WO1985004074A1 - Appat pour insectes a matrice d'amidon gelatinise - Google Patents

Appat pour insectes a matrice d'amidon gelatinise Download PDF

Info

Publication number
WO1985004074A1
WO1985004074A1 PCT/US1985/000405 US8500405W WO8504074A1 WO 1985004074 A1 WO1985004074 A1 WO 1985004074A1 US 8500405 W US8500405 W US 8500405W WO 8504074 A1 WO8504074 A1 WO 8504074A1
Authority
WO
WIPO (PCT)
Prior art keywords
insect
bait
starch
controlling material
amount
Prior art date
Application number
PCT/US1985/000405
Other languages
English (en)
Inventor
Stanley J. Flashinski
Daniel R. Bloch
Original Assignee
S.C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S.C. Johnson & Son, Inc. filed Critical S.C. Johnson & Son, Inc.
Publication of WO1985004074A1 publication Critical patent/WO1985004074A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/002—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits
    • A01N25/006—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing a foodstuff as carrier or diluent, i.e. baits insecticidal

Definitions

  • This invention is directed to insect bait. More particularly, the invention is directed to an insect bait useful in controlling various insects such as ants and roaches having gelatinized starch as the bait matrix.
  • U.S. Patent No. 960,287 discloses an insecticide composition which can contain from 15% to 20% cornstarch. The cornstarch is present in an insecticidal mixture of two metallic salts to separate the respective salt particles and prevent chemical reaction between the salts.
  • U.S. Patent No. 4,321,258, discloses a non-toxic insecticide which can include, inter alia, cornfetarch as an attractant for an insect.
  • an insect-controlling material such as an insecticide or insect repellent
  • the aforesaid objects of the present invention are accomplished by providing an insect bait based on starch in combination with other ingredients including attractants, insecticides or repellents, and preservatives wherein starch and the other materials are extruded under pressure and temperature sufficient to cook the starch and form a gelatinized stable gel bait matrix.
  • starch and the other materials are extruded under pressure and temperature sufficient to cook the starch and form a gelatinized stable gel bait matrix.
  • the invention is directed to the formation of an insect bait using a pregelatinized starch which has been partially cooked by extrusion to provide a water-absorbing property to the starch.
  • the pregelatinized starch and the essential ingredients of an insect bait such as attractants, insecticides, and/or repellents, preservatives, water, and preferably an emulsifier are cold blended.
  • the water essential for forming the gel bait matrix is absorbed by the pregelatinized starch.
  • heating of the materials during formation of the bait is not necessary. However, heating can, at times, be utilized to increase the speed of the gelling process.
  • the starch whether extruded with the materials to form a gel or pregelatinized, provides an inexpensive and practical method of forming an insect bait base which is easily used, without messiness, and which is effective in controlling insects.
  • the use of the pregelatinized starch is particularly convenient and effective and, accordingly, is a highly preferred embodiment.
  • the starch content of the insect bait of the preferred embodiment i.e., where the starch is pregelatinized, can vary over a range of from about 2.5% to 15% by weight. Below about 2.5% a stable gel will not form, but a flowable gel will result. Above about 15%, the pregelatinized starch will very rapidly absorb water and the viscosity of the mixture will increase too rapidly to allow handling of the material before a gel is formed. It has been found that the preferred range is from about 5% to about 15% pregelatinized starch. This range allows easy handling of the materials before the gel is formed, and once formed the gel is stable and non-flowable at temperatures up to at least about 140o F., which is a temperature at times reached in warehouses or the like where the product may be stored.
  • Pregelatinized starches are commercially available under various tradenames and are based on the common starches such as corn flour, cornstarch, maize, tapioca starch, potato starch, rice starch, and the like.
  • Pregelatinized starch as used herein includes the various commercial products which may or may not include additives such as sodium trimetaphosphate to provide improved gelling characteristics.
