WO1981001856A1 - Sorbent-loaded textile yarns and films and methods of fabricating same - Google Patents

Sorbent-loaded textile yarns and films and methods of fabricating same Download PDF

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Publication number
WO1981001856A1
WO1981001856A1 PCT/US1980/001716 US8001716W WO8101856A1 WO 1981001856 A1 WO1981001856 A1 WO 1981001856A1 US 8001716 W US8001716 W US 8001716W WO 8101856 A1 WO8101856 A1 WO 8101856A1
Authority
WO
WIPO (PCT)
Prior art keywords
sorbent
fibers
films
polymeric
sorbent particles
Prior art date
Application number
PCT/US1980/001716
Other languages
English (en)
French (fr)
Inventor
G Lopatin
J Walton
M Coplan
Original Assignee
Albany Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Albany Int Corp filed Critical Albany Int Corp
Priority to NL8020501A priority Critical patent/NL190187C/xx
Priority to DE19803050157 priority patent/DE3050157A1/de
Priority to JP50056881A priority patent/JPS56501839A/ja
Publication of WO1981001856A1 publication Critical patent/WO1981001856A1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28028—Particles immobilised within fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28023—Fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/26—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/08—Addition of substances to the spinning solution or to the melt for forming hollow filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/918—Physical aftertreatment of a cellular product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249955—Void-containing component partially impregnated with adjacent component
    • Y10T428/249958—Void-containing component is synthetic resin or natural rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249978—Voids specified as micro
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2927—Rod, strand, filament or fiber including structurally defined particulate matter
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/298—Physical dimension

