US7820050B2 - Cyclic aeration system for submerged membrane modules - Google Patents

Cyclic aeration system for submerged membrane modules Download PDF

Info

Publication number
US7820050B2
US7820050B2 US12/574,974 US57497409A US7820050B2 US 7820050 B2 US7820050 B2 US 7820050B2 US 57497409 A US57497409 A US 57497409A US 7820050 B2 US7820050 B2 US 7820050B2
Authority
US
United States
Prior art keywords
air
bubbles
flow
seconds
aerators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US12/574,974
Other versions
US20100025327A1 (en
Inventor
Pierre Lucien Cote
Arnold Janson
Hamid R. Rabie
Manwinder Singh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zenon Technology Partnership
Original Assignee
Zenon Technology Partnership
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CA 2278085 external-priority patent/CA2278085A1/en
Priority claimed from CA 2279766 external-priority patent/CA2279766A1/en
Priority claimed from PCT/CA1999/000940 external-priority patent/WO2000021890A1/en
Priority claimed from US09/814,737 external-priority patent/US6550747B2/en
Priority to US12/574,974 priority Critical patent/US7820050B2/en
Application filed by Zenon Technology Partnership filed Critical Zenon Technology Partnership
Assigned to ZENON ENVIRONMENTAL INC. reassignment ZENON ENVIRONMENTAL INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COTE, PIERRE LUCIEN, JANSON, ARNOLD, RABIE, HAMID R., SINGH, MANWINDER
Assigned to ZENON TECHNOLOGY PARTNERSHIP reassignment ZENON TECHNOLOGY PARTNERSHIP ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ZENON ENVIRONMENTAL INC.
Publication of US20100025327A1 publication Critical patent/US20100025327A1/en
Priority to US12/885,063 priority patent/US7922910B2/en
Publication of US7820050B2 publication Critical patent/US7820050B2/en
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/08Prevention of membrane fouling or of concentration polarisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/18Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/026Wafer type modules or flat-surface type modules
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D63/00Apparatus in general for separation processes using semi-permeable membranes
    • B01D63/02Hollow fibre modules
    • B01D63/04Hollow fibre modules comprising multiple hollow fibre assemblies
    • B01D63/043Hollow fibre modules comprising multiple hollow fibre assemblies with separate tube sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • B01F23/23121Diffusers having injection means, e.g. nozzles with circumferential outlet
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • B01F23/23124Diffusers consisting of flexible porous or perforated material, e.g. fabric
    • B01F23/231241Diffusers consisting of flexible porous or perforated material, e.g. fabric the outlets being in the form of perforations
    • B01F23/231242Diffusers consisting of flexible porous or perforated material, e.g. fabric the outlets being in the form of perforations in the form of slits or cut-out openings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/231Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids by bubbling
    • B01F23/23105Arrangement or manipulation of the gas bubbling devices
    • B01F23/2312Diffusers
    • B01F23/23126Diffusers characterised by the shape of the diffuser element
    • B01F23/231265Diffusers characterised by the shape of the diffuser element being tubes, tubular elements, cylindrical elements or set of tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • B01F23/23Mixing gases with liquids by introducing gases into liquid media, e.g. for producing aerated liquids
    • B01F23/2319Methods of introducing gases into liquid media
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F33/00Other mixers; Mixing plants; Combinations of mixers
    • B01F33/40Mixers using gas or liquid agitation, e.g. with air supply tubes
    • B01F33/406Mixers using gas or liquid agitation, e.g. with air supply tubes in receptacles with gas supply only at the bottom
    • B01F33/4062Mixers using gas or liquid agitation, e.g. with air supply tubes in receptacles with gas supply only at the bottom with means for modifying the gas pressure or for supplying gas at different pressures or in different volumes at different parts of the bottom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/10Maintenance of mixers
    • B01F35/145Washing or cleaning mixers not provided for in other groups in this subclass; Inhibiting build-up of material on machine parts using other means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04Cleaning involving contact with liquid
    • B08B3/10Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • C02F3/1273Submerged membrane bioreactors
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/20Activated sludge processes using diffusers
    • C02F3/201Perforated, resilient plastic diffusers, e.g. membranes, sheets, foils, tubes, hoses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2315/00Details relating to the membrane module operation
    • B01D2315/06Submerged-type; Immersion type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18Use of gases
    • B01D2321/185Aeration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/20By influencing the flow
    • B01D2321/2083By reversing the flow
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/74Treatment of water, waste water, or sewage by oxidation with air
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • This invention relates to filtering liquids and particularly to using scouring air bubbles produced by an aeration system to clean or inhibit the fouling of membranes in a submerged membrane filter.
  • Submerged membranes are used to treat liquids containing solids to produce a filtered liquid lean in solids and an unfiltered retentate rich in solids.
  • submerged membranes are used to withdraw substantially clean water from wastewater and to withdraw potable water from water from a lake or reservoir.
  • the membranes are generally arranged in modules which comprise the membranes and headers attached to the membranes.
  • the modules are immersed in a tank of water containing solids.
  • a transmembrane pressure is applied across the membrane walls which causes filtered water to permeate through the membrane walls. Solids are rejected by the membranes and remain in the tank water to be biologically or chemically treated or drained from the tank.
  • Air bubbles are introduced to the tank through aerators mounted below the membrane modules and connected by conduits to an air blower.
  • the air bubbles rise to the surface of the tank water and create an air lift which recirculates tank water around the membrane module.
  • the rate of air flow is within an effective range, the rising bubbles and tank water scour and agitate the membranes to inhibit solids in the tank water from fouling the pores of the membranes.
  • there is also an oxygen transfer from the bubbles to the tank water which, in wastewater applications, provides oxygen for microorganism growth.
  • the air blower generally runs continuously to minimize stress on the air blower motors and to provide a constant supply of air for microorganism growth if desired.
  • an operator increases the rate of air flow to the aerators if more cleaning is desired. This technique, however, stresses the membranes and air blower motors and increases the amount of energy used which significantly increases the operating costs of the process. Conversely, an operator typically decreases the rate of air flow to the aerators if less cleaning is desired. With this technique, however, the rate of air flow is often below the effective range, which does not provide efficient cleaning. Alternately, some operators reduce the average rate of air flow by providing air intermittently. This method allows for an air flow rate in the effective range but at the expense of the air blowers which wear rapidly when turned off and on frequently. In many cases, the warranty on the air blower is voided by such intermittent operation.
  • the recirculation pattern typically includes “dead zones” where tank water is not reached by the recirculating tank water and bubbles.
  • the membranes in these dead zones, or the parts of the membranes in these dead zones, are not effectively cleaned and may be operating in water having a higher concentration of solids than in the tank water generally. Accordingly, these membranes, or the affected parts of these membranes, quickly foul with solids.
  • a related problem occurs in modules where hollow fibre membranes are installed with a small degree of slack to allow the membranes to move and shake off or avoid trapping solids.
  • the movement of tank water in the tank encourages slackened membranes to assume a near steady state position, particularly near the ends of the membranes, which interferes with the useful movement of the fibres.
  • the cyclic aeration system uses a valve set and a valve set controller to connect an air supply to a plurality of distinct branches of an air delivery network.
  • the distinct branches of the air delivery network are in turn connected to aerators located below the membrane modules. While the air supply is operated to supply a steady initial flow of air, the valve set and valve set controller split and distribute the initial air flow between the distinct branches of the air distribution system such that the air flow to each distinct branch alternates between a higher flow rate and a lower flow rate in repeated cycles.
  • valves in the valve set open or close in less than about 5 seconds, preferably less than about 3 seconds.
  • the valve or valves associated with each distinct branch of the air delivery network begin to either open or close, or both, automatically with or in response to the opening or closing of a valve or valves associated with another distinct branch of the air delivery system.
  • the valve or valves associated with each distinct branch of the air delivery network begin to either close automatically with or in response to the opening, preferably to a fully open state, of the valve or valves associated with another distinct branch of the air delivery system.
  • position sensors may be fitted to the valves and the valve set controller configured such that the failure of a valve or valves to open as desired prevents closure of the valve or valves associated with another distinct branch of the air delivery system.
  • the cyclic aeration system is used to provide intermittent aeration to membrane modules arranged in a plurality of filtration zones, each associated with a distinct branch of the air delivery network.
  • the cyclic aeration system is configured and operated to provide aeration for a predetermined amount of time to each filtration zone in turn.
  • the cyclic aeration system is used to provide intense aeration to a group of membrane modules.
  • the cyclic aeration system is configured and operated to provide air to a branch of the air delivery network alternating between a higher flow rate and a lower flow rate in cycles of 120 seconds or less.
  • aerators associated with a first branch of the air delivery network are interspersed with aerators associated with a second branch of the air delivery network. Air flow at a higher flow rate is alternated between the first and second branches of the air delivery network in cycles of 120 seconds or less. Where two distinct branches of the air delivery system are provided, air preferably flows at the higher rate in each distinct branch for about one half of each cycle.
  • FIG. 1A is a schematic drawing of a submerged membrane reactor.
  • FIGS. 1B , 1 C and 1 D are drawings of membrane modules according to embodiments of the present invention.
  • FIG. 2 is a plan view schematic of an aeration system according to an embodiment of the present invention.
  • FIG. 3 is a series of graphs showing the effect of operating an embodiment of the present invention.
  • FIGS. 4A , 4 B, 4 C and 4 D are schematic drawings of valve sets and valve controllers according to embodiments of the invention.
  • FIGS. 4E and 4F are diagrams of valve position over time.
  • FIG. 5 is a plan view schematic of membrane modules and an aeration system according to an embodiment of the invention.
  • FIG. 6 is a plan view schematic of membrane modules and an aeration system according to another embodiment of the invention.
  • FIG. 7A is a plan view schematic of membrane modules and an aeration system according to another embodiment of the invention.
  • FIGS. 7B , 7 C and 7 D are elevational representations of membrane modules and parts of an aeration system according to alternatives to the embodiment of FIG. 7A .
  • FIGS. 8A and 8B are elevational representations of membrane modules and parts of an aeration system according to an embodiment of the invention under the influence of a cyclic aeration system.
  • FIGS. 9A , 9 B, 9 C and 9 D are drawings of aerators according to an embodiment of the invention.
  • FIGS. 10A , 10 B and 10 C are charts showing the results of tests performed on embodiments of the invention having two groups of aerators.
  • FIG. 11 is a chart showing the results of tests performed on embodiments of the invention having a single group of aerators.
  • FIG. 1A the general arrangement of a reactor 10 is shown.
  • the description of the reactor 10 in this section applies generally to various embodiments to be described below to the extent that it is not inconsistent with the description of any particular embodiment.
  • the reactor 10 has a tank 12 which is initially filled with feed water 14 through an inlet 16 .
  • the feed water 14 may contain microorganisms, suspended solids or other matter which will be collectively called solids. Once in the tank, the feed water 14 becomes tank water 18 which may have increased concentrations of the various solids, particularly where the reactor 10 is used to treat wastewater.
  • One or more membrane modules 20 are mounted in the tank and have one or more headers 22 in fluid communication with a permeate side of one or more membranes 6 .
  • the membranes 6 in the membrane modules 20 have a pore size in the microfiltration or ultrafiltration range, preferably between 0.003 and 10 microns.
  • Membrane modules 20 are available in various sizes and configurations with various header configurations.
  • the membranes 6 may be hollow fibres potted in one or more headers 22 such that the lumens of the hollow fibres are in fluid communication with at least one header 22 .
  • the headers 22 may be of any convenient shape but typically have a rectangular or round face where they attach to the membranes 6 .
  • the membranes 6 may be flat sheets which are typically oriented vertically in a spaced apart pair with headers 22 on all four sides in fluid communication with the resulting interior surface.
  • a membrane module 20 may have one or more microfiltration or ultrafiltration membranes 6 and many membrane modules 20 may be joined together to form larger membrane modules, or cassettes, but all such configurations will be referred to as membrane modules 20 .
  • FIGS. 1B , 1 C and 1 D illustrate preferred membrane modules 20 having rectangular skeins 8 .
  • hollow fibre membranes 23 are held between two opposed headers 22 .
  • the ends of each membrane 23 are surrounded by potting resin to produce a watertight connection between the outside of the membrane 23 and the headers 22 while keeping the lumens of the hollow fibre membranes 23 in fluid communication with at least one header 22 .
  • the rectangular skeins 8 may be oriented in a horizontal plane ( FIG. 1B ), vertically ( FIG. 1C ) or horizontally in a vertical plane ( FIG. 1D ).
  • a plurality of rectangular skeins 8 are typically joined together in a membrane module 20 .
  • each rectangular skein 8 has a mass of hollow fibre membranes 23 between 2 cm and 10 cm wide.
  • the hollow fibre membranes 23 typically have an outside diameter between 0.4 mm and 4.0 mm and are potted at a packing density between 10% and 40%.
  • the hollow fibre membranes 23 are typically between 400 mm and 1,800 mm long and typically mounted with between 0.1% and 5% slack.
  • the tank 12 is kept filled with tank water 18 above the level of the membranes 6 in the membrane modules 20 during permeation.
  • Filtered water called permeate 24 flows through the walls of the membranes 6 in the membrane modules 20 under the influence of a transmembrane pressure and collects at the headers 22 to be transported to a permeate outlet 26 through a permeate line 28 .
  • the transmembrane pressure is preferably created by a permeate pump 30 which creates a partial vacuum in a permeate line 28 .
  • the transmembrane pressure may vary for different membranes and different applications, but is typically between 1 kPa and 150 kPa.
  • Permeate 24 may also be periodically flowed in a reverse direction through the membrane modules 20 to assist in cleaning the membrane modules 20 .
  • the membranes 6 reject solids which remain in the tank water 18 . These solids may be removed by a number of methods including digestion by microorganisms if the reactor 10 is a bioreactor or draining the tank 12 periodically or by continuously removing a portion of the tank water 18 , the latter two methods accomplished by opening a drain valve 32 in a drain conduit 34 at the bottom of the tank.
  • An aeration system 37 has one or more aerators 38 connected by an air delivery system 40 and a distribution manifold 51 to an air source 42 , which is typically one or more air blowers, and produces bubbles 36 in the tank water.
  • the aerators 38 may be of various types including distinct aerators, such as cap aerators, or simply holes drilled in conduits attached to or part of the distribution manifold 51 .
  • the bubbles 36 are preferably made of air but may be made of other gasses such as oxygen or oxygen enriched air if required.
  • the aerators 38 are located generally below the membrane modules 20 . If the membrane modules 20 are made of rectangular skeins 8 having vertical hollow fibre membranes 23 , the aerators 38 are preferably located to produce bubbles near the edges of the lower header. With rectangular skeins 8 having hollow fibre membranes 23 in a vertical plane, the aerators 38 are preferably located to produce bubbles in a line directly below the vertical plane. With rectangular skeins 8 having hollow fibre membranes 23 in a horizontal plane, the aerators 38 are preferably located to produce bubbles evenly dispersed below the plane.
  • the bubbles 36 agitate the membranes 6 which inhibits their fouling or cleans them.
  • the bubbles 36 also decrease the local density of tank water 18 in or near the membrane modules 20 which creates an air-lift effect causing tank water 18 to flow upwards past the membrane modules 20 .
  • the air lift effect causes a recirculation pattern 46 in which the tank water 18 flows upwards through the membrane modules 20 and then downwards along the sides or other parts of the tank.
  • the bubbles 36 typically burst at the surface and do not generally follow the tank water 18 through the downward flowing parts of the recirculation pattern 46 .
  • the tank water 18 may also flow according to, for example, movement from the inlet 16 to the drain conduit 34 , but such flow does not override the flow produced by the bubbles 36 .
  • the bubbles 36 have an average diameter between 0.1 and 50 mm. Individual large bubbles 36 are believed to be more effective in cleaning or inhibiting fouling of the membranes 6 , but smaller bubbles 36 are more efficient in transferring oxygen to the tank water 18 and require less energy to produce per bubble 36 . Bubbles 36 between 3 mm and 20 mm, and more preferably between 5 mm and 15 mm in diameter, are suitable for use in many wastewater applications. Bubbles 36 in the ranges described immediately above provide effective cleaning of the membranes 6 and acceptable transfer of oxygen to the tank water 18 without causing excessive foaming of the tank water 18 at the surface of the tank 12 . If the reactor 10 is used to create potable water or for other applications where oxygen transfer is not required, then bubbles between 5 mm and 25 mm are preferred.
  • the bubbles 36 may be larger than a hole in an aerator 38 where the bubble 36 is created according to known factors such as air pressure and flow rate and the depth of the aerators 38 below the surface of the tank water 18 .
  • the aerators 38 are located near the bottom of a large tank 12 , such as those used in municipal treatment works, an aerator 38 with holes of between 2 mm and 15 mm and preferably between 5 mm and 10 mm might be used.
  • the air pressure supplied (relative to atmospheric pressure) is typically determined by the head of water at the depth of submergence of the aerators 38 (approximately 10 kPa per metre) plus an additional pressure required to get the desired rate of air flow through the aerators 38 .
  • a cyclic aeration system 237 having an air supply 242 in fluid communication with a valve set 254 , the valve set 254 controlled by a valve controller 256 .
  • the valve set 254 is in fluid communication with an air delivery network 240 having a plurality of distinct branches each in fluid communication with distinct manifolds 251 in fluid communication with conduit aerators 238 .
  • Other types of aerators may also be used with suitable modifications to the manifolds 251 or air delivery network, but conduit aerators 238 are preferred.
  • the third branch of the air delivery network 240 and the third manifold 251 are shown in dashed lines to indicate that the number of distinct branches of the air delivery network 240 and manifolds 251 may be two or more, but preferably not more than 15.
  • the air supply 242 is a source of pressurized air, typically one or more air blowers, and provides a flow of a gas at an initial rate to the cyclic aeration system.
  • the gas is most often air, but may also be oxygen, oxygen or ozone enriched air, or nitrogen in which cases the air supply 242 will include oxygenation or ozonation equipment etc. in addition to an air blower. In this document, however, the term “air” will be used to refer to any appropriate gas.
  • the amount of air provided by the air supply 242 is best determined by summing the amount of air provided to all conduit aerators 238 (to be described below) serviced by the air supply 242 . It is preferred that the air supply 242 supply a constant amount of air over time.
  • valve set 254 and valve controller 256 will be described in more detail below. In general terms, however, the valve set 254 and valve controller 256 (a) split the air flow from the air supply 242 between the branches of the air delivery network 240 such that, at a point in time, some of the branches receive air at a higher rate of air flow and some of the branches receive air at a lower rate of air flow and (b) switch which branches of the air delivery network 240 receive the higher and lower rates of air flow in repeated cycles.
  • Rh indicates a higher rate of air flow
  • RI indicates a lower rate of air flow
  • the time from 0 to t 3 indicates a cycle which would be repeated.
  • the cycle is divided into three substantially equal time periods, 0-t 1 ; t 1 -t 2 ; and, t 2 -t 3 .
  • one branch of the air delivery system 240 and its associated manifold 251 receive air at Rh while the others receive air at RI.
  • each branch of the air delivery system 240 and its associated manifold 251 receives air at Rh for one third of the cycles and at RI for two thirds of the cycle.
  • valves sets 254 to be described below can be used to produce smooth variations in air flow rate to a manifold 251 , but it is preferred if the variation is fairly abrupt as suggested by FIG. 3 .
  • the inventors have noticed that such an abrupt change produces a short burst of unusually large bubbles 36 which appear to have a significant cleaning or fouling inhibiting effect.
  • the abrupt changes often also produce a spike in air flow rate shortly after the transition from RI to Rh which produces a corresponding pressure surge. This pressure surge must be kept within the design limits of the cyclic aeration system 237 or appropriate blow off valves etc. provided.
  • the amount of air provided to a manifold 251 or branch of air delivery network 240 is dependant on numerous factors but is preferably related to the superficial velocity of air flow for the conduit aerators 238 services.
  • the superficial velocity of air flow is defined as the rate of air flow to the conduit aerators 238 at standard conditions (1 atmosphere and 25 degrees Celsius) divided by the cross sectional area of aeration.
  • the cross sectional area of aeration is determined by measuring the area effectively aerated by the conduit aerators 238 .
  • Superficial velocities of air flow of between 0.013 m/s and 0.15 m/s are preferred at the higher rate (Rh).
  • Air blowers for use in drinking water applications may be sized towards the lower end of the range while air blowers used for waste water applications may be sized near the higher end of the range.
  • RI is typically less than one half of Rh and is often an air off condition with no flow. Within this range, the lower rate of air flow is influenced by the quality of the feed water 14 . An air off condition is generally preferred, but with some feed water 14 , the hollow fibre membranes 23 foul significantly even within a short period of aeration at the lower rate. In these cases, better results are obtained when the lower rate of air flow approaches one half of the higher rate. For feed waters in which the rate of fouling is not significant enough to require a positive lower rate of air flow, RI may still be made positive for other reasons. With some aerators or air delivery systems, a positive lower rate of air flow may be desired, for example, to prevent the aerators from becoming flooded with tank water 18 at the lower rate of air flow.
  • a positive lower rate of air flow may also be used because of leaks in the valves of the valve set 254 or to reduce stresses on the valve set 254 or the air delivery network 240 .
  • the lower rate of air flow may typically be as much as about 10%, but preferably about 5% or less, of the higher rate of air flow without significantly detracting from the performance achieved with a completely air off condition.
  • valves which are typically butterfly valves
  • the lower rate of air flow may be as much as about 10%, but preferably about 5% or less, of the higher rate of air flow typically without significantly detracting from the performance achieved with a completely air off condition.
  • FIGS. 4A , 4 B and 4 C alternative embodiments of the valve set 254 and valve controller 256 are shown.
  • an air supply 242 blows air into a three way valve 292 , preferably a ball valve, with its two remaining orifices connected to two manifolds 251 .