  • the starch content can, in the event only an insecticide or insect repellent is employed, range up to as high as 99%.
  • the starches employed are again the commonly available starch products including potato starch, corn flour, cornstarch, tapioca starch, maize, and the like.
  • the insect baits of the present invention it is preferable to utilize in addition to the starch other attractants such as fruit extracts, honey extracts, the sugars, i.e., sucrose, fructose, maltose, glucose, molasses, and the like, to make the bait more palatable to insects.
  • the additional attractants will vary from about 1% to 35% and will correspondingly decrease the amount of starch utilized.
  • additives including the insecticides and repellents which will withstand the extrusion temperatures of starch without degradation or vaporization.
  • the extrusion temperatures of the insect bait mixture depending upon the content of starch and other additives, will range between about 160 to about 310° F. at pressures of from about 300 through 800.
  • insecticides which can be utilized in the insect baits of the present invention include the insecticides commonly utilized in controlling insects.
  • One insecticide which has been found highly effective is
  • the bait can include any of the insecticides since the materials can be cold blended, or subjected to only slightly elevated temperatures. As previously stated, however, in the embodiment where the materials are mixed and co-extruded, an insecticide which does not degrade under extrusion conditions must be selected.
  • the content of insecticide can range from as low as 0.025%, depending upon the insecticide utilized, up to about 4%. Normally, however, the effective amounts of insecticide will fall below about 1.0% by weight.
  • Attractants including sugars, yeast extract, gelatine, and the like, can be utilized to enhance the attraction of the insect to the bait.
  • Normally food attractants such as the sugars will range from about 1% to 90% in the event the pregelatinized starch is employed. It has been found, for example, that corn syrup as an attractant in the range of from about 60% to 90% is desirable when pregelatinized starch is used, as the lowered moisture within the com syrup can be sufficient to gel the starch source of moisture; whereas, in the event corn flour or yeast extract is used as the attractant, 5% to 15% is highly effective.
  • the aforesaid materials have been found to be effective food ingredients for the insects, particularly ants and cockroaches.
  • the emulisifiers can be any of the commonly employed emulsifiers, and preferably the non-ionic or anionic emulsifiers.
  • the amount of emulisifier utilized will vary depending upon the amount of water in the mix.
  • the water content can vary from a minimum of about 5% which is necessary to form the gel to levels of about 15% or 20%. In the event a water content of above about 20% is utilized, the time forming the gel is substantially increased. It has been found, however, that effective insect baits can be prepared where the water content is as high as 80% to 90%.
  • additives can be at times effectively added to the insect bait.
  • These additives include Binders such as paraffin wax, synthetic clays, and materials commonly utilized in the formation of insect baits. Preferably, however, when the bait is used as an insecticide only food components are included in the bait.
  • the mixture was dry blended to provide a substantially uniform mixture.
  • the mixture was then extruded in a conventional extruder at a temperature in the range of 200 to 220o F., and at a pressure of 500 psi.
  • the extruded material was dispensed in containers in the form of a gel.
  • the gel was stable at room temperature and temperatures up to at least about 140o F.
  • the baits were effective in attracting and destroying roaches and ants.
  • An insect bait was formulated containing ingredients as follows:
  • Emulsifier - Triton X180 which is an alkyl polyether alcohol anionic emulsifier -------------- 0.4%
  • the above ingredients were cold blended. Upon complete blending, the materials provided a gel. The gel was packaged as a stable gel. The all-food bait was effective in attracting and destroying ants and roaches.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Agronomy & Crop Science (AREA)
  • Food Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Insects & Arthropods (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Catching Or Destruction (AREA)
  • Fodder In General (AREA)

