WO1991013074A3 - Composition catalytique a base de metaux de transition pour la polymerisation d'olefines - Google Patents

Composition catalytique a base de metaux de transition pour la polymerisation d'olefines Download PDF

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Publication number
WO1991013074A3
WO1991013074A3 PCT/US1991/001377 US9101377W WO9113074A3 WO 1991013074 A3 WO1991013074 A3 WO 1991013074A3 US 9101377 W US9101377 W US 9101377W WO 9113074 A3 WO9113074 A3 WO 9113074A3
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WO
WIPO (PCT)
Prior art keywords
transition metal
bidentate
reacting
equivalents
ligand
Prior art date
Application number
PCT/US1991/001377
Other languages
English (en)
Other versions
WO1991013074A2 (fr
Inventor
Sudhin Datta
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to DE69104033T priority Critical patent/DE69104033T2/de
Priority to EP91905676A priority patent/EP0516743B1/fr
Publication of WO1991013074A2 publication Critical patent/WO1991013074A2/fr
Publication of WO1991013074A3 publication Critical patent/WO1991013074A3/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Compositions catalytiques à base de métaux de transition bidentés utiles dans la polymérisation par coordination de monomères d'alpha-oléfines. La préparation des nouveaux composés catalytiques consiste: (1) à faire réagir un trihalogénure de métaux de transition, un trialcoxyde de métaux de transition ou un tri(halogénure/alcoxyde) mélangé, ou les additifs de ces matières à des bases de Lewis, avec deux équivalents d'un ligand de chélation bidenté; ou (2) à faire réagir deux équivalents de trischélates (+3) de métaux de transition identiques ou différents comportant un équivalent d'un trihalogénure de métaux de transition ou son additif avec des bases de Lewis. Les ligands de chélation de l'invention sont ceux qui contiennent au moins deux, et de préférence pas plus de deux, hétéroatomes tels que O, N, P ou S, séparés par un radical hydrocarbure permettant d'obtenir une longueur de chaîne suffisante de manière à permettre aux deux hétéroatomes de procéder à la chélation du même atome de métal. Le ligand de chélation doit avoir au moins un ion positif pouvant être facilement retiré, lequel est perdu lors de la chélation afin de permettre d'obtenir un ligand uninégatif bidenté.
PCT/US1991/001377 1990-03-02 1991-02-27 Composition catalytique a base de metaux de transition pour la polymerisation d'olefines WO1991013074A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE69104033T DE69104033T2 (de) 1990-03-02 1991-02-27 Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen.
EP91905676A EP0516743B1 (fr) 1990-03-02 1991-02-27 Composition catalytique a base de metaux de transition pour la polymerisation d'olefines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/487,695 US5021595A (en) 1990-03-02 1990-03-02 Transition metal catalyst composition for olefin polymerization
US487,695 1990-03-02

Publications (2)

Publication Number Publication Date
WO1991013074A2 WO1991013074A2 (fr) 1991-09-05
WO1991013074A3 true WO1991013074A3 (fr) 1991-10-17

Family

ID=23936763

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1991/001377 WO1991013074A2 (fr) 1990-03-02 1991-02-27 Composition catalytique a base de metaux de transition pour la polymerisation d'olefines

Country Status (5)

Country Link
US (1) US5021595A (fr)
EP (1) EP0516743B1 (fr)
JP (1) JPH05504595A (fr)
DE (1) DE69104033T2 (fr)
WO (1) WO1991013074A2 (fr)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
JP3332051B2 (ja) * 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
EP0617052B1 (fr) * 1993-03-23 1998-06-03 Asahi Kasei Kogyo Kabushiki Kaisha Catalyseur de polymérisation d'oléfines possédant un ligand multidenté
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
AU3505497A (en) * 1996-07-15 1998-02-09 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US6054580A (en) * 1996-07-22 2000-04-25 Carnegie Mellon University Long-lived homogenous amide containing macrocyclic compounds
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts
EP0861853A1 (fr) 1997-02-27 1998-09-02 ENICHEM S.p.A. Catalysateur et procédé pour la polymérisation syndiotactique de composés vinylaromatiques
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6051603A (en) * 1998-01-20 2000-04-18 Wayne Hughes Institute Vanadium (IV) metallocene complexes having sperm motility inhibiting activity
US6245808B1 (en) 1998-11-05 2001-06-12 Parker Hughes Institute Oxy-vanadium (IV) complexes having spermicidal activity
WO2000035930A1 (fr) * 1998-01-20 2000-06-22 Parker Hughes Institute Composes a base de vanadium pour traitement anticancereux
US6432941B1 (en) 1998-01-20 2002-08-13 Parker Hughes Institute Vanadium compounds for treating cancer
US6696380B2 (en) 2000-01-12 2004-02-24 Darryl Stephen Williams Procatalysts, catalyst systems, and use in olefin polymerization
WO2001051526A1 (fr) 2000-01-12 2001-07-19 Eastman Chemical Company Procatalyseurs comprenant des ligands bidentes, systemes de catalyseurs et leur utilisation dans la polymerisation d'olefines
US6465383B2 (en) 2000-01-12 2002-10-15 Eastman Chemical Company Procatalysts, catalyst systems, and use in olefin polymerization
CA2465647C (fr) * 2001-11-30 2010-12-14 Exxonmobil Chemical Patents, Inc. Copolymere d'ethylene/d'alpha-olefine constitue d'une combinaison de catalyseurs a site unique et a site non unique, sa preparation et son utilisation
JP2006257193A (ja) * 2005-03-16 2006-09-28 Sumitomo Chemical Co Ltd 共重合体の製造方法
US20070004876A1 (en) * 2005-06-22 2007-01-04 Fina Technology, Inc. Cocatalysts for olefin polymerizations
US20070004875A1 (en) * 2005-06-22 2007-01-04 Fina Technology, Inc. Cocatalysts useful for improving polyethylene film properties

Citations (3)

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Publication number Priority date Publication date Assignee Title
DE1242876B (de) * 1961-04-10 1967-06-22 Du Pont Verfahren zur Herstellung von Polymerisaten aethylenisch ungesaettigter Verbindungen
FR2318879A2 (fr) * 1975-07-21 1977-02-18 Montedison Spa Catalyseurs pour la polymerisation d'olefines
US4374777A (en) * 1981-04-09 1983-02-22 The United States Of America As Represented By The Secretary Of The Navy Synthesis of hydrocarbon soluble vanadium catalyst

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Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1242876B (de) * 1961-04-10 1967-06-22 Du Pont Verfahren zur Herstellung von Polymerisaten aethylenisch ungesaettigter Verbindungen
FR2318879A2 (fr) * 1975-07-21 1977-02-18 Montedison Spa Catalyseurs pour la polymerisation d'olefines
US4374777A (en) * 1981-04-09 1983-02-22 The United States Of America As Represented By The Secretary Of The Navy Synthesis of hydrocarbon soluble vanadium catalyst

Also Published As

Publication number Publication date
DE69104033T2 (de) 1995-01-26
EP0516743A1 (fr) 1992-12-09
US5021595A (en) 1991-06-04
EP0516743B1 (fr) 1994-09-14
WO1991013074A2 (fr) 1991-09-05
JPH05504595A (ja) 1993-07-15
DE69104033D1 (de) 1994-10-20

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