WO1989002952A1 - Pate a papier commerciale, procede de fabrication et utilisation d'une telle pate dans la fabrication de papier - Google Patents
Pate a papier commerciale, procede de fabrication et utilisation d'une telle pate dans la fabrication de papier Download PDFInfo
- Publication number
- WO1989002952A1 WO1989002952A1 PCT/SE1988/000466 SE8800466W WO8902952A1 WO 1989002952 A1 WO1989002952 A1 WO 1989002952A1 SE 8800466 W SE8800466 W SE 8800466W WO 8902952 A1 WO8902952 A1 WO 8902952A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- paper
- pulp
- fibres
- coloured
- paper pulp
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/76—Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
- D21H23/765—Addition of all compounds to the pulp
Definitions
- Cellulosic market paper pulp is manufactured by cooking a raw material of wood chips in suitable diges ⁇ tive chemicals with a view to removing the lignin of the wood and exposing its cellulosic fibres.
- the woody raw material may be both softwood and hardwood, however in most cases being softwood, e.g. from pine and spruce.
- the delignified fibres are washed to re ⁇ move dissolved organic substance and residual digestive chemicals by being abundantly diluted in water so as to form a suspension which is passed on to a suitable dewa- tering device, generally a fourdrinier wire on which the fibres are dewatered, whereupon they are finally dried, e.g.
- the pulp is also bleached in a special bleaching step between cooking and drying, primarily in order to increase the bright ⁇ ness of the pulp. Such drying is conducted to dry so ⁇ lids contents considerably exceeding 80%.
- the dry solids content of paper pulp in sheet or web form is about 90% and that of fluff pulp about 92-93%.
- Dried paper pulp of the above generally described type is supplied to special paper mills where paper is manufactured (in some cases, there are also integrated manufacturing plants in which the pulp mill is integrat- ed with or directly connected to the paper mill. In these cases, the pulp is however not supplied in the dried state, but in a still water-suspended state from the pulp mill to the paper mill or paper machine).
- papermaking is carried out in such a manner that the pulp, optionally together with one or more additional paper pulps, is slushed in water in a so- called machine vat so as to yield a stock which is processed in different ways, primarily by beating in a mill or a refiner, before it is distributed via a head box or the like onto a forming wire (alterna ⁇ tively, a cylinder or the like) on which a coherent web of fibres bonded together is formed as the water in the stock drains through the wire.
- the web is there ⁇ after caused to pass a number of press rolls and a drying station in which it is dried so as to yield finished paper.
- the paper requires colour ⁇ ing.
- Stock colouring which is the commonest colouring method, is done by adding a colouring agent to the stock, always containing uncoloured pulp fibres, in a step somewhere between the slushing of the pulp in the machine vat and the forming on the wire, gene ⁇ rally as early as the machine vat, and fixing it to the fibres in a suitable manner.
- Surface colouring is carried out by adding a dye solution to the formed paper web when it has passed the drying station, for instance in a size press located after the drying station.
- Common agents for stock colouring are so ⁇ dium salts of organic sulphonic acids (C H ?
- Dry-formed paper is manufactured basically in that the pulp supplied in sheet or web form (alternatively in fluff form) is shredded and finely divided, and incorporated in a flow of air which, like the stock, is caused to pass a form ⁇ ing wire on which a paper web of substantially uniform thickness is formed.
- this technique requires the addition of special binders serving to bond the separate fibres together so as to form a coherent web.
- the present invention primarily aims at creating conditions for allowing a simple and high-quality co- louring of dry-formed tissue paper and, to this end, relates to a dried market paper pulp manufactured from a raw material of wood chips, which pulp is character ⁇ ised in that the fibres therein are coloured by means of a colouring agent added to the fibres while they still are in a water suspension, but prior to final drying.
- the invention further relates to a process for mak ⁇ ing market paper pulp, comprising the steps of cooking a raw material of wood chips for delignifying said raw material and exposing the cellulosic fibres therein, washing the thus exposed fibres by dilution in a water suspension and, after dewatering the fibres, drying them prior to sale.
- Characteristic of the inventive process is that the fibres are coloured prior to the final drying, more particularly by adding a colouring agent in a manner known per se or in any optional man ⁇ ner to said fibre-water suspension, so as to produce a dried market pulp the individual fibres of which are coloured.
- Colouring the pulp in accordance with the invention in connection with the very manufacture thereof gives the advantage not only that coloured paper can be manufactured by dry-forming without requiring any co ⁇ louring operation whatsoever in the paper mill or paper machine, but also that colouring can be carried out by conventional stock colouring technique, yielding a homo ⁇ geneous and durable colouring of the fibres.
