WO1993022386A1 - Improved process for preparing silica coated inorganic particles - Google Patents

Improved process for preparing silica coated inorganic particles Download PDF

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Publication number
WO1993022386A1
WO1993022386A1 PCT/US1993/003581 US9303581W WO9322386A1 WO 1993022386 A1 WO1993022386 A1 WO 1993022386A1 US 9303581 W US9303581 W US 9303581W WO 9322386 A1 WO9322386 A1 WO 9322386A1
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Prior art keywords
particles
silica
group
silica coated
amorphous silica
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PCT/US1993/003581
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English (en)
French (fr)
Inventor
Howard Wayne Jacobson
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E.I. Du Pont De Nemours And Company
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Application filed by E.I. Du Pont De Nemours And Company filed Critical E.I. Du Pont De Nemours And Company
Priority to JP51930493A priority Critical patent/JP3524550B2/ja
Priority to DE69321228T priority patent/DE69321228T2/de
Priority to EP93912271A priority patent/EP0638110B1/en
Publication of WO1993022386A1 publication Critical patent/WO1993022386A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C09C3/063—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3653—Treatment with inorganic compounds
    • C09C1/3661—Coating
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/30—Particle morphology extending in three dimensions
    • C01P2004/32—Spheres
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity

Definitions

  • the present invention relates to an improved process for preparing non-agglomerated water insoluble inorganic particles having a dense amorphous silica coating by using a dispersion aid.
  • U. S. Patent 2,885,366 describes several methods for applying a dense silica coating to substrate particles, i.e., core particles by suspending the particles in water and then coating with active silica while maintaining the pH in the range of 7 to 11. If the substrate particles in the suspension are in some degree aggregated together to form clumps or agglomerates these are coated with a layer of dense amorphous silica as well as any primary substrate particles.
  • Such a product embraces a wide distribution of sizes of silica coated substrates.
  • the coated agglomerates can be broken down into smaller fragments, by milling or sonification, the fragmented agglomerates have exposed surfaces which are not coated with silica. This detracts from the performance of these materials in many applications, e.g., rough surface appearance in films such as paints.
  • This invention relates to an improved process for applying a dense amorphous silica coating to water insoluble inorganic core particles, particularly oxides.
  • the improvement comprises adding a dispersion aid to an agitated aqueous suspension of the core particles followed by deposition of a silica coating.
  • Dispersion aids contemplated for use in the process are ammonium and alkali metal salts or acids of mu c- ⁇ arged anions such as phosphate, pyrophosphate and citrate which, when they are adsorbed on the surface of the core particles, prevent agglomeration by conferring a charge on the particles.
  • Other dispersion aids have large molecular organic components, which inhibit particle agglomeration sterically by coating the surface of particles.
  • the process of the invention comprises the steps of forming an aqueous suspension of the particles to be silica coated, adding a dispersion aid and heating with agitation to a temperature in the range of 60°C to 100°C. Then an alkali silicate solution is added and the pH is maintained in the range of 7 to 11 by the simultaneous addition of mineral acid. Stirring is continued at 60°C to 100°C and a coating of amorphous silica is deposited on the surface of the dispersed core particles. The product is separated, washed free from ions and dried. The product consists of non- aggregated, i.e., non-agglomerated particles which are completely coated with a dense layer of amorphous silica, the silica component of the coated composition being between 0.5 and 50 percent by weight.
  • the process is particularly useful for the preparation of improved titanium dioxide pigments having high opacity and outstanding ease of dispersibility in liquid coating compositions, as described in U.S. Re. 27,818. Paints made with the finished pigments have excellent smoothness and outstanding durability upon outdoor exposure.
  • the preparation of electroconductive powders (ECP) described in co-pending U.S. Patent Application 07/386,765, (which corresponds to European Patent Application Publication No. 0359569) requires, as a preliminary step, the application of a dense silica coating to a water insoluble inorganic core particle.