  • a three way valve controller 294 alternately opens an air pathway to one of the manifolds 251 and then the other. Preferably there is a phase shift of 180 degrees so that the air pathway to one of the manifolds 251 opens while the airway to the other manifold 251 closes.
  • the three way valve 292 may be mechanically operated by handle 296 connected by connector 298 to a lever 299 on the three way valve controller 294 .
  • the three way valve controller 294 may be a drive unit turning at the required speed of rotation of the lever 299 .
  • the three way valve controller 294 is a microprocessor and servo, pneumatic cylinder or solenoid combination which can be more easily configured to abruptly move the three way valve 292 .
  • the air supply 242 blows air into a connector 261 which splits the air flow into a low flow line 262 and a high flow line 264 .
  • a valve 266 in the low flow line 262 is adjusted so that flow in the low flow line 262 is preferably less than one half of the flow in the high flow line 264 .
  • a controller 268 preferably a timer, a microprocessor or one or more motors with electrical or mechanical links to the valves to be described next, controls a low valve 270 , which may be a solenoid valve or a 3 way ball valve, and a high valve 272 , which may be a solenoid valve or a 3 way ball valve, so that for a first period of time (a first part of a cycle) air in the low flow line 262 flows to one of the manifolds 251 and air in the high flow line flows to the other manifold 251 .
  • a low valve 270 which may be a solenoid valve or a 3 way ball valve
  • a high valve 272 which may be a solenoid valve or a 3 way ball valve
  • the low valve 270 and high valve 272 are controlled so that air in the low flow line 262 flows to the a manifold 251 through cross conduit 274 and air in the high flow line 264 flows to the other manifold 251 through reverse conduit 276 .
  • air supply 242 blows air into a blower header 260 connected by slave valves 284 to manifolds 251 .
  • Each slave valve 284 is controlled by a slave device 280 , typically a solenoid, pneumatic or hydraulic cylinder or a servo motor.
  • the slave devices 280 are operated by a slave controller 282 set up to open and close the slave valves 284 in accordance with the system operation described in this section and the embodiments below.
  • the slave controller 282 may be a microprocessor, an electrical circuit, a hydraulic or pneumatic circuit or a mechanical linkage.
  • the slave devices 280 and the slave controller 282 together comprise the valve set controller 256 .
  • the valve set controller 256 of FIG. 4C may also be used with the other apparatus of FIG. 4B .
  • air supply 242 blows air into a blower header 260 connected by slave valves 284 to manifolds 251 .
  • Each slave valve 284 is controlled by a valve set controller 256 which consists of a plurality of cams 281 , driven by a motor 279 .
  • the cams 281 may drive the slave valves 284 directly (as illustrated) or control another device, such as a pneumatic cylinder, which directly opens or closes the slave valves 284 .
  • the shape of the cams 281 is chosen to open and close the slave valves 284 in accordance with the system operation described in this section and the embodiments below.
  • the valve set controller 256 of FIG. 4D may also be used with the other apparatus of FIG. 4B .
  • the opening and closing times of the slave valves 284 are mechanically (preferably by a pneumatic circuit) or electrically (preferably with a programmable logic controller—PLC) interconnected such that each slave valve 284 either opens or closes, or both, automatically with or in response to the opening or closing of a slave valve or slave valves 284 in another distinct branch of the air delivery network 240 .
  • PLC programmable logic controller
  • the slave controller 282 may incorporate a timer, but preferably does not open and close slave valves 284 based solely on inputs from the timer. For example, an acceptable set up for the slave controller 282 is to have the opening of the slave valves 284 of a distinct branch determined by time elapsed since those slave valves 284 were closed, but the closing of those slave valves 284 is determined by the slave valves 284 of another distinct branch having opened to a selected degree.
  • the opening and closing movements of the slave valves 284 are preferably overlapped to minimize the spike in air flow rate and pressure surge shortly after the transition from RI to Rh mentioned above.
  • the opening and closing times of the slave valves 284 are arranged such that the slave valve or valves 284 to any distinct branch of the air delivery network 240 do not start to close until the slave valve or valves 284 to any other distinct branch of the air delivery system 240 are fully open.
  • the valve set controller 256 includes a slave controller 282 , position sensors are fitted to the slave valves 284 .
  • the slave controller 282 is configured such that the failure of a slave valve or valves 284 to open as desired prevents the closure of the slave valve or valves 284 of another distinct branch of the air delivery network 240 . In this way, in addition to minimizing and possibly substantially eliminating any spike in air flow, damage to the cyclic aeration system 237 is avoided if the slave valve or valves 284 to a distinct branch of the air delivery network 240 fail to open.
  • the overall goal of the valve set controller 256 is to produce rapid changes between RI and Rh.
  • the time required to open or close (partially or fully as desired) a slave valve 284 from its closed (fully or partially) or opened position respectively is preferably less than about 5 seconds and more preferably less than about 3 seconds when used with very short cycle times of 40 seconds or less.
  • FIGS. 4E and 4F show suitable slave valve 284 positions over time for an air distribution network 240 having two distinct branches where RI is an air off condition, the cycle time is 20 seconds and the valve opening time is 3 seconds. In FIG.
  • the start of the closing times of the slave valves 284 are interconnected such that each slave valve 284 begins to close when the other is fully open.
  • the start of the closing times of the slave valves 284 are interconnected such that each slave valve 284 begins to close when the other begins to open.
  • the fully closed position of the slave valves 284 illustrated can be replaced by a partially closed position, or the apparatus of FIG. 4B can be used.
  • two manifolds 251 are controlled by two slave valves, 284 a and 284 b , through two slave devices, 280 a and 280 b .
  • Each slave valve 284 has a limit switch 285 which provides a signal to the slave controller 282 indicating whether that slave valve 284 is open or at a desired partially or fully closed setting.
  • the slave controller 282 is a PLC and the slave devices 280 are servo motors or pneumatic cylinders
  • the following PLC programming control narrative can be used to obtain air cycling as described in relation to FIG. 4E :
  • slave controller 282 sends a signal to slave devices 280 a and 280 b to open slave valve 284 a and close slave valve 284 b respectively.
  • slave controller 282 checks for an “open” signal from limit switch 285 a and a “closed” signal from limit switch 285 b.
  • slave controller 282 sends a signal to start blower 242 .
  • slave controller 282 sends a signal to slave device 280 b to open slave valve 284 b.
  • slave controller 282 checks for an “open” signal from limit switch 285 b ; if an “open” signal is received, proceed to step 6; if an “open: signal is not received, sound alarm and go to a continuous aeration mode, for example, by operating bypass valves to provide air to all manifolds 251 direct from the blower 242 .
  • Slave controller 282 sends a signal to slave device 280 a to close slave valve 284 a.
  • slave controller 282 checks for a “closed” signal from limit switch 285 a ; if a “closed” signal is received, proceed with step 8; if a “closed” signal is not received, sound alarm and go to a continuous aeration mode.
  • slave controller 282 sends a signal to slave device 280 a to open slave valve 284 a.
  • slave controller 282 checks for an “open” signal from limit switch 285 a ; if an “open” signal is received, proceed with step 10; if an “open” signal is not received, sound alarm and go to a continuous aeration mode.
  • Slave controller 282 sends a signal to slave device 280 b to close slave valve 284 b.
  • slave controller 282 checks for a “closed” signal from limit switch 285 b ; if a “closed” signal is received, proceed with step 12; if a “closed” signal is not received, sound alarm and go to a continuous aeration mode.
  • slave controller 282 sends signal to slave device 280 b to open slave valve 284 b.
  • the regime of FIG. 4E provides the advantage discussed above of having at least one distinct branch of the air delivery network 240 fully open at all times but the total time for the transition between RI to Rh is extended to twice the valve opening time. This method is preferred for cycle times of 20 seconds or more.
  • the regime of FIG. 4F produces a faster transition from RI to Rh but at the risk of over stressing the cyclic aeration system 237 if the valve or valves 262 to a distinct branch start to open but then fail to open completely. This risk must be addressed with other system fail safes known in the art.
  • the regime of FIG. 4F is preferred for cycle time less than 20 seconds and when valve opening/closing times are greater than about 3 seconds. Modifications to the narrative above can be used to produce other regimes of air cycling.
  • an aeration system 237 is shown for use in providing intermittent aeration to six membrane modules 20 (shown with dashed lines) in a filtration tank 412 .
  • the filtration tank 412 has six filtration zones (also shown with dashed lines) corresponding to the six membrane modules 20 .
  • the filtration zones could be provided in separate tanks with one or more membrane modules 20 in each tank.
  • the membrane modules 20 will be used to filter a relatively foulant free surface water such that intermittent aeration is suitable.
  • the air delivery network 240 has six distinct branches each connected to a header 251 in a filtration zone. Each header 251 is in turn connected to conduit aerators 238 mounted generally below the membrane modules 20 .
  • the valve set 254 and valve controller 256 are configured and operated to provide air from the air supply 242 to the air delivery network 240 in a 7.5 minute cycle in which air at the higher rate is supplied for about 75 seconds to each branch of the air delivery network 240 in turn. While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate. Accordingly, each header 251 receives air at the higher rate for 75 seconds out of every 7.5 minutes. Operation of the air supply 242 , however, is constant and an air supply sized for one manifold 251 is used to service six such manifolds.
  • backwashing of the membrane modules 20 is also performed on the membrane modules in turn such that backwashing of a membrane module 20 occurs while the membrane module 20 is being aerated.
  • the membrane modules 20 can be backwashed most easily when each membrane module 20 is serviced by its own permeate pump 30 and associated backwashing apparatus.
  • the permeation and backwashing apparatus are typically limited to about 8 to 11 ML/d capacity. Accordingly a medium size plant (i.e. in the range of 40 ML/d) will have several membrane modules 20 serviced by sets of permeation and backwashing apparatus which can be individually controlled.
  • backwashing is performed on the membrane modules 20 in turn to produce an even supply of permeate 24 regardless of aeration.
  • an aeration system 237 is shown for use in providing aeration alternating between two sets of membrane modules 20 (shown with dashed lines) in a filtration vessel 512 .
  • the filtration vessel 512 has two filtration zones (also shown with dashed lines) corresponding to the two sets of membrane modules 20 .
  • the filtration zones could be provided in separate tanks with one or more membrane modules 20 in each tank.
  • the membrane modules 20 will be used to filter a relatively foulant rich surface water or a wastewater such that intense aeration is suitable.
  • the air delivery network 240 has two distinct branches each connected to headers 251 in a filtration zone. Each header 251 is in turn connected to conduit aerators 238 mounted generally below the membrane modules 20 .
  • the valve set 254 and valve controller 256 are configured and operated to provide air from the air supply 242 to the air delivery network 240 in a short cycle in which air at the higher rate is supplied for one half of the cycle to each branch of the air delivery network 240 . While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate.
  • the preferred total cycle time may vary with the depth of the filtration vessel 512 , the design of the membrane modules 20 , process parameters and the conditions of the feed water 14 to be treated, but preferably is at least 10 seconds (5 seconds at the full rate and 5 seconds at the reduced rate) where the filtration vessel 512 is a typical municipal tank between 1 m and 10 m deep.
  • a cycle time of up to 120 seconds may be effective, but preferably the cycle time does not exceed 60 seconds (30 seconds at the full rate, 30 seconds at the reduced rate) where the filtration vessel 512 is a typical municipal tank.
  • an aeration system 237 is shown for use in aerating membrane modules 20 in a process tank 612 .
  • the membrane modules 20 will be used to filter a relatively foulant rich surface water or a wastewater such that intense aeration is suitable.
  • the air delivery network 240 has two distinct branches each connected to two distinct headers 251 , both in a single filtration zone.
  • the headers 251 will be referred to as header 251 a and 251 b where convenient to distinguish between them.
  • Headers 251 are connected to conduit aerators 238 such that the conduit aerators 238 attached to header 251 a are interspersed with the conduit aerators 238 attached to header 251 b .
  • FIG. 7A One such arrangement is shown in FIG. 7A in which header 251 a is connected to conduit aerators 238 directly beneath the membrane modules 20 while header 251 b is connected to horizontally displaced conduit aerators 238 located beneath and between the membrane modules 20 .
  • header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located beneath the membrane modules 20 .
  • header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located directly beneath alternating membrane modules 20 .
  • header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located directly beneath and between alternating membrane modules 20 . In each of these cases, the pattern may be repeated where more membrane modules 20 are used.
  • Each of header 251 a and header 251 b are connected to a distinct branch of the air delivery network 240 in turn connected to a valve set 254 .
  • the valve set 254 and a valve controller 256 are configured and operated to provide air from an air supply 242 to the air delivery network 240 in a short cycle in which air at a higher rate is supplied for one half of the cycle to each branch of the air delivery network 240 . While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate.
  • the lower flow rate is preferably one half or less of the higher flow rate and, where conditions allow it, the lower flow rate is preferably an air-off condition.
  • the total cycle time may vary with the depth of the process tank 612 , the design of the membrane modules 20 , process parameters and the conditions of the feed water 14 to be treated, but typically is at least 2 seconds (1 second at the full rate and 1 second at the reduced rate), preferably 10 seconds or more, and less than 120 seconds (60 seconds at the full rate, 60 seconds at the reduced rate), preferably less 60 seconds, where the process tank 612 is a typical municipal tank between 1 m and 10 m deep. More preferably, however, the cycle time is between 20 seconds and 40 seconds in length.
  • Short cycles of 10 seconds or less may not be sufficient to establish regions of different densities in the tank water 18 in a deep tank 12 where such time is insufficient to allow the bubbles 36 to rise through a significant distance relative to the depth of the tank 12 .
  • Long cycles of 120 seconds or more may result in parts of a membrane module 20 not receiving bubbles 36 for extended periods of time which can result in rapid fouling.
  • the beneficial effects of the invention may be linked to creating transient flow and it is believed that factors which effect acceleration of the water column above a set of conduit aerators 238 , such as tank depth or shrouding, could modify the preferred cycle times stated above.
  • conduit aerators 238 having the conduit aerators 238 connected to header 251 a interspersed with the conduit aerators 238 attached to header 251 b creates varying areas of higher and lower density in the tank water 18 within a filtration zone. As described above, the inventors believe that these variations produce transient flow in the tank water 18 . Where the effective areas of aeration above conduit aerators 238 attached to distinct branches of the air delivery network 240 are sufficiently small, however, the inventors believe that appreciable transient flow is created in a horizontal direction between areas above conduit aerators 238 attached to different branches of the air delivery network 240 . Referring to FIGS. 7A , 7 B, 7 C, 7 D the membrane modules 20 shown are preferably of the size of one or two rectangular skeins 8 .
  • FIGS. 8A and 8B second membrane modules 220 made of rectangular skeins 8 with hollow fibre membranes 23 oriented vertically aerated by a cyclic aeration system 237 with conduit aerators 238 located relative to the second membrane modules 220 as shown in FIG. 7D .
  • the degree of slack of the hollow fibre membranes 23 is highly exaggerated for easier illustration.
  • only two hollow fibre membranes 23 are illustrated for each vertical rectangular skein 8 although, as discussed above, a rectangular skein 8 would actually be constructed of many hollow fibre membranes 23 .
  • the conduit aerator 238 has an elongated hollow body 302 which is a circular pipe having an internal diameter between 15 mm and 100 mm.
  • a series of holes 304 pierce the body 302 allowing air to flow out of the conduit aerator 238 to create bubbles.
  • the size, number and location of holes may vary but for a rectangular skein 8 , for example, 2 holes (one on each side) of between 5 mm and 10 mm in diameter placed every 50 mm to 100 mm along the body 302 and supplied with an airflow which results in a pressure drop through the holes of between 10 to 100 mm of water at the depth of the conduit aerator 238 are suitable.
  • an outlet 308 At the opposite end of the conduit aerator 238 is an outlet 308 .
  • the highest point on the outlet 308 is located below the lowest point on the aerator inlet 306 by a vertical distance between the minimum and maximum expected pressure drop of water at the depth of the conduit aerator 238 across the holes 304 .
  • the minimum expected pressure drop of water at the depth of the conduit aerator 238 across the holes 304 is preferably at least as much as the distance between the top of the holes 304 and the interior bottom of the body 302 .
  • An air/water interface 309 between the air in the conduit aerator 238 and the water surrounding the conduit aerator 238 will be located below the interior bottom of the body 302 but above the highest point on the outlet 308 . In this way, tank water 18 entering the conduit aerator 238 will flow to the outlet 308 and not accumulate near the holes 304 .
  • FIG. 9B another conduit aerator 238 is shown which is preferred for use with relatively clean tank water 18 .
  • the body 302 has a rectangular cross section but is open on the bottom.
  • the conduit aerator 238 may be a separate component or integrated into the headers 22 of a membrane module 20 in which case the bottom of a lower header 22 may serve as the top of the body 302 .
  • the end of the body 302 is capped with a cap 310 which again may be a part of a header 22 .
  • tank water 18 which seeps into the conduit aerator 238 flows back to the tank water 18 .
  • the sides of the body 302 extend below the bottom of the holes 304 by a distance greater than the expected pressure drop through the holes 304 .
  • FIG. 9C another conduit aerator 238 is similar to the conduit aerator 238 of FIG. 9A except as will be described herein.
  • a rubber sleeve 400 shown partially cut away, covers the body 302 and has slits 402 corresponding with the holes 304 .
  • the slits 402 open when air is flowed into the conduit aerator 238 opening to a larger size when a higher rate of air flow is used. Accordingly, the slits 402 produce larger bubbles 36 at the full rate of air flow and smaller bubbles 36 at the reduced rate of air flow.
  • the reduced size of the bubbles 36 provides improved oxygen transfer efficiency at the reduced rate of air flow.
  • FIG. 9D another conduit aerator is shown which is preferred for use with relatively solids rich tank water 18 .
  • the body 302 is a tube 32 mm in diameter.
  • the holes 304 are 8 mm in diameter and mounted 30 degrees upwards of horizontal. Drainage holes 410 , at the bottom of the body 302 and typically 16 mm in diameter, allow tank water 18 seepage to drain from the body 302 .
  • a cap 411 covers the end of the body 302 .
  • Conduit aerators 238 such as those described above may admit some tank water 18 , even with air flowing through them, which dries out leaving an accumulation of solids.
  • the conduit aerator 238 is alternately flooded and emptied.
  • the difference in water elevation within the body 302 corresponds to the air pressure loss across the holes 304 between the high and low air flow conditions.
  • the resulting cyclical wetting of the conduit aerators 238 helps re-wet and remove solids accumulating in the conduit aerators 238 or to prevent tank water 18 from drying and depositing solids in the conduit aerators 238 . If necessary, this flooding can be encouraged by releasing air from the appropriate manifold by opening a valve vented to atmosphere.
  • ZW 500 membrane modules produced by ZENON Environmental Inc.
  • Each ZW 500 has two rectangular skeins of vertical hollow fiber membranes.
  • the cross sectional area of aeration for each ZW 500 membrane module is approximately 0.175 m2. All air flow rates given below are at standard conditions.
  • a cassette of 8 ZW 500 membrane modules were operated in bentonite suspension under generally constant process parameters but for changes in flux and aeration.
  • a fouling rate of the membranes was monitored to assess the effectiveness of the aeration.
  • Aeration was supplied to the cassette at constant rates of 204 m3/h (i.e. 25.5 m3/h per module) and 136 m3/h and according to various cycling regimes. In the cycled tests, a total air supply of 136 m3/h was cycled between aerators located below the modules and aerators located between and beside the modules in cycles of the durations indicated in FIG. 10A .
  • Aeration at 136 m3/h in 30 second cycles (15 seconds of air to each set of aerators) was approximately as effective as non-cycled aeration at 204 m3/h.
  • 2 ZW 500 membrane modules were operated to produce drinking water from a natural supply of feed water. Operating parameters were kept constant but for changes in aeration. The modules were first operated for approximately 10 days with non-cycled aeration at 25.5 m3/h per module (for a total system airflow 51 m3/h). For a subsequent period of about three days, air was cycled from aerators near one set of modules to aerators near another set of modules such that each module was aerated at 12.8 m3/h for 10 seconds and then not aerated for a period of 10 seconds (for a total system airflow of 12.8 m3/h).
  • the modules were aerated such that each module was aerated at 25.5 m3/h for 10 seconds and then not aerated for a period of 10 seconds (for a total system airflow of 25.5 m3/h).
  • the initial constant airflow was restored.
  • the membrane permeability stabilized at over 250 L/m2/h/bar whereas with non cycled airflow at the initial total system airflow the membrane permeability stabilised at only about 125 L/m2/h/bar.
  • Unit 3 units each containing 2 ZW 500 membrane modules were operated at various fluxes in a membrane bioreactor.
  • Unit 1 had modules operating at 26 L/m2/h and 51 L/m2/h.
  • Unit 2 had modules operating at 31 L/m2/h and 46 L/m2/h.
  • Unit 3 had modules operating at 34 L/m2/h and 51 L/m2/h.
  • the units were first operated for a period of about 10 days with non cycled aeration at 42.5 m3/h per module (total system air flow of 85 m3/h).
  • the permeability decreased and stabilized at between 250 and 275 L/m2/h/bar for Unit 1 , between 200 and 225 L/m2/h/bar for Unit 2 and between 150 and 175 L/m2/h/bar for Unit 3 .
  • a cassette of 6 ZW 500 modules was used to treat sewage. While holding other process parameters generally constant, aeration was varied and permeability of the modules was measured periodically as shown in FIG. 11 .
  • Period A 255 m3/h of air was supplied continuously and evenly to the modules.
  • period B 184 m3/h of air was applied for 10 seconds to aerators below the modules and then for 10 seconds to aerators beside the modules.
  • Period C the same aeration regime was used, but shrouding around the modules was altered.
  • 184 m3/h of air was applied for 10 seconds to aerators near a first set of modules and then for 10 seconds to aerators near a second set of modules.
  • Period E 204 m3/h of air was applied to all of the modules evenly for 10 seconds and then no air was supplied to the modules for 10 seconds.
  • Period F 306 m3/h was applied to all of the modules evenly for 10 seconds and then no air was supplied to the modules for 10 seconds.
  • Period G 153 m3/h was applied to aerators near a first set of modules and then for 10 seconds to aerators near a second set of modules.
  • a single ZW 500 membrane module was used to filter a supply of surface water. While keeping other process parameters constant, the module was operated under various aeration regimes and its permeability recorded periodically. First the module was operated with constant aeration at (a) 20.4 m3/h and (b) 25.5 m3/h. After an initial decrease in permeability, permeability stabilised at (a) about 200 L/m2/h/bar and (b) between 275 and 300 L/m2/h/bar respectively. In a first experiment, aeration was supplied to the module at 25.5 m3/h for two minutes and then turned off for 2 minutes. In this trial, permeability decreased rapidly and could not be sustained at acceptable levels.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Activated Sludge Processes (AREA)

