US9240487B2 - Method of manufacturing thin film transistor and method of manufacturing organic light emitting display having thin film transistor - Google Patents
Method of manufacturing thin film transistor and method of manufacturing organic light emitting display having thin film transistor Download PDFInfo
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- US9240487B2 US9240487B2 US12/266,797 US26679708A US9240487B2 US 9240487 B2 US9240487 B2 US 9240487B2 US 26679708 A US26679708 A US 26679708A US 9240487 B2 US9240487 B2 US 9240487B2
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- 239000010409 thin film Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 37
- 239000004065 semiconductor Substances 0.000 claims abstract description 129
- 238000002161 passivation Methods 0.000 claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 31
- 238000000576 coating method Methods 0.000 claims abstract description 18
- 239000001301 oxygen Substances 0.000 claims abstract description 16
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 16
- -1 oxygen ions Chemical class 0.000 claims abstract description 16
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 239000010408 film Substances 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 26
- 229920002120 photoresistant polymer Polymers 0.000 claims description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 23
- UMIVXZPTRXBADB-UHFFFAOYSA-N benzocyclobutene Chemical compound C1=CC=C2CCC2=C1 UMIVXZPTRXBADB-UHFFFAOYSA-N 0.000 claims description 16
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 8
- 239000004642 Polyimide Substances 0.000 claims description 8
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052733 gallium Inorganic materials 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 229910052738 indium Inorganic materials 0.000 claims description 8
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 8
- 229920001721 polyimide Polymers 0.000 claims description 8
- 238000000059 patterning Methods 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 abstract description 23
- 239000011368 organic material Substances 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 24
- 239000001257 hydrogen Substances 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 150000002500 ions Chemical class 0.000 description 9
- 239000000203 mixture Substances 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 6
- 238000001764 infiltration Methods 0.000 description 6
- 230000008595 infiltration Effects 0.000 description 6
- 239000002075 main ingredient Substances 0.000 description 6
- 238000004528 spin coating Methods 0.000 description 6
- 238000000206 photolithography Methods 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000000053 physical method Methods 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
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- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000001020 plasma etching Methods 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
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- 239000007789 gas Substances 0.000 description 1
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- 229910010272 inorganic material Inorganic materials 0.000 description 1
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- 238000012545 processing Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
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- H—ELECTRICITY
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/7869—Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
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- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
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- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4908—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET for thin film semiconductor, e.g. gate of TFT
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02365—Forming inorganic semiconducting materials on a substrate
- H01L21/02518—Deposited layers
- H01L21/02521—Materials
- H01L21/02565—Oxide semiconducting materials not being Group 12/16 materials, e.g. ternary compounds
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- H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
- H01L27/1222—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs with a particular composition, shape or crystalline structure of the active layer
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- H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
- H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
- H01L27/1251—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs comprising TFTs having a different architecture, e.g. top- and bottom gate TFTs
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- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/41—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
- H01L29/417—Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions carrying the current to be rectified, amplified or switched
- H01L29/41725—Source or drain electrodes for field effect devices
- H01L29/41733—Source or drain electrodes for field effect devices for thin film transistors with insulated gate
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- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78606—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
- H01L29/78618—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device characterised by the drain or the source properties, e.g. the doping structure, the composition, the sectional shape or the contact structure
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/1201—Manufacture or treatment
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/121—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements
- H10K59/1213—Active-matrix OLED [AMOLED] displays characterised by the geometry or disposition of pixel elements the pixel elements being TFTs
Definitions
- aspects of the present invention relate to a method of manufacturing a thin film transistor and a method of manufacturing an organic light emitting display having the thin film transistor, and more particularly to a method of manufacturing a thin film transistor having a compound semiconductor containing oxygen as a semiconductor layer and a method of manufacturing an organic light emitting display having the thin film transistor.
- a thin film transistor includes a semiconductor layer including a channel region and source and drain regions, and a gate electrode formed on the channel region and electrically insulated from the semiconductor layer by a gate insulating layer.
