WO1991005191A1 - Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means - Google Patents

Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means Download PDF

Info

Publication number
WO1991005191A1
WO1991005191A1 PCT/US1989/004410 US8904410W WO9105191A1 WO 1991005191 A1 WO1991005191 A1 WO 1991005191A1 US 8904410 W US8904410 W US 8904410W WO 9105191 A1 WO9105191 A1 WO 9105191A1
Authority
WO
WIPO (PCT)
Prior art keywords
cartridge
base
faucet
resilient
tubular member
Prior art date
Application number
PCT/US1989/004410
Other languages
English (en)
French (fr)
Inventor
Alfons Knapp
Original Assignee
Masco Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Masco Corporation filed Critical Masco Corporation
Priority to DE19893991752 priority Critical patent/DE3991752T/de
Priority to CH167891A priority patent/CH680683A5/fr
Priority to AU44214/89A priority patent/AU638683B2/en
Priority to JP1-511241A priority patent/JPH04503553A/ja
Priority to PCT/US1989/004410 priority patent/WO1991005191A1/en
Priority to DE3991752A priority patent/DE3991752C2/de
Priority to FR8914440A priority patent/FR2654174B1/fr
Publication of WO1991005191A1 publication Critical patent/WO1991005191A1/en
Priority to GB9111056A priority patent/GB2242506B/en
Priority to FI912663A priority patent/FI100425B/fi
Priority to DK199101067A priority patent/DK173504B1/da

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16KVALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
    • F16K11/00Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves
    • F16K11/02Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit
    • F16K11/06Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit comprising only sliding valves, i.e. sliding closure elements
    • F16K11/078Multiple-way valves, e.g. mixing valves; Pipe fittings incorporating such valves with all movable sealing faces moving as one unit comprising only sliding valves, i.e. sliding closure elements with pivoted and linearly movable closure members
    • F16K11/0782Single-lever operated mixing valves with closure members having flat sealing faces