Abstract

An aeration system for a submerged membrane module has a set of aerators connected to an air blower, valves and a controller adapted to alternately provide a higher rate or air flow and a lower rate of air flow in repeated cycles. In an embodiment, the air blower, valves and controller, simultaneously provide the alternating air flow to two or more sets of aerators such that the total air flow is constant, allowing the blower to be operated at a constant speed. In another embodiment, the repeated cycles are of short duration. Transient flow conditions result in the tank water which helps avoid dead spaces and assists in agitating the membranes.

Description

This is a continuation of U.S. Ser. No. 12/015,237, filed Jan. 16, 2008, issued as U.S. Pat. No. 7,625,491, which is a continuation of U.S. Ser. No. 11/515,941, filed Sep. 6, 2006, issued as U.S. Pat. No. 7,347,942, which is a continuation of U.S. Ser. No. 10/986,942, filed Nov. 15, 2004, issued as U.S. Pat. No. 7,198,721; which is a continuation of U.S. Ser. No. 10/684,406, filed Oct. 15, 2003, issued as U.S. Pat. No. 6,881,343; which is a continuation of U.S. application Ser. No. 10/369,699, filed Feb. 21, 2003, issued as U.S. Pat. No. 6,706,189 on Mar. 16, 2004; which is a continuation of U.S. application Ser. No. 09/814,737, filed Mar. 23, 2001, issued as U.S. Pat. No. 6,550,747 on Apr. 22, 2003, which is a continuation-in-part of U.S. application Ser. No. 09/488,359, filed Jan. 19, 2000, issued as U.S. Pat. No. 6,245,239 on Jun. 12, 2001; which is a continuation of international application number PCT/CA99/00940, filed Oct. 7, 1999; which is an application claiming the benefit of provisional application Nos. 60/103,665, filed Oct. 9, 1998; and, 60/116,591, filed Jan. 20, 1999. The entire disclosures of all U.S. Applications mentioned above and international application number PCT/CA99/00940 are incorporated herein by this reference to them.
FIELD OF THE INVENTION
This invention relates to filtering liquids and particularly to using scouring air bubbles produced by an aeration system to clean or inhibit the fouling of membranes in a submerged membrane filter.
BACKGROUND OF THE INVENTION
Submerged membranes are used to treat liquids containing solids to produce a filtered liquid lean in solids and an unfiltered retentate rich in solids. For example, submerged membranes are used to withdraw substantially clean water from wastewater and to withdraw potable water from water from a lake or reservoir.
The membranes are generally arranged in modules which comprise the membranes and headers attached to the membranes. The modules are immersed in a tank of water containing solids. A transmembrane pressure is applied across the membrane walls which causes filtered water to permeate through the membrane walls. Solids are rejected by the membranes and remain in the tank water to be biologically or chemically treated or drained from the tank.
Air bubbles are introduced to the tank through aerators mounted below the membrane modules and connected by conduits to an air blower. The air bubbles rise to the surface of the tank water and create an air lift which recirculates tank water around the membrane module. When the rate of air flow is within an effective range, the rising bubbles and tank water scour and agitate the membranes to inhibit solids in the tank water from fouling the pores of the membranes. Further, there is also an oxygen transfer from the bubbles to the tank water which, in wastewater applications, provides oxygen for microorganism growth. The air blower generally runs continuously to minimize stress on the air blower motors and to provide a constant supply of air for microorganism growth if desired.
With typical aeration systems, an operator increases the rate of air flow to the aerators if more cleaning is desired. This technique, however, stresses the membranes and air blower motors and increases the amount of energy used which significantly increases the operating costs of the process. Conversely, an operator typically decreases the rate of air flow to the aerators if less cleaning is desired. With this technique, however, the rate of air flow is often below the effective range, which does not provide efficient cleaning. Alternately, some operators reduce the average rate of air flow by providing air intermittently. This method allows for an air flow rate in the effective range but at the expense of the air blowers which wear rapidly when turned off and on frequently. In many cases, the warranty on the air blower is voided by such intermittent operation.
Another concern with typical aeration systems is that they cause the tank water to move in a generally steady state recirculation pattern in the tank. The recirculation pattern typically includes “dead zones” where tank water is not reached by the recirculating tank water and bubbles. The membranes in these dead zones, or the parts of the membranes in these dead zones, are not effectively cleaned and may be operating in water having a higher concentration of solids than in the tank water generally. Accordingly, these membranes, or the affected parts of these membranes, quickly foul with solids.
A related problem occurs in modules where hollow fibre membranes are installed with a small degree of slack to allow the membranes to move and shake off or avoid trapping solids. The movement of tank water in the tank encourages slackened membranes to assume a near steady state position, particularly near the ends of the membranes, which interferes with the useful movement of the fibres.
Yet another concern with current aeration systems is that the aerators themselves often foul over time. Even while the air supply is on, the local air pressure near the perimeter of the aerator holes is low and often allows tank water to seep into the aerator. When aeration is stopped from time to time, for example for backwashing, cleaning or other maintenance procedures, more tank water may enter the aeration system. A portion of the tank water entering the aeration system evaporates there, leaving deposits of solids in the aeration system. In wastewater applications in particular, the deposited solids can significantly reduce the efficiency of the aeration system or cause an operator to periodically shut down filtration to clean or replace the aerators.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a cyclic aeration system that may be used for aerating ultrafiltration and microfiltration membranes modules immersed in tank water in a tank. The cyclic aeration system uses a valve set and a valve set controller to connect an air supply to a plurality of distinct branches of an air delivery network. The distinct branches of the air delivery network are in turn connected to aerators located below the membrane modules. While the air supply is operated to supply a steady initial flow of air, the valve set and valve set controller split and distribute the initial air flow between the distinct branches of the air distribution system such that the air flow to each distinct branch alternates between a higher flow rate and a lower flow rate in repeated cycles.
In an embodiment, the valves in the valve set open or close in less than about 5 seconds, preferably less than about 3 seconds. The valve or valves associated with each distinct branch of the air delivery network begin to either open or close, or both, automatically with or in response to the opening or closing of a valve or valves associated with another distinct branch of the air delivery system. For example, the valve or valves associated with each distinct branch of the air delivery network begin to either close automatically with or in response to the opening, preferably to a fully open state, of the valve or valves associated with another distinct branch of the air delivery system. Additionally, position sensors may be fitted to the valves and the valve set controller configured such that the failure of a valve or valves to open as desired prevents closure of the valve or valves associated with another distinct branch of the air delivery system.
In another embodiment, the cyclic aeration system is used to provide intermittent aeration to membrane modules arranged in a plurality of filtration zones, each associated with a distinct branch of the air delivery network. The cyclic aeration system is configured and operated to provide aeration for a predetermined amount of time to each filtration zone in turn. In other embodiment, the cyclic aeration system is used to provide intense aeration to a group of membrane modules. In one such embodiment, the cyclic aeration system is configured and operated to provide air to a branch of the air delivery network alternating between a higher flow rate and a lower flow rate in cycles of 120 seconds or less. In another such embodiment, aerators associated with a first branch of the air delivery network are interspersed with aerators associated with a second branch of the air delivery network. Air flow at a higher flow rate is alternated between the first and second branches of the air delivery network in cycles of 120 seconds or less. Where two distinct branches of the air delivery system are provided, air preferably flows at the higher rate in each distinct branch for about one half of each cycle.
BRIEF DESCRIPTION OF THE DRAWINGS
Preferred embodiments of the present invention will now be described with reference to the following figures.
FIG. 1A is a schematic drawing of a submerged membrane reactor.
FIGS. 1B, 1C and 1D are drawings of membrane modules according to embodiments of the present invention.
FIG. 2 is a plan view schematic of an aeration system according to an embodiment of the present invention.
FIG. 3 is a series of graphs showing the effect of operating an embodiment of the present invention.
FIGS. 4A, 4B, 4C and 4D are schematic drawings of valve sets and valve controllers according to embodiments of the invention.
FIGS. 4E and 4F are diagrams of valve position over time.
FIG. 5 is a plan view schematic of membrane modules and an aeration system according to an embodiment of the invention.
FIG. 6 is a plan view schematic of membrane modules and an aeration system according to another embodiment of the invention.
FIG. 7A is a plan view schematic of membrane modules and an aeration system according to another embodiment of the invention.
FIGS. 7B, 7C and 7D are elevational representations of membrane modules and parts of an aeration system according to alternatives to the embodiment of FIG. 7A.
FIGS. 8A and 8B are elevational representations of membrane modules and parts of an aeration system according to an embodiment of the invention under the influence of a cyclic aeration system.
FIGS. 9A, 9B, 9C and 9D are drawings of aerators according to an embodiment of the invention.
FIGS. 10A, 10B and 10C are charts showing the results of tests performed on embodiments of the invention having two groups of aerators.
FIG. 11 is a chart showing the results of tests performed on embodiments of the invention having a single group of aerators.
DETAILED DESCRIPTION OF THE INVENTION General Description
Referring now to FIG. 1A, the general arrangement of a reactor 10 is shown. The description of the reactor 10 in this section applies generally to various embodiments to be described below to the extent that it is not inconsistent with the description of any particular embodiment.
The reactor 10 has a tank 12 which is initially filled with feed water 14 through an inlet 16. The feed water 14 may contain microorganisms, suspended solids or other matter which will be collectively called solids. Once in the tank, the feed water 14 becomes tank water 18 which may have increased concentrations of the various solids, particularly where the reactor 10 is used to treat wastewater.
One or more membrane modules 20 are mounted in the tank and have one or more headers 22 in fluid communication with a permeate side of one or more membranes 6. The membranes 6 in the membrane modules 20 have a pore size in the microfiltration or ultrafiltration range, preferably between 0.003 and 10 microns.
Membrane modules 20 are available in various sizes and configurations with various header configurations. For example, the membranes 6 may be hollow fibres potted in one or more headers 22 such that the lumens of the hollow fibres are in fluid communication with at least one header 22. The headers 22 may be of any convenient shape but typically have a rectangular or round face where they attach to the membranes 6. Alternatively, the membranes 6 may be flat sheets which are typically oriented vertically in a spaced apart pair with headers 22 on all four sides in fluid communication with the resulting interior surface. A membrane module 20 may have one or more microfiltration or ultrafiltration membranes 6 and many membrane modules 20 may be joined together to form larger membrane modules, or cassettes, but all such configurations will be referred to as membrane modules 20.
FIGS. 1B, 1C and 1D illustrate preferred membrane modules 20 having rectangular skeins 8. In each rectangular skein 8, hollow fibre membranes 23 are held between two opposed headers 22. The ends of each membrane 23 are surrounded by potting resin to produce a watertight connection between the outside of the membrane 23 and the headers 22 while keeping the lumens of the hollow fibre membranes 23 in fluid communication with at least one header 22. The rectangular skeins 8 may be oriented in a horizontal plane (FIG. 1B), vertically (FIG. 1C) or horizontally in a vertical plane (FIG. 1D). A plurality of rectangular skeins 8 are typically joined together in a membrane module 20.
Although a single row of hollow fibre membranes 23 is illustrated in each rectangular skein 8, a typical rectangular skein 8 has a mass of hollow fibre membranes 23 between 2 cm and 10 cm wide. The hollow fibre membranes 23 typically have an outside diameter between 0.4 mm and 4.0 mm and are potted at a packing density between 10% and 40%. The hollow fibre membranes 23 are typically between 400 mm and 1,800 mm long and typically mounted with between 0.1% and 5% slack.
Referring again to FIG. 1A, the tank 12 is kept filled with tank water 18 above the level of the membranes 6 in the membrane modules 20 during permeation. Filtered water called permeate 24 flows through the walls of the membranes 6 in the membrane modules 20 under the influence of a transmembrane pressure and collects at the headers 22 to be transported to a permeate outlet 26 through a permeate line 28. The transmembrane pressure is preferably created by a permeate pump 30 which creates a partial vacuum in a permeate line 28. The transmembrane pressure may vary for different membranes and different applications, but is typically between 1 kPa and 150 kPa. Permeate 24 may also be periodically flowed in a reverse direction through the membrane modules 20 to assist in cleaning the membrane modules 20.
During permeation, the membranes 6 reject solids which remain in the tank water 18. These solids may be removed by a number of methods including digestion by microorganisms if the reactor 10 is a bioreactor or draining the tank 12 periodically or by continuously removing a portion of the tank water 18, the latter two methods accomplished by opening a drain valve 32 in a drain conduit 34 at the bottom of the tank.
An aeration system 37 has one or more aerators 38 connected by an air delivery system 40 and a distribution manifold 51 to an air source 42, which is typically one or more air blowers, and produces bubbles 36 in the tank water. The aerators 38 may be of various types including distinct aerators, such as cap aerators, or simply holes drilled in conduits attached to or part of the distribution manifold 51. The bubbles 36 are preferably made of air but may be made of other gasses such as oxygen or oxygen enriched air if required.
The aerators 38 are located generally below the membrane modules 20. If the membrane modules 20 are made of rectangular skeins 8 having vertical hollow fibre membranes 23, the aerators 38 are preferably located to produce bubbles near the edges of the lower header. With rectangular skeins 8 having hollow fibre membranes 23 in a vertical plane, the aerators 38 are preferably located to produce bubbles in a line directly below the vertical plane. With rectangular skeins 8 having hollow fibre membranes 23 in a horizontal plane, the aerators 38 are preferably located to produce bubbles evenly dispersed below the plane.
The bubbles 36 agitate the membranes 6 which inhibits their fouling or cleans them. In addition, the bubbles 36 also decrease the local density of tank water 18 in or near the membrane modules 20 which creates an air-lift effect causing tank water 18 to flow upwards past the membrane modules 20. The air lift effect causes a recirculation pattern 46 in which the tank water 18 flows upwards through the membrane modules 20 and then downwards along the sides or other parts of the tank. The bubbles 36 typically burst at the surface and do not generally follow the tank water 18 through the downward flowing parts of the recirculation pattern 46. The tank water 18 may also flow according to, for example, movement from the inlet 16 to the drain conduit 34, but such flow does not override the flow produced by the bubbles 36.
The bubbles 36 have an average diameter between 0.1 and 50 mm. Individual large bubbles 36 are believed to be more effective in cleaning or inhibiting fouling of the membranes 6, but smaller bubbles 36 are more efficient in transferring oxygen to the tank water 18 and require less energy to produce per bubble 36. Bubbles 36 between 3 mm and 20 mm, and more preferably between 5 mm and 15 mm in diameter, are suitable for use in many wastewater applications. Bubbles 36 in the ranges described immediately above provide effective cleaning of the membranes 6 and acceptable transfer of oxygen to the tank water 18 without causing excessive foaming of the tank water 18 at the surface of the tank 12. If the reactor 10 is used to create potable water or for other applications where oxygen transfer is not required, then bubbles between 5 mm and 25 mm are preferred.
The bubbles 36 may be larger than a hole in an aerator 38 where the bubble 36 is created according to known factors such as air pressure and flow rate and the depth of the aerators 38 below the surface of the tank water 18. If the aerators 38 are located near the bottom of a large tank 12, such as those used in municipal treatment works, an aerator 38 with holes of between 2 mm and 15 mm and preferably between 5 mm and 10 mm might be used. The air pressure supplied (relative to atmospheric pressure) is typically determined by the head of water at the depth of submergence of the aerators 38 (approximately 10 kPa per metre) plus an additional pressure required to get the desired rate of air flow through the aerators 38. There is typically a pressure drop of between 5 mm and 100 mm of water, and more typically between 10 mm and 50 mm of water, across the holes of the aerators 38. Parts of the aeration system 37 located at a distance below the bottom of the holes of the aerators 38 equal to the pressure drop are generally free of tank water when the air source 42 is operating, although small amounts of tank water 18 may still seep into the aeration system 37.
Cyclic Aeration System
Now referring to FIG. 2 a cyclic aeration system 237 is shown having an air supply 242 in fluid communication with a valve set 254, the valve set 254 controlled by a valve controller 256. The valve set 254 is in fluid communication with an air delivery network 240 having a plurality of distinct branches each in fluid communication with distinct manifolds 251 in fluid communication with conduit aerators 238. Other types of aerators may also be used with suitable modifications to the manifolds 251 or air delivery network, but conduit aerators 238 are preferred. The third branch of the air delivery network 240 and the third manifold 251 are shown in dashed lines to indicate that the number of distinct branches of the air delivery network 240 and manifolds 251 may be two or more, but preferably not more than 15.
