ES485818A1 - Procedimiento para la polimerizacion de polibutadieno en un disolvente organico - Google Patents
Procedimiento para la polimerizacion de polibutadieno en un disolvente organicoInfo
- Publication number
- ES485818A1 ES485818A1 ES485818A ES485818A ES485818A1 ES 485818 A1 ES485818 A1 ES 485818A1 ES 485818 A ES485818 A ES 485818A ES 485818 A ES485818 A ES 485818A ES 485818 A1 ES485818 A1 ES 485818A1
- Authority
- ES
- Spain
- Prior art keywords
- catalyst
- polymerisation
- atoms
- substituents
- denotes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Procedimiento para la polimerización de polibutadieno en un disolvente orgánico, caracterizado porque butadieno se polimeriza en presencia de un catalizador compuesto de un carboxilato de las tierras raras de fórmula **(Fórmula)** un alquilo de aluminio A1R43 y/o R42A1H, y un ácido Lewis, donde en las fórmulas M significa un elemento trivalente de las tierras raras con el número de orden 57 hasta 71, R1, R2 y R3 son iguales o diferentes y significan restos alquilo con 1 hasta 10 átomos de carbono, ascendiendo la suma de todos los átomos de carbono, ascendiendo la suma de todos los átomos de carbono en los sustituyentes a 6 hasta 20, y R4 significa un resto alquilo con 1 hasta 10 átomos de carbono, a temperaturas de -20 hasta +150ºC.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19782848964 DE2848964A1 (de) | 1978-11-11 | 1978-11-11 | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
Publications (1)
Publication Number | Publication Date |
---|---|
ES485818A1 true ES485818A1 (es) | 1980-05-16 |
Family
ID=6054404
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ES485818A Expired ES485818A1 (es) | 1978-11-11 | 1979-11-08 | Procedimiento para la polimerizacion de polibutadieno en un disolvente organico |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0011184B2 (es) |
JP (1) | JPS5566903A (es) |
CA (1) | CA1143711A (es) |
DE (2) | DE2848964A1 (es) |
ES (1) | ES485818A1 (es) |
Families Citing this family (58)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1223396A (en) * | 1981-06-29 | 1987-06-23 | Tooru Shibata | Process for producing conjugated diene polymer |
IT1140452B (it) * | 1981-09-25 | 1986-09-24 | Anic Spa | Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo |
JPS58125714A (ja) * | 1982-01-21 | 1983-07-26 | Asahi Chem Ind Co Ltd | 新しい共重合体とその製造法 |
JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
US4663405A (en) * | 1986-04-16 | 1987-05-05 | The Goodyear Tire & Rubber Company | Molecular weight modifier for use with lanthanide and actinide catalysts |
KR910008275B1 (ko) * | 1987-08-19 | 1991-10-12 | 아사히가세이고오교 가부시끼가이샤 | 공역 디엔 화화물 예비중합체 용액 제조를 위한 예비중합방법 |
JP2609623B2 (ja) * | 1987-09-01 | 1997-05-14 | 株式会社ブリヂストン | 空気入りタイヤ |
GB8830007D0 (en) * | 1988-12-22 | 1989-02-15 | Enichem Elastomers | Polymerization of butadiene |
US5792824A (en) * | 1993-05-21 | 1998-08-11 | Asahi Kasei Kogyo Kabushiki Kaisha | Cyclic conjugated diene polymer and method of producing same |
US5795945A (en) * | 1993-06-16 | 1998-08-18 | Asahi Kasei Kogyo Kabushiki Kaisha | Polymer containing a cyclic olefin monomer unit |
DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
US5428119A (en) * | 1993-11-09 | 1995-06-27 | Polysar Rubber Corporation | Process for polybutadiene production using catalyst with high activity |
KR0174806B1 (ko) * | 1994-02-01 | 1999-04-01 | 유미꾸라 레이이찌 | 새로운 변성 환상 분자구조 단위 함유 중합체 |
US5453471B1 (en) * | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
