Classifications

• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B3/00—Electrolytic production of organic compounds
  • C25B3/20—Processes
  • C25B3/23—Oxidation
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
  • C07C41/48—Preparation of compounds having groups
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
  • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
  • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
  • C07C45/65—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
  • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
  • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
  • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
  • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
  • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups
• • C—CHEMISTRY; METALLURGY
  • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
  • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
  • C25B3/00—Electrolytic production of organic compounds
  • C25B3/01—Products
  • C25B3/07—Oxygen containing compounds
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C2601/00—Systems containing only non-condensed rings
  • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
  • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Definitions

• the invention is a new invention.
• Ci / derivative of the invention is a new compound not listed in the article, and is represented by the self-propelled formula (I).
• Guidance (books are manufactured, for example, by the methods shown below]?
• the compound represented by the formula (2) is processed in the presence of a lower lipoprotective agent, a call, and a neutral supporting electrode.
• the compound (Liao) used as a starting material is a known compound.
• the compound ( ⁇ ) is 2, 6 -- ⁇ in the medium --4 — metric eno.
• the amount of ⁇ -class aliphatic J-cycle used is not limited to waiting and can be selected as appropriate within a wide range, but the amount of the alcohol can be selected as appropriate for the compound ( ⁇ ) I j. For use in the range of 500 to 15
• the current density is high, the current efficiency will decrease.]) Also, the production rate of by-products will be high]), and if it is ⁇ , the production efficiency will be poor.
• the electric pressure applied to ⁇ is greatly affected by the amount of supporting electrolyte added, but in the above electrolytic reaction, the range of about 5 to 15 is preferable, and the range of about 2 to 5 is preferable. It is better to go with S.
• the electrolysis temperature is in the range of 10 to 50 ° C and anti-IS is in the range of I 0 to 30 ° C. In the case of a friend's invention, the electric sword reaction should be carried out by a positive quake.
• Compound (I) which is used as a starting material, is a known compound and is relatively easy to obtain. Specific examples of compounding (BI) are 3, 4, 5 — Trime-time Truen, 3, 4, 5-Tri-I Tri-Medium Citruen, etc. Can be done. Examples of the francium-grade oil-based reaction that is involved in the above electrolytic reaction include metanol, etano, and isola mouth pillar u.
• a Le co Lumpur, Ru can and this include n one 7 Chi Le A Le co chromatography such C.
• the amount of IS-class oil-based alcohol used is not limited to waiting and can be changed as appropriate within a wide range.
• the compound (M) is in the range of 5 0 0'to I 5 ⁇ , and it is particularly preferable that the compound is in the range of about 5 to ⁇ 0. ..
• alcoholic metal hydroxides such as sodium hydroxide, potassium hydroxide, and lithium hydroxide
• sodium hydroxide Alkali metals such as Liu Otsu, Caliu ⁇ , etc.
• the mouth of the terrain is Pila 3 ⁇ 4 ⁇ ⁇ idro ⁇ side, the terrain of the compound The data of ⁇ ,!
• the aluminum hydroxide can be mentioned.
• the amount of such supporting electric material used is not particularly limited and can be appropriately selected within a wide range, but the amount of the electric material used is about 0 ⁇ 0 1 to i ru for a combination of 1 ⁇ . It is preferable to use it in the range, especially in the range of 0.1 to 0.5 j. C: Better . However, since the amount of this supporting electrolyte used affects the voltage, it is preferable to determine the amount by considering the selectivity of the reaction and the diameter of the note.]) For the current density, applied voltage, and electrolysis temperature in this electrolytic reaction, the above-mentioned compound ( ⁇ ) is electrolyzed to obtain a compound.
• the same conditions as those in the reaction to obtain (I) should be deepened.
• the electronic material used in this electrolytic reaction is a compound of the above-mentioned compound (I).
• OR 2 is a compound showing -- ⁇ - [Immediate killing formula (compound of I]] li
• CH 2 is produced by the following formula (by treating the compound represented by R in the presence of an acid catalyst]? 0 ⁇ ⁇ X, OR- /? ⁇ X OR 1
• acid catalysts can be used.
• the amount of catalyst added is not particularly limited and can be determined appropriately from a wide range. About 0. I 0% of the amount of normal compound (JV) is used, but considering economic efficiency. About 1 to 3% by weight is enough.
• Solvents can be used in the friendship reaction, for example, by the cationized methyle, the crocodile porcelain, and the quaternized carbon; Run, medium
• Aromatic hydrocarbons such as 2 /, ether: [: 1 del, isozu ropyredel, 7 til liter, 3 ⁇ 4 aliphatic ether, "— ⁇ ⁇ ,” — It is possible to mention the aliphatic hydrocarbons, etc. by the pentan. Especially the amount of solvent used
• the anti-S temperature can be selected from a wide range of S, for example, in the range of about 0 to 100, especially in the range of about 20 to 50 ° C, and is usually about 1 to 1 2 during the reaction. Time, especially about 3 hours, is sufficient, and the resulting compound (a typical example of I is 2, 6 --meto medium temperature -4, metric T --2, 5--- nine
• reaction-liquid is concentrated under reduced pressure.
• residue was extracted with a chrometa, and the extract was concentrated under reduced pressure to recover the tax product.
• the lead conductor represented by the above-mentioned one-pronged formula (I) is useful as a synthetic raw material for medical products.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Engineering & Computer Science (AREA)
• Electrochemistry (AREA)
• Materials Engineering (AREA)
• Metallurgy (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Priority Applications (1)

Applications Claiming Priority (6)

Publications (1)

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• 1981
  • 1981-10-28 GB GB8218154A patent/GB2097399B/en not_active Expired
  • 1981-10-28 WO PCT/JP1981/000300 patent/WO1982001547A1/ja active IP Right Grant
  • 1981-10-28 DE DE813152459T patent/DE3152459T1/de active Granted
  • 1981-10-28 CH CH3963/82A patent/CH651285A5/de not_active IP Right Cessation
  • 1981-10-28 EP EP81902955A patent/EP0063608B1/en not_active Expired
• 1983
  • 1983-06-03 US US06/500,949 patent/US4475992A/en not_active Expired - Lifetime

Non-Patent Citations (1)

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