Definitions

  • This invention relates generally to textile quality polymeric fibers and thin polymer films which are highly sorptive for organic vapors, mists, solutes, and in particular, noxious or harmful substances in these forms. More specifically, the invention relates to polymeric fibers and films that incorporate a substantial amount of active sorptive materials throughout the fiber or film structure with high reten ⁇ tion of activity, and methods of fabricating the " same.
  • a principal object of this invention is to produce highly sorbent monofila- ment or multifilament yarns or staple fibers having properties suitable for textile uses generally.
  • Such qualities include, for example, a denier satisfactory for fabric handle, adequate tensile strength for pro ⁇ cessing and use, substantial elongation to the breaking point, good recovery from a moderate extension, and generally textile fiber-like durability. It is desirable that the fibers retain the sorptive con ⁇ stituents in an active state through repeated wearing and cleaning, and that the sorptive properties may be renewed.
  • An object of the invention is to provide fibers and films suitable for use as protective clothing, coverings or the like, containing sorptive media or species capable of sorbing vapors, liquids and solutes to a high percentage of the weight of such media.
  • sorptive media it is desirable not only that the sorptive media be present in a highly active form, but also that the media comprise a substantial quantity per unit weight of the fibers or films in which they are contained.
  • sorptive materials are securely retained within the body of ' the fibers or films so as not to be dislodged in ordinary usages.
  • This in turn imposes a requirement upon the polymeric matrix, namely, that such matrix must permit the ready permeation of materials to be sorbed, so as to have ready access to the sorptive constituents.
  • sorptive materials in polymeric fibers or film-forming polymers have produced undesirably low levels of sor-ption capa ⁇ city.
  • One of the problems has been that when such sorp ⁇ tive materials as active carbon particles have been loaded in polymers, difficulties have arisen in spinning and drawing filaments, except at relatively low levels of carbon loading.
  • carbon or other pigment loading of only about 10 to 12 percent has been commonly accepted as a limit for extrusion of such materials.
  • spinneret orifices often tend to become plugged due to poor flow, or the spin line breaks during the draw-down. This is often avoidable only by using a larger spinning orifice than desired.
  • Another problem is that the active media when incorporated in a polymeric matrix exhibit little or no sorption capability, apparently due to the fact that the polymer occludes access to the internal pore structure of the sorptive particles in the finished fiber or film.
  • this invention features filaments or fibers that consist of a micro- porous " polymeric body highly loaded with active sorbent particles dispersed throughout, such particles comprising a substantially higher percent of the fiber composition than hitherto achieved and being in a highly active state in said body. Also, sheets or films may be formed comprising such a microporous polymer body with similar loading.
  • this invention features a process by which the sorptive particles are blended with a selected extractable, phase separable diluent as well as the polymeric material.
  • the diluent material serves a.plurality of functions: it renders the polymeric matrix microporous; it allows heavily pigment-loaded fiber to be cold drawn to produce suitable mechanical properties for a textile; and it allows a very high draw-down from the melt so that fine spinning orifices are not needed to make fine yarns.
  • the product of this invention comprises a microporous polymeric body with actively sorbent par ⁇ ticles dispersed throughout the body.
  • the particles are characterized by highly active sorbency when incor ⁇ porated in the polymeric body, with minimal occlusion of the sorbent particle surfaces or internal structure by the polymer.
  • the particles comprise a high percentage of the total weight of the body as compared with sorbent-loaded yarns and films in the prior art, for example more than 10% and up to 50% of the weight of the finished fiber.
  • the products of this invention may comprise fibers or filaments suitable for making yarns for many ordinary textile uses, as well as thin polymeric films used as protective sheaths, coverings, linings or the like.
  • the fibers may be felted, or the yarns may be woven, knitted or otherwise employed as textile yarns generally. Fibers may also be chopped or otherwise com ⁇ minuted and assembled in paper-like sheets, pads or other molded forms.
  • a sorbent material which comprises, for example, active carbon particles, silica gel, or other particles of molecular filter-type materials.
  • the diluting material for example paraffin wax
  • paraffin wax is a material that is apparently (a) compatible with the polymer at melt spinning tem- peratures, (b) separable from the polymer into a fine, distinct phase upon cooling, and (c) extractable to pro ⁇ quiz the desired open-cell porous configuration in the polymer matrix.
