WO1994017783A2 - Composition nettoyante - Google Patents

Composition nettoyante Download PDF

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Publication number
WO1994017783A2
WO1994017783A2 PCT/EP1994/000278 EP9400278W WO9417783A2 WO 1994017783 A2 WO1994017783 A2 WO 1994017783A2 EP 9400278 W EP9400278 W EP 9400278W WO 9417783 A2 WO9417783 A2 WO 9417783A2
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WO
WIPO (PCT)
Prior art keywords
group
acyl
alkyl
integer
following structure
Prior art date
Application number
PCT/EP1994/000278
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English (en)
Other versions
WO1994017783A3 (fr
Inventor
Paul Anthony Bowser
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to AU60007/94A priority Critical patent/AU6000794A/en
Publication of WO1994017783A2 publication Critical patent/WO1994017783A2/fr
Publication of WO1994017783A3 publication Critical patent/WO1994017783A3/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the invention relates to cleansing compositions.
  • the invention is concerned with very mild and high foaming cleansing compositions suitable for cleansing the skin and hair.
  • anionic surfactants in cleansing compositions are alkyl sulphates, polyoxyethylene alkyl sulphates and alkyl benzene sulphonates. These compounds are known to have a good foaming and deterging power. Due to their harshness, however, they are not desirable as components for cleansing compositions topically applied to human skin and hair. Their damaging effect particularly where young, tender or damaged skin is involved, has been the subject of intense study for many years.
  • US-A-3,728,447 discloses hair shampoo compositions containing fatty acid lactylates or glycolates. While the cleaning action of shampoos based on the fatty acid glycolates is satisfactory, the foam is minimal. In order to achieve higher foaming action it is described to include harsh detergents such as sodium lauryl sulphate or triethanolamine lauryl sulphate. When the glycolates are used in conjunction with such a booster, detergent the quantity of the glycolates present in the composition is reduced down to about 1 to 2% by weight.
  • compositions in particular for cleansing human skin or hair, with the added attribute that full lather is produced, have unexpectedly discovered that a narrow range of acyl glycolates in combination with specific co- surfactants provide the desired effects when used in particular amounts.
  • the compositions so obtained are capable of producing a superior lather and accordingly have great consumer appeal. Also, the compositions are so mild that they can safely be used for cleansing the skin and the hair and other more delicate skin areas.
  • the invention provides a cleansing composition which comprises, in addition to water,
  • R ] CO represents a C 6 to C 16 acyl radical
  • a is an integer from 1 to 3
  • M 1 represents hydrogen or a counterion chosen from alkali metal, ammonium or a substituted ammonium group having one or more Cj to C 3 alkyl or hydroxy alkyl group(s) ;
  • R 2 CO represents a C 10 to C 18 acyl group
  • M 2 is as M 1 in structure (1) ;
  • R 3 C0 represents a C 10 to C 18 acyl group
  • M 3 is as M 1 in structure (1) ;
  • R 4 represents a C 10 to C ⁇ 8 alkyl group
  • M 4 is as M 1 in structure (1)
  • (b) is an integer from 1 to 3;
  • R 5 CO represents a C 10 to C 18 acyl group
  • M 5 is as M 1 in structure (1)
  • c is an integer from 1 to 10;
  • R 6 CO represents a C 10 to C 18 acyl group
  • M 6 is as M 1 in structure (1)
  • d is an integer from 1 to 4;
  • Z 7 is chosen from the following groups (i) to (i ⁇ ):
  • R a C0 - NH - (CH,CH,0) e - where R a CO represents a C 10 to C 18 acyl group; and e is an integer from 1 to 10;
