WO1995005158A1 - Preparations d'aerosols-mousses - Google Patents

Preparations d'aerosols-mousses Download PDF

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Publication number
WO1995005158A1
WO1995005158A1 PCT/EP1994/002647 EP9402647W WO9505158A1 WO 1995005158 A1 WO1995005158 A1 WO 1995005158A1 EP 9402647 W EP9402647 W EP 9402647W WO 9505158 A1 WO9505158 A1 WO 9505158A1
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WO
WIPO (PCT)
Prior art keywords
weight
water
alkyl
foam
glycoside
Prior art date
Application number
PCT/EP1994/002647
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German (de)
English (en)
Inventor
Kurt Seidel
Detlef Hollenberg
Anke Kaczich
Christian Priebe
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Publication of WO1995005158A1 publication Critical patent/WO1995005158A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/02—Shaving preparations

Definitions

  • the invention relates to aqueous cosmetic or pharmaceutical preparations and household products packed with an aerosol propellant in a pressure container with a foam valve.
  • Foam aerosol preparations have long been used in cosmetics and for the preparation of topical pharmaceutical preparations. They contain water, a foaming surfactant and an aerosol propellant as essential components. It is also already known to add strengthening and conditioning polymers to such foam aerosols for hair treatment.
  • alkylglycosides are much more suitable as surfactants for the production of foam aerosol preparations than most of the known anionic, cationic, zwitter ⁇ ionic, amphoteric or nonionic surfactants if they contain a dissolved polymer in the aqueous phase of the preparation is.
  • the present invention therefore relates to a foam aerosol preparation containing water, water-soluble surfactant and propellant gas, which as the surfactant is an alkyl glycoside of the formula I.
  • Rl is an alkyl group with 8 to 22 carbon atoms and the average degree of oligomerization x of the glycoside is 1 to 10 and which additionally contains a polymer dissolved in the aqueous phase.
  • the foam aerosol preparations according to the invention are distinguished by a particularly rich, fine-bubble to creamy and stable foam.
  • Alkyl glycosides their preparation and use as surface-active substances are known, for example, from DE 1943689 or from DE 3827 543. They are produced, for example, by reacting glucose or oligosaccharides with primary alcohols having 8 to 22 carbon atoms or by transacetalizing starch with, for example, lower alcohols and reactivating them again with the C ⁇ -C22 _F: et ' ta ⁇ ohol.
  • the glycoside residue both monoglycosides in which a cyclic sugar residue is glycosidically bound to the fatty alcohol and oligomeric glycosides with a degree of oligomerization of up to about 10 are suitable.
  • Preferred alkyl glycosides for the preparation of the preparations according to the invention are those of the general formula R 0 - [C5H10O5-I X - H, in which R * is an aliphatic radical of a primary fatty alcohol having 8 to 22 carbon atoms and
  • oligoglucoside radical with an average degree of oligomerization x from 1 to 10.
  • Rl is an aliphatic, linear alkyl radical having 10 to 16 carbon atoms
  • - [ C6H ⁇ o ⁇ 5] x -H means an oligoglucoside residue with an average degree of oligomerization x of 1 to 3.
  • the average degree of oligomerization results from the molar proportions of the individual oligomers by dividing the sum of the structural units by the sum of the molecules (cf. Principles of Polymer Chemistry, Paul J. Flory, Georgia University Press, Ithaca, New York 1953, pages 35-36).
  • Suitable water-soluble polymers can be natural substances, for example plant gums such as agar-agar, guar or soluble starch, biopolymers such as xanthan-gu or water-soluble derivatives of such natural products, such as carboxymethyl starch, hydroxyethyl cellulose, hydroxypropyl guar, water-soluble proteins and others.
  • synthetic nonionic polymers for example polyvinylpyrrolidone, polyvinyl alcohol, polyethylene oxides, polyacrylamides, anionic synthetic polymers such as, for example, the salts of the homo- and copolymers of acrylic acid and methacrylic acid, the copolymers of crotonic acid, maleic acid and the itaconic acid and its anhydrides, the poly sulfonic acids such as polyvinyl sulfonic acid and the poly styrene sulfonic acid.
  • the cationic polymers which contain amino groups in the polymer chain or bound to it or carry quaternary ammonium groups.
  • cationic polymers are, for example, cellulose ethers which have been modified with epoxypropyltrimethylmonium chloride and are commercially available under trade names such as Polymer JR. Analogously, cationically modified guar gums are available under the name Jaguar C 13 S or Cosmedia Guar C 261.