  • the process of the present invention can be used for this purpose by subsequently applying a coating layer consisting essentially of hydrous oxides of antimony and tin to the silica coated particles and then calcming at a temperature in the range of from 400°C to 900°C.
  • a coating layer consisting essentially of hydrous oxides of antimony and tin
  • calcming at a temperature in the range of from 400°C to 900°C.
  • the invention relates to an improved process for preparing dense amorphous silica coated water insoluble inorganic particles, particularly oxides.
  • the improvement comprises adding a dispersion aid to an agitated aqueous suspension of the core particles followed by deposition of a silica coating.
  • the process of this invention comprises the steps of:
  • step (d) drying and recovering dense amorphous silica coated inorganic particles.
  • An optional surfactant such as triethanolamine, may be added in step (a).
  • the process can be used to apply a dense amorphous silica coating to a wide variety of inorganic particulate materials. Suitable core compositions must be insoluble in water in the pH range of 7 to 11.
  • Inorganic oxide powders are preferred such as oxides of titanium, magnesium, calcium, barium, strontium, zinc, tin, nickel and iron.
  • the process is also applicable to applying silica coatings to complex oxides such as mica, cordierite, enorthite and pyrophyllite.
  • the most preferred inorganic particles are titanium dioxide pigment particles, which when coated with a dense skin of silica are useful in making greatly improved paints, enamels and lacquers as described in U.S. Re. 27,818.
  • insoluble carbonates or sulfates such as calcium, barium and strontium may be used as core particles in the process of the invention.
  • the average diameter of suitable core particles ranges from submicron to tens of microns and is preferably in the range 0.1 to 20 microns. In the case of titanium dioxide, the range is 0.1 to 1 micron.
  • the nitrogen surface area of core particles which can be used in the process is between 0.1 to 50 m ⁇ /g, most commonly between 2 and 20 ⁇ /g. In general, the preferred surface area will be in the lower part of the above range for high density materials and in the higher part of the above range for low density materials--.
  • Particles shapes which are contemplated for use in this invention may vary widely, e.g., spherical particles, rods, whiskers, fibers, needles, and platelets.
  • the shape-of the core particles used depends primarily on the intended application of the silica coated product. Acicular particles are generally preferred for use in paint films, and equiaxial shaped particles are generally preferred for use as filler in plastics. Other factors such as smoothness of the conducting film and optional properties may lead to a different preference in a specific application and may readily be selected by one skilled in the art.
  • Dispersion aids useful in the process of the invention fall into two categories depending on the mechanism of stabilization of the particle surface which inhibits aggregation, i.e.,
  • Charge stabilization is achieved by the use of metal salts or acids of multicharged anions.
  • Ammonium and alkali metal phosphates, polyphosphates and citrates are particularly effective when used in the process. Potassium salts are preferred because of their ease of solubility and since the larger cation has little tendency to coagulate the silica coated particles, whereas sodium and ammonium cations have a greater flocculating effect.
  • the dispersion aids have bulky molecular components which inhibit aggregation of the particles by coating their surface. Suitable dispersion aids of this type are the alkali metal salts of organic fatty acids such as laurates, palmitates, stearates, oleates and the like. The amount of dispersion aid employed is 0.05 to 2 wt % based on the core material. The compositions which are useful as dispersion aids must not interfere with the silica coating process.
  • dispersion aids decreases particle agglomeration thus reducing the viscosity of the particulate core suspension and enables the present process to be operated at lower temperatures and at higher solids concentrations, thus providing economic benefits and permitting savings on equipment.
  • the more highly dispersed particles require less silica to give an effective coating and when they are used as pigments the resulting films show improvements in smoothness and reflectance.
