WO1990005031A1 - Systeme de revetement transparent d'un recipient en verre - Google Patents

Systeme de revetement transparent d'un recipient en verre Download PDF

Info

Publication number
WO1990005031A1
WO1990005031A1 PCT/US1989/004887 US8904887W WO9005031A1 WO 1990005031 A1 WO1990005031 A1 WO 1990005031A1 US 8904887 W US8904887 W US 8904887W WO 9005031 A1 WO9005031 A1 WO 9005031A1
Authority
WO
WIPO (PCT)
Prior art keywords
container
glass
coating
glass container
coating material
Prior art date
Application number
PCT/US1989/004887
Other languages
English (en)
Inventor
Thomas L. Brandt
Daniel N. Willkens
Original Assignee
Brandt Manufacturing Systems, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brandt Manufacturing Systems, Inc. filed Critical Brandt Manufacturing Systems, Inc.
Publication of WO1990005031A1 publication Critical patent/WO1990005031A1/fr

Links

Classifications

    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17Dry transfer
    • B44C1/1712Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00Labelling other than flat surfaces
    • B65C3/06Affixing labels to short rigid containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00Labelling other than flat surfaces
    • B65C3/06Affixing labels to short rigid containers
    • B65C3/08Affixing labels to short rigid containers to container bodies
    • B65C3/14Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C3/00Labelling other than flat surfaces
    • B65C3/06Affixing labels to short rigid containers
    • B65C3/08Affixing labels to short rigid containers to container bodies
    • B65C3/14Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical
    • B65C3/16Affixing labels to short rigid containers to container bodies the container being positioned for labelling with its centre-line vertical by rolling the labels onto cylindrical containers, e.g. bottles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/08Label feeding
    • B65C9/18Label feeding from strips, e.g. from rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/08Label feeding
    • B65C9/18Label feeding from strips, e.g. from rolls
    • B65C9/1865Label feeding from strips, e.g. from rolls the labels adhering on a backing strip
    • B65C9/1869Label feeding from strips, e.g. from rolls the labels adhering on a backing strip and being transferred directly from the backing strip onto the article
    • B65C9/1873Label feeding from strips, e.g. from rolls the labels adhering on a backing strip and being transferred directly from the backing strip onto the article the transfer involving heating means, e.g. for decals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/20Gluing the labels or articles
    • B65C9/24Gluing the labels or articles by heat
    • B65C9/25Gluing the labels or articles by heat by thermo-activating the glue
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65CLABELLING OR TAGGING MACHINES, APPARATUS, OR PROCESSES
    • B65C9/00Details of labelling machines or apparatus
    • B65C9/40Controls; Safety devices
    • B65C9/42Label feed control
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • B65D23/08Coverings or external coatings
    • B65D23/0807Coatings
    • B65D23/0814Coatings characterised by the composition of the material
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F3/0286Forms or constructions provided with adaptations for labelling machines
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/023Adhesive
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer
    • G09F2003/0258Multilayer without carrier
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0257Multilayer
    • G09F2003/0261Multilayer encapsulated in polymer
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/027Forms or constructions used to hang up an item, e.g. a perfusion bottle
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0272Labels for containers
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0272Labels for containers
    • G09F2003/0273Labels for bottles, flasks
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • G09F2003/0272Labels for containers
    • G09F2003/0275Shock absorbing labels