  • cationic polymers which can be used according to the invention are e.g. the copolymers of vinyl pyrrolidone and dialkylaminoalkyl acrylate (or methacrylate), which are available under the trade name Gafquat 734 or Gafquat 755.
  • Other cationic polymers are the poly-dimethyldiallylammonium chloride, which is commercially available under the name Merquat 100, or a copolymer of dimethyldiallylammonium chloride and acrylamide, which is commercially available under the name Merquat 550.
  • cationic polymers which are commercially available under the name Mirapol A 15 or poly- [N- (3-dimethylammonio) propyl] -N '- [3- (ethyleneoxyethylene dimethy lammonio) propyl -] - urea dichloride are.
  • the known zwitterionic polymers are also suitable, which are obtainable, for example, from polymers bearing amino groups by reaction with sodium chloroacetate, by copolymerization of anionic and cationic monomers or by polymerization of zwitterionic monomers. It is characteristic of the zwitterionic polymers that they carry more than one anionic group (for example carboxyl or sulfonic acid groups) and more than one cationic group (for example amino or quaternary ammonium groups) on the molecule. Mixtures of polymers of different structure and ionogenicity can also be used. According to the invention The polymers used must be dissolved in the aqueous phase, ie their water solubility should be at least 0.01% by weight at normal temperature (20 ° C.).
  • All gases known for this purpose can be used as the friction gases, that is to say both the gases which are partially soluble in the aqueous phase under pressure, such as nitrogen oxide (N2O), carbon dioxide, nitrogen and air, and the gases which are liquid under pressure, such as propane, butane and isobutane , Pentane and dimethyl ether.
  • the fluorine-chlorohydrocarbons (Frigen ( R )) liquefied under pressure are also suitable, but their use is not preferred for ecological reasons.
  • Liquefied gases from the group propane, butane, isobutane, pentane and dimethyl ether and mixtures thereof are preferably used as propellant gases.
  • the components required for foam generation are preferably used in amounts of
  • preparations according to the invention contain the components required for cosmetic or dermatological or other components for the desired effect. Depending on the type of application, these can be very different:
  • Anionic surfactants and / or ampho- or betaine surfactants are also used to produce cleaning preparations, for example skin cleaners and shampoo aerosols.
  • Suitable as anionic surfactants for example, A 'lkyl- (Ci2-Ci6) -polyglycolether-sulfate salts having 1 to 10 glycol ether groups, alkane sulfonates containing 12 to 15 carbon atoms, alpha olefin sulfonates, sulfosuccinic acid mono- (alkyl polyglycol ethers) di sodium salts, Acyl taurides, acyl sarcosinates or acyl isethionates, each with 12 to 16 carbon atoms in the alkyl or acyl group.
  • Suitable betaine surfactants are for example N-Ci2 "Ci8- a lkyl dimethyl betaine (Ci2-CI8-acylamido-pro ⁇ yl-dimethylammonio-acetic acid, suitable A - photenside are for example the N-Ci2-C ⁇ g-alkylaminopropionic oc * er ie N-Ci2 -Ci8-al! Yl-hydroxy-ethyl-amino-acetic acid.
  • cationic surfactants e.g. Cetyl-trimethyl-ammonium chloride, lauryl-dimethyl-benzyl-ammonium chloride, cetyl-pyridinium chloride, distearyl-dimethyl-ammonium chloride or di- (stearyloxyethyl) -oxy-ethyl-methyl-ammonium methosulfate and stearamidopropyl-dimethylamine ( Tego Amid S18).
  • Cationic or zwitterionic water-soluble polymers are preferably used as polymers in such preparations.
  • Foam hair fixatives contain an increased proportion of setting polymers. Foam tinting agents are additionally provided with hair dyes.
  • Suitable oil components are, above all, liquid paraffin oils, vegetable oils, fatty acid esters of monohydric alcohols, fatty alcohols with 16 to 22 carbon atoms, branched alcohols such as 2-0ctyl-dodecanol, synthetic triglycerides of CO-C 1- fatty acids, squalane and silicone oils.
  • Suitable emulsifiers for the stable emulsification of such oil components in the aqueous phase are, in particular, fatty alcohol polyglycol ethers, fatty acid polyglycol esters, castor oil oxethylates, fatty acid sorbitan esters, fatty acid partial glycerides, alkyl Ci2-Ci8 glycosides, methyl glucoside fatty acid esters and their oxethylates as well as polyglyceryl methyl glucose distearate (TEGO-Care 450, Goldschmidt).
  • Cosmetic oils or fat components are also used to manufacture sunscreen foam aerosols.
  • UV radiation protection agents e.g. tocopherol
  • skin moisturizers e.g. Na lactate or Na glycolate
  • deodorising agents e.g. Triethyl citrate, triacetin or known antimicrobial substances are used.