Abstract

Appât pour insectes contenant une substance agissant contre les insectes dans une matrice d'amidon gélatinisé. L'appât est obtenu par co-extrusion de l'amidon avec la substance insecticide à une température et à une pression suffisantes pour cuire et gélatiniser l'amidon, ou alors en mélangeant de l'amidon préalablement gélatinisé avec la substance insecticide et de l'eau pour former un gel. L'appât est efficace dans la lutte contre les insectes.
PCT/US1985/000405 1984-03-14 1985-03-12 Appat pour insectes a matrice d'amidon gelatinise WO1985004074A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA449,585 1984-03-14
CA000449585A CA1265044A (fr) 1984-03-14 1984-03-14 Gel d'amidon-appat pour insectes

Publications (1)

Publication Number Publication Date
WO1985004074A1 true WO1985004074A1 (fr) 1985-09-26

Family

ID=4127405

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1985/000405 WO1985004074A1 (fr) 1984-03-14 1985-03-12 Appat pour insectes a matrice d'amidon gelatinise

Country Status (3)

Country Link
AU (1) AU564323B2 (fr)
CA (1) CA1265044A (fr)
WO (1) WO1985004074A1 (fr)

Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2614507A1 (fr) * 1987-02-11 1988-11-04 Chelle Rene Produit attractif, pour piege a guepes, qui melange a l'eau donne naissance a des molecules volatiles et attractives pour les guepes
EP0289756A2 (fr) * 1987-04-27 1988-11-09 The Clorox Company Composition d'un appât insecticide pour combattre les invasions domestiques de blattes
WO1989000419A1 (fr) * 1987-07-10 1989-01-26 Doane William M Encapsulation par piegage dans une matrice d'amidon
WO1990000351A1 (fr) 1988-07-12 1990-01-25 Aquaspersions Limited Elimination des organismes indesirables
US4992275A (en) * 1989-06-30 1991-02-12 Lush Raymon W Sweet corn based pesticide
WO1991003940A1 (fr) * 1989-09-15 1991-04-04 Goodman Fielder Wattie Australia Limited Matrices biodegradables de liberation regulee
WO1991007972A1 (fr) * 1989-11-29 1991-06-13 S.C. Johnson & Son, Inc. Appat aqueux gelifie pour insectes
EP0485452A1 (fr) * 1989-08-03 1992-05-20 Univ Temple Systeme de liberation d'insecticide et agent attirant les insectes.
US5183690A (en) * 1990-06-25 1993-02-02 The United States Of America, As Represented By The Secretary Of Agriculture Starch encapsulation of biologically active agents by a continuous process
US5186935A (en) * 1989-06-08 1993-02-16 Hedley Pacific Ventures, Ltd. Insecticidal bait composition and method of making same
EP0563963A1 (fr) * 1992-04-02 1993-10-06 AgriSense Système de livraison pour les insecticides
US5484587A (en) * 1991-10-31 1996-01-16 Micro Flo Company Diabroticine bait
US5571522A (en) * 1994-01-31 1996-11-05 Micro Flo Company Bait with corn germ
US5607684A (en) * 1991-10-31 1997-03-04 Micro Flo Company Manufacture of bait with hot melt binder