- Another major advantage of the invention is that it allows manu ⁇ facturing not only a dry-formed but also a wet-formed paper of veined structure.
- the paper can be manufactured from two or more paper pulps at least one of which is coloured while the other is uncoloured or differently coloured.
- the inventive pulp-making process can be carried out, for example in the manner appearing from the en ⁇ closed flow diagram.
- a suspension of cellulosic fibres and water (pulp concentration of about 1%) is pumped to a first mixer 1 in which a hardening agent is added to adjust the hardness of the water to 5° dH.
- a colouring agent supplied in a following mixer 2.
- the colouring agent may be an azo dye, for instance of the type commercially available under the trade designation CARTASOL ROT, which is dosed in an amount of 5% by weight based on the amount of dry pulp.
- the colouring agent After the addition of the colouring agent, this should have a residence time of about 5 minutes in a reaction vessel 3.
- a fixing agent for instance a quarternary polyhydroxy- alkylene polyamine sold under the designation CARTAFIX FF, is dosed at 4 in order that the last dye residues should be added to the cellulose and also in order to obtain sufficient colour fastness.
- the fibre suspension passes through a reaction vessel 5 in which the fibres supplied with fixing agent are allowed to remain for about one minute.
- the cellulosic fibres are now coloured.
- the defibering mills used in dry-forming plants require that the pulp be supplied with a debonding agent which reduces the fibre bonds when the cellulose is dried.
- a cellulose as above can also be manufactured without any debonding agent but in that case, the defibering mill of the dry- forming plant must have a considerably increased capacity.
- the colouring agent here discussed is added to the fibres most advantageously while they remain sus ⁇ pended in water at low concentrations, e.g. about 1%, it is conceivable to add the colouring agent also at higher pulp concentrations, e.g. even up to about 50%, which may prevail in press sections after the wire. The main point is that the addition of the colouring agent is carried out prior to the final drying.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
Abstract
Pâte à papier commerciale séchée réalisée à partir d'une matière première de copeaux de bois, caractérisée en ce que les fibres qu'elle contient sont colorées au moyen d'un agent de coloration ajouté aux fibres pendant qu'elles se trouvent encore dans une suspension d'eau, mais avant le séchage final. On peut ensuite utiliser avantageusement la pâte à papier pour la fabrication de papier mousseline formé à sec et de haute qualité, ayant une couleur uniforme.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8703654-7 | 1987-09-22 | ||
SE8703654A SE462108B (sv) | 1987-09-22 | 1987-09-22 | Framstaellning av torrformat tissuepapper, varvid en faergad massa anvaendes |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1989002952A1 true WO1989002952A1 (fr) | 1989-04-06 |
Family
ID=20369639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1988/000466 WO1989002952A1 (fr) | 1987-09-22 | 1988-09-12 | Pate a papier commerciale, procede de fabrication et utilisation d'une telle pate dans la fabrication de papier |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU2484888A (fr) |
SE (1) | SE462108B (fr) |
WO (1) | WO1989002952A1 (fr) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000066835A1 (fr) * | 1999-04-30 | 2000-11-09 | Kimberly-Clark Worldwide, Inc. | Articles en papier et procede pour l'application d'un additif chimique adsorbable a des fibres cellulosiques |
WO2003035979A1 (fr) * | 2001-10-25 | 2003-05-01 | M-Real Oyj | Procede de fabrication d'une pate chimique contenant une charge |
US6582560B2 (en) | 2001-03-07 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
EP1342845A1 (fr) * | 2002-03-06 | 2003-09-10 | SCA Hygiene Products GmbH | Papier tissu a couches multiples |
FR2839519A1 (fr) * | 2002-05-07 | 2003-11-14 | Weyerhaeuser Compagny | Pate blanchie pour duvet de cellulose, et procede pour sa production |