  • the known disinfectant active ingredients e.g. Iodophores, ethanol, isopropanol, hydrogen peroxide or aldehydes are used.
  • AntiperSpiranten in the form of foam aerosols according to the invention contain aluminum chlorohydrate, aluminum zirconium chlorohydrate or other known antiperspirant components.
  • Household cleaners can also be packaged as foam aerosol preparations. This applies in particular to glass and tile cleaners, to carpet and upholstery cleaners, oven cleaners and metal care products. All of these preparations can be formulated very advantageously with the foam aerosol carrier system according to the invention.
  • the surfactants, alkalis, complexing agents, care waxes and auxiliaries customary for such preparations are added.
  • the foam aerosol preparations according to the invention are produced by dissolving the water-soluble polymers in water and adding the other water-soluble components.
  • the heated oil phase which contains all the oil-soluble components and emulsifiers, is incorporated into the heated water phase at a temperature at which the oil phase is present as a homogeneous melt, and then cooled to normal temperature.
  • This incorporation can be carried out using the usual mixing and emulsifying devices and homogenizers.
  • the foam aerosol preparations are preferably prepared in such a way that the propellant gas or the liquefied aerosol propellant is added under pressure in a filling station provided for this purpose to the aqueous phase presented in a pressure pack (aerosol can). The pressure packaging is then closed with a foam vent.
  • the percentages relate to the active ingredient content of the commercial products.
  • Plantaren 1200 (25) 0.50% by weight
  • Copolymer 937 (19) 0.40% by weight
  • Plantaren 1200 (25) 1.20% by weight
  • Luviskol K 30 (1) 0.50% by weight *
  • Luviskol K 30 (1) 0.50% by weight *
  • Plantaren 1200 (25) 1.0% by weight * Celquat L 200 (14) 0.6% by weight * Antaron V 220 (4) 0.2% by weight * Drivosol 35 (47) 7.0% by weight * Water ad 100.0
  • Vitamin E TPGS (45) 0.30% by weight * Plantaren 1200 (25) 0.60% by weight * Luviskol K 90 (2) 4.00% by weight * Celquat L 200 (14) 0.50% by weight * Drivosol 12 (48) 8.50 wt. * Water ad 100.00
  • Plantaren 1200 (25) 0.90% by weight *
  • Drivosol 27 (50) 4.70% by weight water ad 100.00
  • Drivosol 27 (50) 9.60% by weight water ad 100.00 5. Tint foam
  • Texapon N 25 (35) 3.40% by weight * Lorol techn. (38) 1.25% by weight * Stenol 1618 (39) 3.25% by weight * direct hair dye 3.50% by weight * Plantaren 1200 (25) 1.20% by weight * Luviquat HM 552 (11) 0 , 20% by weight * Drivosol 32 (50) 10.00% by weight * water ad 100.00
  • Luviskol K 30 (BASF): Po1yviny1pyrro1idon
  • Luviskol VA 64 (BASF): vinyl pyrrolidone-vinyl acetate copolymer (60:40)
  • Antaron V 220 (GAF): vinyl pyrrolidone / 1-eicose copolymer
  • Benecel MP 943 (Aqualon): methyl hydroxypropyl cellulose
  • Luviquat FC 550 (BASF): vinyl imidazolinium methochloride / vinyl pyrrole idone (50:50) copolymer
  • Luviquat FC 905 (BASF): vinylimidazolinium methochloride / vinyl pyrrole idone (95: 5) copoly erisate
  • Luviquat HM 552 (BASF): vinylimidazolinium methochloride / vinyl pyrrole idone (50:50) copolymer
  • Gafquat HS 100 (ISP): vinylpyrrolidone / methacrylamido-propyl-trimethylammonium chloride copolymer (polyquaterium 28)
  • Quatrisoft LM 200 alkyl hydroxyethyl cellulose
  • Celquat L 200 hydroxyethyl cellulose + di- (Delft-Chemie) allyl-dimethylammonium chloride polymer (Polyquaternium 4)
  • Polymer JR 400 hydroxyethyl cellulose, quater ⁇ (Union Carbide) niert (Polyquaternium 10)
  • Merquat 550 Dimethy1-dially1-ammonium chloride (Merck & Co.) rid / acrylamide copolymer (Polyquaternium 7)
  • Copolymer 937 (ISP): vinyl pyrrolidone-dimethylaminoethyl methacrylate copolymer
  • Shellac MHP 101 natural resin (acid number 65 - 80 (MHP Shellac GmbH) saponification number 190 - 230, melting range 65 - 85 ° C)
  • Plantaren 1200 Ci2-Ci6-alkyl- (1,4) -glucoside (Henkel KGaA)
  • Eumulgin B 1 Ci6-C-.8 fatty alcohol poly (12 (Henkel KGaA) E0) glycol ether
  • Tegoamid S 18 Stearamidopropy1-dimethy1amin (Goldschmidt) (32) Rewoquat WE 18: di- (tallow carboxylethyl) hydroxy (REWO) ethyl methyl ammonium methosulfate
  • Dehyton G N-coconut amidoethyl hydroxyethyl (Henkel KGaA) carboxy ethyl glycinate, Na salt
  • Stenol 1618 (Henkel KGaA): cetyl stearyl alcohol
  • Myritol 318 (Henkel KGaA): caprylic / capric acid triglyceride
  • Vitamin E-TPGS tocopheryl polyethylene glycol (Eastman Kodak) 1000 succinate
  • Drivosol 35 (Hüls AG) propane / isobutane / butane / DME (24: 72: 3: 1)
  • Drivosol 12 (Hüls AG): butane / dimethyl ether (99: 1)
  • Drivosol 42 (Hüls AG) isobutane / propane / butane / DME (60: 37: 2: 1)
  • Drivosol 27 (Hüls AG) isobutane / propane / butane / DME (84: 11: 4: 1