  • R b O - (CH,CH 2 0) f -, where R b represents a C 10 to C 18 alkyl group; and f is an integer from l to 10;
  • X 7 and Y 7 are independently from each other chosen from the counterions represented by M 1 in structure (1) ;
  • R 8 represents a C 10 to C ]8 alkyl group
  • M 83 and M 85 are independently from each other chosen from the group of species represented by M 1 in structure (1)
  • g is an integer from 0 to 3;
  • R 9 represents a C 10 to C 18 alkyl group
  • M 9 is as M 1 in structure (1)
  • h is an integer from 1 to 10;
  • R 10 CO represents a C 10 to C 18 acyl group
  • Z 10 represents H or C, to C, alkyl
  • Y 10 represents H, C, to C 3 alkyl or Cj to C 3 alkyl substituted with a COOH group
  • M 10 is chosen from the counterions represented by M 1 in structure ( 1) ;
  • R 11 represents a C 10 to C ]4 alkyl group
  • n is an integer f om 1 to 3;
  • R 12 represents a C 8 to C 18 alkyl group
  • Z 12 is a C 2 or C 3 alkylene group
  • p is an integer from 1 to 10;
  • Z 14 represents a C w to C 18 alkyl group or a C ⁇ 0 to C x8 acyl amido group
  • R 15 CO represents a C l0 to C 18 acyl group
  • Z 15 and Y 15 are independently from each other chosen from H, CH 2 CH,OH or (CH 2 ) r COO "
  • r is 1 or 2
  • M 15 is as M 1 in structure (1) ;
  • composition according to the invention has a foam height of more than 130mm, as measured by the foam height test described herein.
  • composition according to the invention comprises from 10 to 35% by weight of one or more acyl glycolate(s) of the following structure (1)
  • R ⁇ O represents a C 6 to C 16 acyl radical
  • a is an integer from 1 to 3
  • M 1 represents hydrogen or a counterion chosen from alkali metal, ammonium or substituted ammonium group having one or more Cj to C 3 alkyl or hydroxy alkyl group(s) .
  • acyl glycolates having the above structure (1) include:
  • Triethanolammonium dodecanoyl monoglycolate Ammonium decanoyl monoglycolate
  • Triethanolammonium decanoyl monoglycolate Triethanolammonium decanoyl monoglycolate.
  • the preferred acyl group RC0 is a C 10 to C 14 acyl group.
  • Preferred examples for M 1 include sodium, potassium, ammonium and triethanolammonium.
  • the amount of the acyl glycolate present in the composition according to the invention is preferably from 15 to 30%, most preferred from 20 to 30% by weight of the composition.
  • composition according to the invention further comprises one or more co-surfactant(s) in an amount from 5 to 25% by weight of the composition.
  • the co-surfactant is chosen from the compounds (A) to (0) described hereinafter.
  • the preferred amount of the co-surfactant present in the composition is from 10 to 25% by weight.
  • co-surfactants useful in the present invention are not only very mild but also result in high foaming compositions when combined with the acyl glycolate in the specified amounts.
  • the following compounds are suitable as co-surfactant in the cleansing composition according to the invention.
  • R 2 C0 represents a C, 0 to C ]8 acyl group
  • M 2 is as M 1 in structure (1) .
  • Preferred examples for taurates having the structure (2) include:
  • R 3 C0 represents a Cj 0 to C 18 acyl group
  • M 3 is as M 1 in structure (1) .
  • the preferred example for an Acylisethionate having the structure (3) is sodium cocoyl isethionate, eg. available as Fenopon AC 78 from Rhone Poulenc.
  • R 4 represents a C 10 to C 18 alkyl group
  • M 4 is as M 1 in structure (1)
  • (b) is an integer from 1 to 3.
  • Alkylester of a ⁇ - sulphonated carboxylic acid having the structure (4) is sodium lauryl sulphoacetate, eg. available as Lathanol LAL from Stepan or as Nikkol LSA and Nikkol Chemicals.
  • R 5 C0 represents a C 10 to C 18 acyl group
  • M 5 is as M 1 in structure (1)
  • c is an integer from 1 to 10.