Definitions

  • the present invention relates to a cartridge for a mixing faucet having a control lever moving about a single pivot point in which the sealing force between the water conduits of the cartridge and the corresponding water conduits from the body of the faucet is achieved by- tubular members which are provided with a resilient spring element.
  • the delivery passages for hot and cold water through the metallic base of the faucet form an elongated counterbore for the passage of water toward the cavity that houses the cartridge.
  • An elastomeric sealing tubular member and biasing spring is inserted in the counterbore.
  • the ring can be elongated and resemble a tube. The tube exerts a radial force upon the walls of the counterbore containing it, and is biased by the spring to protrude out from the counterbore above the base wall surface of the cavity in the body.
  • the cylindrical walls of the counterbores need to be precisely finished to insure the radial sealing of the rubber tubing.
  • the precise finishing of the counterbores can be a technically difficult and costly operation.
  • the assembly of the respective rubber tubes and springs in the counterbores is a delicate and difficult operation because the counterbores are found at the base of the cavity of the faucet body and consequently there is poor accessibility to easily position the springs and rubber tubes. Later repair and replacement of the rubber tubes are also difficult.
  • a passage of water in the base of the cartridge includes a counterbore which opens toward the external surface of the base of the cartridge.
  • An elastomeric tubular sealing member is located in the counterbore of the cartridge and is held in position in such a way as to protrude from the bottom of the cartridge to abut against said end of the cavity in the faucet body.
  • the base of the cavity formed by the metallic body of the faucet to house the cartridge requires only one smoothing operation that is easily executed.
  • the tubular sealing member contained in the counterbore of the base of the cartridge abuts frontally with the smooth surface of the base of the body of the faucet now that the cartridge is inserted in the preformed cavity in the body of the faucet.
  • Work performed on the counterbores for the tubing located in the base of the cartridge does not present any difficulty because of the immediate accessibility of these counterbores.
  • an extra work step is not generally even necessary because the cartridge is made of a plastic material and can be integrally molded with the needed counterbores.
  • the counterbores are easily accessible at the end of the cartridge when its out of the cavity which makes any operation of insertion or disassembly of the elastomeric tubular sealing members afterward extremely easy. Also, every time the cartridge is removed from the body of the faucet, the tubular members protrude from the counterbores and can be easily inspected without even removing them from the counterbores.
  • elastomeric tubular sealing members commonly used in mixing valve faucets can be used.
  • the elastomeric sealing members have a tubular body with a restricted extremity which defines a shoulder for abutting the end of a helical spring inserted into the interior of the tubular body.
  • an elastomeric tubular body which provides its own biasing force sufficient to assure the resilience from which the compression is provided.
  • the spring that loads the seals are constituted by the seals themselves.
  • it is possible to shape the elastomeric sealing members such that the pressure of the water traveling within it tends to deform it and cause it to bias against the faucet body with adequate force to create an effective seal.
  • a tubular sealing member can be made of a substantially rigid material and be provided with acditions of defor able 0-rings tending to radially seal against the counterbores in the cartridge and frontally abut the base of the cavity of the body of the faucet.
  • the resilient biasing member for biasing the sealing member can be a helical spring or it can be made up of a resilient elastomeric coupling.
  • the coupling can be made in such a way that water pressure within it tends to deform it, advantageously increasing the biasing pressure that applies to the sealing member and provides the frontal compressive sealing force against the end of the cavity.
  • Fig. 1 illustrates the segmented view of a faucet body housing a cartridge according to one embodiment of the invention
  • Fig. 2 is a side elevational view of an elastomeric seal shown in Fig. 1;
  • Fig. 3 is a top plan view of the fixed plate shown in Fig. 1;
  • Fig. 4 is a fragmentary and segmented view of the lower part of the faucet body showing a second embodiment of the invention
  • Fig. 5 is a fragmentary and segmented view of the lower part of the faucet body showing a third embodiment of the invention
  • Fig. 6 is a fragmentary and segmented view of the lower part of the faucet body showing a fourth embodiment of the invention.
  • Fig. 7 is a fragmentary and segmented view of the lower part of the faucet body showing a fifth embodiment of the invention.
  • the faucet has a metallic body 1 in whose interior is formed a cavity or chamber 2 for housing a cartridge.
  • Supply passages 4 and 5 for hot and cold water are formed in body 1 and have ends in base 3 of chamber 2.
  • An annular chamber 6 is positioned to receive the mixed water from the cartridge and guide it to a spout (not shown) in conventional fashion.
