US4152272A - Fabric conditioning composition - Google Patents

Fabric conditioning composition Download PDF

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Publication number
US4152272A
US4152272A US05/845,090 US84509077A US4152272A US 4152272 A US4152272 A US 4152272A US 84509077 A US84509077 A US 84509077A US 4152272 A US4152272 A US 4152272A
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particles
alkyl
composition according
cationic surfactant
perfume
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Kenneth Young
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Procter and Gamble Co
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Procter and Gamble Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q13/00—Formulations or additives for perfume preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C11D3/502—Protected perfumes
    • C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/005—Compositions containing perfumes; Compositions containing deodorants
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/65—Characterized by the composition of the particulate/core
    • A61K2800/652—The particulate/core comprising organic material

Definitions

  • the German Offenlegungsschrift No. 26 31 129 describes textile treatment compositions containing prills of size 5 to 2000 microns comprising 95 to 99.5% of a fabric softening (and antistatic) agent and 0.5 to 5% of a non-fabric softening fabric conditioning material, e.g. a perfume.
  • a fabric softening (and antistatic) agent e.g. a fabric softening fabric conditioning material
  • a non-fabric softening fabric conditioning material e.g. a perfume.
  • Such prills are entrained and carried with the fabrics into a fabric dryer where they melt or soften at the temperature reached in the dryer.
  • the melting of the prills allows the fabric softening agent to spread over the fabric surfaces by virtue of the tumbling action of the dryer and further causes the non-fabric softening agent to deposit efficiently on to the fabrics being dried.
  • German Offenlegungsschrift No. 27 02 162 describes fabric conditioning particles of size from 5 to 2000 microns comprising 20-53% castor wax, 45-80% quaternary fabric softener and optionally from 0.1 to 2% perfume. They are intended to be dispersed in detergent compositions.
  • British Patent 1,204,123 describes mixtures of perfumes--other things in an extrudable solid, which mixtures are formed into granules, which are added to surfactant-containing powders.
  • the enhanced utilization of perfume enables the use of lower levels with the same or even improved perfume impact.
  • a perfumed conditioning composition which comprises from 0.1% to 20% by weight of the composition of particles having an average particle size in the range from 0.1 to 200 microns and having a melting point in the range from 38° C. to 150° C. said particles comprising, by weight of the particles, (a) less than 95% and at least 25% of a carrier substance and (b) from 1% to 75% of a perfume, said particles being incorporated into a composition which contains a fabric-substantive cationic surfactant.
  • the present invention is based on the recognition that perfume-contaning particles, of a defined melting point and size, can be incorporated into a composition containing a fabric-substantive cationic surfactant. It is believed that the cationic surfactant in the composition becomes associated, in use of the composition, with the perfumed particles and assists in carying the particles to a fabric surface where they are retained and subsequently release their perfume, especially during heat treatment such as drying or ironing.
  • the composition can be of any type and in any physical form. However, aqueous rinse-added fabric softening compositions are highly preferred.
  • the perfume-containing particles have a specific size range.
  • the useful size range of the particles is limited at the low end by undue loss of perfume from the surface of the particles even before they are melted, as, if the particles are less than about 0.1 microns, their surface area per unit weight becomes too great.
  • the particles if they have a dimension greater than about 200 microns, they are not sufficiently susceptible to the action of the cationic surfactant in the remainder of the composition in promoting substantivity.
  • the size of the particles is in the range from about 1 to 100 microns especially about 10 to 50 microns. This linear dimension for any individual particle represents the length of the longest straight line joining two points on the surface of the particle.
  • Another critical physical property of the particles used in the present invention is their melting point and it is essential that they melt in the range from 38° C. to 150° C., preferably from 65° C. to 100° C.
  • the melting point of the particles is usually a function of the carrier substance employed but it should be understood that it is the melting point of the particle rather than of the carrier substance that is important.
  • the carrier substance can be any substantially water-insoluble substance compatible with and miscible with the perfume and harmless or beneficial to the fabrics when dispersed and melted on to them.
  • the mixture of carrier and perfume must have a melting point in the range defined above.
  • the carrier substance is normally a waxy material and a description of waxes is given in the book "Chemistry and Technology of Waxes" A.H. Warth Second Edition, 1960, incorporated herein by reference.
  • Suitable materials include macro- and microcrystalline hydrocarbon waxes, derived from petroleum or made synthetically, ester waxes such as bees wax, carnauba wax, ozokerite; fatty acid esters of mono- or polyhydric alcohols; hardened fatty acids and hydroxy fatty acids; higher monohydric alcohols.