GB2305607A (en) * 1995-09-27 1997-04-16 Rhone Poulenc Agrochimie Poisonous baits for controlling noxious pests
US5690951A (en) * 1991-10-31 1997-11-25 Micro Flo Company Bait with hot melt binder
WO1998007315A1 (fr) * 1996-08-21 1998-02-26 The United States Of America, As Represented By The Secretary Of Agriculture Appareil de destruction de parasites
US5837273A (en) * 1991-07-16 1998-11-17 The United States Of America As Represented By The Secretary Of Agriculture Methods and compositions of adherent starch granules for encapsulating pest control agents
WO2000002447A1 (fr) * 1998-07-08 2000-01-20 Kiwicare Corporation Limited Pesticide sous forme de gel
US6190591B1 (en) 1996-10-28 2001-02-20 General Mills, Inc. Embedding and encapsulation of controlled release particles
EP1109448A1 (fr) * 1998-07-28 2001-06-27 The United States of America, represented by The Secretary of Agriculture Appats hydrodynamiques pour insectes
EP1116515A2 (fr) * 2000-01-11 2001-07-18 Givaudan SA Liquide encapsulé
WO2002052937A1 (fr) * 2001-01-04 2002-07-11 Nimrod Israely Composition insecticide
US6436453B1 (en) 2000-06-16 2002-08-20 General Mills, Inc. Production of oil encapsulated minerals and vitamins in a glassy matrix
US6468568B1 (en) 2000-06-16 2002-10-22 General Mills, Inc. Oligosaccharide encapsulated mineral and vitamin ingredients
US6500463B1 (en) 1999-10-01 2002-12-31 General Mills, Inc. Encapsulation of sensitive components into a matrix to obtain discrete shelf-stable particles
US6558718B1 (en) 2000-06-19 2003-05-06 General Mills, Inc. Nutrient clusters for food products and methods of preparation
EP1342548A1 (fr) 1996-10-28 2003-09-10 General Mills, Inc. Inclusion et encapsulation de particules à libération contrôlée et produit encapsulé
US6723358B1 (en) 1998-03-23 2004-04-20 General Mills, Inc. Encapsulation of components into edible products
WO2008061655A2 (fr) * 2006-11-24 2008-05-29 Bayer Cropscience Aktiengesellschaft Granulés phytosanitaires pour application à la surface des feuilles
US7803413B2 (en) 2005-10-31 2010-09-28 General Mills Ip Holdings Ii, Llc. Encapsulation of readily oxidizable components
JP2011098945A (ja) * 2009-11-09 2011-05-19 Fumakilla Ltd アリ用毒餌剤
US8143092B2 (en) 2008-03-10 2012-03-27 Pragati Kumar Methods for forming resistive switching memory elements by heating deposited layers
US8257749B2 (en) 2007-02-08 2012-09-04 Biolargo Life Technologies, Incorporated Systems providing at least pesticidal activity
WO2013063509A1 (fr) * 2011-10-28 2013-05-02 Sterling International Inc. Huiles essentielles et leurs composés comme produits répulsifs des pentatomes
JP2014077016A (ja) * 2014-01-24 2014-05-01 Fumakilla Ltd アリ用毒餌剤の製造方法
US9101124B2 (en) 2006-12-21 2015-08-11 Dow Agrosciences Llc Composite material including a thermoplastic polymer, a pest food material and a pesticide

