DE69104033T2 - Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen. - Google Patents

Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen.

Info

Publication number
DE69104033T2
DE69104033T2 DE69104033T DE69104033T DE69104033T2 DE 69104033 T2 DE69104033 T2 DE 69104033T2 DE 69104033 T DE69104033 T DE 69104033T DE 69104033 T DE69104033 T DE 69104033T DE 69104033 T2 DE69104033 T2 DE 69104033T2
Authority
DE
Germany
Prior art keywords
olefins
polymerization
transition metal
catalyst composition
metal containing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69104033T
Other languages
English (en)
Other versions
DE69104033D1 (de
Inventor
Sudhin Datta
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of DE69104033D1 publication Critical patent/DE69104033D1/de
Publication of DE69104033T2 publication Critical patent/DE69104033T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
    • C07F11/005—Compounds containing elements of Groups 6 or 16 of the Periodic Table compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
    • B01J2531/56—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69104033T 1990-03-02 1991-02-27 Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen. Expired - Fee Related DE69104033T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/487,695 US5021595A (en) 1990-03-02 1990-03-02 Transition metal catalyst composition for olefin polymerization
PCT/US1991/001377 WO1991013074A2 (en) 1990-03-02 1991-02-27 Transition metal catalyst composition for olefin polymerization

Publications (2)

Publication Number Publication Date
DE69104033D1 DE69104033D1 (de) 1994-10-20
DE69104033T2 true DE69104033T2 (de) 1995-01-26

Family

ID=23936763

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69104033T Expired - Fee Related DE69104033T2 (de) 1990-03-02 1991-02-27 Übergangsmetall enthaltende katalysatorzusammensetzung zur polymerisation von olefinen.

Country Status (5)

Country Link
US (1) US5021595A (de)
EP (1) EP0516743B1 (de)
JP (1) JPH05504595A (de)
DE (1) DE69104033T2 (de)
WO (1) WO1991013074A2 (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0590486A3 (en) * 1992-09-24 1994-08-24 Idemitsu Kosan Co Polymerization catalysts and process for producing polymers
JP3332051B2 (ja) * 1992-12-18 2002-10-07 出光興産株式会社 重合用触媒及び該触媒系を用いる重合体の製造方法
EP0816386B1 (de) * 1993-03-23 1998-12-16 Asahi Kasei Kogyo Kabushiki Kaisha Olefinpolymerisationskatalysator mit mehrzähnigem Ligand
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
EP0912244A4 (de) * 1996-07-15 2001-09-12 Mobil Oil Corp Mit comonomer vorbehandelter bimetallischer katalysator zum blasformen und filme
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts
US6054580A (en) * 1996-07-22 2000-04-25 Carnegie Mellon University Long-lived homogenous amide containing macrocyclic compounds
EP0861853A1 (de) 1997-02-27 1998-09-02 ENICHEM S.p.A. Katalysator und Verfahren für die syndiotaktische Polymerisation von vinylaromatischen Verbindungen
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6245808B1 (en) 1998-11-05 2001-06-12 Parker Hughes Institute Oxy-vanadium (IV) complexes having spermicidal activity
WO2000035930A1 (en) * 1998-01-20 2000-06-22 Parker Hughes Institute Vanadium compounds for treating cancer
US6432941B1 (en) * 1998-01-20 2002-08-13 Parker Hughes Institute Vanadium compounds for treating cancer
US6051603A (en) * 1998-01-20 2000-04-18 Wayne Hughes Institute Vanadium (IV) metallocene complexes having sperm motility inhibiting activity
US6696380B2 (en) 2000-01-12 2004-02-24 Darryl Stephen Williams Procatalysts, catalyst systems, and use in olefin polymerization
US6465383B2 (en) 2000-01-12 2002-10-15 Eastman Chemical Company Procatalysts, catalyst systems, and use in olefin polymerization
BRPI0107604B1 (pt) 2000-01-12 2015-03-31 Westlake Longview Corp Pró-catalisador sólido, sistema catalisador, e, processo para a polimerização de pelo menos uma ou mais olefinas
WO2003048213A1 (en) * 2001-11-30 2003-06-12 Exxonmobil Chemical Patents, Inc. Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use
JP2006257193A (ja) * 2005-03-16 2006-09-28 Sumitomo Chemical Co Ltd 共重合体の製造方法
US20070004876A1 (en) * 2005-06-22 2007-01-04 Fina Technology, Inc. Cocatalysts for olefin polymerizations
US20070004875A1 (en) * 2005-06-22 2007-01-04 Fina Technology, Inc. Cocatalysts useful for improving polyethylene film properties

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL277017A (de) * 1961-04-10
GB1512981A (en) * 1974-05-02 1978-06-01 Gen Electric Curable epoxide compositions
CH594706A5 (de) * 1975-02-17 1978-01-31 Battelle Memorial Institute
IT1049565B (it) * 1975-07-21 1981-02-10 Montedison Spa Catalizzatori per la polimerizaazione delle olefine
US4373079A (en) * 1978-09-26 1983-02-08 Occidental Research Corporation Layered or amorphous cyclic organometallic inorganic polymers
US4351775A (en) * 1981-03-20 1982-09-28 Stauffer Chemical Company Method for preparation of alkyl vanadates
US4374777A (en) * 1981-04-09 1983-02-22 The United States Of America As Represented By The Secretary Of The Navy Synthesis of hydrocarbon soluble vanadium catalyst
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US4508842A (en) * 1983-03-29 1985-04-02 Union Carbide Corporation Ethylene polymerization using supported vanadium catalyst
US4540753A (en) * 1983-06-15 1985-09-10 Exxon Research & Engineering Co. Narrow MWD alpha-olefin copolymers

Also Published As

Publication number Publication date
DE69104033D1 (de) 1994-10-20
US5021595A (en) 1991-06-04
JPH05504595A (ja) 1993-07-15
EP0516743A1 (de) 1992-12-09
WO1991013074A3 (en) 1991-10-17
WO1991013074A2 (en) 1991-09-05
EP0516743B1 (de) 1994-09-14

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