  • a sulphate having the structure (5) is sodium cocoyl amide EO-3 sulphate, eg. available as Sunamide C-3 from Nippon Oils & Fats.
  • R 6 CO represents a C 10 to C 18 acyl group
  • M 6 is as M 1 in structure (1)
  • d is an integer from 1 to 4;
  • a preferred example for a fatty acyl poly(glyceride) sulphate having the structure (6) is sodium cocoyl monoglyceride sulphate, available from Jan Dekker International.
  • Z 7 is chosen from the following groups (i) to (i ⁇ ):
  • R a CO - NH - (CH,CH,0) c - where R a CO represents a C 10 to C 18 acyl group; and e is an integer from l to 10;
  • X 7 and Y 7 are independently from each other chosen from the counterions represented by M 1 in structure (1) .
  • Preferred examples for mono substituted sulphosuccinates represented by the structures (7a) and (7b) include:
  • Disodium lauryl (PEG) -2 sulphosuccinate a mixture of Disodium lauryl (PEG) -2 sulphosuccinate and Disodium myristyl (PEG) -2 sulphosuccinate, eg. available as Beaulight ESS from Sanyo Chemicals, -Disodium lauryl (PEG) -2 to 3 sulphosuccinate, eg. available as Rewopol SBFA 30 from Rewo, and
  • the short form (E0)-2 to 3 denotes that, as an averaage value, 2 to 3 oxyethylene groups are present per molecule sulphosuccinate.
  • the short form (PEG) -2 to 3 stands for the presence of a polyethylene glycol group derived from, as an average value, 2 to 3 ethylene glycol molecules per molecule sulphosuccinate.
  • R 8 represents a C 10 to C 18 alkyl group
  • M 83 and M 8b are independently from each other chosen from the group of species represented by M 1 in structure (1)
  • g is an integer from 0 to 3.
  • Preferred examples for Mono substituted phosphates having the structure (8) include:
  • E0 Monosodium monolauryl (E0)-1 phosphate, eg. available as Phosten HLP-1 from Nikkol Chemicals, and
  • R 9 represents a C ⁇ 0 to C 18 alkyl group
  • M 9 is as M 1 in structure (1)
  • h is an integer from 1 to 10.
  • Alkyl (PEG) acetates having the structure (9) include, Sodium Cocoyl PEG-10 acetate, eg. available as Marlinat CM 105 from Huls, and Sodium tridecyl
  • R 10 CO N CH OM 10 QD where R>1 ⁇ 0 ⁇ ,CO represents a C 10 to C 18 acyl group; Z10 represents H or C j to C, alkyl; Y 10 represents H, Cj to C 3 alkyl or C j to C 3 alkyl substituted with a COOH group; and M 10 is chosen from the counteriouns represented by M 1 in structure (1) .
  • Preferred examples for salts of N-acyl ⁇ -amino acids having the structure (10) include:
  • Triethanolammonium N-cocoyl sarcosinate eg. available as Firet KT from Nippon Oil and Fats,
  • R 11 represents a C, 0 to C, 4 alkyl group; and n is an integer from 1 to 3.
  • R 12 represents a C 8 to C 18 alkyl group
  • Z 12 is a C 2 or C 3 alkylene group
  • p is an integer from 1 to 10.
  • Preferred examples for a poly(oxyalkylene)-fatty alkyl ether having the structure (12) are (PEG)-6 lauryl ether and (PEG)-6 myristyl ether.
  • a mixture of (PEG)-6 C 12 -C 15 is available as Dobanol 91-6 from Shell Chemicals.
  • N-substituted Betaines having the structure (13) include:
  • Lauryl dimethyl betaine eg. available as Empigen BB from Albright & Wilson, and
  • Cocoamidopropyl betaine eg. available as
  • Z 14 represents a C ]0 to C 18 alkyl group or a C 10 to C 18 acyl amido group.
