WO1994004624A1 - Bei raumtemperatur vernetzbare massen, verfahren zu ihrer herstellung und ihre verwendung - Google Patents
Bei raumtemperatur vernetzbare massen, verfahren zu ihrer herstellung und ihre verwendung Download PDFInfo
- Publication number
- WO1994004624A1 WO1994004624A1 PCT/CH1993/000182 CH9300182W WO9404624A1 WO 1994004624 A1 WO1994004624 A1 WO 1994004624A1 CH 9300182 W CH9300182 W CH 9300182W WO 9404624 A1 WO9404624 A1 WO 9404624A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition according
- compositions
- groups
- binder
- polymers
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J113/00—Adhesives based on rubbers containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/34—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups
- C08C19/36—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with oxygen or oxygen-containing groups with carboxy radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Definitions
- the invention relates to cross-linkable, two-component compositions according to the preamble of claim 1, processes for their production and their use.
- Liquid polymers or copolymers which contain acid anhydride groups are valuable raw materials for the formulation of reactive adhesives, sealing compounds, coatings and casting compounds.
- the acid anhydride groups can be distributed randomly or regularly over the molecule, or in the terminal position.
- the acid anhydride groups can be introduced by copolymerization, by reaction with terminal reactive groups, by subsequent addition of unsaturated anhydrides to single or conjugated double bonds or by graft reactions.
- crosslinkable, two-component composition according to claim 1 and the process for its manufacture according to claim 14. It is in particular solved by two-component compositions of polymers containing acid anhydride groups, which contain sterically hindered aromatic amines, diamines or polyamines as crosslinking agents. Sterically hindered means that the amino group is substituted in the neighboring positions or ortho positions.
- Suitable substituents are: linear or branched alkyl groups with 1 to 4 carbon atoms, such as methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, tert-butyl groups.
- Adducts of sterically hindered, aromatic diamines with a deficit of di- or polyfunctional epoxies, isocyanates, acrylic monomers, low molecular weight anhydrides, acid chlorides, aliphatic or aromatic acids, acetoacetates are also preferred.
- the preferred amines are liquid or solid at room temperature.
- Liquid amines are used as undiluted liquids or diluted with plasticizers, the solid ones as a solution in a solvent or plasticizer. Mixtures of several solid amines can form eutectic mixtures and are therefore liquid at room temperature. These amines are advantageously characterized by a low vapor pressure and are toxicologically harmless for commercial use.
- crosslinking agent for producing crosslinkable, two-component compositions based on polymers containing anhydride groups solves the problem on which this invention is based in a particularly advantageous manner.
- Polymers which form the basis of these two-component compositions as binders are polymers or copolymers containing acid anhydride groups which are liquid at room temperature and have molecular weights of up to 50,000.
- the acid anhydride groups can be distributed statistically or regularly over the molecule or in the terminal position.
- the acid anhydride groups can be introduced by copolymerization, by reaction with terminal reactive groups, by subsequent addition of unsaturated anhydrides to single or conjugated double bonds, or by graft reactions.
- crosslinkable polymers examples include copolymers with olefinically unsaturated monomers, such as Example copolymers of maleic or itaconic anhydride with olefins, dienes, vinyl compounds, vinyl aromatic compounds, vinyl esters, vinyl ethers, acrylic and methacrylic compounds,
- Addition products of unsaturated anhydrides with single or conjugated double bonds are preferably those with polymers of butadiene, isoprene, with copolymers of butadiene or isoprene with cyclopentadiene, styrene, acrylonitrile, olefins with up to 12 carbon atoms, with esters of unsaturated fatty acids, with terpenes , or to liquid, unsaturated degradation products of high molecular weight elastomers, such as natural rubber, styrene-butadiene rubber, SBS and SIS thermoplastic rubber. Adducts of maleic anhydride with polymers or copolymers of polybutadiene are particularly preferred.
- the unsaturated anhydride can also be added to partially hydrogenated polymers, or the hydrogenation of excess double bonds can be carried out catalytically after the anhydride addition.
- Graft products which are obtained by adding olefinically unsaturated anhydrides to liquid polymers and copolymers, mostly under the action of radical donors, such as peroxides and azo compounds.
