WO1981001713A1 - Fluidized-bed process to convert solid wastes to clean energy - Google Patents

Fluidized-bed process to convert solid wastes to clean energy Download PDF

Info

Publication number
WO1981001713A1
WO1981001713A1 PCT/US1980/001657 US8001657W WO8101713A1 WO 1981001713 A1 WO1981001713 A1 WO 1981001713A1 US 8001657 W US8001657 W US 8001657W WO 8101713 A1 WO8101713 A1 WO 8101713A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
biomass material
oil
products
vessel
Prior art date
Application number
PCT/US1980/001657
Other languages
English (en)
French (fr)
Inventor
R Davis
H Kosstrin
D Himmelblau
Original Assignee
Energy Resources Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Energy Resources Co Inc filed Critical Energy Resources Co Inc
Priority to AU67053/81A priority Critical patent/AU6705381A/en
Priority to DE19803050127 priority patent/DE3050127A1/de
Priority to NL8020492A priority patent/NL8020492A/nl
Priority to BR8008928A priority patent/BR8008928A/pt
Publication of WO1981001713A1 publication Critical patent/WO1981001713A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
    • C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
    • C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
    • C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
    • C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/02—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by distillation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
    • C10J3/56—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0909—Drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0956—Air or oxygen enriched air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the process will decompose not only rice hulls but also wood waste, coal, shale, cotton gin trash, wheat straw, peat, petroleum, coke, paper, peanut shells, coffee grounds, bagasse, municipal solid waste and rubber products such as tires.
  • the biomass material is shredded or otherwise treated so as to reduce the particle sizes to acceptable dimensions.
  • the material may be dried so as to reduce its moisture content.
  • the material is then fed to a pyrolizer or gasifier in the form of a fluidized-bed reactor vessel.
  • the gas for fluidization may be supplied by a positive displacement blower or some similar machine, and pressure relief valves may regulate the pressure in the bed.
  • the yield products of gas, oil and char that leave the vessel are separated by a cyclone separator or some other such device, and the gas and oil may then be used as an energy source for any number of purposes. For example, they may be used to generate steam or could be used to supply the electrical needs of the system.
  • the char may be stored in any suitable facility and may be recycled. The volume of the char is a small fraction of the volume of the original biomass material.
  • FIG. 1 is a block diagram suggesting the various steps in the process of converting biomass materials in accordance with this invention.
  • FIG. 2 is a diagrammatic view of a biomass conversion system utilizing the process of FIG. 1.
  • biomass materials are gasified in a fluid bed reactor vessel to yield clean energy products in the form of oil , gas and char.
  • the amounts of these products produced by the process depend on operating temperature , fluidization velocity and the biomass feed material employed.
  • the clean energy products are the following:
  • gas - Having a heating content between 80 to 300 BTU per standard cubic foot .
  • the gas contains large amounts of carbon monoxide and hydrogen, but it also contains between 10 and 50% water .
  • the gas product can be easily burned in an external combustion system such as a steam boiler or gas turbine.
  • FIG. 1 suggests the several steps of the process of the present invention.
  • the biomass material to be treated is fed to a shredder so as to convert the mass to a suitable size.
  • the shredded material is dried to reduce its moisture content to the moisture limitation placed on the feed material by the gasifier .
  • the material After the material has been pretreated so as to achieve the proper particle size and moisture content , it is fed to a fluidized-bed reactor having an inert bed of material such as refractory sand , alumdun balls , glass , etc. The material is thereafter gasified to yield the clean energy products of oil , char and gas.
  • a fluidized-bed reactor having an inert bed of material such as refractory sand , alumdun balls , glass , etc.
  • the material is thereafter gasified to yield the clean energy products of oil , char and gas.
  • the gasified yield is next conveyed to a separator where the char may be removed from the oil and gas , or all three of the products may be separated from one another .
  • the char is returned to the gasifier to be burned in the fluidized bed .
  • the other products namely oil and gas