- the semiconductor layer of the thin film transistor configured as above is generally formed of amorphous silicon or poly-silicon. However, if the semiconductor layer is formed of amorphous silicon, charge mobility in the semiconductor layer is low and causes difficulties in implementing a driving circuit to be operated at high speeds. If the semiconductor is formed of the poly-silicon, charge mobility in the semiconductor layer is high whereas threshold voltage in the semiconductor layer becomes uneven and results in additional use of a separate compensation circuit.
- LTPS low temperature poly-silicon
- Japanese Patent Publication No. 2004-273614 discloses a thin film transistor using zinc oxide (ZnO) or a compound semiconductor using zinc oxide (ZnO) as a main ingredient as the semiconductor layer.
- the compound semiconductor is used as the semiconductor layer, a problem arises in that conductivity is reduced due to infiltration of hydrogen (H) when exposed to air.
- the hydrogen infiltrated into a surface part of the compound semiconductor layer acts as a shallow donor to reduce the conductivity of the semiconductor layer, and such a reduction of the conductivity intensifies according to the exposed time thereof. Therefore, owing to the reduction of the conductivity on the channel region, the electrical property of the thin film transistor is deteriorates, thereby leading to an increase in a leakage current, etc.
- aspects of the present invention include a method of manufacturing a thin film transistor capable of preventing or reducing an electrical property change of a semiconductor layer due to diffusion (infiltration) of hydrogen ions and a method of manufacturing an organic light emitting display having the thin film transistor.
- Another aspect of the present invention includes a method of manufacturing a thin film transistor having improved electrical property and reliability, and a method of manufacturing an organic light emitting display having the thin film transistor.
- An aspect of the present invention includes a method of manufacturing a thin film transistor, including: forming a gate electrode on an insulating substrate; forming a gate insulating layer on the gate electrode; forming a semiconductor layer including oxygen ions on the gate insulating layer, and including a channel region, a source region, and a drain region; forming a source electrode and a drain electrode to contact the semiconductor layer in the source region and the drain region, respectively; and forming a passivation layer on the semiconductor layer by coating a material, wherein a carrier density of the semiconductor layer is 1E+17 to 1E+18/cm 3 .
- An aspect of the present invention includes a method of manufacturing a thin film transistor, including: forming a gate electrode on an insulating substrate; forming a gate insulating layer on the gate electrode; forming a semiconductor layer including oxygen ions, on the gate insulating layer, and including a channel region, a source region, and a drain region; forming a passivation layer on the semiconductor layer by coating a material; forming a photoresist film on the passivation layer and then patterning the photoresist film to expose the source region and drain region of the semiconductor layer; and forming a source electrode and a drain electrode to contact the semiconductor layer in the source region and the drain region, respectively, wherein a carrier density of the semiconductor layer is 1E+17 to 1E+18/cm 3 .
- An aspect of the present invention includes a method of manufacturing an organic light emitting display having a thin film transistor, including: forming a gate electrode on an insulating substrate; forming a gate insulating layer on the gate electrode; forming a semiconductor layer including oxygen ions on the gate insulating layer, and including a channel region, a source region, and a drain region; forming a passivation layer on the semiconductor layer by coating a material; forming a photoresist film on the passivation layer and then patterning the photoresist film to expose the source region and drain region of the semiconductor layer; forming a source electrode and a drain electrode to contact the semiconductor layer in the source region and the drain region, respectively; forming a planarization layer over the source electrode or the drain electrode and patterning the planarization layer to expose the source electrode or the drain electrode; forming a first electrode to contact the source electrode or the drain electrode exposed on the planarization layer; forming a pixel definition layer over the first electrode and exposing the first electrode in the light emitting region
- An aspect of the present invention includes a thin film transistor, including: a substrate; a compound semiconductor layer formed over the substrate, and including a channel region, a source region, and a drain region; a gate electrode formed to correspond to the channel region; and a passivation layer over the substrate and the thin film transistor to seal the compound semiconductor from intrusion of hydrogen.
- An aspect of the present invention includes a method of manufacturing a thin film transistor, including: forming the thin film transistor on a substrate, the thin film transistor including a compound semiconductor layer comprising a channel region, a source region, and a drain region; and forming a passivation layer over the substrate and the thin film transistor to seal the compound semiconductor from intrusion of hydrogen.