The air supply 242 is a source of pressurized air, typically one or more air blowers, and provides a flow of a gas at an initial rate to the cyclic aeration system. The gas is most often air, but may also be oxygen, oxygen or ozone enriched air, or nitrogen in which cases the air supply 242 will include oxygenation or ozonation equipment etc. in addition to an air blower. In this document, however, the term “air” will be used to refer to any appropriate gas. The amount of air provided by the air supply 242 is best determined by summing the amount of air provided to all conduit aerators 238 (to be described below) serviced by the air supply 242. It is preferred that the air supply 242 supply a constant amount of air over time.
The valve set 254 and valve controller 256 will be described in more detail below. In general terms, however, the valve set 254 and valve controller 256 (a) split the air flow from the air supply 242 between the branches of the air delivery network 240 such that, at a point in time, some of the branches receive air at a higher rate of air flow and some of the branches receive air at a lower rate of air flow and (b) switch which branches of the air delivery network 240 receive the higher and lower rates of air flow in repeated cycles.
An example is illustrated in FIG. 3. In each of parts a), b), and c) of FIG. 3, Rh indicates a higher rate of air flow; RI indicates a lower rate of air flow; and, the time from 0 to t3 indicates a cycle which would be repeated. The cycle is divided into three substantially equal time periods, 0-t1; t1-t2; and, t2-t3. In each of these periods, one branch of the air delivery system 240 and its associated manifold 251 receive air at Rh while the others receive air at RI. Similarly, each branch of the air delivery system 240 and its associated manifold 251 receives air at Rh for one third of the cycles and at RI for two thirds of the cycle.
Many of the valves sets 254 to be described below can be used to produce smooth variations in air flow rate to a manifold 251, but it is preferred if the variation is fairly abrupt as suggested by FIG. 3. The inventors have noticed that such an abrupt change produces a short burst of unusually large bubbles 36 which appear to have a significant cleaning or fouling inhibiting effect. The abrupt changes often also produce a spike in air flow rate shortly after the transition from RI to Rh which produces a corresponding pressure surge. This pressure surge must be kept within the design limits of the cyclic aeration system 237 or appropriate blow off valves etc. provided.
The amount of air provided to a manifold 251 or branch of air delivery network 240 is dependant on numerous factors but is preferably related to the superficial velocity of air flow for the conduit aerators 238 services. The superficial velocity of air flow is defined as the rate of air flow to the conduit aerators 238 at standard conditions (1 atmosphere and 25 degrees Celsius) divided by the cross sectional area of aeration. The cross sectional area of aeration is determined by measuring the area effectively aerated by the conduit aerators 238. Superficial velocities of air flow of between 0.013 m/s and 0.15 m/s are preferred at the higher rate (Rh). Air blowers for use in drinking water applications may be sized towards the lower end of the range while air blowers used for waste water applications may be sized near the higher end of the range.
RI is typically less than one half of Rh and is often an air off condition with no flow. Within this range, the lower rate of air flow is influenced by the quality of the feed water 14. An air off condition is generally preferred, but with some feed water 14, the hollow fibre membranes 23 foul significantly even within a short period of aeration at the lower rate. In these cases, better results are obtained when the lower rate of air flow approaches one half of the higher rate. For feed waters in which the rate of fouling is not significant enough to require a positive lower rate of air flow, RI may still be made positive for other reasons. With some aerators or air delivery systems, a positive lower rate of air flow may be desired, for example, to prevent the aerators from becoming flooded with tank water 18 at the lower rate of air flow. While periodic flooding is beneficial in some aerator designs, in others it causes unwanted foulants to accumulate inside the aerator. A positive lower rate of air flow may also be used because of leaks in the valves of the valve set 254 or to reduce stresses on the valve set 254 or the air delivery network 240. Regarding leaks, the lower rate of air flow may typically be as much as about 10%, but preferably about 5% or less, of the higher rate of air flow without significantly detracting from the performance achieved with a completely air off condition. Continuing to use valves (which are typically butterfly valves) even after they have developed small leaks decreases the operating expense of the cyclic aeration system 237. Regarding stresses on the valves in the valve set 254 or the air delivery network 240, such stresses can be reduced by purposely not closing the valves entirely. As in the cases of leaks, the lower rate of air flow may be as much as about 10%, but preferably about 5% or less, of the higher rate of air flow typically without significantly detracting from the performance achieved with a completely air off condition.
Referring now to FIGS. 4A, 4B and 4C, alternative embodiments of the valve set 254 and valve controller 256 are shown. In FIG. 4A, an air supply 242 blows air into a three way valve 292, preferably a ball valve, with its two remaining orifices connected to two manifolds 251. A three way valve controller 294 alternately opens an air pathway to one of the manifolds 251 and then the other. Preferably there is a phase shift of 180 degrees so that the air pathway to one of the manifolds 251 opens while the airway to the other manifold 251 closes. The three way valve 292 may be mechanically operated by handle 296 connected by connector 298 to a lever 299 on the three way valve controller 294. The three way valve controller 294 may be a drive unit turning at the required speed of rotation of the lever 299. Preferably, however, the three way valve controller 294 is a microprocessor and servo, pneumatic cylinder or solenoid combination which can be more easily configured to abruptly move the three way valve 292.
In FIG. 4B, the air supply 242 blows air into a connector 261 which splits the air flow into a low flow line 262 and a high flow line 264. A valve 266 in the low flow line 262 is adjusted so that flow in the low flow line 262 is preferably less than one half of the flow in the high flow line 264. A controller 268, preferably a timer, a microprocessor or one or more motors with electrical or mechanical links to the valves to be described next, controls a low valve 270, which may be a solenoid valve or a 3 way ball valve, and a high valve 272, which may be a solenoid valve or a 3 way ball valve, so that for a first period of time (a first part of a cycle) air in the low flow line 262 flows to one of the manifolds 251 and air in the high flow line flows to the other manifold 251. For a second period of time (a second part of a cycle), the low valve 270 and high valve 272 are controlled so that air in the low flow line 262 flows to the a manifold 251 through cross conduit 274 and air in the high flow line 264 flows to the other manifold 251 through reverse conduit 276.
In FIG. 4C, air supply 242 blows air into a blower header 260 connected by slave valves 284 to manifolds 251. Each slave valve 284 is controlled by a slave device 280, typically a solenoid, pneumatic or hydraulic cylinder or a servo motor. The slave devices 280 are operated by a slave controller 282 set up to open and close the slave valves 284 in accordance with the system operation described in this section and the embodiments below. The slave controller 282 may be a microprocessor, an electrical circuit, a hydraulic or pneumatic circuit or a mechanical linkage. The slave devices 280 and the slave controller 282 together comprise the valve set controller 256. The valve set controller 256 of FIG. 4C may also be used with the other apparatus of FIG. 4B.
In FIG. 4D, air supply 242 blows air into a blower header 260 connected by slave valves 284 to manifolds 251. Each slave valve 284 is controlled by a valve set controller 256 which consists of a plurality of cams 281, driven by a motor 279. The cams 281 may drive the slave valves 284 directly (as illustrated) or control another device, such as a pneumatic cylinder, which directly opens or closes the slave valves 284. The shape of the cams 281 is chosen to open and close the slave valves 284 in accordance with the system operation described in this section and the embodiments below. The valve set controller 256 of FIG. 4D may also be used with the other apparatus of FIG. 4B.
With the apparatus of FIG. 4B, 4C or 4D, the opening and closing times of the slave valves 284 are mechanically (preferably by a pneumatic circuit) or electrically (preferably with a programmable logic controller—PLC) interconnected such that each slave valve 284 either opens or closes, or both, automatically with or in response to the opening or closing of a slave valve or slave valves 284 in another distinct branch of the air delivery network 240. This occurs naturally, for example, in the embodiment of FIG. 4D by virtue of the cams 281 being linked to a common motor 279. If the motor 279 fails or turns at an improper speed, the opening and closing times of the slave valves 284 relative to each other is preserved. Where the valve set controller 256 incorporates a slave controller 282, the slave controller 282 may incorporate a timer, but preferably does not open and close slave valves 284 based solely on inputs from the timer. For example, an acceptable set up for the slave controller 282 is to have the opening of the slave valves 284 of a distinct branch determined by time elapsed since those slave valves 284 were closed, but the closing of those slave valves 284 is determined by the slave valves 284 of another distinct branch having opened to a selected degree.
The opening and closing movements of the slave valves 284 are preferably overlapped to minimize the spike in air flow rate and pressure surge shortly after the transition from RI to Rh mentioned above. Preferably, the opening and closing times of the slave valves 284 are arranged such that the slave valve or valves 284 to any distinct branch of the air delivery network 240 do not start to close until the slave valve or valves 284 to any other distinct branch of the air delivery system 240 are fully open. Further preferably, where the valve set controller 256 includes a slave controller 282, position sensors are fitted to the slave valves 284. The slave controller 282 is configured such that the failure of a slave valve or valves 284 to open as desired prevents the closure of the slave valve or valves 284 of another distinct branch of the air delivery network 240. In this way, in addition to minimizing and possibly substantially eliminating any spike in air flow, damage to the cyclic aeration system 237 is avoided if the slave valve or valves 284 to a distinct branch of the air delivery network 240 fail to open.
Despite the concern for controlling any spikes in air flow rate or pressure, the overall goal of the valve set controller 256 is to produce rapid changes between RI and Rh. The time required to open or close (partially or fully as desired) a slave valve 284 from its closed (fully or partially) or opened position respectively is preferably less than about 5 seconds and more preferably less than about 3 seconds when used with very short cycle times of 40 seconds or less. For example, FIGS. 4E and 4F show suitable slave valve 284 positions over time for an air distribution network 240 having two distinct branches where RI is an air off condition, the cycle time is 20 seconds and the valve opening time is 3 seconds. In FIG. 4E, the start of the closing times of the slave valves 284 are interconnected such that each slave valve 284 begins to close when the other is fully open. In FIG. 4F, the start of the closing times of the slave valves 284 are interconnected such that each slave valve 284 begins to close when the other begins to open. In either case, where a positive RI is desired, the fully closed position of the slave valves 284 illustrated can be replaced by a partially closed position, or the apparatus of FIG. 4B can be used.
As an example of the interconnection of slave valves 284 described above, the regime of FIG. 4E will be discussed further below. Referring again to FIG. 4C, two manifolds 251 are controlled by two slave valves, 284 a and 284 b, through two slave devices, 280 a and 280 b. Each slave valve 284 has a limit switch 285 which provides a signal to the slave controller 282 indicating whether that slave valve 284 is open or at a desired partially or fully closed setting. Where the slave controller 282 is a PLC and the slave devices 280 are servo motors or pneumatic cylinders, the following PLC programming control narrative can be used to obtain air cycling as described in relation to FIG. 4E:
1. At start-up, slave controller 282 sends a signal to slave devices 280 a and 280 b to open slave valve 284 a and close slave valve 284 b respectively.
2. After 3 seconds, slave controller 282 checks for an “open” signal from limit switch 285 a and a “closed” signal from limit switch 285 b.
3. If both valves are confirmed in their correct positions, slave controller 282 sends a signal to start blower 242.
4. Seven seconds after the blower 242 is started, slave controller 282 sends a signal to slave device 280 b to open slave valve 284 b.
5. Three seconds after the preceding step, slave controller 282 checks for an “open” signal from limit switch 285 b; if an “open” signal is received, proceed to step 6; if an “open: signal is not received, sound alarm and go to a continuous aeration mode, for example, by operating bypass valves to provide air to all manifolds 251 direct from the blower 242.
6. Slave controller 282 sends a signal to slave device 280 a to close slave valve 284 a.
7. Three seconds after step 6, slave controller 282 checks for a “closed” signal from limit switch 285 a; if a “closed” signal is received, proceed with step 8; if a “closed” signal is not received, sound alarm and go to a continuous aeration mode.
8. Four seconds after step 7, slave controller 282 sends a signal to slave device 280 a to open slave valve 284 a.
9. Three seconds after step 4, slave controller 282 checks for an “open” signal from limit switch 285 a; if an “open” signal is received, proceed with step 10; if an “open” signal is not received, sound alarm and go to a continuous aeration mode.
10. Slave controller 282 sends a signal to slave device 280 b to close slave valve 284 b.
11. Three seconds after step 10, slave controller 282 checks for a “closed” signal from limit switch 285 b; if a “closed” signal is received, proceed with step 12; if a “closed” signal is not received, sound alarm and go to a continuous aeration mode.
12. Four seconds after step 11, slave controller 282 sends signal to slave device 280 b to open slave valve 284 b.
13. Repeat steps 5-12 until unit is shut down or other control regime activated.
The regime of FIG. 4E provides the advantage discussed above of having at least one distinct branch of the air delivery network 240 fully open at all times but the total time for the transition between RI to Rh is extended to twice the valve opening time. This method is preferred for cycle times of 20 seconds or more. The regime of FIG. 4F produces a faster transition from RI to Rh but at the risk of over stressing the cyclic aeration system 237 if the valve or valves 262 to a distinct branch start to open but then fail to open completely. This risk must be addressed with other system fail safes known in the art. The regime of FIG. 4F is preferred for cycle time less than 20 seconds and when valve opening/closing times are greater than about 3 seconds. Modifications to the narrative above can be used to produce other regimes of air cycling.
Use of Cyclic Aeration to Provide Efficient Intermittent Aeration
Use of the cyclic aeration system 237 to provide efficient intermittent aeration will now be described with reference to the following embodiment, it being understood that the invention is not limited to the embodiment. Referring to FIG. 5, an aeration system 237 is shown for use in providing intermittent aeration to six membrane modules 20 (shown with dashed lines) in a filtration tank 412. The filtration tank 412 has six filtration zones (also shown with dashed lines) corresponding to the six membrane modules 20. Alternately, the filtration zones could be provided in separate tanks with one or more membrane modules 20 in each tank. The membrane modules 20 will be used to filter a relatively foulant free surface water such that intermittent aeration is suitable.
The air delivery network 240 has six distinct branches each connected to a header 251 in a filtration zone. Each header 251 is in turn connected to conduit aerators 238 mounted generally below the membrane modules 20. The valve set 254 and valve controller 256 are configured and operated to provide air from the air supply 242 to the air delivery network 240 in a 7.5 minute cycle in which air at the higher rate is supplied for about 75 seconds to each branch of the air delivery network 240 in turn. While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate. Accordingly, each header 251 receives air at the higher rate for 75 seconds out of every 7.5 minutes. Operation of the air supply 242, however, is constant and an air supply sized for one manifold 251 is used to service six such manifolds.
It is preferable if backwashing of the membrane modules 20 is also performed on the membrane modules in turn such that backwashing of a membrane module 20 occurs while the membrane module 20 is being aerated. The membrane modules 20 can be backwashed most easily when each membrane module 20 is serviced by its own permeate pump 30 and associated backwashing apparatus. In large municipal systems, for example, the permeation and backwashing apparatus are typically limited to about 8 to 11 ML/d capacity. Accordingly a medium size plant (i.e. in the range of 40 ML/d) will have several membrane modules 20 serviced by sets of permeation and backwashing apparatus which can be individually controlled. In some plants, backwashing is performed on the membrane modules 20 in turn to produce an even supply of permeate 24 regardless of aeration.
In a pilot study conducted with feed water having turbidity of 0.3 NTU and colour of 3.9 TCU, for example, the inventors were able to achieve acceptable sustained permeability of a membrane module using 75 seconds of aeration at a higher rate of 0.035 m/s superficial velocity every 15 minutes and 15 seconds. For the remainder of the cycle there was no aeration. Each cycle involved 15 minutes of permeation through the membrane modules 20 and 15 seconds of backwashing. The 75 seconds of aeration was timed so that there was 30 seconds of aeration before the backpulse, aeration during the backpulse, and 30 seconds of aeration after the backpulse. The test suggests that if cycled aeration is timed to coincide for each manifold 251 with the backwashing of the associated membrane module 20, then about 12 membrane modules 20 could be serviced by a single air supply 242 as part of the cyclic aeration system 237.
Use of Cyclic Aeration to Provide Intense Aeration
Use of the cyclic aeration system 237 to provide intense aeration will now be described with reference to the following embodiment, it being understood that the invention is not limited to the embodiment. Referring to FIG. 6, an aeration system 237 is shown for use in providing aeration alternating between two sets of membrane modules 20 (shown with dashed lines) in a filtration vessel 512. The filtration vessel 512 has two filtration zones (also shown with dashed lines) corresponding to the two sets of membrane modules 20. Alternately, the filtration zones could be provided in separate tanks with one or more membrane modules 20 in each tank. The membrane modules 20 will be used to filter a relatively foulant rich surface water or a wastewater such that intense aeration is suitable.
