US9410289B2 - Coating color composition and paper or paperboard coated with it - Google Patents

Coating color composition and paper or paperboard coated with it Download PDF

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Publication number
US9410289B2
US9410289B2 US12/493,626 US49362609A US9410289B2 US 9410289 B2 US9410289 B2 US 9410289B2 US 49362609 A US49362609 A US 49362609A US 9410289 B2 US9410289 B2 US 9410289B2
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Prior art keywords
binder
parts
substitute
coating color
color composition
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US20100159263A1 (en
Inventor
Jonni Ahlgren
Antti Matula
Tarja Turkki
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Kemira Oyj
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Kemira Oyj
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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D103/00—Coating compositions based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09D103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06—Copolymers with styrene
    • C09D109/08—Latex
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y10T428/31906—Ester, halide or nitrile of addition polymer

Definitions

  • the present invention relates to a coating color composition and to the paper or paperboard according to the preambles of the enclosed claims.
  • Paper and paperboard are coated with different coating colors in order to improve, among other things, their strength, printability and appearance, e.g. smoothness and gloss.
  • Conventional coating compositions comprise mainly pigment and binder, and possible other additives, such as co-binders, preservatives, dispersing agents, defoaming agents, lubricants, hardeners and optical brighteners.
  • binder in the coating composition is to bind the pigment particles to each other and to the base paper. They may also have an effect on the Theological properties of the coating composition.
  • Typical synthetic binders are polymers based on butadiene, styrene, vinyl acetate, butyl acrylate and acrylic acid monomers. Such polymer dispersions are conventionally called latex binders, and they have a particle size around 0.1-0.2 ⁇ m. As the latex binders are synthetic compounds their price may be relatively high. Therefore it would be advantageous to minimize the amount of binder in the coating composition without impairing the properties of the composition and the resulting coated paper.
  • Styrene/acrylate copolymers as surface sizing agents are known.
  • U.S. Pat. No. 6,426,381 discloses styrene/(meth)acrylate copolymers that can be used for surface sizing.
  • JP 58/115196 discloses a water soluble paper strength increasing agent which is prepared by graft copolymerizing styrene and acrylate in presence of starch. The agent is said to improve the strength and sizing degree of paper.
  • An object of this invention is to provide a coating color composition with which the disadvantages in the prior art may be minimized or even eliminated.
  • An object is also to provide a coating color composition which improves the strength properties of the coated paper or paperboard.
  • a further object of this invention is to provide a coating color composition, where amount of the binder may be reduced without impairing the strength properties of the coated paper.
  • Typical coating color composition for paper and/or paperboard according to the present invention comprises
  • Typical paper or paperboard according to the present invention is coated with a coating color composition according the present invention.
  • the binder substitute when used to replace a part of the conventional binder it has been found out that the amount of the total binder may easily be reduced by 20-30% without impairment of the strength properties of the paper. Reduction of the amount of total binder naturally decreases the costs associated with it.
  • the styrene acrylate copolymer that is used as the binder substitute may be obtained by copolymerization of ethylenically unsaturated monomers.
  • Suitable styrene monomers are styrene and substituted styrenes, such as ⁇ -methylstyrene or vinyltoluene or their mixtures, and suitable acrylate monomers are C1-C4-alkyl acrylates, C1-C4-alkyl methacrylates or their mixtures, e.g.
  • the mixtures of n-butyl acrylate and tert-butyl acrylate are used in polymerization.
  • the mixing ratio may be 10:90 to 90:10.
  • the binder substitute is styrene acrylate copolymer comprising starch.
  • the styrene acrylate copolymer may be obtained as described in U.S. Pat. No. 6,426,381, i.e. by free radical emulsion copolymerization of ethylenically unsaturated monomers in the presence of starch.
  • Starch may be any suitable native starch, such as potato, rice, corn, waxy corn, wheat, barley or tapioca starch, potato starch being preferred. Starches having a amylopectin content >80%, preferably >95% are advantageous.
