WO1988005812A1 - Shampoo - Google Patents

Shampoo Download PDF

Info

Publication number
WO1988005812A1
WO1988005812A1 PCT/US1988/000357 US8800357W WO8805812A1 WO 1988005812 A1 WO1988005812 A1 WO 1988005812A1 US 8800357 W US8800357 W US 8800357W WO 8805812 A1 WO8805812 A1 WO 8805812A1
Authority
WO
WIPO (PCT)
Prior art keywords
formula
weight percent
shampoo
alk
water
Prior art date
Application number
PCT/US1988/000357
Other languages
English (en)
French (fr)
Inventor
Marvin E. Goldberg
Elizabeth I. Starr
Original Assignee
Revlon, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Revlon, Inc. filed Critical Revlon, Inc.
Priority to BR8805088A priority Critical patent/BR8805088A/pt
Publication of WO1988005812A1 publication Critical patent/WO1988005812A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/02Preparations for cleaning the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers

Definitions

  • the present invention relates to shampoo formulations. More particuarly, it relates to shampoos useful for washing the hair of children, who are particularly sensitive to eye irritation that can be caused by some known shampoo products.
  • the invention relates in particular to a shampoo formulation that can be dispensed from a pressurized container as a mousse-type product.
  • the present invention is a water-based shampoo product comprising
  • R cell is the residue of an anhydroglucose unit; y is an integer having a value of from about
  • each R independently represents a substituent group of the general formula (2):
  • m is an integer having a value of 0 to 10
  • n is 0, 1, 2 or 3
  • p is an integer having a value of 0 to 10
  • q is 0 or 1
  • R is -H, -COOH, -COONa
  • (ALK) is a C 10 -C 18 saturated or mono ⁇ unsaturated straight or branch-chain alkyl or alkylene group and i is 1-6;
  • R (ALK) is a C 10 -C 18 saturated or monounsaturated straight or branched-chain alkyl or alkylene group/ and j is 1-5;
  • the present invention contains as indicated several components which in combination provide a product having useful properties and free of undesirable side effects.
  • the product includes water, typically in an amount comprising about 50 to about 75 weight percent.
  • One component is a quaternary nitrogen-containing cellulose ether of the formula (1) disclosed hereinabove. Particularly preferred are derivatives of hydroxyethyl cellulose/ including the compound known generically as polyquaternium-10 available commercially from Union Carbide.
  • the quaternary nitrogen-containing cellulose ether can be synthesized following the procedure described generally in U.S. Patent No. 3,472,840.
  • the amount of this component can generally range from 0.01 to 1.0 weight percent.
  • a preferred amount is 0.1 to 0.5 weight percent.
  • anhydroglucose residue refers to a glucopyranose in which three of the hydroxy groups have been removed from three of its positions on the backbone of the glucose molecule and which is capable of being substituted to the OR group at these positions.
  • Examples of anhydroglucose residue include:
  • the preferred anhydroglucose residue is:
  • Another component in the shampoo of the present invention is an anionic surfactant of the general formula (3) described above.
  • the preferred embodiment of this ingredient is sodium laureth sulfate (3 EtO), that is, the sodium salt of sulfated ethoxylated lauryl alcohol in which, in the above formula (3), (Alk) is CH 3 (CH 2 ) 11 - and i is 3.
  • EtO sodium laureth sulfate
  • (Alk) is CH 3 (CH 2 ) 11 - and i is 3.
  • the preferred component is available commercially. This component can be present in an amount ranging from about 5 to about 50 weight percent of the composition/ and more preferably about 10 to about 40 weight percent.
  • Another component of the present invention is a betaine of the formula (4) given above.
  • the preferred embodiment of this component is cocamidopropyl betaine, a commercially available product in which in formula (4) above the substitutent (ALK) is derived from coconut oil and j is 3.
  • This component can be present generally in the amount ranging from about 2 to about 20 weight percent of the composition, and more preferably about 2 to about 10 weight percent.
  • Another component of the present invention is 0.05 to 1.0 weight percent of a polyoxyethylene of the general formula (5) given above.
  • a preferred range is 0.1 to 0.5 weight percent.
  • the degree of polymerization d can be about 20,000 to about
  • the preferred polymer in which the degree of polymerization is about 21,000 is available commercially and is known generically as PEG-21M.
  • the composition of the present invention also preferably contains benzyl alcohol, in an amount ranging from about 0.1 to about 2.0 weight percent and more preferably about 0.3 to about 0.7 weight percent.
  • composition of the present invention can also optionally contain preservatives, such as methyl paraben and/or propyl paraben. in an effective amount which will generally be up to about 0.5 weight percent of the composition.
  • preservatives such as methyl paraben and/or propyl paraben.
  • the composition can also optionally contain components to provide cosmetically and esthetically acceptable fragrance; examples of such components are numerous and well known to those skilled in this art.
  • the amount of fragrance is generally up to about 0.5 weight percent or may range up to about 1.0 weight percent.
  • composition of the present invention can be prepared by simply mixing together each of the above components in the water base.
  • the resulting composition is packaged in a pressurized dispensing system, containing typically 75-99 percent by weight of the composition and. the balance a propellant such as any of the hydrocarbons or halogenated hydrocarbons well known for use in this type of application.
  • the mixture and propellant are charged into a pressurized container fitted with an appropriate aerosol dispensing nozzle.
  • One example of a satisfactory shampoo composition in accordance with the present invention is the following: Ingredient Amount (wt.%)
  • This shampoo vehicle contains both anionic and cationic materials and is relatively mild upon contact with the eyes. It is superior in performance to known shampoos in mildness, cleaning, rinseability and conditioning properties.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical & Material Sciences (AREA)
  • Veterinary Medicine (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Cosmetics (AREA)
PCT/US1988/000357 1987-01-30 1988-01-29 Shampoo WO1988005812A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BR8805088A BR8805088A (pt) 1987-01-30 1988-01-29 Xampu