  • the electrical energy may be used to run the shredder , dryer , or blower feeding the fluidizing gas , and the steam may be used as a source of heat for the dryer.
  • FIG. 2 a typical installation for carrying out the process is shown.
  • a storage area 1 is suggested where the biomass material (sometimes referred to as feed) is received .
  • This material may typically be in particle sizes in the range of 2.5 x 7.5 cm.
  • the feed is carried by belt conveyor 2 to a shredder 3 to reduce the size of the feed particles to 6 mm or less .
  • the shredder may be of the hammermill type with a capacity of 1.5 metric tons per hour .
  • the biomass material from the shredder is next dropped into a dryer 4, which may include a conveyor screw, to reduce its moisture content below the limitation placed on the material by the system. Normally the content must be reduced to 50% or less by weight.
  • Heat may be provided in the dryer by passing steam through the screws, and this steam may be generated by utilizing the oil and gas products yielded by the system, as suggested above.
  • the dried feed may be conveyed by a wei ⁇ t belt 5 and elevator 6 to the fluidized-bed feed hopper 10.
  • the hopper 10 is connected by an air lock valve 12 and screw feeder 14 to the inlet port 16 of gasifying chamber 18 of reactor vessel 20.
  • the interior walls of the vessel may be lined with a- refractory material, and an inert bed of materials such as sand, alumdu ⁇ balls, glass, etc. is placed on the horizontal, perforated distributor plate 22 before start-up.
  • Tne distributor plate 22 is below the port 16 and separates the upper, fluidizing chamber 18 from the lower, air supply chamber 24 of vessel 20.
  • a fluidizing gas such as air or mixtures of oxygen, nitrogen, carbon dioxide and water is fed into chamber 24 during operation through a port 26 by a positive displacement air blower 28.
  • Tne fluidizing gas for most applications will contain oxygen concentrations in the range of 0 to 21% by volume, but may be further enriched in oxygen when production of higher BTU gas is desired. Heating values of up to 500 BTU/SCF may be attained. Fluidization velocities in the range of .25 to 10 meters/second and pressures in the range of 1-8 p.s.i. are preferred.
  • air is fed through another port 30 from a gas burner 32 which will bring the chamber 18 up to operating temperature of 400 C to 1,100 C in about two hours.
  • the oil/gas product ratio can be adjusted by varying the operating temperatures; for example, with a biomass feed material such as rice hulls, more oil is produced near 500 C, while the gas yield increases and oil yield declines as the temperature goes to 800 C.
  • the gas producted has a heating value of upwards of 250 BTU/SCF.
  • Some char, comprising about 90% carbon, is produced along with the ash and is shown recycled from the cyclone 38 via an ash screw feeder 40 back through a port 42 into chamber 18 of the reactor vessel 20. It is combusted to help maintain the reaction temperature.
  • Some ash is continuously removed, still hot, from the cyclone by a rotary valve 44 and fed by a screwfeeder 46 under a cooling water spray 48 to an ash bucket conveyor 50.
  • the conveyor dumps it into a chute 52 and thence into a glass storage silo 54.
  • the silo may be equipped with its own screwfeeder 56 for unloading and hauling away the ash.
  • This ash is largely powered silica and has only a fraction of the volume of the original biomass material, perhaps 20%.
  • the oil and gas from the cyclone 39 are shown piped out the top of the cyclone together by duct 59 and, although the oil may be condensed, it is simpler to leave it in the vapor phase mixed with the gas for burning.
  • the gas and/or oil may be utilized to generate steam for the dryer or electrical power to run any of the apparatus in the system.
  • This is shown in the system of FIG. 2 in the form of a conventional gas burner 58 used with a forced draft fan 60 and a boiler 62 to make steam.
  • the boiler 62 may be a standard "D" type water tube boiler designed to generate 150 pound-per-square inch (10.35 bar) saturated steam. Flue gases are discharged to the atmosphere through- a stack 64, and no emission control equipment is required due to low dust loading of the gases. Conventional boiler auxiliary systems may be used if desired.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Centrifugal Separators (AREA)
PCT/US1980/001657 1979-12-14 1980-12-15 Fluidized-bed process to convert solid wastes to clean energy WO1981001713A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU67053/81A AU6705381A (en) 1979-12-14 1980-12-15 Fluidized-bed process to convert solid wastes to clean energy
DE19803050127 DE3050127A1 (de) 1979-12-14 1980-12-15 Fluidized-bed process to convert solid wastes to clean energy
NL8020492A NL8020492A (enrdf_load_stackoverflow) 1979-12-14 1980-12-15
BR8008928A BR8008928A (pt) 1979-12-14 1980-12-15 Processo em leito fluidificado para converter despejos solidos em energia limpa