  • Preferred waxes are the microcrystalline waxes and the Fischer-Tropsch waxes described below.
  • Microcrystalline wax 185/190 sold by Shell Chemicals (the numerical ranges are believed to represent the melting point ranges -° F.)
  • waxy esters are also suitable. These include the naturally derived ester waxes, preferably those with low saponification value, that is not exceeding 100, preferably below 60. Also suitable, provided that they are chosen as having high enough melting point when mixed with the perfume are fatty acid esters and partial esters of mono-and polyhydric alcohols or anhydrides thereof, said alcohols or anhydrides having 1 to 8 carbon atoms. These substances can themselves be employed as textile softeners in fabric conditioning compositions: in the present invention, they can be present both in the particle as the or part of the carrier substance and in the remainder of the composition as part of the fabric softening component.
  • fatty acid esters and partial esters are more fully described in the German Offenlegungsschrift No. 26 31 114. These materials are fatty acid esters of mono- or polyhydric alcohols or anhydrides having from 1 to 8 carbon atoms. It is preferred that the fatty acid ester should have at least 1, more preferably 2, free (i.e. unesterified) hydroxyl groups and at least 1, more preferably at least 2 fatty acyl groups.
  • the mono- or polyhydric alcohol portion of the ester can be represented by methanol, isobutanol, 2-ethylhexanol, isopropanol, ethylene glycol and polyethylene glycol with a maximum of 5 ethylene glycol units, glycerol, diglycerol, xylitol, erythritol, pentaerythritol, sorbitol or sorbitan. Ethylene glycol, glycerol and sorbitan esters are particularly preferred.
  • the fatty acid portion of the ester normally comprises a fatty acid having from 12 to 22 carbon atoms, typical examples being lauric acid, myristic acid, palmitic acid, stearic acid and behenic acid.
  • Specific useful fatty acid partial esters are xylitol monopalmitate, pentaerythritol mono-stearate, glycerol monostearate and ethylene glycol monostearate.
  • commercially available monoesters normally contain substantial quantities of di- or tri-esters.
  • Suitable carrier materials are fatty alcohols of about 16 carbon atoms upwards, such as octadecanol, eicosanol, and tallow alcohols. Higher nearly saturated fatty acids can also be used, for example palmitic, stearic, arachidic, hardened fatty acid from tallow or fish oils, or hydrogenated castor oil (known as castorwax). All these substances are commercially available. A table of physical properties of some common waxes is published in Soap & Chemical Specialties, December 1957, p. 141, and is hereby incorporated by reference.
  • the particles used in the present invention contain, in addition to the carrier substance, a perfume. So that it is not released too soon, it is preferred that the perfumes or their components do not have boiling points less than about 100° C. and preferably have boiling points in excess of 200° C. However, the particles used in the present invention are also useful in enhancing the residuality on fabrics of perfumes containing more labile components by delaying the release of these components.
  • the perfume materials which can be used in the fabric conditioning prills of the present invention can be of any odoriferous material and will be selected according to the desires of the formulator. In general terms, such perfume materials are characterized by a vapor pressure below atmospheric pressure at ambient temperatures.
  • the high boiling perfume materials employed herein wwill most often be solids at ambient temperatures, but also can include high boiling liquids.
  • a wide variety of chemicals are known for perfumery uses, including materials such as aldehydes, ketones, esters, and the like. More commonly, naturallyoccuring plant and animal oils and exudates comprising complex mixtures of various chemical components are known for use as perfumes, and such materials can be used herein.
  • the perfumes herein can be relatively simple in their composition, or can comprise highly sophisticated, complex mixtures of natural and synthetic chemical components, all chosen to provide any desired odor.
  • Typical perfumes herein can comprise, for example the high boiling components of woody/earthy bases containing exotic materials such as sandalwood oil, civet, patchouli oil, and the like.
  • the perfumes herein can be of a light, floral fragrance, e.g., high boiling components of rose extract, violet extract, and the like.
  • the perfumes herein can be formulated to provide desirable fruity odors., e.g., lime, lemon, orange, and the like.
  • the perfume can be any material (of appropriate chemical and physical properties) which exudes a pleasant or otherwise desirable odor when applied to fabrics.
  • Perfume materials such as these are described more fully in S. Arctander, Perfume Flavors and Chemicals, Vols. I and II, Aurthor, Montclair, N.J. and the Merck Index, 8th Edition, Merck & Co., Inc. Rahway, N.J., both references being incorporated herein by reference.