  • hen used to make ECP compositions the low aggregation of the particles and the decreased amount of silica in the coating leads to a final product ECP having a reduced particle size distribution. When such an ECP composition is used in an electroconductive paint system the dried film has excellent smoothness.
  • an aqueous suspension comprising a desired core material, a dispersion aid and optionally a small amount, e.g., 0.1 to 0.5% of a surfactant, such as triethanolamine.
  • Active silica is then added while mamtaining the pH of the suspension at a value in the range of 7 to 11.
  • Active silica is very low molecular weight silica, such as silicic acid or polysilicic acid, which may be added as such to the suspension, or formed in situ as by the continuous reaction of an acid with an alkali silicate.
  • Potassium silicate is generally preferred since the potassium ion has little tendency to coagulate active silica.
  • the bulk commodity is also more stable, which is advantageous from the standpoint of shipping and storing.
  • the concentration of core material in the dispersion is not especially critical. It can range from 100 to 600 g/liter.
  • the amount of dispersion aid added is in the range 0.05 to 2 wt% based on the core material. Having prepared a dispersion of the core material the agitated dispersion is heated to between 60°C to 100°C and the u- ⁇ iformly dispersed particles are then coated with a dense film or - skin of amorphous silica around the individual particles.
  • the silica content of the coated composition is between 0.5 and 50 wt% and most commonly between 0.5 to 25 wt%.
  • the pH is monitored continuously and is maintained within the range 7 to 11 preferably 7 to 10 throughout the mixing step.
  • the pH is allowed to fall gradually to about 7 as the process is completed and the slurry is usually then cured to permit completion of the deposition of the silica onto the surface of the core particles.
  • the curing step comprises holding the slurry at temperatures between 60°C to 100°C, preferably 75 and 90°C, from 30 minutes to four hours, preferably about one hour, while maintaining the pH of the agitated slurry between 6.0 and 7.5.
  • the product is then separated as a silica coated powder, by filtration or centrifugation, combined with aqueous washing to remove soluble salts.
  • a vacuum rotary-type filter is particularly suitable since washing can be carried out without removing the product from the filter. Washing is continued until the filtrate is quite free of ions.
  • the washed product can then be dried in an air or vacuum o oven.
  • a preferred commercial method of drying the product is spray drying with either heated air or superheated steam, preferably at temperatures below 450°C.
  • silica coated titanium dioxide prepared by the process of this invention is a high opacity pigment with outstanding ease of dispersibility in liquid coating 5 composition. Paints containing this pigment have excellent smoothness and outstanding durability upon outdoor exposure.
  • the product can also be modified for other uses.
  • Silica coated particles are particularly useful for making improved ECP compositions of the kind described in copending U.S. Patent Applications 07/386,765 and 07/631,108. It is preferred, however, to use a dispersion of silica o coated particles prepared in situ for this purpose rather than recovering the dry product and re-dispersing this powder prior to applying the additional coatings described in the processes of the above mentioned U.S. Patent Applications. By whichever procedure they are made the resulting products give exceptionally smooth electroconductive paint films. In addition they possess very good 5 electroconductive properties at low pigment binder ratios as described in greater detail in the Examples. '
  • Silica coated particles prepared by the method of this invention were used to make ECP.
  • the powders were analyzed by X-ray fluorescence analysis and the dry powder resistance was measured by the procedure described in U.S. Patent 0 Application 07/386,765, the teachings of which are incorporated herein by reference.
  • the ECP was formulated with a test paint carrier and the surface conductivity of the dry paint film was measured using the method described in U.S. Patent Application 07/386,765. Th surface roughness of the dry paint film was measured in microinches, using a Hobson-Taylor Surtronic 3P surface roughness tester as supplied by G. F. Maier Co., Edgemont, Pennsylvania.
  • EXAMPLE 1 This example describes the preparation of an ECP consisting of a titanium dioxide particle coated with silica and an outer coating of-antimony containing tin oxide, the ratio of Sn ⁇ 2 to Sb in the outer coating being about 10 to 1.
