US8884063B2 - Continuous process for the hydrogenation of 3-cyano-3,5,5-trimethyl-cyclohexylimine - Google Patents

Continuous process for the hydrogenation of 3-cyano-3,5,5-trimethyl-cyclohexylimine Download PDF

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Publication number
US8884063B2
US8884063B2 US12/520,575 US52057507A US8884063B2 US 8884063 B2 US8884063 B2 US 8884063B2 US 52057507 A US52057507 A US 52057507A US 8884063 B2 US8884063 B2 US 8884063B2
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basic
process according
reaction mixture
cyano
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US20100036168A1 (en
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Martin Ernst
Thomas Hill
Piotr Makarczyk
Johann-Peter Melder
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
    • C07C209/52—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of imines or imino-ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/33—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings
    • C07C211/34—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton
    • C07C211/36—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of rings other than six-membered aromatic rings of a saturated carbon skeleton containing at least two amino groups bound to the carbon skeleton
    • C07C2101/14—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
US12/520,575 2006-12-22 2007-12-19 Continuous process for the hydrogenation of 3-cyano-3,5,5-trimethyl-cyclohexylimine Expired - Fee Related US8884063B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP06127089 2006-12-22
EP06127089 2006-12-22
EP06127089.8 2006-12-22
PCT/EP2007/064171 WO2008077852A1 (de) 2006-12-22 2007-12-19 Kontinuierliches verfahren zur hydrierung von 3-cyano-3,5,5-trimethyl-cyclohexylimin

Publications (2)

Publication Number Publication Date
US20100036168A1 US20100036168A1 (en) 2010-02-11
US8884063B2 true US8884063B2 (en) 2014-11-11

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US12/520,575 Expired - Fee Related US8884063B2 (en) 2006-12-22 2007-12-19 Continuous process for the hydrogenation of 3-cyano-3,5,5-trimethyl-cyclohexylimine

Country Status (5)

Country Link
US (1) US8884063B2 (de)
EP (1) EP2125696B1 (de)
JP (1) JP2010513396A (de)
CN (1) CN101568516A (de)
WO (1) WO2008077852A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2310354A2 (de) * 2008-07-25 2011-04-20 Basf Se 3-aminomethyl-1-cyclohexylamin und ein verfahren zu dessen herstellung
US8586794B2 (en) 2008-07-25 2013-11-19 Basf Se 5-isopropyl-3-aminomethyl-2-methyl-1-amino-cyclohexane (carvone diamine), and method for the production thereof
WO2010069856A1 (de) 2008-12-19 2010-06-24 Basf Se Verfahren zur herstellung von reinem triethanolamin (teoa)
CN102924291B (zh) 2011-08-08 2014-08-06 万华化学集团股份有限公司 3-氨甲基-3,5,5-三甲基环己胺的制备方法
KR101732431B1 (ko) 2012-12-07 2017-05-08 완후아 케미컬 그룹 코., 엘티디 3-아미노메틸-3,5,5-트리메틸 사이클로헥실아민의 제조 방법
CN104230721B (zh) * 2013-06-05 2016-05-18 万华化学集团股份有限公司 3-氨甲基-3,5,5-三甲基环己胺的制备方法
CN103664638B (zh) * 2013-12-31 2016-04-13 张锦碧 一种异佛尔酮二胺的简易制备方法
BR112017003878A2 (pt) * 2014-08-28 2018-01-23 Basf Se processo para produzir aminas primárias.
CN104370750B (zh) * 2014-10-14 2016-01-20 万华化学集团股份有限公司 一种3-氨甲基-3,5,5-三甲基环己胺的制备方法
CN108017547B (zh) 2017-12-22 2019-07-02 浙江新和成股份有限公司 一种异佛尔酮腈亚胺加氢还原制备异佛尔酮二胺的方法
CN116867764A (zh) 2021-02-16 2023-10-10 巴斯夫欧洲公司 异佛尔酮二胺的制造方法
WO2022253610A1 (en) 2021-06-02 2022-12-08 Basf Se Method for manufacture of isophoronediamine