US6749721B2 (en) | 2000-12-22 | 2004-06-15 | Kimberly-Clark Worldwide, Inc. | Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition |
EP1659218A1 (fr) * | 2004-11-19 | 2006-05-24 | The Procter & Gamble Company | Papier-tissu avec fibres de soie |
US7670459B2 (en) | 2004-12-29 | 2010-03-02 | Kimberly-Clark Worldwide, Inc. | Soft and durable tissue products containing a softening agent |
US7749356B2 (en) | 2001-03-07 | 2010-07-06 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
WO2010144475A1 (fr) * | 2009-06-09 | 2010-12-16 | Buckeye Technologies Inc. | Feuille de comminution en cellulose colorée, matériau non tissé coloré et leurs procédés de fabrication |
WO2012012633A1 (fr) * | 2010-07-22 | 2012-01-26 | International Paper Company | Procédé de préparation de feuille de pâte défibrée avec colorant cationique et agent tensioactif dispersant et feuille de pâte défibrée fabriquée grâce à ce procédé |
CN104220671A (zh) * | 2009-08-05 | 2014-12-17 | 国际纸业公司 | 包含阳离子三价金属和解胶剂的组合物及其制造方法和使用该组合物提高绒毛浆质量的方法 |
US8951626B2 (en) | 2008-04-07 | 2015-02-10 | Sca Hygiene Products Ab | Hygiene or wiping product comprising at least one patterned ply and method for patterning the ply |
US8974636B2 (en) | 2010-07-20 | 2015-03-10 | International Paper Company | Composition containing a multivalent cationic metal and amine-containing anti-static agent and methods of making and using |
US10260201B2 (en) | 2009-08-05 | 2019-04-16 | International Paper Company | Process for applying composition containing a cationic trivalent metal and debonder and fluff pulp sheet made from same |
US10415190B2 (en) | 2009-08-05 | 2019-09-17 | International Paper Company | Dry fluff pulp sheet additive |
US20220178082A1 (en) * | 2019-02-12 | 2022-06-09 | Stora Enso Oyj | Method of producing a molded fiber product and molded fiber product |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2039034A1 (de) * | 1969-08-08 | 1971-02-25 | Sandoz Ag | Verfahren zum gleichmaessigen Faerben und/oder optischen Aufhellen von Papier |
SE369428B (fr) * | 1969-07-24 | 1974-08-26 | K Kroeyer | |
DE3041682A1 (de) * | 1979-11-09 | 1981-05-21 | Colgate-Palmolive Co., 10022 New York, N.Y. | Farbstoffmischung zum aufhellen und weissmachen von zellulosematerial und ihre verwendung zur herstellung von saugfaehigen wegwerfartikeln mit verbesserter farbe |
SE436768B (sv) * | 1983-06-09 | 1985-01-21 | Korsnaes Marma Ab | Forfarande for framstellning av fluffmassa forfarande for framstellning av fluffmassa |
-
1987
- 1987-09-22 SE SE8703654A patent/SE462108B/sv not_active IP Right Cessation
-
1988
- 1988-09-12 AU AU24848/88A patent/AU2484888A/en not_active Abandoned
- 1988-09-12 WO PCT/SE1988/000466 patent/WO1989002952A1/fr unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE369428B (fr) * | 1969-07-24 | 1974-08-26 | K Kroeyer | |
DE2039034A1 (de) * | 1969-08-08 | 1971-02-25 | Sandoz Ag | Verfahren zum gleichmaessigen Faerben und/oder optischen Aufhellen von Papier |
DE3041682A1 (de) * | 1979-11-09 | 1981-05-21 | Colgate-Palmolive Co., 10022 New York, N.Y. | Farbstoffmischung zum aufhellen und weissmachen von zellulosematerial und ihre verwendung zur herstellung von saugfaehigen wegwerfartikeln mit verbesserter farbe |
SE436768B (sv) * | 1983-06-09 | 1985-01-21 | Korsnaes Marma Ab | Forfarande for framstellning av fluffmassa forfarande for framstellning av fluffmassa |
Cited By (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6423183B1 (en) | 1997-12-24 | 2002-07-23 | Kimberly-Clark Worldwide, Inc. | Paper products and a method for applying a dye to cellulosic fibers |
WO2000066835A1 (fr) * | 1999-04-30 | 2000-11-09 | Kimberly-Clark Worldwide, Inc. | Articles en papier et procede pour l'application d'un additif chimique adsorbable a des fibres cellulosiques |
US6749721B2 (en) | 2000-12-22 | 2004-06-15 | Kimberly-Clark Worldwide, Inc. | Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition |
US7678232B2 (en) | 2000-12-22 | 2010-03-16 | Kimberly-Clark Worldwide, Inc. | Process for incorporating poorly substantive paper modifying agents into a paper sheet via wet end addition |