- FIG. 1 is a cross-sectional view explaining a thin film transistor according to a first aspect of the present invention.
- FIG. 2 is a cross-sectional view explaining a thin film transistor according to a second aspect of the present invention.
- FIGS. 3A to 3D are cross-sectional views explaining a method of manufacturing a thin film transistor according to the first aspect of the present invention.
- FIGS. 4A to 4E are cross-sectional views explaining a method of manufacturing a thin film transistor according to the second aspect of the present invention.
- FIGS. 5A and 5B are graphs explaining electrical property of a thin film transistor according to aspects of the present invention.
- FIGS. 6A and 6B are a plan view and a cross-sectional view explaining a method of manufacturing an organic light emitting display having a thin film transistor according to aspects of the present invention.
- FIG. 7 is a cross-sectional view explaining a method of manufacturing an organic light emitting display having a thin film transistor according to an aspect of the present invention.
- first element when a first element is described as being coupled to a second element, the first element may be not only directly coupled to the second element but may also be indirectly coupled to the second element via a third element. Further, some of the elements that are not essential to the complete understanding of the invention are omitted for clarity.
- FIG. 1 is a cross-sectional view explaining a thin film transistor according to a first aspect of the present invention, wherein the thin film transistor having a bottom gate structure is shown, as an example.
- a gate electrode 11 is formed on a substrate 10 formed of insulating material.
- a gate insulating layer 12 is formed on an entire upper surface of the substrate 10 including the gate electrode 11 .
- a semiconductor layer 13 is formed on the gate electrode 11 , is electrically insulated from the gate electrode 11 , and includes a channel region 13 a , a source region 13 b , and a drain region 13 c .
- the semiconductor layer 13 is formed of a compound semiconductor including oxygen ions, wherein the channel region 13 a is formed to be overlapped with the gate electrode 11 .
- zinc oxide (ZnO) or a compound semiconductor, etc., using zinc oxide (ZnO) doped with gallium (Ga), indium (In), tin (Sn), etc., as a main ingredient, may be used.
- a source electrode 14 a and a drain electrode 14 b are formed on the semiconductor layer 13 to correspond to the source and drain regions 13 b and 13 c .
- a conductive layer 15 to reduce a contact resistance between the source and drain electrodes 14 a and 14 b , and the semiconductor layer 13 may be formed therebetween.
- a passivation layer 16 is formed over the source and drain electrodes 14 a and 14 b and the semiconductor layer 13 .
- the passivation layer 16 is formed of at least one material selected from the group consisting of polyimide, polyacryl, spin on glass (SOG), photoresist film, and benzocyclobutane (BCB).
- the passivation layer 16 entirely covers the semiconductor layer 13 and the source and drain electrodes 14 a and 14 b to seal them. Accordingly, the passivation layer 16 prevents or reduces infiltration of hydrogen into the semiconductor layer 13 .
- FIG. 2 is a cross-sectional view explaining a thin film transistor according to a second aspect of the present invention, wherein the thin film transistor having a bottom gate structure is shown, as an example.
- a buffer layer 21 is formed on a substrate 20 formed of insulating material, and a gate electrode 22 is formed on the buffer layer 21 .
- a semiconductor layer 24 is formed on the gate electrode 22 , is electrically insulated from the gate electrode 22 by a gate insulating layer 23 , and includes a channel region 24 a , a source region 24 b , and a drain region 24 c .
- the semiconductor layer 24 is formed of a compound semiconductor including oxygen ions, wherein the channel region 24 a is formed to be overlapped with the gate electrode 22 .
- zinc oxide (ZnO) or a compound semiconductor, etc., using zinc oxide (ZnO) doped with gallium (Ga), indium (In), tin (Sn), etc., as a main ingredient, may be used.
- a passivation layer 25 is formed on the entire semiconductor layer 24 , and is formed with contact holes to expose the source and drain regions 24 b and 24 c .
- the passivation layer 25 is formed of at least one material selected from the group consisting of polyimide, polyacryl, spin on glass (SOG), photoresist film, and benzocyclobutane (BCB).
- Source and drain electrodes 27 a and 27 b are formed on the passivation layer 25 , and are contacted to the respective source and drain regions 24 b and 24 c through the contact holes.