  • paraffin wax being crystallizable, has the property of separating out of the polymer at room temperature so that, upon extraction in a later step, mutually interconnected pores are dispersed throughout the body of the polymer.
  • the polymer may comprise any of a large number of materials used in textiles or films.
  • a preferred material is polypropylene.
  • a blend of sorbent material, diluent and polymer is physically mixed in a suitable batch-type blender or blending extruder.
  • the order of ' addition is not critical and may be chosen to facilitate the use of the particular mixing apparatus.
  • the presence of the diluent is apparently effective to pre ⁇ vent the polymer from occluding the pore system of the sorbent particles.
  • the mixture so formed is extruded through fine orifices to form filaments or fibers, or through fine slits to form thin polymeric sheets or films.
  • the extrudates so formed may be attenuated by conventional methods, including both spin draw-down from the melt up to 1,000:1 for example; and if desired, subsequent drawing in solid form up to 10:1 for example.
  • the yarns, fibers or films so formed are extracted with a suitable solvent or solvents for removal of the diluent. This extraction porosifies the polymer, leaving the sorbent particles in an active state accessible to vapors, liquids or solutes present on or at the surface of the matrix.
  • Fibers produced according to this invention may be drawn in solid form (cold drawn) from 2:1 to 15:1 in many cases, and may have a denier of from one to 1,000, with a final diameter of between .001 and .020 inch. Likewise, films may be formed with thicknesses ranging from .001 to .020 inch.
  • Example 1 A preferred example of the invention consisted in forming textile filaments of microporous polypropy ⁇ lene in which were embedded active carbon particles.
  • the carbon particles comprised 17% by weight of the finished fiber.
  • the diluent was paraffin wax having a melting point of 55°C.
  • a mixture was formed comprising 61% polypropy- lene, 26% paraffin wax and 13% active carbon (Amoco PX21 Super Sorb), all percentages being by weight.
  • the paraffin wax was first added to a Sigma blade mixer and heated to melting, and the active carbon particles were then added. After initial mixing, the mixture was heated to 230°C. and the polypropylene was then slowly added and the mixing continued until uniform.
  • the mixture was then cooled, chopped and melt spun on a one-inch fiber spinning extruder with a spin ⁇ neret having eleven orifices each of .080 inch diameter, at 175°C, to form a multifilament yarn.
  • the fibers were subjected to a spin draw-down of about 60:1 at 150 feet per minute.
  • the extruder output was 0.4 pounds per hour.
  • the yarn was then drawn in solid form at about a 5:1 draw ratio at 75°C. Finally it was extracted in a
  • the resulting yarn had a total denier of 96 (8.8 denier/filament) and showed the following mechani ⁇ cal properties:
  • the yarn produced in this example exhibited a remarkable sorption capability for organic mists, aero ⁇ sols, solutes, vapors and gases.
  • the physical and che- mical phenomena attending this desirable result are not
  • Example 2 A blend of 58 parts by weight of polypropy ⁇ lene, 25 parts by weight of paraffin having a melting point of 55°C, and 17 parts active carbon (Amoco PX21 Super Sorb) , was prepared by compounding the components in a twin-screw compounding extruder having a die tem ⁇ perature of 232°C. The feeding rates of the various components into the extruder were adjusted so that the above blend was obtained. The extrudate was chopped and then spun into a monofilament at a take-up speed of 48 feet per minute. The filament was then extracted with pentane in a Soxhlett apparatus, and dried under vacuum. The resulting filament contained 23 percent by weight of the carbon and picked up 45 percent of its weight of carbon tetrachloride.
  • Example 3 A mixture of 87 parts by weight of polypropy ⁇ lene and 13 parts by weight of active carbon (Amoco PX21 Super Sorb) was blended in a Sigma blade mixer at 230°C until the blend appeared homogeneous. The mixture was cooled, chopped and spun into a monofilament- with a take up speed of 46 feet per minute. The filament was then extracted with hexane in a Soxhlett apparatus, and dried under vacuum at 90°C. After extraction, the filament was capable of picking up only 2 percent of its weight in carbon tetrachloride.
  • active carbon Amoco PX21 Super Sorb
  • the extraction of the diluent may be carried out either before or after the fibers have been cold drawn or have been incorporated in a finished pro ⁇ duct such as a textile fabric.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Nonwoven Fabrics (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
PCT/US1980/001716 1979-12-28 1980-12-23 Sorbent-loaded textile yarns and films and methods of fabricating same WO1981001856A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
NL8020501A NL190187C (nl) 1979-12-28 1980-12-23 Werkwijze voor het vormen van een opencellig microporeus lichaam en lichaam, verkregen volgens deze werkwijze.
DE19803050157 DE3050157A1 (de) 1979-12-28 1980-12-23 Sorbent-loaded textile yarns and films and methods of fabricating same
JP50056881A JPS56501839A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1979-12-28 1980-12-23

