylene substrates to another substrate e.g. the bonding of mica-filled polypropylene to a woven polyester fabric.
- the use of such polyurethane adhesives in lamination processes represents an occupational health risk and major precautions must be taken during operation of the process in order to protect the personnel involved. It would be desirable to have alternate processes that do not use polyurethane adhesives.
- U.S. Patent 5 241 014 of H. Kehr et al. discloses the production of largely amorphous polyalpha-olefins with a narrow molecular weight distribution by subjecting largely amorphous polyalpha-olefins containing 3-75 weight percent of C 4 -C, 0 alpha-olefin, 25-95 weight percent of propylene and 0-20 weight percent ethylene monomer units to a shearing force at a temperature above the softening point of the polymer in the presence of a radical donor. Grafting reactions may be conducted at the same time. The polymers are stated to be useful as hot-melt adhesives.
- U.S. Patent 4 719 260 of R.K. Stuart et al. discloses hot-melt adhesive compositions useful for bonding polyethylene, that contain amorphous polypropylene polymers and grafted copolymers of saturated polycyclic hydrocarbon resins and maleic anhydride.
- U.S. 4 554 304 of D.R. Hansen et al. discloses hot-melt adhesive compositions formed from butene/ethylene copolymers that have been grafted with maleic anhydride and aliphatic non-polar resins.
- An adhesive has been found that is capable of bonding one polypropylene substrate to another substrate, especially mica-filled polypropylene, foam polypropylene or a woven polypropylene, and be capable of being recycled with polypropylene.
- the present invention provides an adhesive composition comprising a melt blend of:
- the blend is in the form of a melt blend.
- the grafted copolymer of (a) has a melt index in the range of 100-500 dg/ in.
- the copolymers of (a) and/or (b) are grafted copolymers.
- grafted copolymer (b) has a melt index of at least 100 dg/min.
- the copolymer of (b) has been grafted with 0.5-2.0% by weight of the ethylenically unsaturated carboxylic acid or anhydride, or derivative thereof.
- the present invention also provides an adhesive composition comprising a blend of:
- the adhesive composition contains un-grafted ethylene/vinyl acetate copolymer or ethylene/propylene/diene copolymer, especially such ungrafted copolymer in the presence of grafted copolymer of (b) .
- the copolymer of (b) is selected from ethylene/vinyl acetate copolymers, ethylene/ (meth) acrylate copolymers, ethylene/ (meth) acrylic acid copolymers, and copolymers of ethylene, alkyl acrylate and carbon monoxide.
- the present invention provides a process for the bonding of a first substrate to a second substrate comprising coating the first substrate with a molten composition of a blend of: (a) 50-95% by weight of polypropylene that has been grafted with 0-5% by weight of at least one ethylenically-unsaturated carboxylic acid or anhydride, or derivative thereof; and
- the present invention provides a process for the bonding of a first substrate to a second substrate comprising coating the first substrate with a molten composition of a blend of:
- At least one and preferably both of the substrates is formed from polypropylene, including mineral-filled, foamed or woven polypropylene.
- polyolefins may be used in the adhesive of the present invention, as defined above. Different polyolefins are used for the components described as (a) and (b) above, and those polyolefins in the form used in the adhesive must be compatible in order that the resultant adhesive has acceptable properties.
- the copolymer of component (a) is polypropylene.
- polypropylene refers to homopolymers of propylene, to impact or so-called block copolymers of propylene with ethylene in which the ethylene content is less than about 25% by weight and to random copolymers of propylene with ethylene in which the ethylene content is less than about 8% by weight.
- the copolymer of component (b) may be a copolymer of ethylene and at least one comonomer selected from carbon monoxide, vinyl acetate, alkyl acrylates, alkyl methacrylates, in which the alkyl group has 1-4 carbon atoms, acrylic acid and methacrylic acid.
- the copolymer of component (b) is a copolymer of ethylene, alkyl acrylate and carbon monoxide.
- the copolymer is characterized by having a heat of crystallization of less than 70 J/g.
- the copolymer is an ethylene/vinyl acetate copolymer
- the copolymer has a vinyl acetate content of at least 10% by weight.