- the passivation layer 25 entirely covers the semiconductor layer 24 and the source and drain electrodes 27 a and 27 b to seal them. Accordingly, the passivation layer 25 prevents or reduces infiltration of hydrogen into the semiconductor layer 24 .
- FIGS. 3A to 3D are cross-sectional views explaining a method of manufacturing a thin film transistor according to the first aspect of the present invention.
- a gate electrode 11 is formed on an insulating substrate 10 , and then, a gate insulating layer 12 is formed on an entire upper surface of the substrate 10 including the gate electrode 11 .
- a semiconductor layer 13 is formed on the gate insulating layer 12 , and over the gate electrode 11 .
- the semiconductor layer 13 includes a channel region 13 a, a source region 13 b , and a drain region 13 c .
- the semiconductor layer 13 is a compound semiconductor including oxygen ions, wherein the semiconductor layer 13 may be formed of zinc oxide (ZnO) or a compound semiconductor, etc., using zinc oxide (ZnO) doped with gallium (Ga), indium (In), tin (Sn), etc., as a main ingredient.
- metal is deposited and then patterned on an entire upper surface of the semiconductor layer 13 to form source and drain electrodes 14 a and 14 b that contact the respective source and drain regions 13 b and 13 c of the semiconductor layer 13 .
- a conductive layer 15 to reduce a contact resistance between the source and drain electrodes 14 a and 14 b , and the semiconductor layer 13 may further be formed therebetween.
- a passivation layer 16 is formed on an entire surface of the source and drain electrodes 14 a and 14 b , and that of the semiconductor layer 13 by performing a spin coating or a slit coating thereon of at least one material selected from the group consisting of polyimide, polyacryl, spin on glass (SOG), photoresist film, and benzocyclobutane (BCB). At this time, the organic material may be cured after being coated.
- FIGS. 4A to 4E are cross-sectional views explaining a method of manufacturing a thin film transistor according to the second aspect of the present invention.
- a gate electrode 22 is formed on or over an insulating substrate 20 , and then, a gate insulating layer 23 is formed on the gate electrode 22 and over the insulating substrate 20 .
- a buffer layer 21 may be formed on the insulating substrate 20 before the gate electrode 22 is formed.
- the buffer layer 21 may be formed of an insulating material such as silicon oxide or silicon nitride.
- a semiconductor layer 24 is formed on the gate insulating layer 23 that covers the gate electrode 22 .
- the semiconductor layer 24 includes a channel region 24 a , a source region 24 b , and a drain region 24 c .
- the semiconductor layer 24 is a compound semiconductor including oxygen ions, and may be formed of zinc oxide (ZnO) or a compound semiconductor, etc., using zinc oxide (ZnO) doped with gallium (Ga), indium (In), tin (Sn), etc., as a main ingredient.
- a passivation layer 25 is formed on an entire surface of the semiconductor layer 24 by performing a spin coating or a slit coating thereon of at least one material selected from the group consisting of polyimide, polyacryl, spin on glass (SOG), photoresist film, and benzocyclobutane (BCB).
- a photoresist film 26 is formed and then patterned on the passivation layer 25 .
- the passivation layer 25 in the exposed portion is etched through an etching process using the patterned photoresist film 26 as a mask. Accordingly, contact holes 25 a are formed to expose predetermined portions of the source region 24 b and the drain region 24 c .
- the photoresist film 26 can be patterned through exposure and development processes using an established mask.
- source and drain electrodes 27 a and 27 b are formed to be contacted to the source and drain regions 24 b and 24 c of the semiconductor layer 24 through the contact holes 25 a formed on the passivation layer 25 .
- first and second aspects are described as having a spin coating or a slit coating thereon of a material, by way of example, any physical coating method that does not cause a reaction between materials may also be applied. Also, any material that can be patterned through a photolithography process using the photoresist film 26 can be used in addition to the noted materials.
- the passivation layers 16 and 25 are formed by coating, for example, an organic material, such is not required.
- the passivation layers 16 and 25 may be formed by depositing inorganic materials, such as, silicon oxide SiO 2 , silicon nitride SiN, or the like, with plasma deposition equipment.