  • Sodium pyrophosphate is used as a dispersion aid and the silica coating thickness is about half that of the standard ECP silica coating described in U.S. Patent Application Serial No. 07/386,765.
  • an aqueous solution of SnCl SbG-3 and HCl was prepared by combining 202 ml of an aqueous SnC-4 solution, containing the equivalent of 0.445 g. Sn ⁇ 2/ml, with 38.4 ml of an aqueous concentrated HCl solution of SbCl3, containing the equivalent of 0.267 g Sb/ml. This corresponded to a weight ratio of 7.60 parts of Sn ⁇ 2 to 1 part of Sb in the solution.
  • This solution was then added to the well agitated suspension over a period of two hours concurrently with the addition of sufficient 20% NaOH to maintain the pH of the suspension at 2.0. The suspension was then cured by digesting for half an hour at pH 2.0 and 75°C with continuous agitation.
  • the solids were recovered by filtration, washed with deionized water until free from chloride ion and dried by heating at 120°C for several hours.
  • the recovery of dried powder was 291.1 g and the surface area was found to be 56.9 m ⁇ /g.
  • the dried powder was calcined in air at 750°C for 2 hours.
  • the surface area of the calcined product was 26.1 rn ⁇ /g.
  • the calcined powder resistance was 8 ohms.
  • the powder contained, 60.3% Ti ⁇ 2; 2.2% S1O2;
  • the crystallite size was found to be 79 Angstroms by X-ray diffraction analysis.
  • the particle size distribution and average particle diameter were determined using a Microtrac II Standard Range Particle Size Analyzer. 0.8 g of the powder was dispersed by agitation in 80 ml of deionized water containing 15 drops of a surfactant, Darvan C, (R-T.Vanderbilt Co.). Three small samples of the dispersion were analyzed and the average of the particle size distributions showed 81% of the particles to be between 2.6 and 7.5 microns, with an average particle diameter of 3.46 microns.
  • the powder was formulated with a test paint carrier at pigment binder ratios of 35/100 and 40/100 and applied to test surfaces.
  • the resulting dry paint films exhibited surface conductivities of 150 and > 165 Ransburg units respectively and in both cases the surface roughness was only 6 microinches.
  • EXAMPLE 2 This example describes the preparation of a similar composition to that described in example 1 using citric acid instead of sodium pyrophosphate as a dispersion aid. No triethanolamine was added.
  • Dete ⁇ r-ination of the particle size distribution showed 80% of the particles to be between 1.7 and 5.3 microns, with an average particle diameter of 2.70 microns.
  • the powder was formulated with a test paint carrier at a pigment binder ratio of 50/100 and applied to a test surface.
  • the resulting dry paint film exhibited a surface conductivity of 145 Ransburg units and the surface roughness was only 5 microinches.
  • Example 2 This is a comparative example to illustrate the effect on the characteristics of the product by eliminating the dispersion aid in the process.
  • the procedure described in Example 2 was repeated except the amount of K-2Si ⁇ 3 stock solution used was 50 g and the dispersiorkaid, citric acid, was not added to the Ti ⁇ 2 suspension.
  • the surface area of the dried powder was 38.6 m ⁇ /g and of the calcined powder 22.0 m ⁇ /g.
  • the powder contained 60.3% ⁇ O2; 4.4% Si ⁇ 2J 29.2% Sn ⁇ 2 and 3.6% Sb2 ⁇ 3. This corresponds to a weight ratio of 9.7 parts of Sn ⁇ 2 to 1 part Sb.
  • the crystallite size was 84 Angstroms, by X-ray diffraction analysis.
  • the powder was formulated with a test paint carrier at a pigment binder ratio of 50/100 and applied to a test surface.
  • the resulting dry paint film exhibited a surface conductivity of 95 Ransburg units and the surface roughness was 42 microinches, much greater than the 5 microinches measured for a paint film made using the product of Example 2.
  • the surface conductivity was also less when the powder was used at the same pigment to binder ratio as the product of Example 2.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Paints Or Removers (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Silicon Compounds (AREA)
PCT/US1993/003581 1992-04-28 1993-04-22 Improved process for preparing silica coated inorganic particles WO1993022386A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP51930493A JP3524550B2 (ja) 1992-04-28 1993-04-22 シリカ被覆された無機粒子の改良された製造方法
DE69321228T DE69321228T2 (de) 1992-04-28 1993-04-22 Verfahren zur herstellung von mit kieselsäure beschichteten teilchen
EP93912271A EP0638110B1 (en) 1992-04-28 1993-04-22 Improved process for preparing silica coated inorganic particles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87487892A 1992-04-28 1992-04-28
US07/874,878 1992-04-28