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US916787A 1987-01-30 1987-01-30
US009,167 1987-01-30

Publications (1)

Publication Number Publication Date
WO1988005812A1 true WO1988005812A1 (en) 1988-08-11

Family

ID=21735980

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1988/000357 WO1988005812A1 (en) 1987-01-30 1988-01-29 Shampoo

Country Status (7)

Country Link
EP (1) EP0301082A4 (ja)
JP (1) JPH01502030A (ja)
AU (1) AU600108B2 (ja)
BR (1) BR8805088A (ja)
NZ (1) NZ223355A (ja)
WO (1) WO1988005812A1 (ja)
ZA (1) ZA88646B (ja)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4992266A (en) * 1989-08-14 1991-02-12 S. C. Johnson & Son, Inc. Reducing the ocular irritancy of anionic shampoos
EP0636686A1 (fr) * 1993-07-28 1995-02-01 L'oreal Composition de lavage des fibres kératiniques à base de polymères dérivés du chitosane
EP0686388A1 (en) * 1994-05-12 1995-12-13 Kao Corporation Aerosol hairdressing composition
EP0769934A1 (en) * 1994-08-24 1997-05-02 The Procter & Gamble Company Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties
EP0796611A2 (en) * 1996-03-18 1997-09-24 Unilever Plc Hair styling mousse
WO1997048374A2 (en) * 1996-06-20 1997-12-24 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
WO1997048375A2 (en) * 1996-06-20 1997-12-24 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
WO1998027935A1 (en) * 1996-12-20 1998-07-02 The Procter & Gamble Company Foaming personal cleansing product
WO1998027938A1 (en) * 1996-12-20 1998-07-02 The Procter & Gamble Company Foaming personal cleansing product
US6440923B1 (en) 1998-12-24 2002-08-27 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Detergent composition

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3944663A (en) * 1971-06-16 1976-03-16 Colgate Palmolive Company Mild light duty detergent containing homopolymers of ethylene oxide
US4201766A (en) * 1977-03-02 1980-05-06 L'oreal Hair conditioning composition and method of using the same
US4304563A (en) * 1979-02-27 1981-12-08 Societe Anonyne Dite: L'oreal Composition and process for the treatment of keratinic materials based on fluorine derivatives
US4372869A (en) * 1981-05-15 1983-02-08 Johnson & Johnson Baby Products Company Detergent compositions
US4412944A (en) * 1980-02-12 1983-11-01 Alcolac, Inc. High foaming, low eye irritation cleaning compositions containing ethoxylated anionic (C13-C30) sulphates
US4477375A (en) * 1982-01-29 1984-10-16 L'oreal Cleaning product for the hair and skin, based on acylisethionates and cationic polymers