The air delivery network 240 has two distinct branches each connected to headers 251 in a filtration zone. Each header 251 is in turn connected to conduit aerators 238 mounted generally below the membrane modules 20. The valve set 254 and valve controller 256 are configured and operated to provide air from the air supply 242 to the air delivery network 240 in a short cycle in which air at the higher rate is supplied for one half of the cycle to each branch of the air delivery network 240. While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate.
The preferred total cycle time may vary with the depth of the filtration vessel 512, the design of the membrane modules 20, process parameters and the conditions of the feed water 14 to be treated, but preferably is at least 10 seconds (5 seconds at the full rate and 5 seconds at the reduced rate) where the filtration vessel 512 is a typical municipal tank between 1 m and 10 m deep. A cycle time of up to 120 seconds (60 seconds at the full rate, 60 seconds at the reduced rate) may be effective, but preferably the cycle time does not exceed 60 seconds (30 seconds at the full rate, 30 seconds at the reduced rate) where the filtration vessel 512 is a typical municipal tank.
The inventors believe that such rapid cycling creates transient flow within the tank water 18. In particular, an air lift effect is created or strengthened when the rate of airflow changes from RI to Rh causing the tank water 18 to accelerate. Shortly afterwards, however, aeration and the air lift effect are sharply reduced causing the tank water 18 to decelerate. With very short cycles, the tank water 18 is accelerating or decelerating for much of the cycle and is rarely in a steady state. It is believed that formation of quiescent zones in the tank water 18 is inhibited and that beneficial movement of the hollow fibre membranes 23 is enhanced. For example, horizontal hollow fibre membranes 23, as shown in the rectangular skeins 8 of FIGS. 1B and 1D, assume a generally concave downward shape under steady state aeration and experience limited movement at their ends. With cyclic aeration as described above, however, tension in the hollow fibre membranes 23 is released cyclically and, in some cases, local currents which flow downward may be created for brief periods of time. The ends of the horizontal hollow fibre membranes 23 experience more beneficial movement and foul less rapidly. Since the beneficial effects may be linked to creating transient flow, it is also believed that factors which effect acceleration of the water column above a set of conduit aerators 238, such as tank depth or shrouding, could modify the preferred cycle times stated above.
Use of Cyclic Aeration to Promote Horizontal Flow
Use of the cyclic aeration system 237 to promote horizontal flow in the tank water 18 will now be described with reference to the following embodiment, it being understood that the invention is not limited to the embodiment. Referring to FIG. 7A, an aeration system 237 is shown for use in aerating membrane modules 20 in a process tank 612. The membrane modules 20 will be used to filter a relatively foulant rich surface water or a wastewater such that intense aeration is suitable.
The air delivery network 240 has two distinct branches each connected to two distinct headers 251, both in a single filtration zone. The headers 251 will be referred to as header 251 a and 251 b where convenient to distinguish between them. Headers 251 are connected to conduit aerators 238 such that the conduit aerators 238 attached to header 251 a are interspersed with the conduit aerators 238 attached to header 251 b. One such arrangement is shown in FIG. 7A in which header 251 a is connected to conduit aerators 238 directly beneath the membrane modules 20 while header 251 b is connected to horizontally displaced conduit aerators 238 located beneath and between the membrane modules 20. Referring now to FIGS. 7B, 7C and 7D, a set of variations of the embodiment of FIG. 7A is shown. In FIG. 7B, header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located beneath the membrane modules 20. In FIG. 7C, header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located directly beneath alternating membrane modules 20. In FIG. 7C, header 251 a and header 251 b are connected to alternating horizontally displaced conduit aerators 238 located directly beneath and between alternating membrane modules 20. In each of these cases, the pattern may be repeated where more membrane modules 20 are used.
Each of header 251 a and header 251 b are connected to a distinct branch of the air delivery network 240 in turn connected to a valve set 254. The valve set 254 and a valve controller 256 are configured and operated to provide air from an air supply 242 to the air delivery network 240 in a short cycle in which air at a higher rate is supplied for one half of the cycle to each branch of the air delivery network 240. While a branch of the air delivery network 240 is not receiving air at the higher rate, it receives air at the lower rate. The lower flow rate is preferably one half or less of the higher flow rate and, where conditions allow it, the lower flow rate is preferably an air-off condition.
The total cycle time may vary with the depth of the process tank 612, the design of the membrane modules 20, process parameters and the conditions of the feed water 14 to be treated, but typically is at least 2 seconds (1 second at the full rate and 1 second at the reduced rate), preferably 10 seconds or more, and less than 120 seconds (60 seconds at the full rate, 60 seconds at the reduced rate), preferably less 60 seconds, where the process tank 612 is a typical municipal tank between 1 m and 10 m deep. More preferably, however, the cycle time is between 20 seconds and 40 seconds in length. Short cycles of 10 seconds or less may not be sufficient to establish regions of different densities in the tank water 18 in a deep tank 12 where such time is insufficient to allow the bubbles 36 to rise through a significant distance relative to the depth of the tank 12. Long cycles of 120 seconds or more may result in parts of a membrane module 20 not receiving bubbles 36 for extended periods of time which can result in rapid fouling. As discussed above, the beneficial effects of the invention may be linked to creating transient flow and it is believed that factors which effect acceleration of the water column above a set of conduit aerators 238, such as tank depth or shrouding, could modify the preferred cycle times stated above.
In this embodiment, having the conduit aerators 238 connected to header 251 a interspersed with the conduit aerators 238 attached to header 251 b creates varying areas of higher and lower density in the tank water 18 within a filtration zone. As described above, the inventors believe that these variations produce transient flow in the tank water 18. Where the effective areas of aeration above conduit aerators 238 attached to distinct branches of the air delivery network 240 are sufficiently small, however, the inventors believe that appreciable transient flow is created in a horizontal direction between areas above conduit aerators 238 attached to different branches of the air delivery network 240. Referring to FIGS. 7A, 7B, 7C, 7D the membrane modules 20 shown are preferably of the size of one or two rectangular skeins 8.
As an example, in FIGS. 8A and 8B second membrane modules 220 made of rectangular skeins 8 with hollow fibre membranes 23 oriented vertically aerated by a cyclic aeration system 237 with conduit aerators 238 located relative to the second membrane modules 220 as shown in FIG. 7D. In FIGS. 8A and 8B, the degree of slack of the hollow fibre membranes 23 is highly exaggerated for easier illustration. Further, only two hollow fibre membranes 23 are illustrated for each vertical rectangular skein 8 although, as discussed above, a rectangular skein 8 would actually be constructed of many hollow fibre membranes 23.
With steady state aeration, it is difficult to encourage bubbles 36 to penetrate the vertical rectangular skeins 8. The natural tendency of the bubbles 36 is to go through the areas with lowest resistance such as around the second membrane modules 220 or through slots between the second membrane modules 220 and the hollow fibre membranes 23 on the outer edge of the vertical rectangular skeins 8 may have significantly more contact with the bubbles 36. Further, the upper 10-20% of the hollow fibre membranes 23 is often forced into a tightly curved shape by the air lift effect and moves only very little. A smaller portion at the bottom of the hollow fibre membranes 23 may also be tightly curved by the current travelling around the lower header 22. In these tightly curved areas, the hollow fibre membranes 23 foul more rapidly.
With cyclic aeration, however, air at the higher rate is alternated between header 251 a and header 251 b. When more air is supplied to header 251 a, the hollow fibre membranes 23 assume an average shape as shown in FIG. 8A with a first local recirculation pattern 380 as shown. When more air is supplied to header 251 b, the hollow fibre membranes 23 assume an average shape as shown in FIG. 8B with a second local recirculation pattern 382 as shown. Under the influence of a cyclic aeration system 237, the hollow fibre membranes 23 alternate between the positions shown in FIGS. 8A and 8B. Accordingly, the portion of the hollow fibre membranes 23 which moves only very little is decreased in size. The cycling also creates a reversing flow into and out of the vertical rectangular skeins 8 which the inventors believe encourages bubbles 36 to penetrate deeper into the vertical rectangular skeins 8.
Conduit Aerators
Now referring to FIG. 9A, a conduit aerator 238 is shown. The conduit aerator 238 has an elongated hollow body 302 which is a circular pipe having an internal diameter between 15 mm and 100 mm. A series of holes 304 pierce the body 302 allowing air to flow out of the conduit aerator 238 to create bubbles. The size, number and location of holes may vary but for a rectangular skein 8, for example, 2 holes (one on each side) of between 5 mm and 10 mm in diameter placed every 50 mm to 100 mm along the body 302 and supplied with an airflow which results in a pressure drop through the holes of between 10 to 100 mm of water at the depth of the conduit aerator 238 are suitable.
Air enters the conduit aerator 238 at an aerator inlet 306. At the opposite end of the conduit aerator 238 is an outlet 308. The highest point on the outlet 308 is located below the lowest point on the aerator inlet 306 by a vertical distance between the minimum and maximum expected pressure drop of water at the depth of the conduit aerator 238 across the holes 304. The minimum expected pressure drop of water at the depth of the conduit aerator 238 across the holes 304 is preferably at least as much as the distance between the top of the holes 304 and the interior bottom of the body 302. An air/water interface 309 between the air in the conduit aerator 238 and the water surrounding the conduit aerator 238 will be located below the interior bottom of the body 302 but above the highest point on the outlet 308. In this way, tank water 18 entering the conduit aerator 238 will flow to the outlet 308 and not accumulate near the holes 304.
Now referring to FIG. 9B, another conduit aerator 238 is shown which is preferred for use with relatively clean tank water 18. The body 302 has a rectangular cross section but is open on the bottom. The conduit aerator 238 may be a separate component or integrated into the headers 22 of a membrane module 20 in which case the bottom of a lower header 22 may serve as the top of the body 302. The end of the body 302 is capped with a cap 310 which again may be a part of a header 22. With the bottom of the body 302 open to the tank water 18, tank water 18 which seeps into the conduit aerator 238 flows back to the tank water 18. To prevent bubbles 36 from forming at the bottom of the conduit aerator 238, the sides of the body 302 extend below the bottom of the holes 304 by a distance greater than the expected pressure drop through the holes 304.
Now referring to FIG. 9C, another conduit aerator 238 is similar to the conduit aerator 238 of FIG. 9A except as will be described herein. A rubber sleeve 400, shown partially cut away, covers the body 302 and has slits 402 corresponding with the holes 304. The slits 402 open when air is flowed into the conduit aerator 238 opening to a larger size when a higher rate of air flow is used. Accordingly, the slits 402 produce larger bubbles 36 at the full rate of air flow and smaller bubbles 36 at the reduced rate of air flow. In wastewater applications, the reduced size of the bubbles 36 provides improved oxygen transfer efficiency at the reduced rate of air flow.
Now referring to FIG. 9D, another conduit aerator is shown which is preferred for use with relatively solids rich tank water 18. The body 302 is a tube 32 mm in diameter. The holes 304 are 8 mm in diameter and mounted 30 degrees upwards of horizontal. Drainage holes 410, at the bottom of the body 302 and typically 16 mm in diameter, allow tank water 18 seepage to drain from the body 302. A cap 411 covers the end of the body 302.
Conduit aerators 238 such as those described above may admit some tank water 18, even with air flowing through them, which dries out leaving an accumulation of solids. When the supply of air is switched between manifolds as described above, however, the conduit aerator 238 is alternately flooded and emptied. The difference in water elevation within the body 302 corresponds to the air pressure loss across the holes 304 between the high and low air flow conditions. The resulting cyclical wetting of the conduit aerators 238 helps re-wet and remove solids accumulating in the conduit aerators 238 or to prevent tank water 18 from drying and depositing solids in the conduit aerators 238. If necessary, this flooding can be encouraged by releasing air from the appropriate manifold by opening a valve vented to atmosphere.
Embodiments similar to those described above can be made in many alternate configurations and operated according to many alternate methods within the teachings of the invention.
EXAMPLES
The following examples refer to ZW 500 membrane modules produced by ZENON Environmental Inc. Each ZW 500 has two rectangular skeins of vertical hollow fiber membranes. For the purposes of calculating superficial velocities, the cross sectional area of aeration for each ZW 500 membrane module is approximately 0.175 m2. All air flow rates given below are at standard conditions.
Example 1
A cassette of 8 ZW 500 membrane modules were operated in bentonite suspension under generally constant process parameters but for changes in flux and aeration. A fouling rate of the membranes was monitored to assess the effectiveness of the aeration. Aeration was supplied to the cassette at constant rates of 204 m3/h (i.e. 25.5 m3/h per module) and 136 m3/h and according to various cycling regimes. In the cycled tests, a total air supply of 136 m3/h was cycled between aerators located below the modules and aerators located between and beside the modules in cycles of the durations indicated in FIG. 10A. Aeration at 136 m3/h in 30 second cycles (15 seconds of air to each set of aerators) was approximately as effective as non-cycled aeration at 204 m3/h.
Example 2
The same apparatus as described in example 1 was tested under generally constant process parameters but for the variations in air flow indicated in FIG. 10B. In particular, 70% of the total air flow of 136 m3/h was cycled in a 20 second cycle such that each group of aerators received 70% of the total airflow for 10 seconds and 30% of the total airflow for 10 seconds. As shown in FIG. 10B, cycling 70% of the air flow resulted in reduced fouling rate at high permeate flux compared to constant aeration at the same total air flow.
Example 3
2 ZW 500 membrane modules were operated to produce drinking water from a natural supply of feed water. Operating parameters were kept constant but for changes in aeration. The modules were first operated for approximately 10 days with non-cycled aeration at 25.5 m3/h per module (for a total system airflow 51 m3/h). For a subsequent period of about three days, air was cycled from aerators near one set of modules to aerators near another set of modules such that each module was aerated at 12.8 m3/h for 10 seconds and then not aerated for a period of 10 seconds (for a total system airflow of 12.8 m3/h). For a subsequent period of about 10 days, the modules were aerated such that each module was aerated at 25.5 m3/h for 10 seconds and then not aerated for a period of 10 seconds (for a total system airflow of 25.5 m3/h). For a subsequent period of about 10 days, the initial constant airflow was restored. As shown in FIG. 10C, with aeration such that each module was aerated at 25.5 m3/h for 10 seconds and then not aerated for a period of 10 seconds (i.e. one half of the initial total system airflow), the membrane permeability stabilized at over 250 L/m2/h/bar whereas with non cycled airflow at the initial total system airflow the membrane permeability stabilised at only about 125 L/m2/h/bar.
Example 4
3 units each containing 2 ZW 500 membrane modules were operated at various fluxes in a membrane bioreactor. Unit 1 had modules operating at 26 L/m2/h and 51 L/m2/h. Unit 2 had modules operating at 31 L/m2/h and 46 L/m2/h. Unit 3 had modules operating at 34 L/m2/h and 51 L/m2/h. The units were first operated for a period of about 10 days with non cycled aeration at 42.5 m3/h per module (total system air flow of 85 m3/h). The permeability decreased and stabilized at between 250 and 275 L/m2/h/bar for Unit 1, between 200 and 225 L/m2/h/bar for Unit 2 and between 150 and 175 L/m2/h/bar for Unit 3. For a second period of about 14 days, a total system airflow of 61.2 m3/h was applied for 10 seconds to aerators below the modules and then for 10 seconds to aerators beside the modules. Under these conditions, permeability increased and stabilized at between 350 and 375 L/m2/h/bar for Unit 1 and between 325 and 350 L/m2/h/bar for Units 2 and 3.
Example 5
A cassette of 6 ZW 500 modules was used to treat sewage. While holding other process parameters generally constant, aeration was varied and permeability of the modules was measured periodically as shown in FIG. 11. In period A, 255 m3/h of air was supplied continuously and evenly to the modules. In period B, 184 m3/h of air was applied for 10 seconds to aerators below the modules and then for 10 seconds to aerators beside the modules. In Period C. the same aeration regime was used, but shrouding around the modules was altered. In period D, 184 m3/h of air was applied for 10 seconds to aerators near a first set of modules and then for 10 seconds to aerators near a second set of modules. In period E, 204 m3/h of air was applied to all of the modules evenly for 10 seconds and then no air was supplied to the modules for 10 seconds. In Period F, 306 m3/h was applied to all of the modules evenly for 10 seconds and then no air was supplied to the modules for 10 seconds. In Period G, 153 m3/h was applied to aerators near a first set of modules and then for 10 seconds to aerators near a second set of modules.
Example 6
A single ZW 500 membrane module was used to filter a supply of surface water. While keeping other process parameters constant, the module was operated under various aeration regimes and its permeability recorded periodically. First the module was operated with constant aeration at (a) 20.4 m3/h and (b) 25.5 m3/h. After an initial decrease in permeability, permeability stabilised at (a) about 200 L/m2/h/bar and (b) between 275 and 300 L/m2/h/bar respectively. In a first experiment, aeration was supplied to the module at 25.5 m3/h for two minutes and then turned off for 2 minutes. In this trial, permeability decreased rapidly and could not be sustained at acceptable levels. In another experiment, however, aeration was supplied to the module at 25.5 m3/h for 30 seconds and then at 8.5 m3/h for 30 seconds. In this trial, permeability again decreased initially but then stabilised at between 275 and 300 L/m2/h/bar.