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US7715979A 1979-12-14 1979-12-14
US77159 1979-12-14

Publications (1)

Publication Number Publication Date
WO1981001713A1 true WO1981001713A1 (en) 1981-06-25

Family

ID=22136409

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1980/001657 WO1981001713A1 (en) 1979-12-14 1980-12-15 Fluidized-bed process to convert solid wastes to clean energy

Country Status (9)

Country Link
JP (1) JPS56501764A (enrdf_load_stackoverflow)
BR (1) BR8008928A (enrdf_load_stackoverflow)
CA (1) CA1160104A (enrdf_load_stackoverflow)
FR (1) FR2473913A1 (enrdf_load_stackoverflow)
GB (1) GB2075543A (enrdf_load_stackoverflow)
NL (1) NL8020492A (enrdf_load_stackoverflow)
SE (1) SE8104818L (enrdf_load_stackoverflow)
WO (1) WO1981001713A1 (enrdf_load_stackoverflow)
ZA (1) ZA807805B (enrdf_load_stackoverflow)

Cited By (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3145066A1 (de) * 1981-11-13 1983-05-19 Fritz Werner Industrie-Ausrüstungen GmbH, 6222 Geisenheim Verfahren zum herstellen eines vergleichsweise energiereicheren, stickstofffreien gases und einrichtung zur durchfuehrung des verfahrens
US4676177A (en) * 1985-10-09 1987-06-30 A. Ahlstrom Corporation Method of generating energy from low-grade alkaline fuels
FR2594140A1 (fr) * 1986-02-13 1987-08-14 Goetaverken Energy Syst Ab Procede pour eliminer des substances indesirables d'un gaz qui est produit par gazeification pyrolytique
WO1994012592A1 (en) * 1992-11-26 1994-06-09 University Of Waterloo An improved process for the thermal conversion of biomass to liquids
EP0722815A4 (en) * 1994-08-05 1997-04-16 Nippo Sangyo METHOD AND DEVICE FOR DEGRADING PLASTIC WASTE
WO1997014001A1 (en) * 1995-10-13 1997-04-17 N.V. Kema Method and installation for processing waste
WO1997020017A1 (en) * 1995-11-28 1997-06-05 Foster Wheeler Energia Oy Method and apparatus for utilizing biofuel or waste material in energy production
AT403726B (de) * 1994-09-29 1998-05-25 Oesterr Draukraftwerke Verfahren zur verbrennung von biomasse
WO2001010981A1 (de) * 1999-08-05 2001-02-15 Krupp Uhde Gmbh Mehrstufiges beschickungsverfahren für stückiges einsatzgut und stoffgemische in druckräume
WO2007124488A3 (en) * 2006-04-21 2008-07-24 Zeropoint Clean Tech Inc Process for producing electrical power and potable water from biomass
CN100408917C (zh) * 2006-01-25 2008-08-06 浙江大学 燃用生物质燃料的循环流化床燃烧装置及方法
CN102154021A (zh) * 2011-02-24 2011-08-17 唐山汇力科技有限公司 生物质原料生产炭、气、油的净化回收系统及加工工艺
US8057641B2 (en) 2010-07-19 2011-11-15 Kior Inc. Method and apparatus for pyrolysis of a biomass
US20120023813A1 (en) * 2010-04-20 2012-02-02 River Basin Energy, Inc. Method of drying biomass
US8288600B2 (en) 2009-05-22 2012-10-16 Kior Inc. Methods for co-processing of biomass and petroleum feed
US8524959B1 (en) 2009-02-18 2013-09-03 Kior, Inc. Biomass catalytic conversion process and apparatus for use therein
US8558043B2 (en) 2009-03-04 2013-10-15 Kior, Inc. Modular biomass treatment unit
US8623634B2 (en) 2009-06-23 2014-01-07 Kior, Inc. Growing aquatic biomass, and producing biomass feedstock and biocrude therefrom
US8772556B2 (en) 2010-09-22 2014-07-08 Kior, Inc. Bio-oil production with optimal byproduct processing
US9017428B2 (en) 2010-11-16 2015-04-28 Kior, Inc. Two-stage reactor and process for conversion of solid biomass material
US9057037B2 (en) 2010-04-20 2015-06-16 River Basin Energy, Inc. Post torrefaction biomass pelletization
US9120990B2 (en) 2011-12-12 2015-09-01 Ensyn Renewables, Inc. Systems for fuels from biomass
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US9422478B2 (en) 2010-07-15 2016-08-23 Ensyn Renewables, Inc. Char-handling processes in a pyrolysis system
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
RU2602107C2 (ru) * 2014-11-27 2016-11-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный технологический университет" (ФГБОУ ВПО "КубГТУ") Установка для газификации рисовой лузги
US9670413B2 (en) 2012-06-28 2017-06-06 Ensyn Renewables, Inc. Methods and apparatuses for thermally converting biomass
WO2017103527A1 (fr) * 2015-12-16 2017-06-22 Compagnie Generale Des Etablissements Michelin Procédé de gazéification à lit fluidisé de pneus
US9809564B2 (en) 2006-04-03 2017-11-07 Pharmatherm Chemicals, Inc. Thermal extraction method and product
US9944837B2 (en) 2008-06-30 2018-04-17 Inaeris Technologies, Llc Co-processing solid biomass in a conventional petroleum refining process unit
US9951278B2 (en) 2010-05-20 2018-04-24 Ensyn Renewables, Inc. Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
US10011792B2 (en) 2010-08-16 2018-07-03 Nikhil Manubhai Patel Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
US10337726B2 (en) 2015-08-21 2019-07-02 Ensyn Renewables, Inc. Liquid biomass heating system
US10400176B2 (en) 2016-12-29 2019-09-03 Ensyn Renewables, Inc. Demetallization of liquid biomass
US10633606B2 (en) 2012-12-10 2020-04-28 Ensyn Renewables, Inc. Systems and methods for renewable fuel
CN112080323A (zh) * 2020-09-18 2020-12-15 浙江水利水电学院 一种固液含碳废弃物综合处理与资源化利用系统
US10934491B2 (en) 2012-01-06 2021-03-02 Mard, Inc. Two-stage process for conversion of solid biomass material
GR1009990B (el) * 2020-07-27 2021-04-26 Αλεξανδρος Χρηστου Παπαδοπουλος Συστημα προστασιας απο την κλιματικη αλλαγη με μοναδες ηλεκτροπαραγωγης αρνητικων εκπομπων διοξειδιου του ανθρακα
US11999920B2 (en) 2020-09-14 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock
US12031097B2 (en) 2021-10-14 2024-07-09 Ecolab Usa Inc. Antifouling agents for plastic-derived synthetic feedstocks
US12304888B2 (en) 2021-03-10 2025-05-20 Ecolab Usa Inc. Stabilizer additives for plastic-derived synthetic feedstock