- the copolymers are ethylene/vinyl acetate copolymers, ethylene/methyl acrylate copolymers, ethylene/ethyl acrylate copolymers, ethylene/butyl acrylate copolymers, ethylene/isobutyl acrylate copolymers, ethylene/vinyl acetate/carbon monoxide copolymers, ethylene/ethyl acrylate/carbon monoxide copolymers, ethylene/butyl acrylate/carbon monoxide copolymers, ethylene/ethyl methacrylate/carbon monoxide copolymers and ethylene/butyl methacrylate/carbon monoxide copolymers. While the copolymer of (b) may be used in an un-grafted state, it is preferred that the copolymer of (b)
- the monomer used in the grafting of the copolymers is at least one monomer selected from ethylenically unsaturated carboxylic acids and ethylenically unsaturated carboxylic acid anhydrides, including, less preferably, derivatives of such acids, and mixtures thereof.
- the acids and anhydrides which may be mono-, di- or polycarboxylic acids, are acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, itaconic anhydride, maleic anhydride, and substituted maleic anhydride, e.g.
- maleic anhydride being particularly preferred.
- the derivatives of the unsaturated acids are salts, amides, imides and esters e.g. mono- and disodiu maleate, acrylamide, maleimide, glycidyl methacrylate and dimethyl fumarate.
- Techniques for the grafting of such monomers onto the copolymers are known e.g. as described in U.S. Patent 4 612 155 of R.A. Zelonka and CS. Wong, which issued September 16, 1986, and in published European patent application No. 0 369 604 of D.J. Mitchell, published May 23, 1990.
- the present invention will be particularly described herein with reference to maleic anhydride as the grafting monomer.
- the copolymer of (b) may be grafted or ungrafted copolymer of ethylene, propylene and a diene i.e. the so-called EPDM copolymers.
- Such copolymers have a Mooney viscosity of less than 20 at 125°C
- the adhesive composition of the present invention has a melt viscosity suitable for use as a hot melt adhesive, especially a melt viscosity of 1000-100 000 cps at 220°C, especially 10 000-75 000 cps at 220°C, and particularly 20 000-50 000 cps at 220°C Melt viscosity is measured using a Brookfield viscometer at a shear rate of 0.35 sec "1 .
- the melt index of the grafted copolymer of (a) when prepared separately, is preferably in the range of 100-500 dg/min, and especially 200-400 dg/min; as used herein, melt index is measured by the procedure of ASTM D-1238 (190/2.16, unless specified to the contrary) .
- the grafted monomer content of the copolymer of (a) when prepared separately, is 0-5% by weight, especially at least 0.1% by weight, and in particular at least 0.5% by weight. In embodiments, the amount of grafted monomer is 0.5-2.0% by weight.
- the melt index of the grafted copolymer or, where applicable, the ungrafted copolymer of (b) , when prepared separately, is preferably at least 100 dg/min, and especially at least 250 dg/min.
- the grafted monomer content of the copolymer of (b) when prepared separately, is 0-5% by weight and especially 0.1-2% by weight. In embodiments, the amount of grafted monomer is 0.5-2.0% by weight.
- blends of grafted and ungrafted polyolefins to order to achieve a desired level of graft in a composition, and such blending in of ungrafted components may be used herein.
- the adhesive composition of the present invention may be in the form of a physical admixture of the grafted copolymers of (a) and (b) described above. Such a physical admixture could be fed to a hot melt adhesive applicator. However, it is preferred that the adhesive composition be melt blended prior to being fed to the hot melt adhesive applicator, including for reasons of consistency of the adhesive composition that is actually applied to a substrate. Alternatively, the respective copolymers of the adhesive composition may be blended and then the blend subjected to a grafting process, using'the monomers described herein, under melt conditions.
- the adhesive is extruded directly onto a substrate i.e. while the adhesive is still in a molten condition.
- Apparatus suitable for the blending or mixing of the adhesive and for application of a hot melt adhesive to a substrate are known.
- the adhesive is applied to a first substrate in a molten condition and then the second substrate is applied over the adhesive while the adhesive is still in a molten condition. Contact of the adhesive while molten with both substrates is important in order to achieve a good bond.
- substrates While a variety of substrates may be bonded together using the adhesive composition described herein, in preferred embodiments at least one and especially both substrates are formed from polypropylene.
- substrates are mineral-filled polypropylene e.g. mica-filled polypropylene, foamed polypropylene, and woven polypropylene including fabrics, woven tapes and the like.