- radical donors such as peroxides and azo compounds.
- the addition of unsaturated anhydrides to EPDM, EVA, poly-alpha-olefins, acrylic polymers is particularly preferred.
- Preferred liquid polymers containing acid anhydride groups are also ester anhydrides, in particular polymeric ester anhydrides, thioester anhydrides or amide anhydrides of polyhydroxyl compounds, polymer capto compounds, of polyamines, with trimellitic acid anhydride, pyromellitic acid dianhydride, benzol tetracarboxylic acid dianhydride dehydrogenated dehydrogenated dehydrogenated dianhydride, benzophenedehyde.
- the binders can also advantageously be mixtures of the crosslinkable polymers.
- the preferred liquid polymers can also contain other functional groups, for example alkoxysilyl groups or carboxyl groups.
- the molecular weight of the liquid polymers containing anhydride groups is in the range from 500 to 50,000.
- Preferred are liquid polymers with a molecular weight of 2,000 to 30,000, which contain an average of 1.5 to 10, preferably 1.8 to 8, anhydride groups per molecule.
- Expressed as the acid number these polymers have a value of 15 to 150 mg KOH / g, preferably 20 to 100 mg KOH / g (determined with anhydrous, alcoholic potassium hydroxide solution, which leads to a half ester).
- the mixtures consist of polymers containing anhydride with different average molecular weights and possibly with different numbers of anhydride groups per molecule.
- the mixtures can consist of polyfunctional polymers containing anhydride groups with monofunctional polymers containing anhydride groups, especially with low molecular weight, monofunctional polymers containing anhydride groups.
- the mixtures must contain an average of at least 1.5 anhydride groups per molecule.
- the stoichiometric ratio of the acid anhydride to the amino groups of the sterically hindered aromatic amine should be in the range from 3 to 0.6, preferably between 2 and 0.8
- Tertiary amines catalyze the addition of sterically hindered aromatic amino groups to acid anhydride groups very little. This allows the use of primary mono-, di- or polyfunctional hydroxyl compounds together with the amines according to the invention for crosslinking polymers containing acid anhydride groups, the reaction of the hydroxyl group with the anhydride group being catalyzed by tertiary amines.
- alcohols and polyols are monofunctional, primary alcohols with 2 to 30 carbon atoms, ethylene glycol, diethylene glycol, low molecular weight polyethylene glycols, butanediols, mixtures of butanediol, pentanediol and hexanediol, polytetramethylene ether glycols, 3-methylpentanediol , liquid bisphenol ethoxylates, neopentyl glycol, cyclohexanedimethanol, functional polybutadienes with hydroxyl groups, N, N-bis-hydroxyethyl-anilines, glycerol, triethanolamine, N, N, N ', N'- Tetrahydroxyethyl-ethylenediamine, N, N'-bis-hydroxyethyl-perrazine.
- Examples of catalytically active, tertiary amines which are used in amounts of up to 2 parts per 100 parts of binder / crosslinking agent mixture are trialkylamines, preferably C12-C14-alkyldimethylamine, di-C12-C14-alkyl-methylamine, N- Alkylimidazoles, N, N, N ', N'-tetramethyl-ethylenediamine, diazabicyclo-octane (Dabco) and -undecene (DBU).
- Alkaline carboxylic acid salts are also effective as catalysts.
- the process for the preparation of the compositions according to the invention includes an intimate mixing of the two components and subsequent curing by crosslinking.
- the mixing and crosslinking is advantageously carried out at temperatures between 0 ° C. and 50 ° C., preferably between 10 and 35 ° C. Even at temperatures in the range from 0 to 15 ° C., the crosslinking reaction with the amines according to the invention takes place almost quantitatively within a day.
- the mixing can be by hand, using dynamic or static mixers * see done. Processing with static or dynamic mixers has proven to be particularly advantageous for higher-viscosity, higher-molecular polybutadienes, since it does not incorporate air.
- the properties of the crosslinked masses can be specifically controlled by the person skilled in the art and depend, among other things. on the polymer content, on the anhydride content of the polymer, on the degree of polymerization, on the proportion of the comonomer, on the functionality, on the ratio of acid anhydride to the amine, on the type of amine.