  • a preferred example for a Sultaine having the structure (14) is Cocoamidopropyl hydroxysultaine, eg. available as Cycloteric BET-CS from Alcolac.
  • R 15 CO represents a C J0 to C 18 acyl group
  • Z 15 and Y 15 are independently from each other chosen from H, CH 2 CH 2 OH or (CH 2 ) r COO " ; r is 1 or 2; and M 15 is as M 1 in structure (1).
  • Alkylamphocarboxylates having the structure (15) include:
  • Cocoamphoglycinate eg. available from GAF, Wheatgerm amphodiglycinate, Cocamphodipropionate, eg. available as Mirataine C2MS from Rhone Poulenc,
  • Caprylamphodipropionate eg. available as Miranol S2MSF from Rhone Poulenc
  • - Cocoamphoacetate eg. available as Nissan Anon
  • the cleansing composition according to the invention also comprises water.
  • the water will normally be present in an amount of up to 85%, preferably from 10 to 85% by weight of the composition.
  • the cleansing composition according to the invention can also comprise optional ingredients to modify the physical or chemical characteristics of the composition, eg. product form, foaming properties, pH-value or shelf life.
  • ingredients which can be included in the compositions according to the invention are:
  • Emollients such as:
  • a group of preferred emollients are poly (oxyalkylene) glycerides mono-substituted with a C ⁇ 0 to C 18 alkyl group and having up to 20 C 2 to C 3 oxyalkylene moieties per molecule of the glyceride, as an average value.
  • Especially preferred emollients are Polyoxyalkylene methyl glucosides having, as an average value, up to 20 C 2 - C 3 oxyalkylene moieties per molecule glucoside. These emollients are very beneficial as they impart a soft feeling to the skin and support the ability of the skin to retain moisture. Examples for such Polyoxyalkylene methyl glucosides are available as Glucam E-20 and Glucam P10, respectively, from Amerchol.
  • Humectants such as glycerine, sorbitol, sodium 2- pyrrolidone-5-carboxylate, soluble collagen, gelatine, ethoxylated (E0)-20 methyl glucoside, and propoxylated (E0)-10 methyl glucoside.
  • Preservatives such as ethanol, benzoic acid, sodium benzoate, sorbic acid, alkali metal halides;
  • PH controlling agents such as Sodium hydroxide
  • Citric acid Triethanolamine, Potassium hydroxide, Amino Sorbitol.
  • the pH controlling agents are preferably present in an amount sufficient to adjust the composition to a pH value in the range of 5.5 to 8.5.
  • Propellants such as fluorochloro hydrocarbons, propane, butane, isobutane, dimethyl ether, carbon dioxide, nitrous oxide;
  • Foam modifying agents such as cationic polymers, especially quaternised ammonium hydroxy ethyl cellulose polymers, eg. available as polyquaternium-24 or polyquaternium-10. These polymers make the foam creamier and richer.
  • composition according to the invention can also contain other optional agents, that is ingredients other than the main ingredients already defined which are conventionally employed in cleansing compositions, such as thickeners.
  • the cleansing composition according to the invention is primarily intended as a personal washing product for cleansing the face. It can also be used for washing the hair as well as the whole body.
  • the composition according to the invention is preferably used as facial cleanser, facial wash foam, hair shampoo, body shampoo, bath foam or shaving cream. Due to the high detergency provided by the composition it is also possible to use it in non-cosmetic applications, such as a household cleanser, carpet cleanser or detergent for tableware.
  • the following procedure is an example for the use of the cleansing composition according to the invention; a small quantity, for example from 1 to 5ml, of the composition is either rubbed between the hands, together with water together to form a foam which is then used for washing or applied via a sponge to the area to be cleansed, or the foam is generated directly on that area. The foam is subsequently rinsed away with clean water.
  • the cleansing composition according to the invention can take the form of a liquid or gel, intended to be dispensed from a capped container such as a bottle, roll-on applicator or tube, or a pump-operated or propellant-driven aerosol dispenser.