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU576034B2 (en) * 1984-12-10 1988-08-11 R & C Products Pty Limited Non-crumbly solid edible insect bait

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR834530A (fr) * 1937-06-22 1938-11-23 Appâts-insecticides
US4332792A (en) * 1980-07-14 1982-06-01 Zoecon Corporation Insect attractant

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR834530A (fr) * 1937-06-22 1938-11-23 Appâts-insecticides
US4332792A (en) * 1980-07-14 1982-06-01 Zoecon Corporation Insect attractant

Cited By (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2614507A1 (fr) * 1987-02-11 1988-11-04 Chelle Rene Produit attractif, pour piege a guepes, qui melange a l'eau donne naissance a des molecules volatiles et attractives pour les guepes
EP0289756A2 (fr) * 1987-04-27 1988-11-09 The Clorox Company Composition d'un appât insecticide pour combattre les invasions domestiques de blattes
EP0289756A3 (en) * 1987-04-27 1990-03-14 American Cyanamid Company Insecticidal bait composition for control of household infestations of cockroaches
WO1989000419A1 (fr) * 1987-07-10 1989-01-26 Doane William M Encapsulation par piegage dans une matrice d'amidon
WO1990000351A1 (fr) 1988-07-12 1990-01-25 Aquaspersions Limited Elimination des organismes indesirables
US5186935A (en) * 1989-06-08 1993-02-16 Hedley Pacific Ventures, Ltd. Insecticidal bait composition and method of making same
US4992275A (en) * 1989-06-30 1991-02-12 Lush Raymon W Sweet corn based pesticide
EP0485452A1 (fr) * 1989-08-03 1992-05-20 Univ Temple Systeme de liberation d'insecticide et agent attirant les insectes.
EP0485452A4 (en) * 1989-08-03 1993-04-21 Temple University Insecticide delivery system and attractant
CN1044547C (zh) * 1989-09-15 1999-08-11 古德曼·菲尔德·瓦蒂澳大利亚有限公司 可生物降解控制释放的基质
WO1991003940A1 (fr) * 1989-09-15 1991-04-04 Goodman Fielder Wattie Australia Limited Matrices biodegradables de liberation regulee
EP0502959A1 (fr) * 1989-11-29 1992-09-16 S.C. JOHNSON & SON, INC. Appat aqueux gelifie pour insectes
EP0502959A4 (en) * 1989-11-29 1992-10-21 S.C. Johnson & Son, Inc. Gelled aqueous insect bait
WO1991007972A1 (fr) * 1989-11-29 1991-06-13 S.C. Johnson & Son, Inc. Appat aqueux gelifie pour insectes
GR900100829A (el) * 1989-11-29 1992-04-17 Johnson & Son Inc S C Πυκτωματωμενο υδατικο δολωμα εντομου.
US5183690A (en) * 1990-06-25 1993-02-02 The United States Of America, As Represented By The Secretary Of Agriculture Starch encapsulation of biologically active agents by a continuous process
US5837273A (en) * 1991-07-16 1998-11-17 The United States Of America As Represented By The Secretary Of Agriculture Methods and compositions of adherent starch granules for encapsulating pest control agents
US5607684A (en) * 1991-10-31 1997-03-04 Micro Flo Company Manufacture of bait with hot melt binder
US6174538B1 (en) * 1991-10-31 2001-01-16 Micro Flo Company Bait with cucurbitacin
US5690951A (en) * 1991-10-31 1997-11-25 Micro Flo Company Bait with hot melt binder
US5484587A (en) * 1991-10-31 1996-01-16 Micro Flo Company Diabroticine bait
EP0563963A1 (fr) * 1992-04-02 1993-10-06 AgriSense Système de livraison pour les insecticides
US5609880A (en) * 1994-01-31 1997-03-11 Micro Flo Company Bait with corn germ
US5571522A (en) * 1994-01-31 1996-11-05 Micro Flo Company Bait with corn germ
GB2305607A (en) * 1995-09-27 1997-04-16 Rhone Poulenc Agrochimie Poisonous baits for controlling noxious pests
GB2305607B (en) * 1995-09-27 1999-06-23 Rhone Poulenc Agrochimie Poisonous baits for controlling noxious pests
WO1998007315A1 (fr) * 1996-08-21 1998-02-26 The United States Of America, As Represented By The Secretary Of Agriculture Appareil de destruction de parasites
US6190591B1 (en) 1996-10-28 2001-02-20 General Mills, Inc. Embedding and encapsulation of controlled release particles
EP1342548A1 (fr) 1996-10-28 2003-09-10 General Mills, Inc. Inclusion et encapsulation de particules à libération contrôlée et produit encapsulé