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Des aérosols-mousses contenant de l'eau, un agent tensioactif soluble dans l'eau et un gaz propulseur présentant une consistance et une onctuosité particulièment bonne de la mousse produite, grâce au fait qu'ils renferment comme agent tensioactif, un alkyl(oligo)glucoside de formule R1O - [C¿6?H10O5]x - H, dans laquelle R?1¿ représente un groupe alkyle de 8 à 22 atomes de carbone, le degré moyen d'oligomérisation x du glucoside étant de 1 à 10, et un polymère dissous dans la phase aqueuse.
PCT/EP1994/002647 1993-08-19 1994-08-10 Preparations d'aerosols-mousses WO1995005158A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4327699.7 1993-08-19
DE4327699A DE4327699A1 (de) 1993-08-19 1993-08-19 Schaumaerosol-Zubereitungen

Publications (1)

Publication Number Publication Date
WO1995005158A1 true WO1995005158A1 (fr) 1995-02-23

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DE (1) DE4327699A1 (fr)
WO (1) WO1995005158A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon
US6589518B2 (en) 1999-04-27 2003-07-08 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mousse forming hair treatment composition
US6627585B1 (en) 1999-06-15 2003-09-30 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mousse-forming shampoo compositions
US7300912B2 (en) 2005-08-10 2007-11-27 Fiore Robert A Foaming cleansing preparation and system comprising coated acid and base particles
EP1156774B2 (fr) † 1999-02-23 2009-10-21 Henkel AG & Co. KGaA Preparations destinees au traitement de fibres keratiniques