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816616A (en) * 1971-11-30 1974-06-11 Warner Lambert Co Unitary shampoo and cream rinse compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3944663A (en) * 1971-06-16 1976-03-16 Colgate Palmolive Company Mild light duty detergent containing homopolymers of ethylene oxide
US4201766A (en) * 1977-03-02 1980-05-06 L'oreal Hair conditioning composition and method of using the same
US4304563A (en) * 1979-02-27 1981-12-08 Societe Anonyne Dite: L'oreal Composition and process for the treatment of keratinic materials based on fluorine derivatives
US4412944A (en) * 1980-02-12 1983-11-01 Alcolac, Inc. High foaming, low eye irritation cleaning compositions containing ethoxylated anionic (C13-C30) sulphates
US4372869A (en) * 1981-05-15 1983-02-08 Johnson & Johnson Baby Products Company Detergent compositions
US4477375A (en) * 1982-01-29 1984-10-16 L'oreal Cleaning product for the hair and skin, based on acylisethionates and cationic polymers

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP0301082A4 *

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4992266A (en) * 1989-08-14 1991-02-12 S. C. Johnson & Son, Inc. Reducing the ocular irritancy of anionic shampoos
EP0636686A1 (fr) * 1993-07-28 1995-02-01 L'oreal Composition de lavage des fibres kératiniques à base de polymères dérivés du chitosane
FR2708276A1 (fr) * 1993-07-28 1995-02-03 Oreal Composition de lavage des fibres kératiniques à base de polymères dérivés du chitosane.
US5571458A (en) * 1993-07-28 1996-11-05 L'oreal Washing composition for keratin fibres which is based on chitosan-derived polymers
EP0686388A1 (en) * 1994-05-12 1995-12-13 Kao Corporation Aerosol hairdressing composition
EP0769934A4 (en) * 1994-08-24 1997-11-26 Procter & Gamble GENTLE SHOWER GEL COMPOSITION CONTAINING A FATTY ALCOHOL PROVIDING IMPROVED THICKENING AND FOAMING CHARACTERISTICS
EP0769934A1 (en) * 1994-08-24 1997-05-02 The Procter & Gamble Company Mild shower gel composition comprising fatty alcohol which imparts improved lathering and thickening properties
EP0796611A2 (en) * 1996-03-18 1997-09-24 Unilever Plc Hair styling mousse
EP0796611A3 (ja) * 1996-03-18 1997-10-29 Unilever Plc
WO1997048374A2 (en) * 1996-06-20 1997-12-24 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
WO1997048375A2 (en) * 1996-06-20 1997-12-24 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
WO1997048374A3 (en) * 1996-06-20 1998-02-05 Procter & Gamble Perfume delivery systems in liquid personal cleansing compositions
WO1997048375A3 (en) * 1996-06-20 1998-02-05 Procter & Gamble Perfume delivery systems in liquid personal cleansing compositions
US5804538A (en) * 1996-06-20 1998-09-08 The Procter & Gamble Company Perfume delivery systems in liquid personal cleansing compositions
WO1998027935A1 (en) * 1996-12-20 1998-07-02 The Procter & Gamble Company Foaming personal cleansing product
WO1998027938A1 (en) * 1996-12-20 1998-07-02 The Procter & Gamble Company Foaming personal cleansing product
US6440923B1 (en) 1998-12-24 2002-08-27 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Detergent composition

Also Published As

Publication number Publication date
BR8805088A (pt) 1989-08-15
ZA88646B (en) 1988-08-03
EP0301082A4 (en) 1991-03-20
JPH01502030A (ja) 1989-07-13
NZ223355A (en) 1990-11-27
AU600108B2 (en) 1990-08-02
AU1366188A (en) 1988-08-24
EP0301082A1 (en) 1989-02-01

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