Definitions

  • the present invention is directed to a technique for protecting glass containers, and more particularly to a technique for applying a coating to protect a label and impart high impact and abrasion resistance to the glass container.
  • a technique for protecting glass containers and more particularly to a technique for applying a coating to protect a label and impart high impact and abrasion resistance to the glass container.
  • the containers are subject to considerable line pressures as well as abrading of one container against another. Surface damage may result and, if severe enough, may result in a weakened bottle. As glass container production rates increase, the frequency and severity of impact and abrasion increases.
  • heat- or UV-curable acrylic materials is a UV-curable acrylic composed of film formers, resins, reactive diluents and additives and butyl acetate solvents.
  • the material is typically sprayed on the bottle, solvent flashed off and the remaining solids cured with ultraviolet light.
  • the resulting coating is at once scratch and abrasion resistant, impact resistant and retains a high gloss throughout its life.
  • Impact resistance of containers with the topcoat has been demonstrated at 30% to 40% greater than like containers with existing surface treatments. Other demonstrations of water immersion for extended time have been successfully concluded with no loss of adhesion or abrasion resistance.
  • tin oxide film prior to annealing and with a second 10 film, e.g., polyethylene, after annealing.
  • a film of a material such as ammonium stearate is deposited after annealing.
  • the topcoat and ammonium stearate are compatible with one another, to insure 15 optimum adhesion of the topcoat to the glass surface while also providing lubricity adequate for conveying through the glass plant operations prior to application of the topcoat.
  • the coating solution would be applied after the labelling, and suitable coating materials to be used are heat cured acrylic and ultraviolet (UV) curable acrylic available from PPG Industries, Inc.
  • suitable coating materials to be used are heat cured acrylic and ultraviolet (UV) curable acrylic available from PPG Industries, Inc.
  • UV curable acrylic available from PPG Industries, Inc.
  • One such material is a UV-curable acrylic identified as R796Z80, which is composed of film formers, resins, reactive diluents and additives and butyl acetate solvents.
  • the material is typically sprayed on the bottle, the solvent flashed off and the remaining solids cured with ultraviolet light.
  • the coating is to be colored blue, or if it is desired to have a UV blocking function, the use of a UV-curable acrylic becomes difficult and a heat- curable acrylic may be used instead.
  • the resulting coating is at once scratch and abrasion resistant, impact resistant and retains a high gloss throughout its life.
  • Impact resistance of containers with the topcoat has been demonstrated at 30% to 40% greater than like containers with existing surface treatments. Other demonstrations of water immersion for extended time have been successfully concluded with no loss of adhesion or abrasion resistance. .
  • the containers are conveyed into a multi-station spray system which has been designed to address the needs of uniform coverage of the container, recycling of the overspray, and recovery and re-use of the evaporated solvent.
  • the • residual heat in the container is adequate to flash off the solvent at an accelerated rate.
  • the flashing off of the solvent will occur at the elevated bottle temperature in the labelling system described above and in copending application A-5477-1. If no such labelling system is used, other heating must be provided, e.g., hot air, to prevent trapping of solvent which would otherwise weaken the coating. Sufficient space is allowed between the spray booth and the cure chamber for flash to occur.
  • the materials are sprayed, it is desirable to prevent any material from contacting the finish of the container.
  • This is the area including the opening, top seal surface, thread or closure cover area and protuberance immediately below.
  • This could be accomplished using a container gripper device designed to completely cover the area described above, e.g., with a split housing which, when closed, dovetails to form a barrier to the spray material. Dipping and flow coating are other processes that may be used to apply the coating.
  • the gripper devices are attached to a conveyor network whose design allows for spacing of the glass containers to optimize the coating and curing of the coating materials.
  • the grippers should also be designed for rotating the container at the spraying and curing positions to insure uniform coating and processing.
  • the application of the coating solution could be accomplished by belt or roller coating as described in copending application A-5477-1 identified above.
  • Alternative methods of applying the topcoat include, but are not limited to, the use of a roller shaped to conform to the contour of the container, a belt flexible enough to conform to the container contour, or flowing the coating over the " container while it is slowly rotated. Dipping may also be advantageous. Each option has its own merits and must be weighed against economics, quality and production rates.
  • the containers are then conveyed to an ultraviolet light cure chamber designed to provide the necessary ultraviolet light exposure to completely cure the topcoat. It has been demonstrated that an energy level of 300 watts/in. for 6 seconds insures a complete cure.
  • the container can be packaged for shipment and subsequent wash, filling and pasteurization, if required, by the various food and beverage packaging operations.
  • the single figure herein illustrates the use of the present invention in conjunction with the labelling system described in copending application A- 5477-1.
  • the coating with ammonium stearate would be performed before the bottles are received at the upper right of the figure along a conveyor 100.
  • the bottles would then be transferred to a loading station 104 one at a time by a star wheel control device 102.
  • the bottles are then moved downwardly onto an indexing table 106 by means of a suitable placement device.
  • the indexing table 106 will include container holders, e.g., suction holders or the like, which are arranged in groups of three, with each group of three being arranged rectilinearly. There may be supports at the neck of each container to absorb pressure during the container transfer.
  • container holders e.g., suction holders or the like, which are arranged in groups of three, with each group of three being arranged rectilinearly.
  • the indexing table is then rotated counterclockwise from the loading station to a container orienting station generally designated at reference character 108.
  • the container may here be rotated to a particular orientation, although this will be unnecessary in many container labeling systems.
  • the rotating of the container would preferably be performed by rotation of individual container holder suction cups on the indexing table 106 until the correct position is detected, e.g., by suitable photo-electric means, at which point the holders would be locked in their correct positions. (If locked, they will have to be unlocked prior to the label application step, as the label application step requires rotation of the bottles as will be described in more detail below. )
  • the indexing table 106 is further rotated to bring the bottles to the label transfer station where the labels are applied, and the indexing table is then rotated to a coating station 114 where the coating of this invention is applied.
  • the indexing table 106 is then further rotated to bring the labeled and coated bottles to an unloading station where each container is off-loaded onto a container conveyor.
  • the bottles could be removed. All bottles could be removed from the indexing table 106 to a single conveyor 120, taking care to ensure that the coatings are not disturbed. It may, be necessary, with suitable care taken, to use an air knife. It may, however, be necessary to move the bottles by clamping them at their "finish" and carrying them onto the conveyor 120 in a known manner. It is also to be remembered that the bottles are held in groups of three on the indexing table 106. In the interest of speed, it would be possible to arrange three separate conveyors 120 each for receiving one of the three bottles in each group from the indexing table 106.
  • the coating on the bottles is cured in a suitable manner, e.g., by heat or U-V energy.
  • a suitable manner e.g., by heat or U-V energy.
  • the conveyor 120 carries the bottles to a further container inspection area (if desired) and thence to a packing or filling station.
  • a topcoating material as described herein will increase abrasion and impact resistance of the glass container, will be waterproof and unaffected by the contents of any food or beverage, will be glossy and will not be abraded by like material, and will cover flaws and irregularities on the surface of glass containers such as to render them nearly invisible. It will also bond to a protective label.