Claims (8)

1. A method of cleaning or inhibiting the fouling of a plurality of hollow fibre membranes immersed in water in a tank during an outside-in membrane separation process with permeate withdrawn by providing a partial vacuum in communication with the insides of the plurality of hollow fibre membranes, the method comprising the step of operating the plurality of hollow fibre membranes under an aeration regime wherein a first flow of bubbles which agitate the plurality of hollow fibre membranes, varies from a higher flow rate to a lower flow rate during each of a plurality of successive periods of time, each of the successive periods of time being between 2 and 40 seconds long, the lower flow rate being in the range from and including no flow to one half of the higher flow rate.
2. The method according to claim 1 wherein the plurality of hollow fiber membranes are oriented vertically.
3. The method according to claim 1 further comprising a step of backwashing the plurality of hollow fibre membranes with permeate.
4. The method according to claim 3 wherein the backwashing step further comprises adding a chemical cleaner to the permeate used for backwashing the plurality of hollow fibre membranes.
5. The method according to claim 1 wherein the successive periods of time are about 20 seconds or less.
6. The method according to claim 1 wherein the first flow of bubbles is produced while providing the partial vacuum to withdraw permeate from the plurality of hollow fibre membranes.
7. The method of claim 1 further comprising producing a second flow of bubbles in the water in the tank in a location horizontally spaced from the first flow of bubbles, the second flow of bubbles varying from about the higher flow rate to about the lower flow rate and comprising a plurality of periods of flow at about the higher flow rate occurring while the first flow of bubbles is at the lower flow rate.
8. The method accordingly to claim 1 wherein the bubbles are produced from an aerator having a plurality of holes for discharging the bubbles.
US12/574,974 1998-10-09 2009-10-07 Cyclic aeration system for submerged membrane modules Expired - Lifetime US7820050B2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/574,974 US7820050B2 (en) 1998-10-09 2009-10-07 Cyclic aeration system for submerged membrane modules
US12/885,063 US7922910B2 (en) 1998-10-09 2010-09-17 Cyclic aeration system for submerged membrane modules

Applications Claiming Priority (17)

Application Number Priority Date Filing Date Title
US10366598P 1998-10-09 1998-10-09
CA2258715 1999-01-14
CA2258715 1999-01-14
US11659199P 1999-01-20 1999-01-20
CA2278085 1999-07-20
CA 2278085 CA2278085A1 (en) 1999-07-20 1999-07-20 Aeration system for submerged membrane module
CA 2279766 CA2279766A1 (en) 1999-07-30 1999-07-30 Aeration system for submerged membrane module
CA2279766 1999-07-30
PCT/CA1999/000940 WO2000021890A1 (en) 1998-10-09 1999-10-07 Cyclic aeration system for submerged membrane modules
US09/488,359 US6245239B1 (en) 1998-10-09 2000-01-19 Cyclic aeration system for submerged membrane modules
US09/814,737 US6550747B2 (en) 1998-10-09 2001-03-23 Cyclic aeration system for submerged membrane modules
US10/369,699 US6706189B2 (en) 1998-10-09 2003-02-21 Cyclic aeration system for submerged membrane modules
US10/684,406 US6881343B2 (en) 1998-10-09 2003-10-15 Cyclic aeration system for submerged membrane modules
US10/986,942 US7198721B2 (en) 1998-10-09 2004-11-15 Cyclic aeration system for submerged membrane modules
US11/515,941 US7347942B2 (en) 1998-10-09 2006-09-06 Cyclic aeration system for submerged membrane modules
US12/015,237 US7625491B2 (en) 1998-10-09 2008-01-16 Cyclic aeration system for submerged membrane modules
US12/574,974 US7820050B2 (en) 1998-10-09 2009-10-07 Cyclic aeration system for submerged membrane modules

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US12/015,237 Continuation US7625491B2 (en) 1998-10-09 2008-01-16 Cyclic aeration system for submerged membrane modules

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/885,063 Continuation US7922910B2 (en) 1998-10-09 2010-09-17 Cyclic aeration system for submerged membrane modules

Publications (2)

Publication Number Publication Date
US20100025327A1 US20100025327A1 (en) 2010-02-04
US7820050B2 true US7820050B2 (en) 2010-10-26

Family

ID=31982546

Family Applications (8)

Application Number Title Priority Date Filing Date
US10/369,699 Expired - Lifetime US6706189B2 (en) 1998-10-09 2003-02-21 Cyclic aeration system for submerged membrane modules
US10/684,406 Expired - Lifetime US6881343B2 (en) 1998-10-09 2003-10-15 Cyclic aeration system for submerged membrane modules
US10/986,942 Expired - Lifetime US7198721B2 (en) 1998-10-09 2004-11-15 Cyclic aeration system for submerged membrane modules
US11/177,383 Expired - Lifetime US7186343B2 (en) 1998-10-09 2005-07-11 Cyclic aeration system for submerged membrane modules
US11/515,941 Expired - Lifetime US7347942B2 (en) 1998-10-09 2006-09-06 Cyclic aeration system for submerged membrane modules
US12/015,237 Expired - Fee Related US7625491B2 (en) 1998-10-09 2008-01-16 Cyclic aeration system for submerged membrane modules
US12/574,974 Expired - Lifetime US7820050B2 (en) 1998-10-09 2009-10-07 Cyclic aeration system for submerged membrane modules
US12/885,063 Expired - Lifetime US7922910B2 (en) 1998-10-09 2010-09-17 Cyclic aeration system for submerged membrane modules

Family Applications Before (6)

Application Number Title Priority Date Filing Date
US10/369,699 Expired - Lifetime US6706189B2 (en) 1998-10-09 2003-02-21 Cyclic aeration system for submerged membrane modules
US10/684,406 Expired - Lifetime US6881343B2 (en) 1998-10-09 2003-10-15 Cyclic aeration system for submerged membrane modules
US10/986,942 Expired - Lifetime US7198721B2 (en) 1998-10-09 2004-11-15 Cyclic aeration system for submerged membrane modules
US11/177,383 Expired - Lifetime US7186343B2 (en) 1998-10-09 2005-07-11 Cyclic aeration system for submerged membrane modules
US11/515,941 Expired - Lifetime US7347942B2 (en) 1998-10-09 2006-09-06 Cyclic aeration system for submerged membrane modules
US12/015,237 Expired - Fee Related US7625491B2 (en) 1998-10-09 2008-01-16 Cyclic aeration system for submerged membrane modules

Family Applications After (1)

Application Number Title Priority Date Filing Date
US12/885,063 Expired - Lifetime US7922910B2 (en) 1998-10-09 2010-09-17 Cyclic aeration system for submerged membrane modules

Country Status (1)

Country Link
US (8) US6706189B2 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100326897A1 (en) * 1995-08-11 2010-12-30 Mailvaganam Mahendran Membrane filtration module with adjustable header spacing
US20110006003A1 (en) * 1998-10-09 2011-01-13 Pierre Lucien Cote Cyclic aeration system for submerged membrane modules
US8596989B2 (en) 2011-06-06 2013-12-03 King Fahd University Of Petroleum And Minerals Dual injection airlift pump
US10351815B2 (en) 2016-05-09 2019-07-16 Global Algae Technologies, Llc Biological and algae harvesting and cultivation systems and methods
US11767501B2 (en) 2016-05-09 2023-09-26 Global Algae Technology, LLC Biological and algae harvesting and cultivation systems and methods
US12097467B2 (en) 2021-01-18 2024-09-24 Ecolab Usa Inc. Systems and techniques for cleaning pressure membrane systems using a water-in-air cleaning stream

Families Citing this family (101)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5639373A (en) 1995-08-11 1997-06-17 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
WO1997006880A2 (en) * 1995-08-11 1997-02-27 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces
US7037426B2 (en) * 2000-05-04 2006-05-02 Zenon Environmental Inc. Immersed membrane apparatus
US6863823B2 (en) * 2001-03-23 2005-03-08 Zenon Environmental Inc. Inverted air box aerator and aeration method for immersed membrane
CA2639642C (en) 1996-12-20 2013-01-15 Siemens Water Technologies Corp. Scouring method
US6641733B2 (en) * 1998-09-25 2003-11-04 U. S. Filter Wastewater Group, Inc. Apparatus and method for cleaning membrane filtration modules
US7014173B2 (en) * 1998-10-09 2006-03-21 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
CA2290053C (en) * 1999-11-18 2009-10-20 Zenon Environmental Inc. Immersed membrane module and process
US20040007527A1 (en) * 1998-11-23 2004-01-15 Zenon Environmental Inc. Membrane filtration device and process
WO2000030742A1 (en) * 1998-11-23 2000-06-02 Zenon Environmental Inc. Water filtration using immersed membranes
AUPR421501A0 (en) * 2001-04-04 2001-05-03 U.S. Filter Wastewater Group, Inc. Potting method
AUPR692401A0 (en) 2001-08-09 2001-08-30 U.S. Filter Wastewater Group, Inc. Method of cleaning membrane modules
US6706180B2 (en) * 2001-08-13 2004-03-16 Phase Inc. System for vibration in a centrifuge
AUPS300602A0 (en) 2002-06-18 2002-07-11 U.S. Filter Wastewater Group, Inc. Methods of minimising the effect of integrity loss in hollow fibre membrane modules
AU2002950934A0 (en) * 2002-08-21 2002-09-12 U. S. Filter Wastewater Group, Inc. Aeration method
KR101002466B1 (en) 2002-10-10 2010-12-17 지멘스 워터 테크놀로지스 코포레이션 Backwash method
AU2002953111A0 (en) * 2002-12-05 2002-12-19 U. S. Filter Wastewater Group, Inc. Mixing chamber
DE602004013731D1 (en) * 2003-03-05 2008-06-26 Hydranautics DIPLOCKABLE MEMBRANE MODULE WITH REPLACEABLE MEMBRANE ELEMENTS
EP1610879A4 (en) * 2003-03-11 2007-02-21 Phase Inc Centrifuge with controlled discharge of dense material
US20040262209A1 (en) * 2003-04-25 2004-12-30 Hiroyuki Umezawa Filtration apparatus
US8513147B2 (en) 2003-06-19 2013-08-20 Eastman Chemical Company Nonwovens produced from multicomponent fibers
US7892993B2 (en) 2003-06-19 2011-02-22 Eastman Chemical Company Water-dispersible and multicomponent fibers from sulfopolyesters
US20040260034A1 (en) 2003-06-19 2004-12-23 Haile William Alston Water-dispersible fibers and fibrous articles
US6971525B2 (en) * 2003-06-25 2005-12-06 Phase Inc. Centrifuge with combinations of multiple features
US7294274B2 (en) * 2003-07-30 2007-11-13 Phase Inc. Filtration system with enhanced cleaning and dynamic fluid separation
US7371322B2 (en) * 2003-07-30 2008-05-13 Phase Inc. Filtration system and dynamic fluid separation method
JP4611982B2 (en) 2003-08-29 2011-01-12 シーメンス・ウォーター・テクノロジーズ・コーポレーション Backwash method
US7282147B2 (en) * 2003-10-07 2007-10-16 Phase Inc. Cleaning hollow core membrane fibers using vibration
FR2861718B1 (en) * 2003-10-30 2006-03-03 Otv Sa INSTALLATION AND METHOD FOR PURIFYING AQUEOUS EFFLUENT BY OXIDATION AND MEMBRANE FILTRATION
EP1687078B1 (en) 2003-11-14 2012-03-14 Siemens Industry, Inc. Improved module cleaning method
AT412847B (en) * 2003-12-09 2005-08-25 Va Tech Wabag Gmbh MEMBRANE FILTER SYSTEM WITH PARALLEL FLUSHABLE FILTER MODULES
US8758621B2 (en) 2004-03-26 2014-06-24 Evoqua Water Technologies Llc Process and apparatus for purifying impure water using microfiltration or ultrafiltration in combination with reverse osmosis
DE102004048416B4 (en) * 2004-04-02 2007-08-30 Koch Membrane Systems Gmbh Process for gassing membrane modules
WO2005107929A2 (en) * 2004-04-22 2005-11-17 Siemens Water Technologies Corp. Filtration apparatus comprising a membrane bioreactor and a treatment vessel for digesting organic materials
CN101052457B (en) * 2004-08-20 2012-07-04 西门子工业公司 Square mbr manifold system
JP4838248B2 (en) 2004-09-07 2011-12-14 シーメンス・ウォーター・テクノロジーズ・コーポレーション Reduction of backwash liquid waste
AU2005284677B2 (en) 2004-09-14 2010-12-23 Evoqua Water Technologies Llc Methods and apparatus for removing solids from a membrane module
WO2006029465A1 (en) 2004-09-15 2006-03-23 Siemens Water Technologies Corp. Continuously variable aeration
EP1819426A4 (en) * 2004-11-02 2009-08-12 Siemens Water Tech Corp Submerged cross-flow filtration
JP2008525167A (en) 2004-12-24 2008-07-17 シーメンス・ウォーター・テクノロジーズ・コーポレーション Simple gas cleaning method and apparatus in the technical field
ATE549076T1 (en) 2004-12-24 2012-03-15 Siemens Industry Inc CLEANING IN MEMBRANE FILTRATION SYSTEMS
AU2006206046B2 (en) * 2005-01-14 2010-10-28 Evoqua Water Technologies Llc Filtration system
CA2605757A1 (en) 2005-04-29 2006-11-09 Siemens Water Technologies Corp. Chemical clean for membrane filter
WO2007024761A1 (en) * 2005-08-22 2007-03-01 Ashford Edmundo R Compact membrane unit and methods
CA2618107A1 (en) 2005-08-22 2007-03-01 Siemens Water Technologies Corp. An assembly for water filtration using a tube manifold to minimise backwash
US7563363B2 (en) * 2005-10-05 2009-07-21 Siemens Water Technologies Corp. System for treating wastewater
WO2007044415A2 (en) 2005-10-05 2007-04-19 Siemens Water Technologies Corp. Method and apparatus for treating wastewater
US20070095754A1 (en) * 2005-10-28 2007-05-03 Dennis Livingston Efficient MBR operation in wastewater treatment
NZ569210A (en) * 2006-01-12 2012-03-30 Siemens Water Tech Corp Improved operating strategies in filtration processes
US7614279B2 (en) * 2006-10-10 2009-11-10 Porous Materials, Inc. Determination of pore structure characteristics of filtration cartridges as a function of cartridge length
US8272252B2 (en) * 2006-10-10 2012-09-25 Porous Materials, Inc. Pore structure characterization of filtration cartridges at specific locations along cartridge length
US8293098B2 (en) 2006-10-24 2012-10-23 Siemens Industry, Inc. Infiltration/inflow control for membrane bioreactor
EP2129629A1 (en) 2007-04-02 2009-12-09 Siemens Water Technologies Corp. Improved infiltration/inflow control for membrane bioreactor
US9764288B2 (en) 2007-04-04 2017-09-19 Evoqua Water Technologies Llc Membrane module protection
WO2008130885A2 (en) 2007-04-20 2008-10-30 Zenon Technology Partnership Membrane supported biofilm apparatus and process
KR20170092708A (en) 2007-05-29 2017-08-11 에보쿠아 워터 테크놀로지스 엘엘씨 Water treatment system
US7553418B2 (en) * 2007-08-18 2009-06-30 Khudenko Engineering, Inc. Method for water filtration
US20090071901A1 (en) * 2007-09-19 2009-03-19 Rabie Hamid R System and method for filtering liquids
CA2731774A1 (en) 2008-07-24 2010-01-28 Siemens Water Technologies Corp. Frame system for membrane filtration modules
EP2315625B1 (en) 2008-08-20 2018-05-16 Evoqua Water Technologies LLC Improved membrane system backwash energy efficiency
US8513119B2 (en) 2008-12-10 2013-08-20 Taiwan Semiconductor Manufacturing Company, Ltd. Method of forming bump structure having tapered sidewalls for stacked dies
US20100171197A1 (en) 2009-01-05 2010-07-08 Hung-Pin Chang Isolation Structure for Stacked Dies
KR101256705B1 (en) * 2009-03-23 2013-05-02 코오롱인더스트리 주식회사 Apparatus for filtering
US8512519B2 (en) 2009-04-24 2013-08-20 Eastman Chemical Company Sulfopolyesters for paper strength and process
WO2010142673A1 (en) 2009-06-11 2010-12-16 Siemens Water Technologies Corp. Methods for cleaning a porous polymeric membrane and a kit for cleaning a porous polymeric membrane
US8791549B2 (en) 2009-09-22 2014-07-29 Taiwan Semiconductor Manufacturing Company, Ltd. Wafer backside interconnect structure connected to TSVs
AU2010319846B2 (en) * 2009-10-28 2015-05-28 Oasys Water LLC Forward osmosis separation processes
JP5887273B2 (en) 2009-10-30 2016-03-16 オアシス ウォーター,インコーポレーテッド Osmotic separation system and method
US20130020261A1 (en) * 2010-03-15 2013-01-24 Mitsubishi Rayon Co., Ltd. Filtering method of water to be treated
US8466059B2 (en) 2010-03-30 2013-06-18 Taiwan Semiconductor Manufacturing Company, Ltd. Multi-layer interconnect structure for stacked dies
HUE045642T2 (en) 2010-04-30 2020-01-28 Evoqua Water Tech Llc Fluid flow distribution device
EP2618916A4 (en) 2010-09-24 2016-08-17 Evoqua Water Technologies Llc Fluid control manifold for membrane filtration system
US9273417B2 (en) 2010-10-21 2016-03-01 Eastman Chemical Company Wet-Laid process to produce a bound nonwoven article
DE102010053180A1 (en) * 2010-12-03 2012-06-06 Aquantis Gmbh Gas distribution valve and method for controlling the gas distribution for cleaning immersed filter elements
KR20130127524A (en) * 2011-04-01 2013-11-22 미쯔비시 레이온 가부시끼가이샤 Operating method for air diffusion apparatus
DE102011001962A1 (en) * 2011-04-11 2012-10-11 Thyssenkrupp Uhde Gmbh Process and plant for biological treatment of coking plant wastewater
US8900994B2 (en) 2011-06-09 2014-12-02 Taiwan Semiconductor Manufacturing Company, Ltd. Method for producing a protective structure
KR101304944B1 (en) * 2011-09-14 2013-09-06 현대자동차주식회사 Device for carbon dioxide solidification
WO2013049109A1 (en) 2011-09-30 2013-04-04 Siemens Industry, Inc. Isolation valve
JP2014528352A (en) 2011-09-30 2014-10-27 エヴォクア ウォーター テクノロジーズ エルエルシーEvoqua Water Technologiesllc Improved manifold structure
US8840757B2 (en) 2012-01-31 2014-09-23 Eastman Chemical Company Processes to produce short cut microfibers
JP6077223B2 (en) * 2012-05-17 2017-02-08 サンスイエンジニアリング株式会社 Drainage membrane filtration device
KR102108593B1 (en) 2012-06-28 2020-05-29 에보쿠아 워터 테크놀로지스 엘엘씨 A potting method
US10828607B2 (en) * 2012-08-09 2020-11-10 Lotte Chemical Corporation Aerator device, filter system including an aerator device, and method of aerating a filter using an aerator device
US9764289B2 (en) 2012-09-26 2017-09-19 Evoqua Water Technologies Llc Membrane securement device
AU2013231145B2 (en) 2012-09-26 2017-08-17 Evoqua Water Technologies Llc Membrane potting methods
WO2014052139A1 (en) 2012-09-27 2014-04-03 Evoqua Water Technologies Llc Gas scouring apparatus for immersed membranes
US10702829B2 (en) 2012-11-14 2020-07-07 Bl Technologies, Inc. Open bottom multiple channel gas delivery device for immersed membranes
US10105659B2 (en) * 2013-03-15 2018-10-23 Claudius Jaeger Dual control lateral air manifold assembly
US9303357B2 (en) 2013-04-19 2016-04-05 Eastman Chemical Company Paper and nonwoven articles comprising synthetic microfiber binders
EP3052221B1 (en) 2013-10-02 2022-12-14 Rohm & Haas Electronic Materials Singapore Pte. Ltd Device for repairing a membrane filtration module
US9605126B2 (en) 2013-12-17 2017-03-28 Eastman Chemical Company Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion
US9598802B2 (en) 2013-12-17 2017-03-21 Eastman Chemical Company Ultrafiltration process for producing a sulfopolyester concentrate
KR101704864B1 (en) * 2013-12-31 2017-02-08 롯데케미칼 주식회사 Aerator device and filter system including the same
US20150290597A1 (en) * 2014-04-09 2015-10-15 Therapeutic Proteins International, LLC Aeration device for bioreactors
HUE057069T2 (en) 2014-04-25 2022-04-28 South Dakota Board Of Regents High capacity electrodes
US9380797B2 (en) * 2014-10-24 2016-07-05 Safe Foods Corporation Antimicrobial capture system with carbon container
AU2016294153B2 (en) 2015-07-14 2022-01-20 Evoqua Water Technologies Llc Aeration device for filtration system
CN105036300B (en) * 2015-08-26 2017-08-15 中山朗清膜业有限公司 A kind of segmented membrane shell structure of MBR membrane modules
US20200339456A1 (en) * 2017-12-19 2020-10-29 Gis Gas Infusion Systems Inc. High-efficiency airlift pump
US10468674B2 (en) 2018-01-09 2019-11-05 South Dakota Board Of Regents Layered high capacity electrodes