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US108178 1979-12-28
US06/108,178 US4342811A (en) 1979-12-28 1979-12-28 Open-celled microporous sorbent-loaded textile fibers and films and methods of fabricating same

Publications (1)

Publication Number Publication Date
WO1981001856A1 true WO1981001856A1 (en) 1981-07-09

Family

ID=22320747

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1980/001716 WO1981001856A1 (en) 1979-12-28 1980-12-23 Sorbent-loaded textile yarns and films and methods of fabricating same

Country Status (9)

Country Link
US (1) US4342811A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0031719B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS56501839A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU543966B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA1159809A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IL (1) IL61804A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL190187C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SE (1) SE446823B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO1981001856A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Cited By (3)

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EP0074063A3 (en) * 1981-09-04 1983-08-17 Collo Gmbh Process for making a sorption-active body, in particular for the removal of odours, for scenting rooms and the like
WO1993024684A1 (en) * 1992-05-22 1993-12-09 Courtaulds Plc Fibre and film
US5413747A (en) * 1991-04-26 1995-05-09 Courtaulds Fibres (Holdings) Limited Water absorbent fibres

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US4397907A (en) * 1981-06-22 1983-08-09 Hughes Aircraft Company Multi-purpose air permeable composites
US4377616A (en) * 1981-12-30 1983-03-22 Mobil Oil Corporation Lustrous satin appearing, opaque film compositions and method of preparing same
US4510194A (en) * 1982-04-28 1985-04-09 Asahi Kasei Textiles Ltd. Heat-retaining moisture-transmissible water-resistant fabric
US4797318A (en) * 1986-07-31 1989-01-10 Kimberly-Clark Corporation Active particle-containing nonwoven material, method of formation thereof, and uses thereof
US4948639A (en) * 1986-07-31 1990-08-14 Kimberly-Clark Corporation Vacuum cleaner bag
US4764282A (en) * 1986-09-26 1988-08-16 The Uniroyal Goodrich Tire Company Disposal of toxic and polymeric wastes
US4906378A (en) * 1987-12-28 1990-03-06 Minnesota Mining And Manufacturing Company Composite chromatographic article
US4971736A (en) * 1987-12-28 1990-11-20 Minnesota Mining And Manufacturing Company Method of preparing composite chromatographic article
US4810381A (en) * 1987-12-28 1989-03-07 Minnesota Mining And Manufacturing Company Composite chromatographic article
US5130342A (en) * 1988-10-14 1992-07-14 Mcallister Jerome W Particle-filled microporous materials
US5226937A (en) * 1989-08-18 1993-07-13 Pall Corporation Void-containing sorbent pad
EP0528048A4 (en) * 1991-03-05 1994-03-18 Ube Nitto Kasei Co COMPOSITE FIBER WITH POROUS ENVELOPE.
EP0656964B1 (en) * 1991-07-01 1998-06-10 E.I. Du Pont De Nemours And Company Activated carbon-containing fibrids
IL102338A (en) * 1991-07-01 1996-11-14 Du Pont Polymeric fibers containing activated carbon
US5482773A (en) * 1991-07-01 1996-01-09 E. I. Du Pont De Nemours And Company Activated carbon-containing fibrids
US5993935A (en) * 1991-10-11 1999-11-30 3M Innovative Properties Company Covalently reactive particles incorporated in a continous porous matrix
EP0565720A4 (en) * 1991-10-31 1994-03-18 Ube Nitto Kasei Co POROUS FIBER AND METHOD FOR PRODUCING THE SAME.
US5350443B2 (en) * 1993-04-19 1999-08-10 Von Hasso Bluecher Filter sheet material for passenger cabins in motor vehicles
AU5671296A (en) 1995-05-12 1996-11-29 Donaldson Company Inc. Filter device
JPH11508185A (ja) * 1995-06-20 1999-07-21 ドナルドソン カンパニー，インコーポレイティド フィルターおよびフィルターの製造法
JPH09271662A (ja) * 1996-04-05 1997-10-21 Aguri Create:Kk 炭素入り包装用資材
US5762840A (en) * 1996-04-18 1998-06-09 Kimberly-Clark Worldwide, Inc. Process for making microporous fibers with improved properties
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NL190187B (nl) 1993-07-01
IL61804A (en) 1985-07-31
US4342811A (en) 1982-08-03
AU543966B2 (en) 1985-05-09
EP0031719A3 (en) 1981-07-22
AU6773681A (en) 1981-07-22
NL8020501A (nl) 1981-11-02
NL190187C (nl) 1993-12-01
JPS56501839A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1981-12-17
CA1159809A (en) 1984-01-03
EP0031719A2 (en) 1981-07-08
EP0031719B1 (en) 1984-06-13
US4342811B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1985-02-10
SE446823B (sv) 1986-10-13
SE8104996L (sv) 1981-08-24

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