Abstract

Le revêtement de surface pour des récipients en verre est résistant à l'abrasion, présente un fini très brillant et accroît la résistance aux impacts. L'invention concerne également un procédé d'application à haute vitesse et à la chaîne de ce revêtement sur des récipients en verre ainsi que sa polymérisation. Le revêtement adhère au récipient en verre pendant toutes les diverses opérations de conditionnement d'aliments et de boissons ainsi que lors de la manipulation dans les commerces et par le consommateur.
PCT/US1989/004887 1988-11-07 1989-11-07 Systeme de revetement transparent d'un recipient en verre WO1990005031A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26787788A 1988-11-07 1988-11-07
US267,877 1988-11-07

Publications (1)

Publication Number Publication Date
WO1990005031A1 true WO1990005031A1 (fr) 1990-05-17

Family

ID=23020505

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US1989/004888 WO1990005353A1 (fr) 1988-11-07 1989-11-07 Etiquette pour recipient et procede d'application de l'etiquette
PCT/US1989/004886 WO1990005667A1 (fr) 1988-11-07 1989-11-07 Procede d'application d'un revetement couleur sur un recipient en verre
PCT/US1989/004885 WO1990005088A1 (fr) 1988-11-07 1989-11-07 Etiquette pour recipient et systeme d'application de l'etiquette
PCT/US1989/004887 WO1990005031A1 (fr) 1988-11-07 1989-11-07 Systeme de revetement transparent d'un recipient en verre

Family Applications Before (3)

Application Number Title Priority Date Filing Date
PCT/US1989/004888 WO1990005353A1 (fr) 1988-11-07 1989-11-07 Etiquette pour recipient et procede d'application de l'etiquette
PCT/US1989/004886 WO1990005667A1 (fr) 1988-11-07 1989-11-07 Procede d'application d'un revetement couleur sur un recipient en verre
PCT/US1989/004885 WO1990005088A1 (fr) 1988-11-07 1989-11-07 Etiquette pour recipient et systeme d'application de l'etiquette

Country Status (5)

Country Link
EP (4) EP0441858B1 (fr)
JP (2) JPH04503260A (fr)
AT (4) ATE157059T1 (fr)
DE (4) DE68928740T2 (fr)
WO (4) WO1990005353A1 (fr)