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WO1993022386A1 true WO1993022386A1 (en) 1993-11-11

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EP (1) EP0638110B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP3524550B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU4288093A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE69321228T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TW221381B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1993022386A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

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EP0785238A1 (de) * 1996-01-19 1997-07-23 Basf Aktiengesellschaft Eisenoxid-Gelbpigmente mit Silicium-dioxidbeschichtung
FR2747569A1 (fr) * 1996-04-22 1997-10-24 Rhone Poulenc Chimie Composition dentifrice comprenant un abrasif a base de silice et de carbonate de calcium, compatible avec le fluor
EP0824086A1 (en) * 1996-08-13 1998-02-18 Tioxide Specialties Limited Zinc oxide dispersions
WO1998013299A1 (de) * 1996-09-27 1998-04-02 Coty B.V. Ti-Sn-O-NANOCLUSTER, VERFAHREN ZU IHRER HERSTELLUNG UND VERWENDUNG DERSELBEN
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US6695906B2 (en) 2000-04-12 2004-02-24 Millennium Inorganic Chemicals, Inc. Continuous processes for producing titanium dioxide pigments
EP1544256A3 (en) * 2003-12-16 2006-01-04 E.I. du Pont de Nemours and Company Aluminium oxide coated titanium dioxide particles and methods of preparing the same in presence of a densifying agent
EP1975126A4 (en) * 2005-12-16 2009-07-01 Sakai Chemical Industry Co ULTRAFINE BARIUM SULFATE PARTICLES, WATER BASED COATING COMPOSITION AND WATER BASED INK COMPOSITION
WO2009090150A1 (en) * 2008-01-16 2009-07-23 Bim Kemi Ab Silica composition
DE102008026300A1 (de) * 2008-06-02 2009-12-03 Kronos International, Inc. Verfahren zur Oberflächenbeschichtung von anorganischen Festkörperpartikeln, insbesondere Titandioxid-Pigmentpartikel
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US7863215B2 (en) 2005-02-15 2011-01-04 Mitsui Chemicals, Inc. Photocatalyst, method for producing same, liquid dispersion containing photocatalyst and photocatalyst coating composition

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JP4165969B2 (ja) * 1999-08-23 2008-10-15 日清紡績株式会社 インクジェット記録用シート
PL202358B1 (pl) * 1999-11-17 2009-06-30 Roche Diagnostics Gmbh Sposób wytwarzania kompozycji magnetycznych cząstek szklanych, magnetyczne cząstki szklane, kompozycja magnetycznych cząstek szklanych, zawiesina z magnetycznymi cząstkami szklanymi, probówka z kompozycją lub zawiesiną magnetycznych cząstek szklanych, zestaw części z tą probówką, zastosowanie kompozycji, zawiesiny i zestawu zawierających magnetyczne cząstki szklane, sposób izolowania materiału biologicznego
SE516810C2 (sv) * 1999-11-30 2002-03-05 Stora Kopparbergs Bergslags Ab Fyllmedelskomposition för papper och sätt för framställning
DE10035451C2 (de) * 2000-07-19 2002-12-05 November Ag Molekulare Medizin Verfahren und Vorrichtung zur Identifizierung einer Polymersequenz
JP4843858B2 (ja) * 2001-03-27 2011-12-21 大日本印刷株式会社 黒色樹脂組成物、黒色被膜、ブラックマトリックス基板および黒色樹脂組成物の製造方法
JP5017752B2 (ja) * 2001-06-06 2012-09-05 堺化学工業株式会社 ストロンチウム化合物又はバリウム化合物の組成物
US7285162B2 (en) * 2001-07-30 2007-10-23 Millennium Inorganic Chemicals, Inc. Titanium dioxide pigment having improved light stability
US6743286B2 (en) * 2001-07-30 2004-06-01 Millennium Inorganic Chemicals, Inc. Inorganic particles and methods of making
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WO1997039728A1 (fr) * 1996-04-22 1997-10-30 Rhodia Chimie Composition dentifrice comprenant un abrasif ou additif a base de silice et de carbonate de calcium, compatible avec le fluor
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EP0638110B1 (en) 1998-09-23
DE69321228T2 (de) 1999-03-18
JPH07506081A (ja) 1995-07-06
US5340393A (en) 1994-08-23
AU4288093A (en) 1993-11-29
TW221381B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1994-03-01
DE69321228D1 (de) 1998-10-29
EP0638110A1 (en) 1995-02-15
JP3524550B2 (ja) 2004-05-10

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