  • Starch may be also modified, for example, anionized, cationized or degraded.
  • Anionized starch comprises anionic groups, such as carboxylate or phosphate groups, whereas cationized starch comprises cationic groups, such as quaternized ammonium groups.
  • Degree of substitution (DS) indicating the number of anionic/cationic groups in the starch on average per glucose unit, is typically 0.01-0.20
  • Amphoteric starches comprising both anionic and cationic groups, may also be used in the preparation of the styrene acrylate copolymer.
  • Degraded starch is obtained by subjecting the starch to oxidative, thermal, acidic or enzymatic degradation, oxidative degradation being preferred. Hypochlorite, peroxodisulfate, hydrogen peroxide or their mixtures may be used as oxidizing agents.
  • Degraded starch has typically an average molecular weight (Mn) 500-10 000, which can be determined by known gel chromatography methods.
  • the intrinsic viscosity is typically 0.05 to 0.12 dl/g, determined, for example, by known viscosimetric methods.
  • any other polysaccharide which contains a free hydroxyl group, such as amylose, amylopectine, carrageen, cellulose, chitosan, chitin, dextrines, guar gum (guarane) and other galactomannans, arabic gum, hemicellulose components, and pullulan, for obtaining styrene acrylate copolymer used in the present invention.
  • Dextrin is more preferred of the polysaccharides listed, i.e. the styrene acrylate copolymer comprises dextrin.
  • the binder substitute may be used in form of aqueous polymer dispersion having a solids content of 10-50%, preferably 20-50%, more preferably 21-29%, most preferably 35-40%. High solids content is advantageous as the amount of water in the coating composition may be minimized.
  • the mean particle size of the binder substitute as an aqueous dispersion is at least 20 nm, preferably at least 25 nm, more preferably 30 nm, still more preferably 35 nm, most preferably at least 40 nm, and less than 90 nm, preferably less than 80 nm, more preferably less than 70 nm, still more preferably less than 60, most preferably less than 50 nm.
  • the mean particle size of the binder substitute is ⁇ 100 nm.
  • the mean particle size of the binder substitute as an aqueous dispersion is in the range 20-100, preferably 30-80 nm, more preferably 40-70 nm, most preferably 60-70.
  • the mean particle size of the binder substitute may be determined by photon correlation spectroscopy using for example a Malvern Zetamaster equipment.
  • the coating composition comprises, besides binder substitute, also a latex binder.
  • Typical synthetic latex binders that may be used in the present invention are latices known in the art, such as styrene butadiene (SB), styrene acrylate (SA) or polyvinyl acetate (PVAc) latices.
  • the latex binder is styrene butadiene (SB) latex.
  • the coating composition may also comprise in addition to the binder substitute and possible main binder also starch binder, which starch may be anionic or cationic.
  • Typical pigments that may be used in the present invention are calcium carbonate, kaolin, calcinated kaolin, talc, titanium dioxide, gypsum, chalk, satine white, barium sulfate, sodium aluminum silicate, aluminum hydroxide or any of their mixture.
  • Calcium carbonate may be ground calcium carbonate (GCC) or precipitated calcium carbonate (PCC) or their mixture.
  • GCC ground calcium carbonate
  • PCC precipitated calcium carbonate
  • the pigment is calcium carbonate.
  • composition of the coating color mixture is given, as conventional in the art, by giving the total amount of pigments value 100, and calculating the amounts of other components relative to the amount of the total pigment (pph). Proportions of all components are given as active substances.
  • the binder substitute may be used together with conventional co-binders, such as carboxy methyl cellulose (CMC), polyvinyl alcohol (PVOH), starch, casein or protein.
  • co-binders such as carboxy methyl cellulose (CMC), polyvinyl alcohol (PVOH), starch, casein or protein.
  • Amount of the co-binders in the coating composition is normally 0.05-3 parts. In case of starch, the amount of may be 0.05-12 parts, preferably 0.1-10 parts.
  • additives are, for example, preservatives, dispersing agents, defoaming agents, lubricants, hardeners and optical brighteners.
  • the amount of other additives are normally 0-3 parts.
  • the coating color according to the present invention may be prepared in conventional way, i.e. the pigment slurry is mixed with the binder substitute in dispersion form and possible other additives as added as customary. If conventional binder is used in addition to the binder substitute it is also added to the coating color composition as customary. As existing equipment and procedures may be used when using the binder substitute according to the present invention, no extensive modification of the equipment is needed.