Citations (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58141796A (en) 1982-02-18 1983-08-23 Kyowa Hakko Kogyo Co Ltd Preparation of peptide
DE3318412A1 (en) 1983-05-20 1984-11-22 Menzel Gmbh & Co, 7000 Stuttgart Gassing apparatus
JPS6057302A (en) 1983-09-08 1985-04-03 Agency Of Ind Science & Technol Production for buried optical waveguide circuit
JPS61107905A (en) 1984-10-30 1986-05-26 Toshiba Corp Filter
US4647377A (en) * 1984-07-24 1987-03-03 Kabushiki Kaisha Ito Tekkousho Filter apparatus
JPS62250908A (en) 1986-04-24 1987-10-31 Asahi Chem Ind Co Ltd Hollow yarn type filter
JPS6338884A (en) 1986-07-30 1988-02-19 大同特殊鋼株式会社 Thermal treatment equipment
JPS63143905A (en) 1986-12-08 1988-06-16 Toshiba Corp Hollow yarn membrane filter
JPH01168304A (en) 1987-12-22 1989-07-03 Kubota Ltd Solid/liquid separation and condensation apparatus
JPH0136099B2 (en) 1980-01-24 1989-07-28 Ricoh Kk
US4876006A (en) * 1985-10-08 1989-10-24 Ebara Corporation Hollow fiber filter device
US4923614A (en) * 1986-06-12 1990-05-08 Wilke Engelbart Process and device for large surface-area fine-bubble gasification of liquids
JPH04180821A (en) 1990-11-16 1992-06-29 Ebara Infilco Co Ltd Hollow yarn film filtration device
JPH04250898A (en) 1990-12-28 1992-09-07 Yanmar Diesel Engine Co Ltd Batch-wise waste water treating device
JPH04256425A (en) 1991-02-05 1992-09-11 Nippon Millipore Kogyo Kk Back washing device for filtration
JPH04265128A (en) 1991-02-20 1992-09-21 Ebara Infilco Co Ltd Membrane separation equipment
WO1993002779A1 (en) 1991-08-07 1993-02-18 Memtec Limited Concentration of solids in a suspension using hollow fibre membranes
US5192456A (en) * 1991-03-07 1993-03-09 Kubota Corporation Apparatus for treating activated sludge and method of cleaning it
JPH0596136A (en) 1991-10-04 1993-04-20 Toray Ind Inc Hollow-fiber membrane module and using method therefor
US5209852A (en) * 1990-08-31 1993-05-11 Japan Organo Co. Ltd. Process for scrubbing porous hollow fiber membranes in hollow fiber membrane module
US5209582A (en) 1991-01-29 1993-05-11 Kanzaki Paper Manufacturing Co., Ltd. Thermal printer
WO1993015827A1 (en) 1992-02-12 1993-08-19 Mitsubishi Rayon Co., Ltd. Hollow yarn membrane module
US5248424A (en) * 1990-08-17 1993-09-28 Zenon Environmental Inc. Frameless array of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
JPH05285348A (en) 1992-04-04 1993-11-02 Nitto Denko Corp Vertical type hollow fiber membrane module
JPH06285496A (en) 1993-04-07 1994-10-11 Ebara Infilco Co Ltd Hollow fiber membrane separation biological treatment and device for organic drainage
JPH06343837A (en) 1993-06-02 1994-12-20 Ebara Infilco Co Ltd Hollow fiber membrane module
JPH0724272A (en) 1993-07-09 1995-01-27 Mitsubishi Rayon Co Ltd Filtering method
JPH07100486A (en) 1993-10-01 1995-04-18 Mitsubishi Rayon Co Ltd Method for treating drainage
JPH07185268A (en) 1993-12-28 1995-07-25 Toray Ind Inc Hollow fiber filter membrane element and module
JPH07185271A (en) 1993-12-24 1995-07-25 Kurita Water Ind Ltd Immersion membrane apparatus
JPH07185270A (en) 1993-12-24 1995-07-25 Kurita Water Ind Ltd Immersion membrane apparatus
JPH07251042A (en) 1994-03-17 1995-10-03 Kubota Corp Membrane separation apparatus
JPH084722A (en) 1994-06-15 1996-01-09 Masaharu Awano Wedge
JPH0824597A (en) 1994-07-12 1996-01-30 Kurita Water Ind Ltd Immersion-type membrane separator
JPH08187494A (en) 1995-01-09 1996-07-23 Kubota Corp Purifying tank
WO1996022151A1 (en) 1995-01-18 1996-07-25 Dionex Corporation Methods and apparatus for real-time monitoring, measurement and control of electroosmotic flow
JPH08323161A (en) 1995-05-31 1996-12-10 Hitachi Plant Eng & Constr Co Ltd Immersion type membrane separator and membrane separation using the same
JPH0938684A (en) 1995-07-27 1997-02-10 Kurita Water Ind Ltd Waste water treating device
WO1997006880A2 (en) 1995-08-11 1997-02-27 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces
US5607593A (en) * 1993-11-30 1997-03-04 Otv Omnium De Trajtements Et De Valorisation S.A. Installation for making water potable with submerged filtering membranes
JPH0975938A (en) 1995-09-08 1997-03-25 Kurita Water Ind Ltd Membrane separation device
US5639373A (en) * 1995-08-11 1997-06-17 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
JPH09192688A (en) 1996-01-17 1997-07-29 Hitachi Chem Co Ltd Method for intermittently aerating sewage
JP2641341B2 (en) 1991-06-28 1997-08-13 株式会社日立製作所 Multi-stage hollow fiber membrane module assembly
JPH09220569A (en) 1993-06-02 1997-08-26 Kubota Corp Solid-liquid separator
US5878374A (en) 1997-04-09 1999-03-02 Eagle-Picher Industries, Inc. Computer-controlled electromechanical device for determining filtration parameters of a filter aid
JPH11128690A (en) 1997-11-04 1999-05-18 Sumitomo Heavy Ind Ltd Membrane filtration by membrane separator
WO1999029630A1 (en) 1997-12-05 1999-06-17 Mitsubishi Rayon Co., Ltd. Apparatus and method for treating water
WO1999029401A1 (en) 1997-12-08 1999-06-17 Zenon Environmental Inc. System for maintaining a clean skein of hollow fibres while filtering suspended solids
US5922201A (en) * 1992-02-12 1999-07-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module
EP0937494A2 (en) 1998-02-23 1999-08-25 Kubota Corporation Membrane separation system
JPH11244674A (en) 1998-03-06 1999-09-14 Kurita Water Ind Ltd Immersion type membrane separator
JP2000005785A (en) 1998-06-25 2000-01-11 Hitoshi Daido Activated sludge filter
US6077435A (en) 1996-03-15 2000-06-20 Usf Filtration And Separations Group Inc. Filtration monitoring and control system
AU721064B2 (en) 1996-12-20 2000-06-22 Evoqua Water Technologies Llc Scouring method
US6162020A (en) 1998-12-04 2000-12-19 Nca2Bioprocess, Inc. Airlift pump apparatus and method
US6193890B1 (en) * 1995-08-11 2001-02-27 Zenon Environmental Inc. System for maintaining a clean skein of hollow fibers while filtering suspended solids
US6245239B1 (en) * 1998-10-09 2001-06-12 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US6280626B1 (en) * 1998-08-12 2001-08-28 Mitsubishi Rayon Co., Ltd. Membrane separator assembly and method of cleaning the assembly utilizing gas diffuser underneath the assembly
US6284135B1 (en) * 1997-12-16 2001-09-04 Sumitomo Heavy Industries, Ltd. Membrane filter apparatus with gas discharge cleaning means
US20010027951A1 (en) * 1998-10-09 2001-10-11 Christian Gungerich Aerated immersed membrane system
US6319411B1 (en) * 1998-10-09 2001-11-20 Zenon Environmental Inc. Method of maintaining clean vertical skeins of hollow fiber membranes and system therefor
US6325928B1 (en) * 1999-11-18 2001-12-04 Zenon Environmental Inc. Immersed membrane element and module
US6550747B2 (en) * 1998-10-09 2003-04-22 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US6706189B2 (en) * 1998-10-09 2004-03-16 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
JP2004322100A (en) 2004-08-12 2004-11-18 Kurita Water Ind Ltd Device for immersion type membrane separation
US6863823B2 (en) * 2001-03-23 2005-03-08 Zenon Environmental Inc. Inverted air box aerator and aeration method for immersed membrane
JP4180821B2 (en) 2001-12-25 2008-11-12 前島工業株式会社 Weight structure of lifting equipment for cardboard box incision
JP4256425B2 (en) 2003-11-28 2009-04-22 モトローラ・インコーポレイテッド Radio resource management

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE813995C (en) 1948-10-02 1951-09-17 Bertram Mueller G M B H Equipment for fine ventilation or gassing of liquids
US3153682A (en) * 1955-05-27 1964-10-20 Walker Process Equipment Inc Tank aeration with clustered freeflowing air orifices alone
US3242072A (en) * 1960-03-30 1966-03-22 Walker Process Equipment Inc Aerators with water-sealed blow-off
US3501133A (en) * 1969-04-23 1970-03-17 Chicago Bridge & Iron Co Spargers with auxiliary tubes for dependable drain and wide range air flow
US3911064A (en) * 1971-04-08 1975-10-07 Union Carbide Corp System for gas sparging into liquid
US3953554A (en) * 1973-07-11 1976-04-27 Ashland Vault Incorporated Diffuser for aeration systems
US3975276A (en) * 1975-03-17 1976-08-17 Schmid Lawrence A Modular aerator and separator assembly for sewage treatment facility
US4066722A (en) * 1976-05-21 1978-01-03 Union Carbide Corporation Apparatus for sparging gas into liquid
US4313564A (en) * 1979-01-17 1982-02-02 Shames Sidney J Self-cleaning aerator with noise reduction
JPS5613087A (en) 1979-07-11 1981-02-07 Mitsui Miike Mach Co Ltd Preventing device for clogging of floating type activated sludge air diffusion device
US6200468B1 (en) * 1980-09-29 2001-03-13 Sanitaire Corporation Aeration system apparatus with source of in situ cleaning agent and pressure monitoring connection for submerged diffuser
US4474714A (en) * 1983-07-15 1984-10-02 Endurex Corp. Diffuser apparatus
US5051193A (en) * 1986-03-06 1991-09-24 Aeration Engineering Resources Corporation Waste water treatment process
JPS62258729A (en) 1986-05-02 1987-11-11 Mitsubishi Heavy Ind Ltd Gas blowing-in method for aeration tank
FR2600323B1 (en) * 1986-06-18 1991-02-15 Omnium Traitement Valorisa DEVICE FOR TRANSFERRING GAS AND FLOATING IN THE TREATMENT OF PURIFYING WATER
JPH0620520B2 (en) 1986-09-18 1994-03-23 三菱重工業株式会社 Cleaning method of air diffuser nozzle
JPS63137741A (en) 1986-11-28 1988-06-09 Mitsubishi Heavy Ind Ltd Gas blowing device for breathing tank
US5090352A (en) * 1987-02-24 1992-02-25 Corwin R. Horton Bow foil
JPH0420557Y2 (en) * 1987-08-25 1992-05-11
US4881286A (en) * 1987-11-27 1989-11-21 Kamyr Ab Effective diffuser/thickener screen backflushing
US4793161A (en) * 1987-11-27 1988-12-27 Kamyr Ab Effective diffuser/thickener screen backflushing
US5032325A (en) * 1989-11-02 1991-07-16 Environmental Dynamics, Inc. Plastic coarse bubble diffuser for waste water aeration systems
US5378355A (en) * 1992-12-04 1995-01-03 Water Pollution Control Corporation Direct delivery in-situ diffuser cleaning
JPH07171587A (en) 1993-12-20 1995-07-11 Ebara Res Co Ltd Method and apparatus for treating organic sewage
TW255835B (en) 1994-01-07 1995-09-01 Kubota Kk Filtration membrane module
JPH07313850A (en) * 1994-05-30 1995-12-05 Kubota Corp Method for backward washing immersion-type ceramic membrane separator
JPH08141587A (en) 1994-11-18 1996-06-04 Hitachi Chem Co Ltd Method and apparatus for treating waste water
WO1997002938A1 (en) * 1995-07-11 1997-01-30 Beamech Group Limited Apparatus and process for producing polymeric foam
DE59603362D1 (en) 1995-08-17 1999-11-18 Basf Ag FUNGICIDAL MIXTURES OF AN OXIMETHER CARBONIC ACID WITH FENARIMOL
JPH10235390A (en) 1997-02-24 1998-09-08 Matsushita Electric Works Ltd Aeration apparatus
JP2000061273A (en) 1998-08-25 2000-02-29 Sumitomo Heavy Ind Ltd Membrane separator and its membrane cleaning method
WO2000030742A1 (en) * 1998-11-23 2000-06-02 Zenon Environmental Inc. Water filtration using immersed membranes
US20040007527A1 (en) * 1998-11-23 2004-01-15 Zenon Environmental Inc. Membrane filtration device and process
JP2000155478A (en) * 1998-11-24 2000-06-06 Minolta Co Ltd Belt driving device
JP2000343095A (en) 1999-06-02 2000-12-12 Mitsubishi Rayon Co Ltd Activated sludge treating device
DE60125594T2 (en) 2000-12-04 2007-10-11 Kubota Corp. AIR DISTRIBUTION AND SPILLING PROCESS THEREFOR
US6843908B2 (en) * 2000-12-04 2005-01-18 Kubota Corporation Multistage immersion type membrane separator and high-concentration wastewater treatment facility using same
US20050224412A1 (en) * 2004-04-09 2005-10-13 Best Graham J Water treatment system having upstream control of filtrate flowrate and method for operating same