  • Preferred perfume materials include musk ambrette, musk ketone, musk tibetene, musk xylol, aurantiol, ethyl vanillin and mixtures of these perfume materials.
  • the particles used in the present invention contain less than 95% and at least 25% of the carrier substance and from 1% to 75% of the perfume. Preferably, there is from 50% to 90% of the carrier and from 10% to 40% of the perfume.
  • the melting point of the particles is preferably from 64° C. to 100° C. as determined by a capillary tube method, for instance the method of the American Oil Chemists Association(A.O.C.A.) Cc 1-25, incorporated herein by reference.
  • particles consisting entirely of the above two components are entirely satisfactory, it is also possible to include an additional component or components into the particle.
  • This component may be simply a diluent, but normally it is selected to have some other function.
  • the additional component can also be an absorbent solid such as finely divided silica, clay, starch, etc.
  • Suitable fine silica materials are well known commercially available pyrogenic or fumed silicas, sold under Trade names such as Cabosil (G. L. Cabot Inc.), Aerogel 500 (J. M. Huber Corp.), Syloid 244, -63, -65 (W. R. Grace and Co.), and Li-sil 233 (Pittsburg Plate Glass Co.).
  • Suitable clay materials include kaolinites and bentonites, as described in British Pat. No. 1,460,646.
  • Such clays are available unde Trade names, for example: Thixogel No. 1 and Gelwhite GP and Soft Dark from Georgia Kaolin Co.; Volclay BC and Volclay No. 325 from American Colloid Co.; Veegum Pro and Veegum F. from T. R. Venderbilt.
  • any additional component is usually present in an amount from 10% to 50% by weight of the particles.
  • the ratio of carrier substance to cationic surfactant is preferably at least 3:1, especially from 5:1 to 20:1. These preferred weight ratios help to keep the particle in a homogeneous phase, although such homogeneity is not essential.
  • the wax/perfume particles of the present invention are incorporated into a liquid or solid composition which itself contains a fabric substantive cationic surfactant.
  • cationic surfactants Very many cationic surfactants are known in the art, and almost any cationic surfactant having at least one long chain alkyl group of about 10 to 24 carbon atoms in the molecule is suitable. Numerous such compounds are described in "Cationic Surfactants", Jungermann 1970, the disclosures of which are incorporated herein by reference.
  • R is an alkyl or alkenyl group having 10 to 22 carbon atoms
  • the R 5 's which may be the same or different each represent hydrogen, a (C 2 H 4 O) p H or (C 3 H 6 O) q H, or a C 1-3 alkyl group, where each of p and q may be 0 or a number such that (p+q) does not exceed 25, m is from 1 to 9, n is from 2 to 6, and
  • A.sup.(-) represents one or more anions having total charge balancing that of the nitrogen atoms
  • Preferred cationic surfactants of class (i) are of the general formula
  • groups R 1 , R 2 , R 3 and R 4 are alkyl or substituted alkyl, and one or two of which are alkyl groups with 12 to 30 carbon atoms, and A is an anion, of example chloride, bromide, methyl sulfate, etc.
  • cationic compounds in this group are: dodecyl trimethyl ammonium bromide, tetradecyl trimethyl ammonium chloride, pentadecyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium bromide, tallow trimethyl ammonium chloride, eicosyl trimethyl ammonium chloride, dodecyl trimethyl ammonium methyl sulphate, tallow trimethyl ammonium acetate and tallow dimethyl benzyl ammonium chloride.
  • Conventional quaternary ammonium softening agents are preferred ingredients of the compositions of the present invention. These materials have the above formula wherein R 1 and R 2 are each C 12 -C 22 fatty alkyl and R 3 and R 4 are each C 1 -C 4 alkyl. Such softening agent can be used in the present invention in conjunction with the preferred single long chain cationic surfactants.
  • quaternary ammonium softening agents are: di dodecyl dimethyl ammonium bromide, di tetradecyl dimethyl ammonium chloride, di pentadecyl dimethyl ammonium chloride, di dodecyl diethyl ammonium chloride, di tetradecyl dipropyl ammonium chloride, di tallow dimethyl ammonium chloride, di tallow dimethyl ammonium methyl sulphate, di tallow diethyl ammonium chloride, di dodecyl diethyl ammonium chloride, di dodecyl diethyl ammonium acetate and di tallow dipropyl ammonium phosphate.