  • the coating color according to the present invention has a solids content of 60-74%, preferably 63-72%, more preferably 65-71% and viscosity ⁇ 2000 mPas. Viscosities are measured by using Brookfield viscometer, type DV-II, with speed 100 rpm and using spindle 3 or 4.
  • the coating color composition is applied on paper or paperboard surface in single or multiple coating layers.
  • Applied coating methods include for example blade, rod, film transfer or air brush coating.
  • Applied coat weights are typically in the range of 5-30 g/m 2 /side. In one applied coating layer the coat weight is generally 5-16 g/m 2 /side, more typically 6-14 g/m 2 /side, and most typically 8-12 g/m 2 /side.
  • Oxidatively degraded potato starch (Perfectamyl® A 4692) in amount of 67 g is dispersed in 536 g of demineralized water under constant stirring in a 2 L three-necked flask having a reflux condenser. Starch is dissolved by heating to a temperature of 85° C., whereby 20.0 g of a 1% aqueous solution of FeSO 4 ⁇ 7H 2 O (0.72 mmol) and 4.0 g of 35% hydrogen peroxide are added in succession.
  • the solution comprising monomers and the initiator solution are metered in simultaneously but separately in the course of 90 min at 85° C. at constant feed rate.
  • the monomer solution comprises 86.6 g of styrene, 43.3 g of n-butyl acrylate and 43.3 g of tert-butyl acrylate.
  • the initiator solution comprises 4.3 g of hydrogen peroxide (35%) and 127 g of water. The polymerization is performed in nitrogen atmosphere.
  • the mean particle size, measured by Malvern Zetamaster, is 61.3 nm.
  • Coating color composition used Coating color component Parts Coating grade ground calcium carbonate 100 Binder 9 Rheology modifiers 0.7
  • Binder substitute 1 comprises styrene acrylate copolymer polymerized in presence of anionic starch and binder substitute 2 comprises styrene acrylate copolymer polymerized in presence of cationic starch.
  • Binder substitute 1 is prepared according to the general description above. Binder substitute 1 and binder substitute 2 have solids contents 24 and 25%, respectively. Commercial styrene butadiene is used in the coating composition as main binder. Type of the binder substitute is the only variable in the coating color compositions. Coating color compositions are prepared using Diaf laboratory dissolver and diluted to 50% solids content. Coating color compositions are shown in Table 1.
  • Binder/ Reference Composition Composition Property composition Composition 1 2 SB-latex (parts) 9 4.5 4.5 Binder substitute1 (parts) — 3 — Binder substitute 2 (parts) — — 3 Solids content (%) 49.6 50.0 50.0 Coat weight (g/m 2 ) 10.8 11.0 10.1 IGT-surface strength (m/s): 0.86 0.84 0.80
  • compositions are run without any problems with the coating apparatus. Blade pressures are on the same level with all compositions.
  • the reference composition has the lowest Brookfield viscosity.
  • Paper samples coated with the test compositions are calendered on Optiload Twinline. Calendering speed is 800 m/min and roll temperature 120° C.
  • coated paper samples are printed using 5-color (B,C,M,B,C) printing with constant density and speed 8000 sheets/h on Man Roland 300 printing press.
  • IGT surface strength results on machine direction (MD) and cross direction (CD) are summarized in table 7.
  • binder substitutes Compatibility of the binder substitutes with starch is tested. Laboratory tests are carried out with binder substitutes 1 and 2, the binder substitute 1 comprising styrene acrylate copolymer polymerized in presence of cationic starch and binder substitute 2 comprising styrene acrylate copolymer polymerized in presence of anionic starch. Binder substitute 1 has solids content of 24%, and binder substitute 2 has solids content of 25%.
  • the used coating color recipe is shown in table 8.
  • composition A comprised binder substitute 1 and composition B binder composition 2.
  • Binder substitute 1 gives similar viscosity to coating color composition than the SB latex used as reference. Coating color composition comprising binder substitute 2 has higher viscosity value than the reference. The reference color has the lowest high shear viscosity. Binder substitute 1 gives lower viscosity to the coating color composition than binder substitute 2. All viscosity values are good or acceptable for the tested coating compositions
  • Paper samples are draw-down coated with the tested coating compositions. The surface strength is determined, and the results are presented in table 10.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
US12/493,626 2008-12-18 2009-06-29 Coating color composition and paper or paperboard coated with it Active 2031-03-27 US9410289B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20086213 2008-12-18
FI20086213A FI124806B (fi) 2008-12-18 2008-12-18 Päällystyspastakoostumus ja sillä päällystetty paperi tai kartonki