- the result is very soft to hard masses with different tensile strength, tear strength and compression set.
- Masses in the liquid or crosslinked state have various additives, for example:
- Inorganic and organic fillers pigments, metal powders, dyes, carbon black, fumed silica, short-cut fibers, rubber powder, plasticizers, extender oils, bitumen, resins, non-reactive polymers, reactive modifiers, tackifying resins, adhesion promoters, silanes, wetting agents agents, silicone oils, flame retardant additives, anti-aging agents, light stabilizers, anti-corrosion agents, odorants, fungistatic and bacteriostatically active substances, thixotropic agents, blowing agents and foam stabilizers, solvents.
- the use and the effect of these additives and the preferred concentrations are known in the art and known to the person skilled in the art.
- the mixtures according to the invention are used for the production of casting compounds, extruding compounds, casting compounds, adhesive compounds and sealing compounds.
- Acid number The acid number was determined using methanolic KOH. One acid group and one methyl ester are formed per anhydride group.
- the tear resistance was determined according to DIN 53 504, the tear resistance according to DIN 53 507. Take-off speed 100 mm / min. The secant module was extrapolated from 50% to 100%. The indentation hardness was determined using the Shore A tester.
- Plasticizer 2-ethylhexyl benzyl phthalate (Santicizer 261 / Monsanto Europe SA, B-Brussels)
- Plasticizer diisopropyl-diphenyl (Sure Sol 300 / Koch Che. Co., Corpus Christi TX USA) Ethoxylated bisphenol A, OH number 272 mg KOH / g, (Dianol, AKZO Chem. Div. NL-Amsterdam)
- Component A maleinized polymer with additives
- Component B plasticizer, with dissolved crosslinker component, optionally also with a catalyst.
- Components A and B were mixed homogeneously under room conditions and cast 3 mm plates within 10 minutes. The mechanical values were determined on the resulting crosslinked compositions after storage for at least 10 days under room conditions.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/211,297 US5633341A (en) | 1992-08-17 | 1993-07-19 | At room temperature crosslinkable compositions, and methods of their manufacture and use |
KR1019940701205A KR100287800B1 (ko) | 1992-08-17 | 1993-07-19 | 실온에서 가교결합될 수 있는 조성물, 그 제조 방법 및 용도 |
EP93914584A EP0617728B1 (de) | 1992-08-17 | 1993-07-19 | Bei raumtemperatur vernetzbare massen, verfahren zu ihrer herstellung und ihre verwendung |
DE59307892T DE59307892D1 (de) | 1992-08-17 | 1993-07-19 | Bei raumtemperatur vernetzbare massen, verfahren zu ihrer herstellung und ihre verwendung |
CA002119759A CA2119759C (en) | 1992-08-17 | 1993-07-19 | Compositions which can be cross-linked at room temperature, method of preparing them and their use |
JP6505721A JPH07504458A (ja) | 1992-08-17 | 1993-07-19 | 室温架橋性組成物、ならびにそれらの調製法および使用 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH2553/92-6 | 1992-08-17 | ||
CH255392 | 1992-08-17 | ||
CH1010/93-3 | 1993-04-02 | ||
CH101093 | 1993-04-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1994004624A1 true WO1994004624A1 (de) | 1994-03-03 |
Family
ID=25686375
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CH1993/000182 WO1994004624A1 (de) | 1992-08-17 | 1993-07-19 | Bei raumtemperatur vernetzbare massen, verfahren zu ihrer herstellung und ihre verwendung |