US6582560B2 (en) | 2001-03-07 | 2003-06-24 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
US7749356B2 (en) | 2001-03-07 | 2010-07-06 | Kimberly-Clark Worldwide, Inc. | Method for using water insoluble chemical additives with pulp and products made by said method |
AU2002335317B2 (en) * | 2001-10-25 | 2007-01-04 | M-Real Oyj | Method for manufacturing filler containing chemical pulp |
WO2003035979A1 (fr) * | 2001-10-25 | 2003-05-01 | M-Real Oyj | Procede de fabrication d'une pate chimique contenant une charge |
EP1342845A1 (fr) * | 2002-03-06 | 2003-09-10 | SCA Hygiene Products GmbH | Papier tissu a couches multiples |
FR2839519A1 (fr) * | 2002-05-07 | 2003-11-14 | Weyerhaeuser Compagny | Pate blanchie pour duvet de cellulose, et procede pour sa production |
EP1659218A1 (fr) * | 2004-11-19 | 2006-05-24 | The Procter & Gamble Company | Papier-tissu avec fibres de soie |
WO2006055789A1 (fr) * | 2004-11-19 | 2006-05-26 | The Procter & Gamble Company | Papier de soie avec fibres de soie |
JP2008518745A (ja) * | 2004-11-19 | 2008-06-05 | ザ プロクター アンド ギャンブル カンパニー | シルク繊維入りティッシュ・ペーパー |
US7670459B2 (en) | 2004-12-29 | 2010-03-02 | Kimberly-Clark Worldwide, Inc. | Soft and durable tissue products containing a softening agent |
US8951626B2 (en) | 2008-04-07 | 2015-02-10 | Sca Hygiene Products Ab | Hygiene or wiping product comprising at least one patterned ply and method for patterning the ply |
WO2010144475A1 (fr) * | 2009-06-09 | 2010-12-16 | Buckeye Technologies Inc. | Feuille de comminution en cellulose colorée, matériau non tissé coloré et leurs procédés de fabrication |
EP2267206A1 (fr) | 2009-06-09 | 2010-12-29 | Buckeye Technologies Inc. | Couche à cellulose teint, non tissé teinté et les procédés de fabrication |
CN102575394A (zh) * | 2009-06-09 | 2012-07-11 | 博凯技术公司 | 染色纤维素碎片、染色非织造材料和它们的生产方法 |
EP2749680A1 (fr) | 2009-06-09 | 2014-07-02 | Buckeye Technologies Inc. | Couche à cellulose teint, non tissé teinté et les procédés de fabrication |
CN104220671A (zh) * | 2009-08-05 | 2014-12-17 | 国际纸业公司 | 包含阳离子三价金属和解胶剂的组合物及其制造方法和使用该组合物提高绒毛浆质量的方法 |
CN104220671B (zh) * | 2009-08-05 | 2016-01-20 | 国际纸业公司 | 包含阳离子三价金属和解胶剂的组合物及其制造方法和使用该组合物提高绒毛浆质量的方法 |
US9260820B2 (en) | 2009-08-05 | 2016-02-16 | International Paper Company | Composition containing a cationic trivalent metal and debonder and methods of making and using the same to enhance fluff pulp quality |
US10260201B2 (en) | 2009-08-05 | 2019-04-16 | International Paper Company | Process for applying composition containing a cationic trivalent metal and debonder and fluff pulp sheet made from same |
US10415190B2 (en) | 2009-08-05 | 2019-09-17 | International Paper Company | Dry fluff pulp sheet additive |
US10513827B2 (en) | 2009-08-05 | 2019-12-24 | International Paper Company | Composition containing a cationic trivalent metal and debonder and methods of making and using the same to enhance fluff pulp quality |
US8974636B2 (en) | 2010-07-20 | 2015-03-10 | International Paper Company | Composition containing a multivalent cationic metal and amine-containing anti-static agent and methods of making and using |
CN103003488A (zh) * | 2010-07-22 | 2013-03-27 | 国际纸业公司 | 使用阳离子型染料和解胶剂型表面活性剂制造绒毛浆片材的方法和由该方法制得的绒毛浆片材 |
US8871054B2 (en) | 2010-07-22 | 2014-10-28 | International Paper Company | Process for preparing fluff pulp sheet with cationic dye and debonder surfactant |
WO2012012633A1 (fr) * | 2010-07-22 | 2012-01-26 | International Paper Company | Procédé de préparation de feuille de pâte défibrée avec colorant cationique et agent tensioactif dispersant et feuille de pâte défibrée fabriquée grâce à ce procédé |
US20220178082A1 (en) * | 2019-02-12 | 2022-06-09 | Stora Enso Oyj | Method of producing a molded fiber product and molded fiber product |
Also Published As
Publication number | Publication date |
---|---|
SE8703654L (sv) | 1989-03-23 |
SE462108B (sv) | 1990-05-07 |
AU2484888A (en) | 1989-04-18 |
SE8703654D0 (sv) | 1987-09-22 |
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