- the adhesive composition and process of the invention may be used in the bonding of substrates, especially polypropylene.
- use of the adhesive composition permits the opportunity of recycling the bonded substrates as the polymeric components are based on or compatible with polypropylene.
- polypropylene would have a melt index (or melt flow index) and other characteristics of polypropylenes used in the forming of articles, which would depend in part on the particular end-use.
- the adhesive forms strong bonds with polypropylene, as illustrated below, but may be used with other substrates.
- the adhesive may be used in a wide variety of industrial applications, including for example in the automotive industry, and in the manufacture of furniture, appliances and small electronic equipment.
- a random copolymer of propylene with 4% of ethylene as comonomer and having a melt flow index (procedure of ASTM D1238 (230/2.16)) of 5 dg/min was grafted with 1.4% by weight of maleic anhydride using a melt grafting process and a free radical initiator.
- the melt index of the grafted copolymer obtained was 260 dg/min. This grafted copolymer is referred to below as component A.
- An ethylene/vinyl acetate copolymer containing 28% by weight of vinyl acetate comonomer and having a melt index of 800 dg/min was grafted with 0.8% by weight of maleic anhydride using a melt grafting process and a free radical initiator.
- This grafted copolymer is referred to below as component B, and had a melt index after grafting of 400 dg/min.
- Component C was an ethylene (70% by weight) /propylene (23% by weight)/hexadiene (4.4% by weight) /norbornadiene (1% by weight) polymer that had been grafted with maleic anhydride.
- the grafted polymer had a Mooney viscosity at 125°C of 22.
- Component D was an ethylene (70% by weight) /propylene (23% by weight)/hexadiene (4.4% by weight) /norbornadiene (1% by weight) that had been grafted with maleic anhydride.
- the grafted polymer had a Mooney viscosity at 125°C of 10.
- a series of hot-melt adhesives were prepared using component A.
- the adhesive was prepared using a Brabender mixer to melt blend component A with another polymeric component, were applicable, and cooled.
- the resultant adhesive was applied, using a hot melt adhesive applicator, to a mica-filled polypropylene sheet, formed from homopolymer polypropylene containing 35% by weight of mica.
- the adhesive while still molten was contacted with either a polyethylene terephthalate (PET) woven fabric or a foamed polypropylene sheet.
- PET polyethylene terephthalate
- the bonded substrates were then subjected to two tests viz. a room temperature 180° peel test and a 95°C creep test.
- the test procedures were as follows:
- the 180° Peel Strength was determined using samples measuring 2.54 cm by 7.6 cm were peeled apart at ambient temperature, by peeling the substrates apart at an angle of 180° at a speed of 200 mm/min. The results are reported in lb/in.
- the creep test involved holding one substrate in a horizontal position and attaching a 200 g weight to the other substrate. The weight was permitted to hang freely, forming a 90° angle to the horizontal substrate. The samples were the same size as those for the peel strength test. The samples being tested were placed in an oven at 95°C shortly after preparation. To pass this test, at least 80% of the samples tested must not show signs of creep after a period of seven days.
- component A by itself as the hot-melt adhesive provided a bond with a good 180° Peel Strength but the failure type was adhesive failure i.e. the failure of the bond was between the adhesive and the substrate. Such a failure was deemed to be unacceptable.
- the adhesive containing component C as polymeric component showed an acceptable 180° Peel Strength with cohesive failure but the creep test was a failure. Thus, this adhesive was also deemed to be unacceptable.
- Example II The creep test and 180° peel tests were carried out according to the procedures outlined in Example I, using PET fabric.
- the blend contained 10% of the ethylene/vinyl acetate copolymer, and had a graft level of 0.9%.