- inorganic materials such as, silicon oxide SiO 2 , silicon nitride SiN, or the like.
- plasma deposition equipment such as hydrogen (H) ions are diffused (infiltrated) into the semiconductor layer to be reacted during the deposition process, a hydrogen density and composition ratio of the semiconductor layer may be changed due to damage by the plasma.
- a carrier density of the semiconductor layer may increase by ⁇ 1E+20/cm 3 due to the increase of the hydrogen density, and the composition ratio of positive ions and negative ions may be changed due to the damage by the plasma.
- the ratio (composition ratio) of positive ions and negative ions of InGaZnO may be represented as In x Ga y Zn 1 ⁇ x ⁇ y O z .
- the carrier density of the semiconductor layer can be stably maintained in a range from about 1E+17 to 1E+18/cm 3 and the conductivity of the channel is not changed even with a composition difference as shown in the following mathematical equation 2.
- the carrier density of the semiconductor layer between about 1E+19 and 1E+20 cm 3 allows the semiconductor layer to have a conductivity similar to that of metal, while the carrier density of the semiconductor layer less than 1E+15 cm 3 allows the semiconductor layer to have insulative properties.
- FIG. 5A shows a transfer curve measurement of an electrical property of a thin film transistor to which a plasma enhanced chemical vapor deposition (PECVD) process and a dry etching process have been applied, and having a passivation layer formed with silicon nitride film SiN.
- PECVD plasma enhanced chemical vapor deposition
- SiN silicon nitride film
- FIG. 5B shows a transfer curve measurement of an electrical property of a thin film transistor to which a spin coating process and a photolithography process have been applied, and having a passivation layer formed with organic material.
- a physical method such as the spin coating process, is used that does not expose a semiconductor layer to hydrogen and does not generate a reaction between materials, and a photolithography process is used that does not cause plasma damage, it can be seen that a carrier density of the semiconductor layer is not changed, and thus a conductivity thereof is not changed.
- aspects of the present invention uses the photolithography process that uses a photoresist film to pattern the passivation layers 16 and 25 , in order to expose the respective source electrodes 14 a and 27 a and drain electrodes 14 b and 27 b . Therefore, the photolithography process prevents or reduces damage to the passivation layers 16 and 25 arising from plasma etching even in subsequent processes, making it possible to effectively and uniformly maintain the conductivity of the channel.
- the first and second aspects of the present invention describe a thin film transistor having a bottom gate structure.
- aspects of the present invention can also be applied to a thin film transistor having any structures using a compound semiconductor, such as a top gate structure, etc., as a semiconductor layer.
- FIG. 6A is a plan view explaining an organic light emitting display having a thin film transistor according to an aspect of the present invention.
- FIG. 6A will be schematically explained focused on a display panel 200 displaying an image.
- a substrate 210 includes a pixel region 220 , and a non-pixel region 230 that is peripheral to the pixel region 220 .
- a portion of the substrate 210 corresponding to the pixel region 220 includes a plurality of organic light emitting elements 300 that are coupled between scan lines 224 and data lines 226 in a matrix arrangement.
- a portion of the substrate 210 corresponding to the non-pixel region 230 is formed with portions of the scan lines 224 and data lines 226 that extend from the scan lines 224 and data lines 226 of the pixel region 220 , power supply lines (not shown) used in the operation of the organic light emitting elements 300 , and a scan driver 234 and a data driver 236 to process signals supplied from an external device through a pad 228 and to supply the process signals to the scan lines 224 and the data lines 226 .
- FIG. 7 is a cross-sectional view explaining a method of manufacturing an organic light emitting display having a thin film transistor according to an aspect of the present invention.
- an organic light emitting element 300 is formed of an anode electrode 317 , a cathode electrode 320 , and an organic thin film layer 319 formed between the anode electrode 317 and the cathode electrode 320 .
- the organic thin film layer 319 may include a hole transport layer, an organic light emitting layer, and an electron transport layer.
- the organic thin film layer 319 may further include a hole injection layer and an electron injection layer.
- a capacitor to maintaining signals and a thin film transistor to control an operation of the organic light emitting element 300 may further be included.
- the organic light emitting element 300 including the thin film transistor will be described in more detail with reference to FIGS. 6A and 7 .