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3153091B2 (ja) * 1994-03-10 2001-04-03 株式会社荏原製作所 廃棄物の処理方法及びガス化及び熔融燃焼装置
DE3603054C2 (de) * 1986-01-30 1994-10-13 Voest Alpine Ind Anlagen Verfahren zur Vergasung von Klärschlamm
USD478776S1 (en) 2001-07-17 2003-08-26 Ming Wide Lighters Co., Ltd. Piezoelectric lighter
US7736501B2 (en) 2002-09-19 2010-06-15 Suncor Energy Inc. System and process for concentrating hydrocarbons in a bitumen feed
CA2471048C (en) 2002-09-19 2006-04-25 Suncor Energy Inc. Bituminous froth hydrocarbon cyclone
CA2455011C (en) 2004-01-09 2011-04-05 Suncor Energy Inc. Bituminous froth inline steam injection processing
US8168071B2 (en) 2005-11-09 2012-05-01 Suncor Energy Inc. Process and apparatus for treating a heavy hydrocarbon feedstock
CA2526336C (en) 2005-11-09 2013-09-17 Suncor Energy Inc. Method and apparatus for oil sands ore mining
CA2567644C (en) 2005-11-09 2014-01-14 Suncor Energy Inc. Mobile oil sands mining system
BRPI0907997A2 (pt) 2008-02-28 2019-02-19 Krones Ag método e dispositivo para converter materiais crus carbônicos
CA2689021C (en) 2009-12-23 2015-03-03 Thomas Charles Hann Apparatus and method for regulating flow through a pumpbox
CN110595154A (zh) * 2019-09-20 2019-12-20 北京金隅琉水环保科技有限公司 飞灰烘干系统及飞灰烘干工艺
US20230114144A1 (en) * 2020-03-24 2023-04-13 Sekisui Chemical Co., Ltd. Pyrolysis gas purification/cooling device, pyrolysis gas purification/cooling method, organic substance production device, and method for producing organic substance