  • the body 1 is closed by a screw cap 8 which abuts and seals the body 1 by means of a resilient 0-ring seal 7.
  • the cartridge includes a caged housing 9 with a base 10 with passages 11 and 12 for entry of hot and cold water. Passage 13 serves as an exit for the mixed water from housing 9 of the cartridge to the annular chamber 6 of body 1.
  • a fixed plate 16 made from a hard material such as rigid plastic or ceramic is mounted into the interior of base 10 of the cartridge and is fixed by means of screw 21.
  • a seal 22 lies under the plate 16 in compression.
  • the fixed plate 16 has its lower level passages 17 and 19 for the entry of cold and hot water aligned with passages 11 and 12 of base 10. On its upper level, the passages 17 and 19 leads to cavities 18 and 20, respectively, for the distribution of water in cooperation with a mobile plate 23 made of a hard material.
  • the plate 23 is positioned above the fixed plate 16 and can be moved translationally and rotatably by means of a guide 24 in a rotatable driving ring 25 between certain limits defined by the housing 9.
  • a lower half bearing 26 connected to the housing 9 is supported against cap 8 of body 1 of the faucet and forms a half seat for a pivot ball 27.
  • Extended from the ball 27 are an internal arm 28 which works against the slide 24 and an external arm 29 which is connected to control lever 30.
  • the seat for the pivot ball 27 is completed by an upper half bearing 31 mounted in cap 8 of the body of the faucet and which exerts compressive force by means of a seal 32 that seals against the lower half bearing 26 and the pivot ball 27.
  • the bidirectional control lever 30 permits! the displacement of the guide 24 that translationally and rotationally moves the mobile plate 23 which selectively opens the cavities 18 and 20 of the fixed plate 16 in different proportions thereby permitting the passage of various quantities and proportions of hot and cold water which is then mixed and exits the faucet. In this way, control over the flow of mixed water and the mixing proportion between hot and cold water is obtained.
  • the structure of the faucet and the cartridge described and illustrated should be considered only in terms of explaining the application of the invention which is not in any way limited to the form of faucet and cartridge described. To the contrary, the invention can apply generally to every cartridge for a mixing faucet of the type in which the compressive sealing force between the passage of the water conduits in the cartridge and the corresponding conduits in the body of the faucet is secured by seal elements and a spring biasing means.
  • counterbores 14 and 15 are located in base 10 of the housing 9 of the cartridge which correspond to entrance passageways 11 and 12 for hot and cold water when the cartridge is inserted in cavity 2 of faucet body 1 over supply passages 4 and 5 of body 1.
  • a sealing member 33 is coupled with a metallic spiral spring 36.
  • the member 33 is made of an elastomeric material and has a tubular form which is constrained at lower extremity forming a shoulder.
  • the spring 36 is compressed between shoulder 34 of member 33 and the upper base of the counterbores 14 and 15 and therefore biases member 33 toward the cavity surface 3.
  • the counterbores 14 and 15, spring 36 and member 33 are sized such that, at rest, the lower shoulder 34 of seal member 33 axially protrudes with respect to base 10 of the cartridge.
  • member 33 has a ringed relief 35 which in its mounted state represented in Fig. 1, becomes imperceptible as its compressed against the wall of counterbore 10, 11.
  • the ringed relief 35 frictionally abuts against the side walls of counterbores 14 and 15 and creates a seal therewith.
  • member 33 When the cartridge 9-26 is inserted into cavity 2 of body 1 of the faucet, member 33 has its lower shoulder end 34 sealingly abut against the lower end surface 3 of cavity 2 aligned about passages 4 and 5 and biased by the respective springs 36.
  • the passage 4 of body 1 is fluidly connected to passage 11 of base 10 of the cartridge
  • passage 5 of body 1 is fluidly connected to passage 12 of base 10 of the cartridge with sealing members 33 preventing leakage laterally outside of passages 4, 5 and 10, 11.
  • the force of spring 36 in addition to hydraulic pressures acting in base 10 of counterbores 14 and 15, biases the whole cartridge against cover 8 maintaining compressive pressure on its components including fixed plate 16 and mobile plate 23.
  • spring 36 exerts a great force, but simply that it should assure an adequate compressive force of sealing members 33 in the absence of pressure against bottom surface 3 of cavity 2.
  • spring 36 exerts a great force, but simply that it should assure an adequate compressive force of sealing members 33 in the absence of pressure against bottom surface 3 of cavity 2.
  • it in part acts on sealing members 33 on precisely an area equal to the difference between the maximum area in cross section of the sealing member and the area of the opening through the shoulder 34.
  • the resultant force is added to the biasing force on the spring in such a way that the compressive force increases on the base end 3 of cavity 2 on an equal basis with the increase in pressure and this causes the net total force to be adequate at all times.
  • base end 3 of chamber 2 of body 1 of the faucet does not require more than a simple smoothing operation.