Country Status (8)
Country | Link |
---|---|
US (1) | US5633341A (de) |
EP (1) | EP0617728B1 (de) |
JP (1) | JPH07504458A (de) |
KR (1) | KR100287800B1 (de) |
CA (1) | CA2119759C (de) |
DE (1) | DE59307892D1 (de) |
ES (1) | ES2111751T3 (de) |
WO (1) | WO1994004624A1 (de) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4426783A1 (de) * | 1994-06-21 | 1995-02-09 | Horst Sommer Recycling | Verfahren zum Reparieren beschädigter Arbeitshandschuhe aus Leder |
EP0870793A2 (de) * | 1997-04-11 | 1998-10-14 | Nippon Shokubai Co., Ltd. | Thermisch umkehrbar vernetzte Materialien sowie ihre Anwendung |
WO1999021917A1 (en) * | 1997-10-23 | 1999-05-06 | Ciba Specialty Chemicals Holding Inc. | Hardener for anhydride group-containing polymers |
US7897688B2 (en) | 2005-08-16 | 2011-03-01 | Sika Technology Ag | Amino group-terminal viscosifiers, resultant products and uses thereof |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3512189B2 (ja) * | 1994-08-19 | 2004-03-29 | レキット ベンキサー (ユーケイ) リミテッド | 芳香を発し、周囲の空気を消毒する芳香発生装置 |
JP4036516B2 (ja) * | 1997-12-05 | 2008-01-23 | 株式会社巴川製紙所 | 電子写真用トナー |
EP0922714B1 (de) * | 1997-06-27 | 2006-09-20 | Tomoegawa Paper Co. Ltd. | Elektrophotographischer toner |
US6143049A (en) * | 1997-06-27 | 2000-11-07 | Donaldson Company, Inc. | Aerosol separator; and method |
US5853439A (en) | 1997-06-27 | 1998-12-29 | Donaldson Company, Inc. | Aerosol separator and method |
WO1999060065A1 (en) | 1998-05-19 | 1999-11-25 | E.I. Du Pont De Nemours And Company | Polyacrylics containing pendant acetoacetonate moieties |
US6187073B1 (en) | 1999-03-17 | 2001-02-13 | Donaldson Company, Inc. | Air cleaner; aerosol separator; and method |
US6290739B1 (en) | 1999-12-29 | 2001-09-18 | Donaldson Company, Inc. | Aerosol separator; and method |
TWI279408B (en) * | 2000-01-31 | 2007-04-21 | Vantico Ag | Epoxy resin composition |
US6846491B1 (en) | 2001-08-28 | 2005-01-25 | International Fragrance & Techology | Clear, polymeric gel composition and method for producing the same |
US20030139548A1 (en) * | 2001-12-21 | 2003-07-24 | Hochgesang Paul J. | Solventless liquid EPDM compounds |
US6812294B2 (en) | 2001-12-21 | 2004-11-02 | Freudenberg-Nok General Partnership | Solventless liquid nitrile compounds |
US7335807B2 (en) * | 2001-12-21 | 2008-02-26 | Freudenberg-Nok General Partnership | Solventless liquid isoprene compounds |
US6852805B2 (en) * | 2001-12-21 | 2005-02-08 | Freudenberg-Nok General Partnership | Solventless liquid FKM compounds |
US20030186008A1 (en) * | 2002-03-29 | 2003-10-02 | Sutton Stephen P. | Spirally wound packages of soft thermoplastic elastomer tape, film, or sheet and processes for producing same |
US7045085B2 (en) * | 2002-04-15 | 2006-05-16 | Sutton Stephen P | Elastomer composition and methods for using same |
US20080015295A1 (en) * | 2006-07-11 | 2008-01-17 | Williams Virgil Ag | Polymeric gel composition and method for making |
KR100971726B1 (ko) | 2008-06-30 | 2010-07-22 | 금호타이어 주식회사 | 타이어 카카스용 고무 조성물 |
CN103153941B (zh) * | 2010-10-14 | 2014-12-10 | 隆萨有限公司 | 卤化二乙基甲苯二胺 |
US8865315B2 (en) | 2011-12-20 | 2014-10-21 | Huntsman International Llc | Self healing coating system for use with fuel tanks |
KR101481710B1 (ko) * | 2013-08-29 | 2015-01-21 | 도레이첨단소재 주식회사 | 전자부품용 점착 조성물 및 그를 이용한 전자부품용 점착 테이프 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0149354A2 (de) * | 1984-01-18 | 1985-07-24 | The British Petroleum Company p.l.c. | Abdruckmaterial |