  • substituted polyamine salts for example compounds of the formula ##STR2## wherein R is a C 10 -C 22 alkyl or alkenyl group, preferably C 16-18 alkyl, and A is an anion.
  • the N-hydrogen atoms are ethoxylated with up to 25 ethoxy groups in all, preferably with from about 3 to 6 ethoxy groups in all.
  • A.sup.(-) may represent a dihalide or any appropriate acidic radical such as the diacetate, or higher saturated or unsaturated acyl groups up to C 22 .
  • Alkyl imidazolinium salts of class (iii) useful in the present invention are generally believed to have cations of the general formula: ##STR3## wherein R 6 is a C 1 -C 4 alkyl radical, R 7 is hydrogen or a C 1 -C 25 alkyl radical, R 8 is a C 8 -C 25 alkyl radical.
  • a preferred member of this class is believed to have formula VII wherein R 5 is H, R 6 is methyl, and R 7 and R 8 are tallow alkyl, and is marketed under the Trade name Varisoft-455 or -475 by Ashland Chemical Company, Ohio, USA. Also suitable are the imidazolinium softeners described in U.S. Pat. application 687,951 filed on July 27, 1976, which application also describes a method of preparing such compounds and is incorporated herein by reference.
  • Alkyl pyridinium salts of class (iv) useful in the present invention have cations of the general formula: ##STR4## wherein R 9 is a C 12 -C 20 alkyl radical.
  • a typical useful material of this type is cetyl pyridinium chloride.
  • Mixtures of more than one cationic surfactant of the foregoing classes may be employed.
  • compositions of the present invention can contain, over and above the wax/perfume particles, any amount of cationic surfactant, for example up to 60%.
  • Preferred compositions have less than 20%, preferably 0.1% to 10%, especially 1% to 8%.
  • the basic composition of the present invention into which the particles are incorporated can contain various optional components. These can vary with the nature of the basic composition and can include non-cationic surfactants, detergency builder salts, nonionic softeners, etc.
  • the main active ingredient is a di-higher alkyl quaternary ammonium softener in aqueous solution.
  • nonionic softeners are advantageously included, for example the materials described in German Offenlegungsschrift No. 26 31 114. These materials, as hereinbefore indicated, are also useful as the carrier substance for the particles of the present invention.
  • ironing aids such as silicones or dextrin derivatives, preservatives, bactericides, whether effective to protect the composition or to treat fabrics, viscosity controllers, coloring materials and the like.
  • the textile conditioning compositions according to the invention may be in any physical form, such as liquid, which is the most usual for for such compositions, pastes, gels, granular solids or briquettes, or they may be releasably associated with a soluble or insoluble rigid or flexible solid substrate.
  • the amounts of the components in the compositions will of course depend upon the physical form and upon the amount of the composition intended to be used in the treatment bath, so as to supply the required concentration of its active components. In every case, it is of course essential that the wax/perfume particles are present, in particulate form, in the bulk of the composition which, essentially, contains a cationic fabric-substantive surfactant.
  • compositions of the present invention contain, by weight of the composition, from 0.1% to 20% of the wax/perfume particles.
  • Preferred compositions have from 0.5% to 10%, especially from 1% to 5%.
  • fabric softening compositions are highly preferred embodiments of the present invention, other types of products utilizing the wax/perfume particles are possible, for example hair conditioners.
  • the composition In preparing the compositions, it is necessary to prepare the mixture constituting the particles, and to disperse it in or on the rest of the composition in the form of finely divided solid particles. This can be done in an effective way.
  • the components of the particles may be melted together, chilled and solidified in the form of chips, ribbons or particles, and these may be ground in a mill such as a colloid mill in the presence of the rest of the liquid composition. In this case the size reduction and dispersion are performed in a single operation.
  • the melt may be solidified and ground and the fine particles mixed into a solid or liquid or paste carrier medium, which may constitute part or the whole of the remainder of the intended finished composition. Cryogenic grinding, as in the presence of liquid nitrogen, may be appropriate in some instances.
  • a particle mixture was prepared by melting together at about 115° C. 3 parts by weight of Veba SP 1044 wax (Trade name of Veba Chemie AG--melting point 106°-111° C.) and 1 part of a blend of perfume raw materials which is widely used in marketed textile softening products. This was a perfume blend intended to be long lasting on fabrics and had boiling temperature above 100° C. The melt was cooled to provide a solid mass which was broken into small pieces. The melting point was 85°-95° C.