- the blend contained 20% of the ethylene/vinyl acetate copolymer, and had a graft level of 0.8%. The results show that a composition that was blended and then grafted passed the creep and 180° peel tests.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP95911165A EP0702710B1 (fr) | 1994-03-11 | 1995-03-10 | Colle thermofusible a base de polypropylene |
AU18864/95A AU1886495A (en) | 1994-03-11 | 1995-03-10 | Polypropylene-based hot-melt adhesive |
DE69507558T DE69507558T2 (de) | 1994-03-11 | 1995-03-10 | Heissschmelzkleber auf polypropylenebasis |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9404708.1 | 1994-03-11 | ||
GB9404708A GB9404708D0 (en) | 1994-03-11 | 1994-03-11 | Polypropylene-based hot-melt adhesive |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995024449A1 true WO1995024449A1 (fr) | 1995-09-14 |
Family
ID=10751657
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CA1995/000132 WO1995024449A1 (fr) | 1994-03-11 | 1995-03-10 | Colle thermofusible a base de polypropylene |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0702710B1 (fr) |
AU (1) | AU1886495A (fr) |
CA (1) | CA2160345A1 (fr) |
DE (1) | DE69507558T2 (fr) |
ES (1) | ES2131309T3 (fr) |
GB (1) | GB9404708D0 (fr) |
WO (1) | WO1995024449A1 (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758675A2 (fr) * | 1995-08-15 | 1997-02-19 | Mitsui Petrochemical Industries, Ltd. | Composition adhésive de polypropylène et laminé multicouche comprenant cette composition |
WO1997007280A1 (fr) * | 1995-08-16 | 1997-02-27 | Basf Lacke Und Farben Aktiengesellschaft | Substrats recouverts de tissu |
WO1998028354A1 (fr) * | 1996-12-23 | 1998-07-02 | Shell Internationale Research Maatschappij B.V. | Compositions copolymerisees greffees |
WO1998048962A2 (fr) * | 1997-04-25 | 1998-11-05 | Brunswick Corporation | Structure composite multicouche thermoplastique |
US6133356A (en) * | 1996-12-23 | 2000-10-17 | Shell Oil Company | Graft copolymerized compositions |
US6218023B1 (en) | 1997-04-21 | 2001-04-17 | Montell North America, Inc. | Co-extruded laminate comprising at least one propylene graft copolymer layer |
US6306518B1 (en) | 1999-05-19 | 2001-10-23 | Montell Technology Company Bv | High surface gloss, co-extruded sheets from propylene polymer materials |
US6361844B1 (en) | 1999-01-27 | 2002-03-26 | David T. Ou-Yang | Release article and adhesive article comprising the release article |
WO2002061011A1 (fr) | 2001-01-29 | 2002-08-08 | Gluco Ltd | Adhesif |
US6465091B1 (en) | 2000-03-27 | 2002-10-15 | 3M Innovative Properties Company | Release article and adhesive article containing a polymeric release material |
US6489019B1 (en) | 1999-05-19 | 2002-12-03 | Basell Poliolefine Italia S.P.A. | High surface gloss, co-extruded sheets from olefin polymer materials |
EP2363444A1 (fr) * | 2006-06-15 | 2011-09-07 | Dow Global Technologies LLC | Interpolymères d'oléfine fonctionnalisés, compositions et articles préparés à partir de ceux-ci et procédé de fabrication associés |
US8957159B2 (en) | 2002-10-15 | 2015-02-17 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
WO2017040023A1 (fr) * | 2015-08-31 | 2017-03-09 | E. I. Du Pont De Nemours And Company | Compositions adhésives et structures multicouches comprenant un polypropylène fonctionnalisé |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
UST972002I4 (en) * | 1977-11-10 | 1978-07-04 | High temperature thermoplastic adhesive compositions comprising a propylene polymer and an ethylene/carboxylic acid copolymer | |
EP0370786A2 (fr) * | 1988-11-22 | 1990-05-30 | MITSUI TOATSU CHEMICALS, Inc. | Composition de résine de polypropylène |
WO1993011175A1 (fr) * | 1991-11-27 | 1993-06-10 | Quantum Chemical Corporation | Produits polymeres greffes, melanges adhesifs et structures composites |
-
1994
- 1994-03-11 GB GB9404708A patent/GB9404708D0/en active Pending
-
1995
- 1995-03-10 CA CA002160345A patent/CA2160345A1/fr not_active Abandoned