EP0359926A1 (de) * | 1988-09-10 | 1990-03-28 | Hüls Aktiengesellschaft | Vernetzbare Massen, Verfahren zur ihrer Herstellung und ihre Verwendung als Gussmassen und zur Herstellung von Formteilen |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4145321A (en) * | 1977-11-14 | 1979-03-20 | Revertex Limited | Pressure-sensitive adhesive compositions and process for preparing them |
EP0023084B1 (de) * | 1979-06-26 | 1985-08-07 | The British Petroleum Company p.l.c. | Zusammensetzungen vernetzter Polymere und ihre Herstellung |
US5071937A (en) * | 1987-12-22 | 1991-12-10 | Mobay Corporation | Coating compositions based on blocked polyisocyanates and sterically hindered aromatic polyamines |
US5244946A (en) * | 1990-02-02 | 1993-09-14 | The Dow Chemical Company | Styrenic copolymer/polyacetal/thermoplastic polyurethane or elastomeric copolyester blend compositions |
EP0453405B1 (de) * | 1990-04-20 | 2000-07-12 | Ciba SC Holding AG | Verbindungen aus o-Hydroxyphenyl-1,3,5-triazinen und sterisch gehinderten Aminen |
-
1993
- 1993-07-19 US US08/211,297 patent/US5633341A/en not_active Expired - Fee Related
- 1993-07-19 KR KR1019940701205A patent/KR100287800B1/ko not_active IP Right Cessation
- 1993-07-19 EP EP93914584A patent/EP0617728B1/de not_active Expired - Lifetime
- 1993-07-19 JP JP6505721A patent/JPH07504458A/ja not_active Ceased
- 1993-07-19 WO PCT/CH1993/000182 patent/WO1994004624A1/de active IP Right Grant
- 1993-07-19 CA CA002119759A patent/CA2119759C/en not_active Expired - Fee Related
- 1993-07-19 DE DE59307892T patent/DE59307892D1/de not_active Expired - Fee Related
- 1993-07-19 ES ES93914584T patent/ES2111751T3/es not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0149354A2 (de) * | 1984-01-18 | 1985-07-24 | The British Petroleum Company p.l.c. | Abdruckmaterial |
EP0359926A1 (de) * | 1988-09-10 | 1990-03-28 | Hüls Aktiengesellschaft | Vernetzbare Massen, Verfahren zur ihrer Herstellung und ihre Verwendung als Gussmassen und zur Herstellung von Formteilen |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4426783A1 (de) * | 1994-06-21 | 1995-02-09 | Horst Sommer Recycling | Verfahren zum Reparieren beschädigter Arbeitshandschuhe aus Leder |
EP0870793A2 (de) * | 1997-04-11 | 1998-10-14 | Nippon Shokubai Co., Ltd. | Thermisch umkehrbar vernetzte Materialien sowie ihre Anwendung |
EP0870793A3 (de) * | 1997-04-11 | 1998-12-09 | Nippon Shokubai Co., Ltd. | Thermisch umkehrbar vernetzte Materialien sowie ihre Anwendung |
US6207762B1 (en) | 1997-04-11 | 2001-03-27 | Nippon Shokubai Co., Ltd. | Thermally reversible crosslinked matter and its use |
WO1999021917A1 (en) * | 1997-10-23 | 1999-05-06 | Ciba Specialty Chemicals Holding Inc. | Hardener for anhydride group-containing polymers |
US7897688B2 (en) | 2005-08-16 | 2011-03-01 | Sika Technology Ag | Amino group-terminal viscosifiers, resultant products and uses thereof |
Also Published As
Publication number | Publication date |
---|---|
KR100287800B1 (ko) | 2001-05-02 |
JPH07504458A (ja) | 1995-05-18 |
CA2119759C (en) | 2001-07-17 |
EP0617728A1 (de) | 1994-10-05 |
US5633341A (en) | 1997-05-27 |
KR940702917A (ko) | 1994-09-17 |
EP0617728B1 (de) | 1997-12-29 |
ES2111751T3 (es) | 1998-03-16 |
CA2119759A1 (en) | 1994-03-03 |
DE59307892D1 (de) | 1998-02-05 |
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