- the thin film transistor has the structure as shown in FIG. 1 or in FIG. 2 .
- Such a thin film transistor can be manufactured according to a manufacturing method of aspects of the present invention with reference to FIGS. 3A to 3D or FIGS. 4A to 4E .
- a thin film transistor having a structure as shown in FIG. 2 will be described by way of example.
- a buffer layer 21 is formed on a substrate 210 , and a gate electrode 22 is formed on the buffer layer 21 in a pixel region 220 .
- scan lines 224 coupled to the gate electrode 22 are formed in the pixel region 220 .
- Scan lines 224 in the non-pixel region 230 are those that extend from the scan lines 224 in the pixel region 220 , and a pad 228 to receive signals from the external device, may be formed in the non-pixel region 230 .
- a gate insulating layer 23 is formed on the upper surface of the buffer layer 21 that includes the gate electrode 22 .
- a semiconductor layer 24 (that includes a channel region 24 a , a source region 24 b , and a drain region 24 c ) is formed on the gate insulating layer 23 and the gate electrode 22 .
- the semiconductor layer 24 is a compound semiconductor including oxygen ions, and may be formed of zinc oxide (ZnO) or a compound semiconductor, etc., that uses zinc oxide doped with gallium (Ga), indium (In) and tin (Sn), etc., as a main ingredient.
- a passivation layer 25 is formed over the entire semiconductor layer 24 and the gate insulating layer 23 by coating at least one material selected from the group consisting of polyimide, polyacryl, spin on glass (SOG), photoresist film, and benzocyclobutane (BCB).
- a photoresist film 26 is formed on the passivation layer 25 , and then, the photoresist film 26 is patterned through an exposure process and development processes using an established mask.
- the passivation layer 25 in an exposed portion is etched through an etching process using the patterned photoresist film 26 as a mask. Thereby, contact holes 25 a are formed to expose predetermined portions of a source region 24 b and a drain region 24 c.
- source and drain electrodes 27 a and 27 b are formed in order to contact the source and drain regions 24 b and 24 c of the semiconductor layer 24 through the contact holes 25 a formed on a passivation layer 25 .
- data lines 226 coupled to the source and drain electrodes 27 a and 27 b are formed in a pixel region 220 .
- Data lines 226 in the non pixel region 230 are those that extend from the data lines 226 in the pixel region 220 , and a pad 228 to receive signals from the external device may be formed in the non-pixel region 230 .
- a planarization layer 30 is formed on an entire upper surface of the passivation layer 25 , and the source and drain electrodes 27 a and 27 b to form a planar surface.
- a via hole is formed in the planarization layer 30 in order to expose a predetermined portion of the source electrode 27 a or drain electrode 27 b .
- an anode electrode 317 is formed and coupled to the source electrode 27 a or the drain electrode 27 b through the via hole.
- a pixel definition layer 318 is formed on the planarization layer 30 to expose some region (a light emitting region) of the anode electrode 317 , and an organic thin film layer 319 is formed on the exposed region of anode electrode 317 .
- a cathode electrode 320 is formed on the pixel definition film 318 and the organic thin film layer 319 .
- an encapsulation substrate 400 to encapsulate a pixel region 220 is disposed over the substrate 210 having the organic light emitting elements 300 .
- the encapsulation substrate 400 is bonded to the substrate 210 by a sealing material 410 to complete a display panel 200 .
- aspects of the present invention form a passivation layer by coating organic material through a physical method, such as, a spin coating process where a reaction between materials does not occur, and patterns the passivation layer through a pattern process using a photoresist film. Accordingly, a change of a hydrogen density of a semiconductor layer, a change of composition ratio due to diffusion (infiltration) of hydrogen, and plasma damage are effectively prevented or reduced. Therefore, specific resistance in a channel region is controlled, conductivity in the channel region is stably maintained, making it possible to improve the electrical property of a thin film transistor, such as a non-generation of leakage current, etc.
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Abstract
Description
Zn1O0.99=1023×0.01˜1021/cm3
Zn1O0.999=1023×0.001˜1020/cm3
Zn1O0.9999=1023×0.0001˜1019/cm3
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