Patent Citations (85)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0136099B2 (en) 1980-01-24 1989-07-28 Ricoh Kk
JPS58141796A (en) 1982-02-18 1983-08-23 Kyowa Hakko Kogyo Co Ltd Preparation of peptide
DE3318412A1 (en) 1983-05-20 1984-11-22 Menzel Gmbh & Co, 7000 Stuttgart Gassing apparatus
JPS6057302A (en) 1983-09-08 1985-04-03 Agency Of Ind Science & Technol Production for buried optical waveguide circuit
US4647377A (en) * 1984-07-24 1987-03-03 Kabushiki Kaisha Ito Tekkousho Filter apparatus
JPS61107905A (en) 1984-10-30 1986-05-26 Toshiba Corp Filter
US4876006A (en) * 1985-10-08 1989-10-24 Ebara Corporation Hollow fiber filter device
JPS62250908A (en) 1986-04-24 1987-10-31 Asahi Chem Ind Co Ltd Hollow yarn type filter
US4923614A (en) * 1986-06-12 1990-05-08 Wilke Engelbart Process and device for large surface-area fine-bubble gasification of liquids
JPS6338884A (en) 1986-07-30 1988-02-19 大同特殊鋼株式会社 Thermal treatment equipment
JPS63143905A (en) 1986-12-08 1988-06-16 Toshiba Corp Hollow yarn membrane filter
JPH01168304A (en) 1987-12-22 1989-07-03 Kubota Ltd Solid/liquid separation and condensation apparatus
US5248424A (en) * 1990-08-17 1993-09-28 Zenon Environmental Inc. Frameless array of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
US5209852A (en) * 1990-08-31 1993-05-11 Japan Organo Co. Ltd. Process for scrubbing porous hollow fiber membranes in hollow fiber membrane module
JP2904564B2 (en) 1990-08-31 1999-06-14 オルガノ株式会社 Method of scrubbing filtration tower using hollow fiber membrane
JPH04180821A (en) 1990-11-16 1992-06-29 Ebara Infilco Co Ltd Hollow yarn film filtration device
JPH04250898A (en) 1990-12-28 1992-09-07 Yanmar Diesel Engine Co Ltd Batch-wise waste water treating device
US5209582A (en) 1991-01-29 1993-05-11 Kanzaki Paper Manufacturing Co., Ltd. Thermal printer
JPH04256425A (en) 1991-02-05 1992-09-11 Nippon Millipore Kogyo Kk Back washing device for filtration
JPH04265128A (en) 1991-02-20 1992-09-21 Ebara Infilco Co Ltd Membrane separation equipment
US5192456A (en) * 1991-03-07 1993-03-09 Kubota Corporation Apparatus for treating activated sludge and method of cleaning it
JP2641341B2 (en) 1991-06-28 1997-08-13 株式会社日立製作所 Multi-stage hollow fiber membrane module assembly
WO1993002779A1 (en) 1991-08-07 1993-02-18 Memtec Limited Concentration of solids in a suspension using hollow fibre membranes
US5643455A (en) * 1991-08-07 1997-07-01 Memtel Limited Concentration of solids in a suspension using hollow fibre membranes
JPH0596136A (en) 1991-10-04 1993-04-20 Toray Ind Inc Hollow-fiber membrane module and using method therefor
WO1993015827A1 (en) 1992-02-12 1993-08-19 Mitsubishi Rayon Co., Ltd. Hollow yarn membrane module
US5480553A (en) * 1992-02-12 1996-01-02 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module
US5922201A (en) * 1992-02-12 1999-07-13 Mitsubishi Rayon Co., Ltd. Hollow fiber membrane module
JPH05285348A (en) 1992-04-04 1993-11-02 Nitto Denko Corp Vertical type hollow fiber membrane module
JPH06285496A (en) 1993-04-07 1994-10-11 Ebara Infilco Co Ltd Hollow fiber membrane separation biological treatment and device for organic drainage
JPH06343837A (en) 1993-06-02 1994-12-20 Ebara Infilco Co Ltd Hollow fiber membrane module
JPH09220569A (en) 1993-06-02 1997-08-26 Kubota Corp Solid-liquid separator
JPH0724272A (en) 1993-07-09 1995-01-27 Mitsubishi Rayon Co Ltd Filtering method
JP2946072B2 (en) 1993-07-09 1999-09-06 三菱レイヨン株式会社 Filtration method
JPH07100486A (en) 1993-10-01 1995-04-18 Mitsubishi Rayon Co Ltd Method for treating drainage
US5607593A (en) * 1993-11-30 1997-03-04 Otv Omnium De Trajtements Et De Valorisation S.A. Installation for making water potable with submerged filtering membranes
JPH07185271A (en) 1993-12-24 1995-07-25 Kurita Water Ind Ltd Immersion membrane apparatus
JPH07185270A (en) 1993-12-24 1995-07-25 Kurita Water Ind Ltd Immersion membrane apparatus
JPH07185268A (en) 1993-12-28 1995-07-25 Toray Ind Inc Hollow fiber filter membrane element and module
JPH07251042A (en) 1994-03-17 1995-10-03 Kubota Corp Membrane separation apparatus
JPH084722A (en) 1994-06-15 1996-01-09 Masaharu Awano Wedge
JPH0824597A (en) 1994-07-12 1996-01-30 Kurita Water Ind Ltd Immersion-type membrane separator
JPH08187494A (en) 1995-01-09 1996-07-23 Kubota Corp Purifying tank
WO1996022151A1 (en) 1995-01-18 1996-07-25 Dionex Corporation Methods and apparatus for real-time monitoring, measurement and control of electroosmotic flow
JPH08323161A (en) 1995-05-31 1996-12-10 Hitachi Plant Eng & Constr Co Ltd Immersion type membrane separator and membrane separation using the same
JPH0938684A (en) 1995-07-27 1997-02-10 Kurita Water Ind Ltd Waste water treating device
US5639373A (en) * 1995-08-11 1997-06-17 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
WO1997006880A2 (en) 1995-08-11 1997-02-27 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces
US5783083A (en) * 1995-08-11 1998-07-21 Zenon Environmental Inc. Vertical cylindrical skein of hollow fiber membranes and method of maintaining clean fiber surfaces
US6193890B1 (en) * 1995-08-11 2001-02-27 Zenon Environmental Inc. System for maintaining a clean skein of hollow fibers while filtering suspended solids
US5910250A (en) * 1995-08-11 1999-06-08 Zenon Environmental Inc. Baffle for conversion of fine bubbles to coarse while filtering with a vertical skein of hollow fibers
USRE37549E1 (en) * 1995-08-11 2002-02-19 Zenon Environmental Inc. Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate
US6042677A (en) * 1995-08-11 2000-03-28 Zenon Environmental, Inc. Potted header for hollow fiber membranes and method for making it
US5944997A (en) * 1995-08-11 1999-08-31 Zenon Environmental Inc. System for maintaining a clean skein of hollow fibers while filtering suspended solids
JPH0975938A (en) 1995-09-08 1997-03-25 Kurita Water Ind Ltd Membrane separation device
JPH09192688A (en) 1996-01-17 1997-07-29 Hitachi Chem Co Ltd Method for intermittently aerating sewage
US6077435A (en) 1996-03-15 2000-06-20 Usf Filtration And Separations Group Inc. Filtration monitoring and control system
AU721064B2 (en) 1996-12-20 2000-06-22 Evoqua Water Technologies Llc Scouring method
US5878374A (en) 1997-04-09 1999-03-02 Eagle-Picher Industries, Inc. Computer-controlled electromechanical device for determining filtration parameters of a filter aid
JPH11128690A (en) 1997-11-04 1999-05-18 Sumitomo Heavy Ind Ltd Membrane filtration by membrane separator
WO1999029630A1 (en) 1997-12-05 1999-06-17 Mitsubishi Rayon Co., Ltd. Apparatus and method for treating water
WO1999029401A1 (en) 1997-12-08 1999-06-17 Zenon Environmental Inc. System for maintaining a clean skein of hollow fibres while filtering suspended solids
US6402955B2 (en) * 1997-12-16 2002-06-11 Sumitomo Heavy Industries, Ltd. Method for operating a membrane filter having a gas discharge cleaning means
US6284135B1 (en) * 1997-12-16 2001-09-04 Sumitomo Heavy Industries, Ltd. Membrane filter apparatus with gas discharge cleaning means
EP0937494A2 (en) 1998-02-23 1999-08-25 Kubota Corporation Membrane separation system
JPH11244674A (en) 1998-03-06 1999-09-14 Kurita Water Ind Ltd Immersion type membrane separator
JP2000005785A (en) 1998-06-25 2000-01-11 Hitoshi Daido Activated sludge filter
US6280626B1 (en) * 1998-08-12 2001-08-28 Mitsubishi Rayon Co., Ltd. Membrane separator assembly and method of cleaning the assembly utilizing gas diffuser underneath the assembly
US6245239B1 (en) * 1998-10-09 2001-06-12 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US7347942B2 (en) * 1998-10-09 2008-03-25 Zenon Technology Partnership Cyclic aeration system for submerged membrane modules
US7625491B2 (en) * 1998-10-09 2009-12-01 Zenon Technology Partnership Cyclic aeration system for submerged membrane modules
US20010027951A1 (en) * 1998-10-09 2001-10-11 Christian Gungerich Aerated immersed membrane system
US6319411B1 (en) * 1998-10-09 2001-11-20 Zenon Environmental Inc. Method of maintaining clean vertical skeins of hollow fiber membranes and system therefor
US6550747B2 (en) * 1998-10-09 2003-04-22 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US6656356B2 (en) * 1998-10-09 2003-12-02 Zenon Environmental Inc. Aerated immersed membrane system
US6706189B2 (en) * 1998-10-09 2004-03-16 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US7198721B2 (en) * 1998-10-09 2007-04-03 Zenon Technology Partnership Cyclic aeration system for submerged membrane modules
US7186343B2 (en) * 1998-10-09 2007-03-06 Zenon Technology Partnership Cyclic aeration system for submerged membrane modules
US6881343B2 (en) * 1998-10-09 2005-04-19 Zenon Environmental Inc. Cyclic aeration system for submerged membrane modules
US6162020A (en) 1998-12-04 2000-12-19 Nca2Bioprocess, Inc. Airlift pump apparatus and method
US6325928B1 (en) * 1999-11-18 2001-12-04 Zenon Environmental Inc. Immersed membrane element and module
US6863823B2 (en) * 2001-03-23 2005-03-08 Zenon Environmental Inc. Inverted air box aerator and aeration method for immersed membrane
JP4180821B2 (en) 2001-12-25 2008-11-12 前島工業株式会社 Weight structure of lifting equipment for cardboard box incision
JP4256425B2 (en) 2003-11-28 2009-04-22 モトローラ・インコーポレイテッド Radio resource management
JP2004322100A (en) 2004-08-12 2004-11-18 Kurita Water Ind Ltd Device for immersion type membrane separation

Non-Patent Citations (28)

* Cited by examiner, † Cited by third party
Title
"Design of Three-Stage, Four-Stage, and Five-Stage ENR Systems", Design and Retrofit of Wastewater Treatment Plants for Biological Nutrient Removal, 1992, pp. 143-146.
Ahahi Chem Ind Co Ltd, English Abstract of JP 62250908, 2010.
Brewster, et al., "Dean Vortices with Wall Flux in a Curved Channel Membrane System", Journal of Membrane Science, 81 (1993) 127-137.
Daido Hitoshi et al., English Abstract of JP 2000005785, 2010.
English Translation of Official Action regarding Japanese Patent Application No. 2000-575802, dated May 26, 2003.
Finnigan, S., et al., "The Effect of Pulsed Flow on Ultrafiltration Fluxes in a Baffled Tubular Membrane System", Desalination, 79 (1990) 181-202.
Hodgson, "Crossflow Microfiltration of Biomass and Biofluids with Inorganic Membranes", University of South Wales, 1993, p. 107.
International Preliminary Examination Report regarding International Application No. PCT/CA99/00940 dated Feb. 9, 2001.
Kaiya et al., "Water Purification Using Hollow Fiber Microfiltration Membranes", 6th World Filtration Congress, Nagoya, 1993, pp. 813-816.
Kubota Corp., English Abstract of JP 09220569, 2010.
Kubota Corp., English Abstract of JP 7251042, 2010.
Kubota Ltd., English Abstract of JP 01168304, 2010.
Kurita Water Ind Ltd., English Abstract of JP 08024597, 2010.
Law, "Recent Developments in Nutrient Removal in Australia, Biological and Biological/Chemical", Joint Technical Seminar on Sewage Treatment Technology, May 12-14, 1998, pp. 1-20.
Leslie, "Bacterial Fouling of Microfiltration Membranes", University of South Wales, 1993, p. 73.
Li, et al., "The Mechanisms of Pulsutile Flow Effect on Crossflow Microfiltration", IMSTEC Conference, 1996, pp. 150-155.
Mills Jr., et al., "Reclamation of Secondary Effluent Using Synthetic Membrane", Proceedings of the International Membranes Science and Technology Conference, Nov. 12-14, 1996, vol. 1, pp. 39-41.
Mitsubishi Rayon Co Ltd, English Abstract of JP 7100486, 2010.
Sudak, et al., "Pilot Plant Testing of Direct Filtration, Microfiltration and Reverse Osmosis at Water Factory 21", Microfiltration for Water Treatment Symposium, 1994, pp. 95-96.
Summons to Oral Proceedings, regarding European Patent Application No. 99947155.0, dated May 27, 2003.
Toray Ind Inc., English Abstract of JP 05096136, 2010.
Toshiba Corp, English Abstract of JP 61107905, 2010.
Tsuchiya, et al., "Visualization of Bubble-Wake Interactions for a Stream of Bubbles in a Two-Dimensional Liquid-Solid Fluidized Bed", Int. J. Multiphase Flow, vol. 15, No. 1, pp. 35-49, 1989.
Ueda et al., "Effects of Aeration on Suction Pressure in a Submerged Membrane Bioreactor", Wat. Res., vol. 31, No. 3, pp. 489-494, 1997.
United States District Court, Southern District of California, CV No. 03-CV-1996B-AJB, "Defendant United States Filter Corporation's First Amended Answer to Complaint and Counterclaims", Jan. 12, 2005.
United States District Court, Southern District of California, CV No. 03-CV-1996W-JFS, "Complaint for Patent Infringement; Demand for Jury Trial", Oct. 8, 2003.
White et al., "Optimisation of Intermittently Operated Microfiltration Processes", The Chemical Engineering Journal, 52 (1993) 73-77.
Written Opinion regarding International Application No. PCT/CA99/00940 dated Jul. 14, 2000.

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100326897A1 (en) * 1995-08-11 2010-12-30 Mailvaganam Mahendran Membrane filtration module with adjustable header spacing
US20110006003A1 (en) * 1998-10-09 2011-01-13 Pierre Lucien Cote Cyclic aeration system for submerged membrane modules
US7922910B2 (en) * 1998-10-09 2011-04-12 Zenon Technology Partnership Cyclic aeration system for submerged membrane modules
US8596989B2 (en) 2011-06-06 2013-12-03 King Fahd University Of Petroleum And Minerals Dual injection airlift pump
US10351815B2 (en) 2016-05-09 2019-07-16 Global Algae Technologies, Llc Biological and algae harvesting and cultivation systems and methods
US10501721B2 (en) 2016-05-09 2019-12-10 Global Algae Technologies, Llc Biological and algae harvesting and cultivation systems and methods
US10934520B2 (en) 2016-05-09 2021-03-02 Global Algae Technology, LLC Biological and algae harvesting and cultivation systems and methods
US11680242B2 (en) 2016-05-09 2023-06-20 Global Algae Technology, LLC Biological and algae harvesting and cultivation systems and methods
US11767501B2 (en) 2016-05-09 2023-09-26 Global Algae Technology, LLC Biological and algae harvesting and cultivation systems and methods
US12097467B2 (en) 2021-01-18 2024-09-24 Ecolab Usa Inc. Systems and techniques for cleaning pressure membrane systems using a water-in-air cleaning stream

Also Published As

Publication number Publication date
US20080251455A1 (en) 2008-10-16
US7198721B2 (en) 2007-04-03
US7186343B2 (en) 2007-03-06
US20050115900A1 (en) 2005-06-02
US20110006003A1 (en) 2011-01-13
US20040113293A1 (en) 2004-06-17
US7625491B2 (en) 2009-12-01
US20070001324A1 (en) 2007-01-04
US20100025327A1 (en) 2010-02-04
US6706189B2 (en) 2004-03-16
US20030127389A1 (en) 2003-07-10
US7922910B2 (en) 2011-04-12
US20060006112A1 (en) 2006-01-12
US7347942B2 (en) 2008-03-25
US6881343B2 (en) 2005-04-19

Similar Documents

Publication Publication Date Title
US7820050B2 (en) Cyclic aeration system for submerged membrane modules
US6550747B2 (en) Cyclic aeration system for submerged membrane modules
US7014173B2 (en) Cyclic aeration system for submerged membrane modules
US6245239B1 (en) Cyclic aeration system for submerged membrane modules
US6656356B2 (en) Aerated immersed membrane system
AU1255800A (en) Water filtration using immersed membranes
AU2003271311B2 (en) Cyclic aeration system for submerged membrane modules
CA2279766A1 (en) Aeration system for submerged membrane module
CA2278085A1 (en) Aeration system for submerged membrane module
TW464532B (en) Method of aerating immersed membranes, cyclic aeration system for submerged membranes and immersed membrane filtration system and reactor
CA2307492A1 (en) Aerated immersed membrane system

Legal Events

Date Code Title Description
AS Assignment

Owner name: ZENON ENVIRONMENTAL INC.,CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:COTE, PIERRE LUCIEN;JANSON, ARNOLD;RABIE, HAMID R.;AND OTHERS;SIGNING DATES FROM 20050119 TO 20050124;REEL/FRAME:023818/0829

Owner name: ZENON ENVIRONMENTAL INC., CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:COTE, PIERRE LUCIEN;JANSON, ARNOLD;RABIE, HAMID R.;AND OTHERS;SIGNING DATES FROM 20050119 TO 20050124;REEL/FRAME:023818/0829

AS Assignment

Owner name: ZENON TECHNOLOGY PARTNERSHIP,CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:ZENON ENVIRONMENTAL INC.;REEL/FRAME:023822/0079

Effective date: 20060530

Owner name: ZENON TECHNOLOGY PARTNERSHIP, CANADA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:ZENON ENVIRONMENTAL INC.;REEL/FRAME:023822/0079

Effective date: 20060530

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 8TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1552)

Year of fee payment: 8

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M1553); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY

Year of fee payment: 12