- 1995-03-10 WO PCT/CA1995/000132 patent/WO1995024449A1/fr active IP Right Grant
- 1995-03-10 ES ES95911165T patent/ES2131309T3/es not_active Expired - Lifetime
- 1995-03-10 DE DE69507558T patent/DE69507558T2/de not_active Expired - Lifetime
- 1995-03-10 EP EP95911165A patent/EP0702710B1/fr not_active Expired - Lifetime
- 1995-03-10 AU AU18864/95A patent/AU1886495A/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
UST972002I4 (en) * | 1977-11-10 | 1978-07-04 | High temperature thermoplastic adhesive compositions comprising a propylene polymer and an ethylene/carboxylic acid copolymer | |
EP0370786A2 (fr) * | 1988-11-22 | 1990-05-30 | MITSUI TOATSU CHEMICALS, Inc. | Composition de résine de polypropylène |
WO1993011175A1 (fr) * | 1991-11-27 | 1993-06-10 | Quantum Chemical Corporation | Produits polymeres greffes, melanges adhesifs et structures composites |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0758675A2 (fr) * | 1995-08-15 | 1997-02-19 | Mitsui Petrochemical Industries, Ltd. | Composition adhésive de polypropylène et laminé multicouche comprenant cette composition |
EP0758675A3 (fr) * | 1995-08-15 | 1998-07-15 | Mitsui Chemicals, Inc. | Composition adhésive de polypropylène et laminé multicouche comprenant cette composition |
WO1997007280A1 (fr) * | 1995-08-16 | 1997-02-27 | Basf Lacke Und Farben Aktiengesellschaft | Substrats recouverts de tissu |
WO1998028354A1 (fr) * | 1996-12-23 | 1998-07-02 | Shell Internationale Research Maatschappij B.V. | Compositions copolymerisees greffees |
US6133356A (en) * | 1996-12-23 | 2000-10-17 | Shell Oil Company | Graft copolymerized compositions |
US6217702B1 (en) | 1996-12-23 | 2001-04-17 | Shell Oil Company | Graft copolymerized compositions |
US6218023B1 (en) | 1997-04-21 | 2001-04-17 | Montell North America, Inc. | Co-extruded laminate comprising at least one propylene graft copolymer layer |
WO1998048962A2 (fr) * | 1997-04-25 | 1998-11-05 | Brunswick Corporation | Structure composite multicouche thermoplastique |
WO1998048962A3 (fr) * | 1997-04-25 | 1999-01-28 | Brunswick Corp | Structure composite multicouche thermoplastique |
US6361844B1 (en) | 1999-01-27 | 2002-03-26 | David T. Ou-Yang | Release article and adhesive article comprising the release article |
US6306518B1 (en) | 1999-05-19 | 2001-10-23 | Montell Technology Company Bv | High surface gloss, co-extruded sheets from propylene polymer materials |
US6489019B1 (en) | 1999-05-19 | 2002-12-03 | Basell Poliolefine Italia S.P.A. | High surface gloss, co-extruded sheets from olefin polymer materials |
US6465091B1 (en) | 2000-03-27 | 2002-10-15 | 3M Innovative Properties Company | Release article and adhesive article containing a polymeric release material |
WO2002061011A1 (fr) | 2001-01-29 | 2002-08-08 | Gluco Ltd | Adhesif |
US8957159B2 (en) | 2002-10-15 | 2015-02-17 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
EP2363444A1 (fr) * | 2006-06-15 | 2011-09-07 | Dow Global Technologies LLC | Interpolymères d'oléfine fonctionnalisés, compositions et articles préparés à partir de ceux-ci et procédé de fabrication associés |
WO2017040023A1 (fr) * | 2015-08-31 | 2017-03-09 | E. I. Du Pont De Nemours And Company | Compositions adhésives et structures multicouches comprenant un polypropylène fonctionnalisé |
CN107922706A (zh) * | 2015-08-31 | 2018-04-17 | 纳幕尔杜邦公司 | 包含官能化的聚丙烯的粘合剂组合物和多层结构 |
US10414139B2 (en) | 2015-08-31 | 2019-09-17 | E. I. Du Pont De Nemours And Company | Adhesive compositions and multilayered structures comprising functionalized polypropylene |
CN107922706B (zh) * | 2015-08-31 | 2021-09-14 | 性能材料北美股份有限公司 | 包含官能化的聚丙烯的粘合剂组合物和多层结构 |
Also Published As
Publication number | Publication date |
---|---|
EP0702710A1 (fr) | 1996-03-27 |
DE69507558D1 (de) | 1999-03-11 |
EP0702710B1 (fr) | 1999-01-27 |
AU1886495A (en) | 1995-09-25 |
ES2131309T3 (es) | 1999-07-16 |
DE69507558T2 (de) | 1999-06-24 |
GB9404708D0 (en) | 1994-04-27 |
CA2160345A1 (fr) | 1995-09-14 |
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