  • the composition can also take the form of a solid, such as a stick or a bar or tablet intended to be used for washing instead of a conventional soap bar. Foaming Properties of the Composition
  • composition according to the invention does not include harsh surfactants, as are found in conventional cleansing compositions, its foaming power is excellent.
  • the test-method which can be used to assess the foaming power of the cleansing compositions according to the invention is the ASTM D 1173-53 test, also referred to as Ross-Miles test, and described in J Ross and G D Miles, American Society for Testing Materials, 1953, pages 644- 646.
  • the test is carried out at a temperature of 20°C by using an aqueous test solution of 0.3% by weight acyl glycolate and 0.1% by weight co-surfactant. This is a realistic concentration of the cleansing composition according to the invention when used by the consumer, eg. when topically applied on the face or body together with water to generate the desired foam.
  • the pH value of the test solution has been adjusted to a pH of 7.5 by addition of aqueous sodium hydroxide solution.
  • the cleaning composition according to the invention conveniently has a foam height of more than 130mm, as measured by the foam height test carried out under the conditions described above.
  • compositions according to the invention have a foam height of more than 150mm, more preferably more than 170mm and most preferably more than 190mm.
  • Methyl gluceth-20 (Humectant/Emollient) 3, .00
  • Polyquaternium 10 (Foam modifier) 0, .40
  • Polyquaternium 24 (Thickener, Foam Modifier) 0.40
  • Citric acid to pH 6. 0-6. .5
  • Citric acid to pH 7. 0-7. .3
  • Example 11 Body Shampoo wt %
  • Citric acid to pH 7.0-7.5
  • Example 12 Mild Body Shampoo wt %
  • Triethanolammonium myristoyl monoglycolate 7.50 Disodium lauryl (PEG) -2.5 sulphosuccinate 10.00 Cocoamidoproyl betaine 5.00
  • Citric acid to pH 7.0-7.5
  • Example 15 Bath Foam Concentrate wt Lauroyl monoglycolic acid 15.00
  • Example 17 Conditioning Bubble Bath wt Triethanolammonium decanoyl monoglycolate 20.00 Cocoamphodiacetate 5.00
  • Example 21 Facial wash foam wt %
  • Polyquaternium 10 0.40 Sodium hydroxide solution to pH 6.8-7.0
  • Example 22 Facial wash foam wt Sodium lauroyl glycolate 14 , . 00

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention se rapporte à une composition nettoyante qui comprend, outre de l'eau, (a) de 10 à 30 % en poids d'un ou plusieurs glycolates d'acyle C6 à C16 et (b) de 5 à 25 % en poids d'un ou plusieurs agents co-tensioactifs, tels que des iséthionates, des sarcosinates, des sulfosuccinates et des taurates d'acyle. Ces compositions nettoyantes sont principalement destinées à être utilisées comme produits d'hygiène personnelle tels que des mousses nettoyantes pour le visage, des mousses pour le bain et des shampoings.