Publications (2)

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US20100159263A1 US20100159263A1 (en) 2010-06-24
US9410289B2 true US9410289B2 (en) 2016-08-09

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Country Status (13)

Country Link
US (1) US9410289B2 (fr)
EP (2) EP3296459B1 (fr)
JP (1) JP5677976B2 (fr)
KR (1) KR101488381B1 (fr)
CN (2) CN102257218A (fr)
CA (1) CA2670397C (fr)
ES (1) ES2655302T3 (fr)
FI (1) FI124806B (fr)
PL (1) PL2370631T3 (fr)
PT (1) PT2370631T (fr)
RU (1) RU2528639C2 (fr)
WO (1) WO2010070205A1 (fr)
ZA (1) ZA201103276B (fr)

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US20220185733A1 (en) * 2020-12-11 2022-06-16 Sika Technology Ag Cementitious compositions comprising oxidatively degraded polysaccharide as water reducing agents
US11685837B2 (en) 2019-08-12 2023-06-27 Awi Licensing Llc Coating composition

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FR2958664B1 (fr) 2010-04-07 2012-10-26 Coatex Sas Utilisation d'un latex de styrene et de taille de 100 nm comme agent rheologique dans une sauce de couchage papetiere, sauce et son procede d'obtention
EP2580257B2 (fr) 2010-06-14 2023-02-15 Basf Se Dispersions polymériques sur base de monomères vinylaromatiques et acryliques, produits en présence de germes de latex et d'hydrates de carbone
DE102011116760A1 (de) 2011-10-20 2013-04-25 Carl Zeiss Meditec Ag Ophthalmologisches Lasersystem und Verfahren zur laserchirurgischen Behandlung der Cornea
JP6196978B2 (ja) * 2011-11-18 2017-09-13 ロケット フレールＲｏｑｕｅｔｔｅ Ｆｒｅｒｅｓ 高分子量の部分的に可溶性のデキストリン
CA2857715A1 (fr) 2011-12-06 2013-06-13 Basf Se Emballage papier et carton avec couche de barrage
FR2992983B1 (fr) * 2012-07-06 2014-07-04 Roquette Freres Sauces de couchage pour papier et carton contenant une dextrine a teneur elevee en amylopectine
FR3005067B1 (fr) * 2013-04-24 2015-04-24 Roquette Freres Sauces de couchage a base de dextrines
JP6205872B2 (ja) * 2013-06-05 2017-10-04 王子ホールディングス株式会社 印刷用塗工紙
CA3017981A1 (fr) * 2016-03-18 2017-09-21 Rohm And Haas Company Composition de revetement de papier et processus de fabrication correspondants
FI20165235A (fi) * 2016-03-22 2017-09-23 Kemira Oyj Koostumus päällystyspastan reologian modifioimiseksi, sen käyttö ja päällystyspasta
FI126948B (en) * 2016-03-22 2017-08-31 Kemira Oyj Aqueous polymer dispersion, its use and a process for preparing an aqueous polymer dispersion
CN106904015B (zh) * 2017-04-20 2020-04-03 东升新材料（山东）有限公司 一种环保可降解高清数码打印水转印纸及其制备方法
KR101881373B1 (ko) * 2017-11-27 2018-07-24 한국제지 주식회사 나노사이즈 바인더를 적용한 도공액
JP2021054897A (ja) * 2019-09-27 2021-04-08 サカタインクス株式会社 紙製バリア材料の基紙用アンカーコート剤、アンカーコート層、積層体、および紙製バリア材料
CN111005258B (zh) * 2019-12-31 2021-09-17 玖龙纸业（东莞）有限公司 一种轻涂牛卡纸及其生产方法
KR102272234B1 (ko) * 2020-09-25 2021-07-02 주식회사 대양포리졸 히트 실링, 안티블로킹성 등을 만족하는 종이용 수성 코팅 조성물

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JP5677976B2 (ja) 2015-02-25
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WO2010070205A1 (fr) 2010-06-24
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EP3296459A1 (fr) 2018-03-21
CA2670397A1 (fr) 2010-06-18
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US20100159263A1 (en) 2010-06-24

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