  • the counterbores 14 and 15 are easily formed and are immediately accessible when the cartridge is not inserted in the cavity of the faucet.
  • the assembly and disassembly of sealing members 33 and springs 34 in counterbores 14 and 15 of base 10 of the cartridge is extremely easy when the cartridge is removed from body 1 of the faucet. Furthermojce, the sealing shoulder sections 34 of members 33 can be inspected when the cartridge is removed from cavity 2 and can be easily replaced when needed in the respective counterbores 14 and 15.
  • Fig. 4 discloses a sealing member 37 that is constructed to eliminate the need for spring 36 shown in Fig. 1 associated with pipe 33.
  • Member 37 is made from resilient material and extends to the end of the respective counterbore located in base 10 of the cartridge. It has a sufficient elasticity to generate the biasing force necessary for the frontal compression against base end 3 of cavity 2 containing the cartridge.
  • the resilient member 37 extends to the end of the counterbore in the base of the cartridge, and when under compression, effects a seal not only frontally against the base of the counterbore but also radially against the cylindrical walls of the same.
  • Fig. 4 illustrates how it is possible to have sealing member 37 penetrate the cavities presented by base 3 of chamber 2 to prevent the accidental rotation of the cartridge.
  • the counterbore in base end 3 does not add significant expense because the counterbore in base 3 for receiving member 37 does not require any precision of measurement in its diameter or in its interfaces, and does not require precision of measurement over its peripheral walls, but should only be smooth at its frontal base.
  • the stiffness of the members' resilient material is not sufficient to assure the cartridge against rotation, it is possible to form an extension of the cartridge from the collars surrounding members 37 to be received in part in the counterbores of base 3 of cavity 2.
  • resilient members 38 act, in principle, like those in Fig. 4, with the added feature that their walls are curved toward their interior. Hydraulic pressure which stabilizes in the interior of member 38 radially flex the arched portion of their walls, generating a force which tends to lengthen its distance from base 10 of the cartridge to base 3 of cavity 2 of body 1 of the faucet. In this way, the resilient force is advantageously increased to stabilize the frontal compressive force between members 37, base 10, and base end 3 of body 1.
  • Fig. 6 demonstrates how resilient members 33 of Fig. 1 can be substituted by tubes 43 of substantially rigid material provided with Q-ring seals made out of resilient elastomeric material.
  • An 0-ring 44 is placed frontally to stabilize the tension with base 3 of chamber 2 containing the cartridge, and an 0-ring 45 is placed peripherally to create a seal with respect to the cylindrical walls of counterbores 14 or 15.
  • the biasing force to load the tube 43 is given by a metallic spiral spring 36, as seen in Fig. 1.
  • tubular sealing members are made of substantially rigid materials are particularly adaptable to prevent the accidental rotation of the cartridge, penetrating into the counterbore in base end 3 of chamber 2 as shown in Fig. 4.
  • the metallic helical spring 36 of Fig. 6 can be replaced by a tube of a resilient elastomeric material which works, from the point of view of its resiliency, analogously to member 37 of Fig. 4.
  • the tube can have its walls curved inward, as illustrated at 46 in Fig. 7, and the hydraulic pressure which acts on the interior of tubes 46, flexes the inwardly arched portion of its walls radially outward which generates a force which tends to bias base 10 of the cartridge away from base 3 of cavity 2 in the body of the faucet.
  • the resilient force is increased advantageously which assures the frontal compressive force of the pipe to bias the cartridge and provide adequate sealing.
  • the counterbores formed in the base of the cartridge by the sealing members can extend through to the fixed plate, and the sealing members could then be made to directly push against the lower surface of the fixed plate, avoiding the necessity of inserting a seal between the fixed plate and the base of the cartridge.
PCT/US1989/004410 1989-10-05 1989-10-05 Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means WO1991005191A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
DE19893991752 DE3991752T (de) 1989-10-05 1989-10-05
CH167891A CH680683A5 (de) 1989-10-05 1989-10-05
AU44214/89A AU638683B2 (en) 1989-10-05 1989-10-05 Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means
JP1-511241A JPH04503553A (ja) 1989-10-05 弾性装置によって補強された連結パイプを有する単一制御レバー式混合蛇口のためのカートリッジ
PCT/US1989/004410 WO1991005191A1 (en) 1989-10-05 1989-10-05 Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means
DE3991752A DE3991752C2 (de) 1989-10-05 1989-10-05 Kartusche für einen Einhebelmischhahn mit durch elastische Mittel verstärkten Verbindungsrohren
FR8914440A FR2654174B1 (fr) 1989-10-05 1989-11-03 Cartouche pour robinet de melange a une poignee avec des conduites de connexion renforcees par des moyens elastiques.
GB9111056A GB2242506B (en) 1989-10-05 1991-05-22 Mixing faucet cartridge
FI912663A FI100425B (fi) 1989-10-05 1991-06-03 Kasetti yksiotesekoitushanaa varten
DK199101067A DK173504B1 (da) 1989-10-05 1991-06-04 Indsats til et et-grebs blandingsbatteri med forbindelsesrør, som er forstærket ved hjælp af elastiske midler