PCT/EP1994/000278 1993-02-03 1994-01-29 Composition nettoyante WO1994017783A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU60007/94A AU6000794A (en) 1993-02-03 1994-01-29 Cleansing composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9302130.1 1993-02-03
GB939302130A GB9302130D0 (en) 1993-02-03 1993-02-03 Cleasing composition

Publications (2)

Publication Number Publication Date
WO1994017783A2 true WO1994017783A2 (fr) 1994-08-18
WO1994017783A3 WO1994017783A3 (fr) 1994-10-13

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Country Status (3)

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AU (1) AU6000794A (fr)
GB (1) GB9302130D0 (fr)
WO (1) WO1994017783A2 (fr)

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998020854A1 (fr) * 1996-11-12 1998-05-22 S.C. Johnson & Son, Inc. Compositions dermatologiques moussantes
DE19828643A1 (de) * 1998-06-26 1999-12-30 Wella Ag Einphasiges, schaumförmiges Haarbehandlungsmittel zur Erzielung eines Pomadeneffektes
WO2000007564A1 (fr) * 1998-08-04 2000-02-17 Johnson & Johnson Gmbh Preparation a base d'huile moussante et son utilisation
DE19841339A1 (de) * 1998-09-10 2000-03-23 Goldwell Gmbh Aerosol-Haarwaschmittel
FR2789573A1 (fr) * 1999-02-16 2000-08-18 Oreal Compositions cosmetiques detergentes contenant un tensioactif hydroxyalkylether anionique et une silicone et leurs utilisations
US6183732B1 (en) 1997-03-06 2001-02-06 Johnson & Johnson Consumer Companies Chemical composition
WO2001078664A1 (fr) * 2000-04-12 2001-10-25 Aveda Corporation Shampooing colorant
EP1172096A1 (fr) * 2000-07-12 2002-01-16 L'oreal Composition de nettoyage moussante sous la forme d'un gel transparent
US6368584B1 (en) 2000-02-15 2002-04-09 L'oreal S.A. Detergent cosmetic compositions comprising an anionic hydroxyalkyl ether surfactant and a silicone, and their uses
DE10221813A1 (de) * 2002-05-16 2003-11-27 Beiersdorf Ag Stark schäumendes Reinigungsgel
DE10327433A1 (de) * 2003-06-18 2005-01-05 Beiersdorf Ag Durch den Anwender bedarfsgerecht aufschäum- und carbonisierbares Hautpflegeprodukt
WO2013091999A2 (fr) * 2011-12-19 2013-06-27 Henkel Ag & Co. Kgaa Agent cosmétique pour la mise en forme temporaire de fibres kératiniques
US9622951B2 (en) 2012-10-29 2017-04-18 The Procter & Gamble Company Personal care compositions
US9889080B2 (en) 2015-05-07 2018-02-13 Celeb LLC Color depositing shampoo
US10865178B2 (en) * 2016-09-30 2020-12-15 Daikin Industries, Ltd. Carboxylate salt or sulfonate salt, and surfactant
US20210353518A1 (en) * 2020-05-15 2021-11-18 The Procter & Gamble Company Shampoo composition
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11904036B2 (en) 2017-10-10 2024-02-20 The Procter & Gamble Company Sulfate free clear personal cleansing composition comprising low inorganic salt
US11980679B2 (en) 2019-12-06 2024-05-14 The Procter & Gamble Company Sulfate free composition with enhanced deposition of scalp active
US11986543B2 (en) 2021-06-01 2024-05-21 The Procter & Gamble Company Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants

Citations (6)

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Publication number Priority date Publication date Assignee Title
US3728447A (en) * 1970-03-03 1973-04-17 Patterson Co C Fatty acid lactylates and glycolates for conditioning hair
US4301820A (en) * 1980-02-04 1981-11-24 Redken Laboratories, Inc. Permanent waving compositions containing fatty acid lactylates and glycolates and their method of use
EP0224796A2 (fr) * 1985-11-28 1987-06-10 Kao Corporation Composition détergente
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US5976520A (en) * 1996-11-12 1999-11-02 S. C. Johnson & Son, Inc. Foamable skin preparations