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DE4130682A1 (de) * 1991-09-14 1993-03-18 Herberts Gmbh Verfahren, ueberzugsmittel und vorrichtung zur herstellung von beschichteten glashohlkoerpern
DE4302123A1 (de) * 1993-01-27 1994-07-28 Herberts Gmbh Verfahren zum Bedrucken von Glashohlkörpern
EP0993871A3 (fr) * 1996-05-07 2000-06-07 Firma Hermann Heye Récipients en verre pourvus d'un revêtement
US7091162B2 (en) 2003-07-03 2006-08-15 Johnsondiversey, Inc. Cured lubricant for container coveyors
US7976947B2 (en) 2005-08-10 2011-07-12 Dupont Polymer Powders Switzerland Sarl Article of manufacture comprising surfaces of thermoplastic composites coated with a powder coating composition
US9034442B2 (en) 2012-11-30 2015-05-19 Corning Incorporated Strengthened borosilicate glass containers with improved damage tolerance
US9428302B2 (en) 2012-06-28 2016-08-30 Corning Incorporated Delamination resistant glass containers with heat-tolerant coatings
US9668936B2 (en) 2012-02-28 2017-06-06 Corning Incorporated Glass articles with low-friction coatings
US10065884B2 (en) 2014-11-26 2018-09-04 Corning Incorporated Methods for producing strengthened and durable glass containers
US10117806B2 (en) 2012-11-30 2018-11-06 Corning Incorporated Strengthened glass containers resistant to delamination and damage
US10737973B2 (en) 2012-02-28 2020-08-11 Corning Incorporated Pharmaceutical glass coating for achieving particle reduction
US10899659B2 (en) 2014-09-05 2021-01-26 Corning Incorporated Glass articles and methods for improving the reliability of glass articles
US11208348B2 (en) 2015-09-30 2021-12-28 Corning Incorporated Halogenated polyimide siloxane chemical compositions and glass articles with halogenated polyimide siloxane low-friction coatings
US11497681B2 (en) 2012-02-28 2022-11-15 Corning Incorporated Glass articles with low-friction coatings
US11772846B2 (en) 2015-10-30 2023-10-03 Corning Incorporated Glass articles with mixed polymer and metal oxide coatings

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DE10014466A1 (de) * 1999-12-24 2001-07-05 Gerd Stoffel Verfahren und Vorrichtung zum Herstellen von mit einem Aufdruck versehenen Behälter
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DE10019355A1 (de) * 2000-04-18 2001-10-31 Schott Glas Glaskörper mit erhöhter Festigkeit
EP1193185A1 (fr) 2000-10-02 2002-04-03 Heineken Technical Services B.V. Récipient en verre à revêtement amélioré
NL1021968C2 (nl) 2002-11-21 2004-05-26 Heineken Tech Services Etiketteerinrichting voorzien van een oscillerende etikettenbaan-positioneringseenheid, alsmede werkwijze voor het aanbrengen van een etiket.
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JP2007326224A (ja) * 2005-02-28 2007-12-20 Yoshino Kogyosho Co Ltd 転写フィルム及び転写フィルムで加飾された合成樹脂製成形品
US20110250346A1 (en) * 2010-04-07 2011-10-13 Remington Jr Michael P Adhesion of organic coatings on glass
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CN112384371B (zh) 2018-07-02 2022-08-05 阿克特加北美技术股份有限公司 用于对基材进行装饰的系统和方法
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US10034816B2 (en) 2012-02-28 2018-07-31 Corning Incorporated Glass articles with low-friction coatings
US11071689B2 (en) 2012-02-28 2021-07-27 Corning Incorporated Glass articles with low-friction coatings
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US11951072B2 (en) 2012-11-30 2024-04-09 Corning Incorporated Glass containers with improved strength and improved damage tolerance
US9034442B2 (en) 2012-11-30 2015-05-19 Corning Incorporated Strengthened borosilicate glass containers with improved damage tolerance
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US10065884B2 (en) 2014-11-26 2018-09-04 Corning Incorporated Methods for producing strengthened and durable glass containers
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Also Published As

Publication number Publication date
ATE293825T1 (de) 2005-05-15
EP0441858A4 (en) 1992-05-27
EP0441879B1 (fr) 1998-07-15
DE68929534T2 (de) 2006-02-23
EP0441858A1 (fr) 1991-08-21
EP0945842A2 (fr) 1999-09-29
DE68929237T2 (de) 2000-12-14
EP0737954B1 (fr) 2000-08-02
DE68929534D1 (de) 2005-05-25
ATE195193T1 (de) 2000-08-15
JPH04503260A (ja) 1992-06-11
JPH04501694A (ja) 1992-03-26
DE68928268T2 (de) 1998-03-19
ATE157059T1 (de) 1997-09-15
DE68928740D1 (de) 1998-08-20
WO1990005353A1 (fr) 1990-05-17
EP0945842A3 (fr) 2000-03-22
DE68928740T2 (de) 1999-04-22
EP0737954A2 (fr) 1996-10-16
WO1990005088A1 (fr) 1990-05-17
EP0945842B1 (fr) 2005-04-20
WO1990005667A1 (fr) 1990-05-31
ATE168344T1 (de) 1998-08-15
EP0441879A4 (en) 1992-02-26
DE68929237D1 (de) 2000-09-07
DE68928268D1 (de) 1997-09-25
EP0441858B1 (fr) 1997-08-20
EP0441879A1 (fr) 1991-08-21
EP0737954A3 (fr) 1996-10-23

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