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3852048A (en) * 1972-07-14 1974-12-03 Kingsford Co Process for producing industrial fuel from waste woody materials
US3853498A (en) * 1972-06-28 1974-12-10 R Bailie Production of high energy fuel gas from municipal wastes
US3977947A (en) * 1972-07-26 1976-08-31 The Kingsford Company Fluidized bed carbonization
US4029550A (en) * 1973-01-05 1977-06-14 Agency Of Industrial Science & Technology Process for the dry distallation of rubber

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1553381A (en) * 1975-08-11 1979-09-26 Occidental Petroleum Corp Processing of solid wastes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853498A (en) * 1972-06-28 1974-12-10 R Bailie Production of high energy fuel gas from municipal wastes
US3852048A (en) * 1972-07-14 1974-12-03 Kingsford Co Process for producing industrial fuel from waste woody materials
US3977947A (en) * 1972-07-26 1976-08-31 The Kingsford Company Fluidized bed carbonization
US4029550A (en) * 1973-01-05 1977-06-14 Agency Of Industrial Science & Technology Process for the dry distallation of rubber

Cited By (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3145066A1 (de) * 1981-11-13 1983-05-19 Fritz Werner Industrie-Ausrüstungen GmbH, 6222 Geisenheim Verfahren zum herstellen eines vergleichsweise energiereicheren, stickstofffreien gases und einrichtung zur durchfuehrung des verfahrens
US4676177A (en) * 1985-10-09 1987-06-30 A. Ahlstrom Corporation Method of generating energy from low-grade alkaline fuels
FR2594140A1 (fr) * 1986-02-13 1987-08-14 Goetaverken Energy Syst Ab Procede pour eliminer des substances indesirables d'un gaz qui est produit par gazeification pyrolytique
WO1994012592A1 (en) * 1992-11-26 1994-06-09 University Of Waterloo An improved process for the thermal conversion of biomass to liquids
US5605551A (en) * 1992-11-26 1997-02-25 University Of Waterloo Process for the thermal conversion of biomass to liquids
EP0722815A4 (en) * 1994-08-05 1997-04-16 Nippo Sangyo METHOD AND DEVICE FOR DEGRADING PLASTIC WASTE
AT403726B (de) * 1994-09-29 1998-05-25 Oesterr Draukraftwerke Verfahren zur verbrennung von biomasse
WO1997014001A1 (en) * 1995-10-13 1997-04-17 N.V. Kema Method and installation for processing waste
WO1997020017A1 (en) * 1995-11-28 1997-06-05 Foster Wheeler Energia Oy Method and apparatus for utilizing biofuel or waste material in energy production
WO2001010981A1 (de) * 1999-08-05 2001-02-15 Krupp Uhde Gmbh Mehrstufiges beschickungsverfahren für stückiges einsatzgut und stoffgemische in druckräume
CN100408917C (zh) * 2006-01-25 2008-08-06 浙江大学 燃用生物质燃料的循环流化床燃烧装置及方法
US9809564B2 (en) 2006-04-03 2017-11-07 Pharmatherm Chemicals, Inc. Thermal extraction method and product
WO2007124488A3 (en) * 2006-04-21 2008-07-24 Zeropoint Clean Tech Inc Process for producing electrical power and potable water from biomass
US7566351B2 (en) * 2006-04-21 2009-07-28 Zeropoint Clean Tech, Inc. Process for producing electrical power and potable water from biomass
US9944837B2 (en) 2008-06-30 2018-04-17 Inaeris Technologies, Llc Co-processing solid biomass in a conventional petroleum refining process unit
US8524959B1 (en) 2009-02-18 2013-09-03 Kior, Inc. Biomass catalytic conversion process and apparatus for use therein
US8558043B2 (en) 2009-03-04 2013-10-15 Kior, Inc. Modular biomass treatment unit
US8288600B2 (en) 2009-05-22 2012-10-16 Kior Inc. Methods for co-processing of biomass and petroleum feed
US8623634B2 (en) 2009-06-23 2014-01-07 Kior, Inc. Growing aquatic biomass, and producing biomass feedstock and biocrude therefrom
US9057037B2 (en) 2010-04-20 2015-06-16 River Basin Energy, Inc. Post torrefaction biomass pelletization
US20120023813A1 (en) * 2010-04-20 2012-02-02 River Basin Energy, Inc. Method of drying biomass
US9988588B2 (en) 2010-04-20 2018-06-05 River Basin Energy, Inc. Post torrefaction biomass pelletization
US8956426B2 (en) * 2010-04-20 2015-02-17 River Basin Energy, Inc. Method of drying biomass