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1989/004410 WO1991005191A1 (en) 1989-10-05 1989-10-05 Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means

Publications (1)

Publication Number Publication Date
WO1991005191A1 true WO1991005191A1 (en) 1991-04-18

Family

ID=22215275

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1989/004410 WO1991005191A1 (en) 1989-10-05 1989-10-05 Cartridge for a single control lever mixing faucet with connecting pipes reinforced by elastic means

Country Status (8)

Country Link
AU (1) AU638683B2 (de)
CH (1) CH680683A5 (de)
DE (2) DE3991752C2 (de)
DK (1) DK173504B1 (de)
FI (1) FI100425B (de)
FR (1) FR2654174B1 (de)
GB (1) GB2242506B (de)
WO (1) WO1991005191A1 (de)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1783408A1 (de) * 2005-11-03 2007-05-09 Studio Tecnico Sviluppo E Ricerche S.T.S.R. S.r.l. Umschaltventil- oder Mehrwege-Umschaltventil-Vorrichtung für Wasseranlagen
NL1034235C2 (nl) * 2007-08-07 2009-02-10 Bosch Sprang Beheer B V Thermovorminrichting met verbeterde drukflenskoeling.
US7721761B2 (en) 2007-01-31 2010-05-25 Masco Corporation Of Indiana Diverter integrated into a side sprayer
US8646476B2 (en) 2008-05-21 2014-02-11 Masco Corporation Of Indiana Integrated kitchen faucet side spray and diverter
US8931500B2 (en) 2012-02-17 2015-01-13 Masco Corporation Of Indiana Two handle centerset faucet
US8985146B2 (en) 2006-05-26 2015-03-24 Delta Faucet Company Faucet including a molded waterway assembly
US8991425B2 (en) 2006-05-26 2015-03-31 Delta Faucet Company Waterway assembly including an overmolded support plate
US9115818B2 (en) 2012-02-28 2015-08-25 Fluehs Drehtechnik Gmbh Single-lever mixing cartridge
US9151397B2 (en) 2008-04-10 2015-10-06 Delta Faucet Company Molded waterway for a two handle faucet
US9403304B2 (en) 2011-03-11 2016-08-02 Delta Faucet Company Centerset faucet body and method of making same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1247777B (it) * 1990-11-16 1994-12-30 Studio Tec Sviluppo Richerche Cartuccia per rubinetto miscelatore, con fondello interno ad effetto idraulico

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2558087A (en) * 1944-02-28 1951-06-26 James W F Holl Fluid seal for rotary fluid valves
US2832561A (en) * 1953-05-04 1958-04-29 James W F Holl Rotary valve with seal seat
US3913612A (en) * 1974-12-16 1975-10-21 Price Pfister Brass Mfg Eccentric shear seal cartridge valve
US4064904A (en) * 1976-04-30 1977-12-27 Price Pfister Brass Mfg. Co. Washerless cartridge valve for faucets
US4453567A (en) * 1982-03-29 1984-06-12 Masco Corporation Valve assembly
US4736772A (en) * 1986-08-30 1988-04-12 Ostertag Ulrich K Sanitary valve
US4738281A (en) * 1985-12-20 1988-04-19 Compagnie Internationale des Produits Sanitaires CIPS Mixing valve