DE4436059A1 (de) | 1994-10-10 | 1996-04-11 | Bayer Ag | Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch |
DE19505355A1 (de) * | 1995-02-17 | 1996-08-22 | Bayer Ag | Neue Trägerkatalysatoren, Verfahren zu deren Herstellung sowie deren Verwendung zur Polymerisation konjugierter Diene in der Gasphase |
DE19512120A1 (de) * | 1995-04-04 | 1996-10-10 | Bayer Ag | Verfahren zur Herstellung von Dien-Kautschuken in der Gasphase |
US5914377A (en) * | 1995-04-04 | 1999-06-22 | Bayer Ag | Method for the production of diene rubbers in the gas phase |
DE19512116A1 (de) * | 1995-04-04 | 1996-10-10 | Bayer Ag | Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden |
DE19720171A1 (de) | 1997-05-14 | 1998-11-19 | Bayer Ag | Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen |
DE19746266A1 (de) | 1997-10-20 | 1999-04-22 | Bayer Ag | Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen |
WO2000052062A1 (en) | 1999-03-04 | 2000-09-08 | Riken | Catalyst composition |
DE19919870A1 (de) | 1999-04-30 | 2000-11-02 | Bayer Ag | Verfahren zur Suspensions-Polymerisation von konjugierten Dienen |
DE19922640A1 (de) * | 1999-05-18 | 2000-11-23 | Bayer Ag | Verfahren zur Herstellung von thermoplastischen Formmassen unter Verwendung von Kautschuklösungen |
DE19939842A1 (de) * | 1999-08-23 | 2001-03-01 | Bayer Ag | Verfahren zur Copolymerisation von konjugierten Diolefinen (Dienen) und vinylaromatischen Monomeren mit Katalysatoren der Seltenen Erden sowie die Verwendung der Copolymerisate in Kautschukmischungen für Reifenanwendungen |
DE10022497A1 (de) | 2000-05-09 | 2001-11-15 | Bayer Ag | Copolymerisation konjugierter Diene mit nichtkonjugierten Olefinen mittels Katalysatoren der Seltenen Erden |
DE10037076A1 (de) | 2000-07-27 | 2002-02-07 | Bayer Ag | Polybutadiene mit verringertem Verhältnis Lösungsviskosität/ Mooney-Viskosität |
MXPA03001608A (es) * | 2000-08-23 | 2003-10-15 | Bayer Ag | Aniones polimeros insaturados, estabilizados meidante enlace por coordinacion, metalizados, con una elevada proporcion en dobles enlaces situados en posicion cis. |
DE10105401A1 (de) | 2001-02-07 | 2002-08-22 | Bayer Ag | Kontinuierliches Verfahren zur Herstellung von Elastomeren |
DE10115106A1 (de) | 2001-03-27 | 2002-10-10 | Bayer Ag | Blockcopolymerisat auf Basis von konjugierten Diolefinen und polaren Monomeren |
EP1397390B1 (de) | 2001-04-23 | 2008-01-09 | Lanxess Deutschland GmbH | Modifizierte polymere mit einem hohen anteil an cis-ständigen doppelbindungen, ein verfahren zu deren herstellung sowie deren verwendung |
FR2824834B1 (fr) * | 2001-05-18 | 2005-05-13 | Rhodia Elect & Catalysis | Procede de preparation de copolymeres blocs, copolymeres blocs ainsi obtenus et utilisation comme agents compatibilisants |
JP3624290B2 (ja) | 2002-05-08 | 2005-03-02 | 独立行政法人理化学研究所 | 重合用触媒 |
KR100553249B1 (ko) | 2003-05-15 | 2006-02-20 | 금호석유화학 주식회사 | 고 1,4-시스 폴리부타디엔-폴리우레탄 공중합체 및 그 제조방법 |
JP4467258B2 (ja) * | 2003-06-25 | 2010-05-26 | 株式会社ブリヂストン | ブタジエン系重合体及びその製造方法、並びにそれを用いたゴム組成物及びタイヤ |
US7094849B2 (en) * | 2003-12-15 | 2006-08-22 | Bridgestone Corporation | Bulk polymerization process for producing polydienes |
DE102004022676A1 (de) | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
KR100700624B1 (ko) | 2005-09-08 | 2007-03-27 | 금호석유화학 주식회사 | 니오디뮴-탄소나노튜브 합성과, 이를 이용한 고 1,4-시스폴리부타디엔 제조방법 |
DE102007038442A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Modifizierte Polymere auf Basis von konjugierten Dienen oder von konjugierten Dienen und vinylaromatischen Verbindungen, ein Verfahren zu deren Herstellung sowie deren Verwendung |