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0394968A1 (de) 1989-04-25 1990-10-31 Union Carbide Chemicals And Plastics Company, Inc. Aminierung von Karbonylen
EP0449089A1 (de) 1990-03-30 1991-10-02 BASF Aktiengesellschaft Verfahren zur Herstellung von 3-Aminomethyl-3,5,5,-trimethyl-cyclohexylamin
EP0623585A1 (de) 1993-04-27 1994-11-09 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von Aminen durch reduktive Aminierung in Gegenwart eines Cobalt-Katalysators
DE4343890A1 (de) 1993-12-22 1995-06-29 Degussa Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
DE19507398C1 (de) 1995-03-03 1996-09-12 Basf Ag Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
DE19747913C1 (de) 1997-10-30 1999-02-11 Degussa Verfahren zur Herstellung primärer und/oder sekundärer Amine aus Iminen oder Nitrilen, insbesondere zur Herstellung von 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamin (Isophorondiamin) aus 3-Cyano-3,5,5-trimethylcyclohexanimin (Isophoronnitril-imin) durch Hydrierung in Gegenwart eines quaternären Ammoniumhydroxids
DE19756400A1 (de) 1997-12-18 1999-06-24 Basf Ag Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamin mit einem cic/trans-Isomerenverhältnis von mindestens 70/30

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0394968A1 (de) 1989-04-25 1990-10-31 Union Carbide Chemicals And Plastics Company, Inc. Aminierung von Karbonylen
EP0449089A1 (de) 1990-03-30 1991-10-02 BASF Aktiengesellschaft Verfahren zur Herstellung von 3-Aminomethyl-3,5,5,-trimethyl-cyclohexylamin
DE4010227A1 (de) 1990-03-30 1991-10-02 Basf Ag Verfahren zur herstellung von 3-aminomethyl-3,5,5-trimethyl-cyclohexylamin
US5371292A (en) 1990-03-30 1994-12-06 Basf Aktiengesellschaft Preparation of 3-aminomethyl-3,5,5-trimethyl-cyclohexylamine
EP0623585A1 (de) 1993-04-27 1994-11-09 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von Aminen durch reduktive Aminierung in Gegenwart eines Cobalt-Katalysators
US5504254A (en) 1993-12-22 1996-04-02 Degussa Aktiengesellschaft Process for the preparation of isophoronediamine
DE4343890A1 (de) 1993-12-22 1995-06-29 Degussa Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
DE19507398C1 (de) 1995-03-03 1996-09-12 Basf Ag Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethylcyclohexylamin
US5756845A (en) 1995-03-03 1998-05-26 Basf Aktiengesellschaft Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine
DE19747913C1 (de) 1997-10-30 1999-02-11 Degussa Verfahren zur Herstellung primärer und/oder sekundärer Amine aus Iminen oder Nitrilen, insbesondere zur Herstellung von 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamin (Isophorondiamin) aus 3-Cyano-3,5,5-trimethylcyclohexanimin (Isophoronnitril-imin) durch Hydrierung in Gegenwart eines quaternären Ammoniumhydroxids
US6011179A (en) 1997-10-30 2000-01-04 Degussa-Huls Ag Process for the production of amines from imines of nitriles
DE19756400A1 (de) 1997-12-18 1999-06-24 Basf Ag Verfahren zur Herstellung von 3-Aminomethyl-3,5,5-trimethyl-cyclohexylamin mit einem cic/trans-Isomerenverhältnis von mindestens 70/30
US6022999A (en) 1997-12-18 2000-02-08 Basf Aktiengesellschaft Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30

Also Published As

Publication number Publication date
CN101568516A (zh) 2009-10-28
US20100036168A1 (en) 2010-02-11
EP2125696B1 (de) 2012-10-31
WO2008077852A1 (de) 2008-07-03
EP2125696A1 (de) 2009-12-02
JP2010513396A (ja) 2010-04-30

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