  • a textile treatment composition was then prepared consisting of 6% by weight ditallowyl dimethyl ammonium chloride (DTDMAC), 92.6% water and 1.4% of said wax/perfume mix.
  • the composition was prepared by forming an emulsion of DTDMAC and water, adding said wax/perfume mix in small pieces and passing the whole at about 20° C. through a colloid mill (Premier Colloid Mill B84 made by Premier Colloid Mills Ltd., Walton-on-Thames, England), set so as to reduce the pieces to particles of linear dimension about 50 microns.
  • DTDMAC ditallowyl dimethyl ammonium chloride
  • the composition was prepared by forming an emulsion of DTDMAC and water, adding said wax/perfume mix in small pieces and passing the whole at about 20° C. through a colloid mill (Premier Colloid Mill B84 made by Premier Colloid Mills Ltd., Walton-on-Thames, England), set so as to reduce the pieces to particles of linear dimension
  • Veba Wax is replaced by beeswax; carnauba wax; Shell's Microcrystalline wax 160/185, or Microcrystalline wax 185/190 (m.pt. 160°/185° F. and 185°/190° F. respectively); Mobil wax 2305, Mobil wax 2360, octadecanol, eicosanol, tallow alcohol, palmitic, stearic, or behenic acid, hardened tallow fatty acid or castor wax. Similar results were obtained when the Veba wax was replaced by Witcodur 263 or 273, Witcotack 143 or 145 or Witcovar 146 (Trade Names).
  • a particle mixture was prepared by melting together at about 115° C. 3 parts by weight of Veba SP 1044 wax and 1 part of DTDMAC, and thereafter melting together at about 115° C. 3 parts of this mix with 1 part of the same perfume blend as employed in Example 1. The melt was cooled to a solid mass and broken into pieces. Their melting point was about 80° C.
  • a textile treatment composition was prepared as in Example 1 but containing the present wax/DTDMAC/perfume particles. The whole mixture was passed through the colloid mill set so as to reduce the particles to linear dimensions in the range about 5 to 50 microns.
  • the DTDMAC is replaced by an equal weight of ditallowyl-dimethyl ammonium methosulphate, N-tallow-N,N,N',N',N'-pentamethyl-1,3-propylenediamine dihydro chloride (Duoquad, Trade name), a ditallow imidazoline softener(Varisoft 455 or 475 Trade name), or N-tallow-N,N',N'-triethanol-1,3-propylenediamine hydrochloride (Dinoramox XH3 - Trade name) with substantially similar effect.
  • a composition is prepared containing by weight 3% DTDMAC, 1.5% silicone (polymethyl siloxane having viscosity about 4000 c.s. at 25° C.), 1.5% glycerine monostearate, 1.4% wax/DTDMAC/perfume particles of composition as in Example 2.
  • the composition is prepared by melting together at about 80° C. the DTDMAC and the glycerine monostearate, mixing them into warm water to form an emulsion, adding the silicone, itself in the form of an emulsion prepared in the presence of a cationic emulsifier as described in our above mentioned pending British Pat. application 23171/76, and finally adding the pre-ground wax/DTDMAC/perfume particles.
  • These last are prepared by cryogenically grinding the solid wax/DTDMAC/perfume mix to a particle size of about 100 microns. Fabrics treated as in Example 1 with this composition have improved perfume impact during ironing.
  • the DTDMAC may be replaced by an equal amount of dodecyl trimethyl bromide, cetyl trimethyl bromide, cetyl pyridinium chloride, N-tallow propylene diamine dihydrochloride (Dinoramac Trade name), or a polyethyleneimine chloride containing 10 ethyleneimine units, or by a 50/50 mixture of DTDMAC and dodecyl trimethyl ammonium chloride.
  • a concentrated liquid textile treatment composition comprises
  • the mixture is passed through a colloid mill (Premier Colloid Mill as in Example 1) set so as to reduce the particle size to about 20 microns.
  • a colloid mill Premier Colloid Mill as in Example 1
  • composition makes fabrics treated therewith softer and easier to iron, and provides improved perfume impact during ironing.
  • a composition is prepared as in Example 2 wherein the particle mixture comprises by weight 85 parts by weight Shell Microcrystalline 160/185, melting point 160° to 185° F., 5 parts DTDMAC, 10 parts of a blend of perfume oils.
  • the melting point of the mixture is about 60° C.