US9951278B2 (en) 2010-05-20 2018-04-24 Ensyn Renewables, Inc. Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
US10563127B2 (en) 2010-05-20 2020-02-18 Ensyn Renewables, Inc. Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
US9422478B2 (en) 2010-07-15 2016-08-23 Ensyn Renewables, Inc. Char-handling processes in a pyrolysis system
US8057641B2 (en) 2010-07-19 2011-11-15 Kior Inc. Method and apparatus for pyrolysis of a biomass
US8557193B2 (en) 2010-07-19 2013-10-15 Kior, Inc. Method and apparatus for pyrolysis of a biomass
US11220641B2 (en) 2010-08-16 2022-01-11 Nikhil Manubhai Patel Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
US10550343B2 (en) 2010-08-16 2020-02-04 Nikhil Manubhai Patel Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
US10011792B2 (en) 2010-08-16 2018-07-03 Nikhil Manubhai Patel Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
US8772556B2 (en) 2010-09-22 2014-07-08 Kior, Inc. Bio-oil production with optimal byproduct processing
US9017428B2 (en) 2010-11-16 2015-04-28 Kior, Inc. Two-stage reactor and process for conversion of solid biomass material
US11028325B2 (en) 2011-02-22 2021-06-08 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
CN102154021B (zh) * 2011-02-24 2013-03-27 唐山汇力科技有限公司 生物质原料生产炭、气、油的净化回收系统及加工工艺
CN102154021A (zh) * 2011-02-24 2011-08-17 唐山汇力科技有限公司 生物质原料生产炭、气、油的净化回收系统及加工工艺
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US9120988B2 (en) 2011-12-12 2015-09-01 Ensyn Renewables, Inc. Methods to increase gasoline yield
US9120990B2 (en) 2011-12-12 2015-09-01 Ensyn Renewables, Inc. Systems for fuels from biomass
US9969942B2 (en) 2011-12-12 2018-05-15 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US9422485B2 (en) 2011-12-12 2016-08-23 Ensyn Renewables, Inc. Method of trading cellulosic-renewable identification numbers
US10975315B2 (en) 2011-12-12 2021-04-13 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US9410091B2 (en) 2011-12-12 2016-08-09 Ensyn Renewables, Inc. Preparing a fuel from liquid biomass
US9127223B2 (en) 2011-12-12 2015-09-08 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US10570340B2 (en) 2011-12-12 2020-02-25 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US10934491B2 (en) 2012-01-06 2021-03-02 Mard, Inc. Two-stage process for conversion of solid biomass material
US9670413B2 (en) 2012-06-28 2017-06-06 Ensyn Renewables, Inc. Methods and apparatuses for thermally converting biomass
US10633606B2 (en) 2012-12-10 2020-04-28 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US10640719B2 (en) 2013-06-26 2020-05-05 Ensyn Renewables, Inc. Systems and methods for renewable fuel
RU2602107C2 (ru) * 2014-11-27 2016-11-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Кубанский государственный технологический университет" (ФГБОУ ВПО "КубГТУ") Установка для газификации рисовой лузги
US10337726B2 (en) 2015-08-21 2019-07-02 Ensyn Renewables, Inc. Liquid biomass heating system
US10948179B2 (en) 2015-08-21 2021-03-16 Ensyn Renewables, Inc. Liquid biomass heating system
FR3045655A1 (fr) * 2015-12-16 2017-06-23 Michelin & Cie Procede de gazeification a lit fluidise de pneus
WO2017103527A1 (fr) * 2015-12-16 2017-06-22 Compagnie Generale Des Etablissements Michelin Procédé de gazéification à lit fluidisé de pneus
US10400176B2 (en) 2016-12-29 2019-09-03 Ensyn Renewables, Inc. Demetallization of liquid biomass
US10982152B2 (en) 2016-12-29 2021-04-20 Ensyn Renewables, Inc. Demetallization of liquid biomass
GR1009990B (el) * 2020-07-27 2021-04-26 Αλεξανδρος Χρηστου Παπαδοπουλος Συστημα προστασιας απο την κλιματικη αλλαγη με μοναδες ηλεκτροπαραγωγης αρνητικων εκπομπων διοξειδιου του ανθρακα
US11999920B2 (en) 2020-09-14 2024-06-04 Ecolab Usa Inc. Cold flow additives for plastic-derived synthetic feedstock
CN112080323A (zh) * 2020-09-18 2020-12-15 浙江水利水电学院 一种固液含碳废弃物综合处理与资源化利用系统
US12304888B2 (en) 2021-03-10 2025-05-20 Ecolab Usa Inc. Stabilizer additives for plastic-derived synthetic feedstock
US12031097B2 (en) 2021-10-14 2024-07-09 Ecolab Usa Inc. Antifouling agents for plastic-derived synthetic feedstocks