WO1998020854A1 (fr) * 1996-11-12 1998-05-22 S.C. Johnson & Son, Inc. Compositions dermatologiques moussantes
CN1098065C (zh) * 1997-03-06 2003-01-08 庄臣及庄臣有限公司 化学组合物
US6183732B1 (en) 1997-03-06 2001-02-06 Johnson & Johnson Consumer Companies Chemical composition
US6497866B2 (en) * 1998-06-26 2002-12-24 Wella Aktiengesellschaft Method for producing a pomade effect based on a single-phase, foam-forming hair treatment composition
DE19828643A1 (de) * 1998-06-26 1999-12-30 Wella Ag Einphasiges, schaumförmiges Haarbehandlungsmittel zur Erzielung eines Pomadeneffektes
WO2000007564A1 (fr) * 1998-08-04 2000-02-17 Johnson & Johnson Gmbh Preparation a base d'huile moussante et son utilisation
US6620773B1 (en) 1998-08-04 2003-09-16 Johnson & Johnson Gmbh Foaming oil preparation and its use
DE19841339A1 (de) * 1998-09-10 2000-03-23 Goldwell Gmbh Aerosol-Haarwaschmittel
EP1029535A1 (fr) * 1999-02-16 2000-08-23 L'oreal Compositions cosmétiques détergentes contenant un tensioactif hydroxyalkylether anionique et une silicone et leurs utilisations
FR2789573A1 (fr) * 1999-02-16 2000-08-18 Oreal Compositions cosmetiques detergentes contenant un tensioactif hydroxyalkylether anionique et une silicone et leurs utilisations
US6368584B1 (en) 2000-02-15 2002-04-09 L'oreal S.A. Detergent cosmetic compositions comprising an anionic hydroxyalkyl ether surfactant and a silicone, and their uses
WO2001078664A1 (fr) * 2000-04-12 2001-10-25 Aveda Corporation Shampooing colorant
US6500413B1 (en) 2000-04-12 2002-12-31 Aveda Corporation High performance color-depositing shampoo
KR100552549B1 (ko) * 2000-04-12 2006-02-14 아베다 코포레이션 착색 샴푸
EP1172096A1 (fr) * 2000-07-12 2002-01-16 L'oreal Composition de nettoyage moussante sous la forme d'un gel transparent
FR2811570A1 (fr) * 2000-07-12 2002-01-18 Oreal Composition de nettoyage moussante sous la forme d'un gel transparent
US7186674B2 (en) 2000-07-12 2007-03-06 L'oreal Topical cleansing composition
DE10221813A1 (de) * 2002-05-16 2003-11-27 Beiersdorf Ag Stark schäumendes Reinigungsgel
DE10327433A1 (de) * 2003-06-18 2005-01-05 Beiersdorf Ag Durch den Anwender bedarfsgerecht aufschäum- und carbonisierbares Hautpflegeprodukt
WO2013091999A2 (fr) * 2011-12-19 2013-06-27 Henkel Ag & Co. Kgaa Agent cosmétique pour la mise en forme temporaire de fibres kératiniques
WO2013091999A3 (fr) * 2011-12-19 2013-10-24 Henkel Ag & Co. Kgaa Agent cosmétique pour la mise en forme temporaire de fibres kératiniques
US9622951B2 (en) 2012-10-29 2017-04-18 The Procter & Gamble Company Personal care compositions
US9889080B2 (en) 2015-05-07 2018-02-13 Celeb LLC Color depositing shampoo
US10865178B2 (en) * 2016-09-30 2020-12-15 Daikin Industries, Ltd. Carboxylate salt or sulfonate salt, and surfactant
US11904036B2 (en) 2017-10-10 2024-02-20 The Procter & Gamble Company Sulfate free clear personal cleansing composition comprising low inorganic salt
US11992540B2 (en) 2017-10-10 2024-05-28 The Procter & Gamble Company Sulfate free personal cleansing composition comprising low inorganic salt
US11980679B2 (en) 2019-12-06 2024-05-14 The Procter & Gamble Company Sulfate free composition with enhanced deposition of scalp active
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US20210353518A1 (en) * 2020-05-15 2021-11-18 The Procter & Gamble Company Shampoo composition
CN115605180A (zh) * 2020-05-15 2023-01-13 宝洁公司（Us） 包含烷基葡糖苷的洗发剂组合物
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11986543B2 (en) 2021-06-01 2024-05-21 The Procter & Gamble Company Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants

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AU6000794A (en) 1994-08-29
WO1994017783A3 (fr) 1994-10-13

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