US8313757B2 (en) 1998-03-23 2012-11-20 General Mills, Inc. Encapsulation of sensitive liquid components into a matrix to obtain discrete shelf-stable particles
US6723358B1 (en) 1998-03-23 2004-04-20 General Mills, Inc. Encapsulation of components into edible products
WO2000002447A1 (fr) * 1998-07-08 2000-01-20 Kiwicare Corporation Limited Pesticide sous forme de gel
US7179455B2 (en) 1998-07-08 2007-02-20 Kiwicare Corporation Limited Pesticide in gel form
EP1109448A1 (fr) * 1998-07-28 2001-06-27 The United States of America, represented by The Secretary of Agriculture Appats hydrodynamiques pour insectes
EP1109448A4 (fr) * 1998-07-28 2002-10-23 Us Agriculture Appats hydrodynamiques pour insectes
US6500463B1 (en) 1999-10-01 2002-12-31 General Mills, Inc. Encapsulation of sensitive components into a matrix to obtain discrete shelf-stable particles
EP1116515A2 (fr) * 2000-01-11 2001-07-18 Givaudan SA Liquide encapsulé
EP1116515A3 (fr) * 2000-01-11 2002-08-21 Givaudan SA Liquide encapsulé
US6436453B1 (en) 2000-06-16 2002-08-20 General Mills, Inc. Production of oil encapsulated minerals and vitamins in a glassy matrix
US6468568B1 (en) 2000-06-16 2002-10-22 General Mills, Inc. Oligosaccharide encapsulated mineral and vitamin ingredients
US6558718B1 (en) 2000-06-19 2003-05-06 General Mills, Inc. Nutrient clusters for food products and methods of preparation
US6837682B2 (en) 2000-06-19 2005-01-04 General Mills, Inc. Nutrient clusters for food products and methods of preparation
WO2002052937A1 (fr) * 2001-01-04 2002-07-11 Nimrod Israely Composition insecticide
US8142831B2 (en) 2005-10-31 2012-03-27 General Mills Ip Holdings Ii, Llc Encapsulation of readily oxidizable components
US7803413B2 (en) 2005-10-31 2010-09-28 General Mills Ip Holdings Ii, Llc. Encapsulation of readily oxidizable components
US7803414B2 (en) 2005-10-31 2010-09-28 General Mills Ip Holdings Ii, Llc Encapsulation of readily oxidizable components
WO2008061655A2 (fr) * 2006-11-24 2008-05-29 Bayer Cropscience Aktiengesellschaft Granulés phytosanitaires pour application à la surface des feuilles
WO2008061655A3 (fr) * 2006-11-24 2009-04-23 Bayer Cropscience Ag Granulés phytosanitaires pour application à la surface des feuilles
US8323697B2 (en) 2006-11-24 2012-12-04 Bayer Intellectual Property Gmbh Plant protection granulates to be applied to leaf surface
US9101124B2 (en) 2006-12-21 2015-08-11 Dow Agrosciences Llc Composite material including a thermoplastic polymer, a pest food material and a pesticide
US9775341B2 (en) 2006-12-21 2017-10-03 Dow Agrosciences Llc Composite material including a thermoplastic polymer, a pest food material and a pesticide
US9861097B2 (en) 2006-12-21 2018-01-09 Dow Agrosciences Llc Method of making a composite material including a thermoplastic polymer, a pest food material and a pesticide
US11083193B2 (en) 2006-12-21 2021-08-10 Dow Agrosciences Llc Method of making a composite material including a thermoplastic polymer, a pest food material and a pesticide
US11350627B2 (en) 2006-12-21 2022-06-07 Corteva Agriscience Composite material including a thermoplastic polymer, a pest food material, and a pesticide
US8257749B2 (en) 2007-02-08 2012-09-04 Biolargo Life Technologies, Incorporated Systems providing at least pesticidal activity
US8143092B2 (en) 2008-03-10 2012-03-27 Pragati Kumar Methods for forming resistive switching memory elements by heating deposited layers
JP2011098945A (ja) * 2009-11-09 2011-05-19 Fumakilla Ltd アリ用毒餌剤
WO2013063509A1 (fr) * 2011-10-28 2013-05-02 Sterling International Inc. Huiles essentielles et leurs composés comme produits répulsifs des pentatomes
JP2014077016A (ja) * 2014-01-24 2014-05-01 Fumakilla Ltd アリ用毒餌剤の製造方法

Also Published As

Publication number Publication date
CA1265044A (fr) 1990-01-30
AU564323B2 (en) 1987-08-06
AU4117785A (en) 1985-10-11

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