Also Published As

Publication number Publication date
SE8104818L (sv) 1981-08-13
BR8008928A (pt) 1981-10-20
NL8020492A (enrdf_load_stackoverflow) 1981-11-02
GB2075543A (en) 1981-11-18
CA1160104A (en) 1984-01-10
ZA807805B (en) 1982-01-27
JPS56501764A (enrdf_load_stackoverflow) 1981-12-03
FR2473913A1 (enrdf_load_stackoverflow) 1981-07-24

Similar Documents

Publication Publication Date Title
CA1160104A (en) Fluidized-bed process to convert solid wastes to clean energy
RU2134713C1 (ru) Способ газификации порошкообразного твердого углеродистого топлива и устройство для его осуществления, интегрированный способ получения энергии
US6808390B1 (en) Process for carbonizing wood residues and producing activated carbon
RU2525491C2 (ru) Способ и система получения синтез-газа из биомассы карбонизацией
EP1278813B1 (en) A method and a system for decomposition of moist fuel or other carbonaceous materials
EP2385096B1 (en) Process for biomass torrefaction
US4568362A (en) Gasification method and apparatus for lignocellulosic products
BG64909B1 (bg) Метод и устройство за пиролиза и газифициране на органични вещества или смеси от органични вещества
KR20130001284A (ko) 열분해에 의해 바이오매스로부터 합성 가스를 제조하는 시스템 및 방법
WO2007081296A1 (en) Downdraft/updraft gasifier for syngas production from solid waste
US20190390128A1 (en) Method of drying biomass
JP2000505123A (ja) 下方流固定床ガス化炉とその使用
GB2099014A (en) Bi-flow rotary kiln coal gasification process
CA2888044A1 (en) A method for performing pyrolysis and a pyrolysis apparatus
JP3559163B2 (ja) バイオマスと化石燃料を用いたガス化方法
RU2408820C1 (ru) Установка для мультифазового пиролиза органического сырья
RU74918U1 (ru) Установка для конверсии твердого топлива (варианты)
JPS6045935B2 (ja) 隔板付内筒を用いて紛粒体を循環する流動層熱分解ガス化方法およびその装置
AU2004212548B2 (en) Process for carbonizing wood residues and producing activated carbon
RO132583B1 (ro) Instala- ţie de gazificare atmosferică a biomasei/ deşeurilor solide, cu control avansat al regimului gazodinamic şi termic
RU92011U1 (ru) Установка для мультифазового пиролиза органического сырья
JPS5829997B2 (ja) 都市固形廃棄物の流動熱分解法
AU4275600A (en) Process for carbonizing wood residues and producing activated carbon
Holmes et al. Synthetic Fuel from Wood Using Steam and Air

Legal Events

Date Code Title Description
AK Designated states

Designated state(s): AU BR DE GB JP NL SE

RET De translation (de og part 6b)

Ref document number: 3050127

Country of ref document: DE

Date of ref document: 19820325

WWE Wipo information: entry into national phase

Ref document number: 3050127

Country of ref document: DE