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4200123A (en) * 1978-10-10 1980-04-29 Brandelli Anthony R Ball-type faucet
IT1134430B (it) * 1980-11-24 1986-08-13 Stella Rubinetterie Spa Dispositivo di tenuta per orifizi di ammissione di fluido in rubinetti miscelatori monoleva
DE3309339A1 (de) * 1983-03-16 1984-09-20 Hans Grohe Gmbh & Co Kg, 7622 Schiltach Mischbatterie
GB2158554B (en) * 1984-05-09 1988-05-18 Gevipi Ag A mixer valve with hard material plaques
DE3510060A1 (de) * 1985-03-20 1986-09-25 Karsten Dipl.-Ing. 7148 Remseck Laing Einhebel-mischventil
DE3623585A1 (de) * 1986-07-12 1988-01-28 Knebel & Roettger Fa Abdichtung einer in einem ventil angeordenten steuerkartusche

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2558087A (en) * 1944-02-28 1951-06-26 James W F Holl Fluid seal for rotary fluid valves
US2832561A (en) * 1953-05-04 1958-04-29 James W F Holl Rotary valve with seal seat
US3913612A (en) * 1974-12-16 1975-10-21 Price Pfister Brass Mfg Eccentric shear seal cartridge valve
US4064904A (en) * 1976-04-30 1977-12-27 Price Pfister Brass Mfg. Co. Washerless cartridge valve for faucets
US4453567A (en) * 1982-03-29 1984-06-12 Masco Corporation Valve assembly
US4738281A (en) * 1985-12-20 1988-04-19 Compagnie Internationale des Produits Sanitaires CIPS Mixing valve
US4736772A (en) * 1986-08-30 1988-04-12 Ostertag Ulrich K Sanitary valve

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007051597A1 (de) * 2005-11-03 2007-05-10 Masco Corporation Of Indiana Umschaltventil- oder mehrwege-umschaltventil-vorrichtung für wasseranlagen
EP1783408A1 (de) * 2005-11-03 2007-05-09 Studio Tecnico Sviluppo E Ricerche S.T.S.R. S.r.l. Umschaltventil- oder Mehrwege-Umschaltventil-Vorrichtung für Wasseranlagen
US8985146B2 (en) 2006-05-26 2015-03-24 Delta Faucet Company Faucet including a molded waterway assembly
US9951880B2 (en) 2006-05-26 2018-04-24 Delta Faucet Company Faucet including a molded waterway assembly
US8991425B2 (en) 2006-05-26 2015-03-31 Delta Faucet Company Waterway assembly including an overmolded support plate
US7721761B2 (en) 2007-01-31 2010-05-25 Masco Corporation Of Indiana Diverter integrated into a side sprayer
NL1034235C2 (nl) * 2007-08-07 2009-02-10 Bosch Sprang Beheer B V Thermovorminrichting met verbeterde drukflenskoeling.
US9151397B2 (en) 2008-04-10 2015-10-06 Delta Faucet Company Molded waterway for a two handle faucet
US8646476B2 (en) 2008-05-21 2014-02-11 Masco Corporation Of Indiana Integrated kitchen faucet side spray and diverter
US9243389B2 (en) 2008-05-21 2016-01-26 Delta Faucet Company Integrated kitchen faucet side spray and diverter
US9403304B2 (en) 2011-03-11 2016-08-02 Delta Faucet Company Centerset faucet body and method of making same
US8931500B2 (en) 2012-02-17 2015-01-13 Masco Corporation Of Indiana Two handle centerset faucet
US9115818B2 (en) 2012-02-28 2015-08-25 Fluehs Drehtechnik Gmbh Single-lever mixing cartridge

Also Published As

Publication number Publication date
GB2242506A (en) 1991-10-02
DE3991752C2 (de) 1997-07-10
DK106791D0 (da) 1991-06-04
DK173504B1 (da) 2001-01-15
GB9111056D0 (en) 1991-07-17
AU638683B2 (en) 1993-07-08
FI100425B (fi) 1997-11-28
DE3991752T (de) 1992-01-30
GB2242506B (en) 1993-09-22
FR2654174A1 (fr) 1991-05-10
FI912663A0 (fi) 1991-06-03
CH680683A5 (de) 1992-10-15
AU4421489A (en) 1991-04-28
JPH0652105B1 (de) 1994-07-06
DK106791A (da) 1991-06-04
FR2654174B1 (fr) 1993-01-15

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