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4405127A1 (de) * 1994-02-18 1995-08-31 Henkel Kgaa Haarbehandlungsmittel
GB9515023D0 (en) * 1995-07-21 1995-09-20 Cussons Int Ltd Cleaning composition
FR2745496B1 (fr) † 1996-03-01 1998-04-30 Oreal Dispositif pressurise transparent a composition moussante comprenant des tensioactifs non-ioniques et amphoteres
US5858343A (en) * 1997-01-31 1999-01-12 S. C. Johnson & Son, Inc. Post-foaming shaving gel including poly(ethylene oxide) and polyvinylpyrrolidone in a preferred range of weight ratios
US6277365B1 (en) * 1997-09-18 2001-08-21 Bausch & Lomb Incorporated Ophthalmic composition including a cationic glycoside and an anionic therapeutic agent
DE19828643A1 (de) * 1998-06-26 1999-12-30 Wella Ag Einphasiges, schaumförmiges Haarbehandlungsmittel zur Erzielung eines Pomadeneffektes
DE19841339A1 (de) * 1998-09-10 2000-03-23 Goldwell Gmbh Aerosol-Haarwaschmittel
DE10057925A1 (de) * 2000-11-22 2002-05-23 Beiersdorf Ag Kosmetische Zubereitungen für die Rasur mittels eines Rasiergerätes
DE10227868A1 (de) * 2002-06-22 2004-01-08 Beiersdorf Ag Cremiger Haarfestiger
US8114855B2 (en) 2006-11-22 2012-02-14 L'oreal Low density cosmetic formulations, cosmetic products containing the same and methods of treating hair, nails and/or skin using the same
DE102010028420A1 (de) 2010-04-30 2011-11-03 Henkel Ag & Co. Kgaa Deo-Schäume
DE102010055817A1 (de) * 2010-12-23 2012-06-28 Henkel Ag & Co. Kgaa Treibmittelhaltige verschäumbare kosmetische Zusammensetzung zur Haut- und Körperpflege
DE102010055816A1 (de) * 2010-12-23 2012-06-28 Henkel Ag & Co. Kgaa Deodorant- und Antitranspirant-Zusammensetzungen Zusammensetzungen zur Verhinderung von Körpergeruch

Citations (5)

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Publication number Priority date Publication date Assignee Title
EP0357484A2 (fr) * 1988-08-25 1990-03-07 L'oreal Composition pour induire et stimuler la croissance des cheveux et/ou freiner leur chute, à base d'alkyl-polyglycoside et d'un dérivé de pyrimidine
JPH03131680A (ja) * 1989-10-17 1991-06-05 Kao Corp 発泡組成物
WO1993021897A1 (fr) * 1992-04-24 1993-11-11 Henkel Kommandtigesellschaft Auf Aktien Procede pour permanenter les cheveux
DE4229922A1 (de) * 1992-09-08 1994-03-10 Kao Corp Gmbh Mittel zur Konditionierung von menschlichen Haaren
WO1994007458A1 (fr) * 1992-09-29 1994-04-14 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'un shampoing/apres-shampoing

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0357484A2 (fr) * 1988-08-25 1990-03-07 L'oreal Composition pour induire et stimuler la croissance des cheveux et/ou freiner leur chute, à base d'alkyl-polyglycoside et d'un dérivé de pyrimidine
JPH03131680A (ja) * 1989-10-17 1991-06-05 Kao Corp 発泡組成物
WO1993021897A1 (fr) * 1992-04-24 1993-11-11 Henkel Kommandtigesellschaft Auf Aktien Procede pour permanenter les cheveux
DE4229922A1 (de) * 1992-09-08 1994-03-10 Kao Corp Gmbh Mittel zur Konditionierung von menschlichen Haaren
WO1994007458A1 (fr) * 1992-09-29 1994-04-14 Henkel Kommanditgesellschaft Auf Aktien Combinaison d'un shampoing/apres-shampoing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 9129, Derwent World Patents Index; AN 91-210738 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6555100B1 (en) 1997-12-31 2003-04-29 L'ORéAL S.A. Compositions for treating keratinous materials containing a combination of a zwitterion polymer and a water insoluble non-volatile silicon
EP1156774B2 (fr) † 1999-02-23 2009-10-21 Henkel AG & Co. KGaA Preparations destinees au traitement de fibres keratiniques
US6589518B2 (en) 1999-04-27 2003-07-08 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mousse forming hair treatment composition
US6627585B1 (en) 1999-06-15 2003-09-30 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mousse-forming shampoo compositions
US7300912B2 (en) 2005-08-10 2007-11-27 Fiore Robert A Foaming cleansing preparation and system comprising coated acid and base particles

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DE4327699A1 (de) 1995-02-23

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