DE102007038439A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Nanostrukturierte Polymere auf Basis von konjugierten Dienen |
DE102007038441A1 (de) | 2007-08-16 | 2009-02-19 | Lanxess Deutschland Gmbh | Gekoppelte und Heteroatome enthaltende modifizierte Polymere auf Basis von konjugierten Dienen |
KR100970767B1 (ko) | 2007-12-12 | 2010-07-16 | 금호석유화학 주식회사 | 방향족 유기황화합물로 기능화된 1,4-시스 폴리부타디엔 |
DE102008053888A1 (de) | 2008-10-30 | 2010-05-06 | Lanxess Deutschland Gmbh | Neues Verfahren zur Herstellung von Polybutadien-haltigen Formteilen |
EP2311889A1 (de) | 2009-10-16 | 2011-04-20 | LANXESS Deutschland GmbH | Neodym-katalysierte Polybutadiene |
EP2363303A1 (de) | 2010-02-19 | 2011-09-07 | LANXESS Deutschland GmbH | Bimodales NdBR |
WO2013066329A1 (en) | 2011-11-03 | 2013-05-10 | Lanxess Deutschland Gmbh | NdBR WET MASTERBATCH |
US9758646B2 (en) | 2011-11-03 | 2017-09-12 | Arlanxeo Deutschland Gmbh | NdBR wet masterbatch |
EP2676968A1 (de) | 2012-06-18 | 2013-12-25 | LANXESS Deutschland GmbH | Hoch Mooney NdBR mit Mooneysprung |
JP6450067B2 (ja) * | 2013-08-23 | 2019-01-09 | 住友ゴム工業株式会社 | 共役ジエン重合体の製造方法、ゴム組成物および空気入りタイヤ |
WO2015055508A1 (en) | 2013-10-16 | 2015-04-23 | Lanxess Deutschland Gmbh | Functionalized polymer composition |
CN105745228B (zh) | 2013-10-16 | 2017-07-21 | 阿朗新科德国有限责任公司 | 支化度的测定 |
EP2865540A1 (de) | 2013-10-24 | 2015-04-29 | LANXESS Deutschland GmbH | Kautschukzusammensetzung |
EP3053934A1 (en) | 2015-02-06 | 2016-08-10 | LANXESS Deutschland GmbH | Heteroatom containing modified diene polymers |
JP6669220B2 (ja) * | 2018-09-05 | 2020-03-18 | 住友ゴム工業株式会社 | 共役ジエン重合体の製造方法、ゴム組成物および空気入りタイヤ |
US20230303734A1 (en) | 2020-09-28 | 2023-09-28 | Arlanxeo Deutschland Gmbh | Partially hydrogenated diene polymers |
WO2022207551A1 (en) | 2021-03-29 | 2022-10-06 | Arlanxeo Netherlands B.V. | Process for producing polymers |
WO2023193943A1 (en) | 2022-04-08 | 2023-10-12 | Arlanxeo Deutschland Gmbh | Branched modified diene rubbers |
WO2023217397A1 (en) | 2022-05-09 | 2023-11-16 | Arlanxeo Netherlands B.V. | Process for producing polymers |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3297667A (en) * | 1963-02-28 | 1967-01-10 | Union Carbide Corp | Production of cis-1, 4-polydienes by polymerization of 1, 3-dienes |
US3541063A (en) * | 1967-12-29 | 1970-11-17 | Goodyear Tire & Rubber | Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds |
GB1294725A (en) * | 1969-03-27 | 1972-11-01 | Goodyear Tire & Rubber | Polymerization of diolefins |
JPS5485119A (en) * | 1977-12-20 | 1979-07-06 | Meidensha Electric Mfg Co Ltd | Production of aluminium casting rotor |
DE2830080A1 (de) * | 1978-07-08 | 1980-01-17 | Bayer Ag | Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien |
-
1978
- 1978-11-11 DE DE19782848964 patent/DE2848964A1/de not_active Withdrawn
-
1979
- 1979-10-31 EP EP79104244A patent/EP0011184B2/de not_active Expired
- 1979-10-31 DE DE7979104244T patent/DE2965399D1/de not_active Expired
- 1979-11-08 ES ES485818A patent/ES485818A1/es not_active Expired
- 1979-11-09 CA CA000339569A patent/CA1143711A/en not_active Expired
- 1979-11-09 JP JP14458379A patent/JPS5566903A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
CA1143711A (en) | 1983-03-29 |
EP0011184B2 (de) | 1988-05-18 |
EP0011184A1 (de) | 1980-05-28 |
JPS6364444B2 (es) | 1988-12-12 |
DE2965399D1 (en) | 1983-06-16 |
JPS5566903A (en) | 1980-05-20 |
DE2848964A1 (de) | 1980-05-22 |
EP0011184B1 (de) | 1983-05-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FD1A | Patent lapsed |
Effective date: 19970203 |