  • An effective textile softening composition which comprises, by weight
  • silicone viscosity 4000 centistokes, prepared by polymerising dimethyl siloxane in the presence of DTDMAC
  • the composition is prepared by melting together at 100° C. the DTDMAC and diamine salt, and melting the glycerine monostearate and mixing these into the water, then mixing in the silicone emulsion to form an emulsion. To this is added the solid wax/perfume mixture, and the whole is passed through a Premier Colloid Mill set so as to reduce the particle size of the wax/perfume mixture to less than 100 microns.
  • the resulting granular product constitutes an effective rinse added textile softening and antistatic composition, and provides excellent perfume impact during ironing of treated fabrics.
  • a pasty textile conditioning composition comprises
  • the particles are prepared by forming a molten slurry of the components and cooling to solidify it. Particles of the solid are cryogenically ground to particle size about 100 microns, and mixed with strong agitation into a paste comprising the DTDMAC and water.
  • a liquid textile softening composition comprises, by weight, 3% cetyltrimethyl ammonium chloride, 3% ditallow dimethyl ammonium chloride (DTDMAC) and 3% of particles comprising, by weight of the particles, 93% waxy material (Tallow alcohol), 3% DTDMAC, and 4% perfume oil.
  • An emulsion in water is made of the first two components and fine particles mixed into it with strong agitation at room temperature.
  • the fine particles are prepared by forming a melt of the tallow alcohol, DTDMAC and perfume at about 80° C., solidifying it and cryogenically grinding the solid to particle size about 75 microns.
  • the product has textile softening properties when added to a rinse liquor and provides improved perfume.
  • a dispersion of textile conditioning agents is made comprising
  • the particles comprise 2.25 parts by weight Veba SP 1044 wax (as in Example 1), 0.75 parts perfume oil, and 1 part imidazolinium softener (Varisoft 455), and are prepared by melting these components together at about 100° C. cooling the mix to solidify it, and cryogenically grinding the solid to particle size about 75 microns. The melting point of the particles is about 80° C.
  • a 9 inch ⁇ 11 inch substrate sheet is prepared from a roll of randomly laid regenerated cellulose fibres of gauge 3 denier, bonded with a polyvinyl acetate binder (70% cellulose, 30% binder solids) and having a basic weight of 3.8 grs/sheet.
  • the substrate is impregnated by immersion in the above dispersion and surplus dispersion removed by passing the sheet between a pair of rolls.
  • the sheet is then cooled, dried in warm air (at about 35° C.) and weighed and found to have a loading of 3.0 grs/sheet ie. a conditioning agent to substrate weight ratio of 1:1.3.
  • One such sheet is added to the final rinse (30 liters) in a washing process, providing a concentration of 0.01% conditioning agents.
  • the treated fabrics are softened and provide improved perfume impact.
  • a cream hair rinse composition comprises
  • a fabric softening composition is prepared as follows: 2.3 parts by weight of DTDMAC, 3 parts glycerol monostearate and 1.2 parts N-tallow-N,N',N'-triethanol-1,3-propylene diamine hydrochloride are melted together at 70° C. Some, viz. 90% by weight, of this melt is mixed, with vigorous agitation, into 93.5 parts of warm water and the mixture cooled to room temperature. The remaining 10% of the melt is mixed with 0.2 parts by weight of perfume oil and cooled to solidify. The solid is cryogenically ground to form particles of linear dimension about 100 microns, and these particles are mixed into the above mentioned cooled mixture.
  • the product so made has textile softening properties when added to a rinse liquor, and fabrics treated thereby have improved perfume impact.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Textile Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Birds (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Wrappers (AREA)
  • Fats And Perfumes (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
US05/845,090 1976-10-29 1977-10-25 Fabric conditioning composition Expired - Lifetime US4152272A (en)

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GB45078/76A GB1587122A (en) 1976-10-29 1976-10-29 Fabric conditioning compositions
GB45078/76 1976-10-29

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CA (1) CA1111616A (enrdf_load_stackoverflow)
DE (1) DE2747726A1 (enrdf_load_stackoverflow)
FR (1) FR2369340A1 (enrdf_load_stackoverflow)
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Cited By (155)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0011499A1 (en) * 1978-11-17 1980-05-28 Unilever Plc Liquid formulations for depositing perfumes on fabric surfaces
US4272386A (en) * 1978-11-16 1981-06-09 The Procter & Gamble Company Antistatic, fabric-softening detergent additive
US4294576A (en) * 1979-06-23 1981-10-13 Basf Aktiengesellschaft Removal of oligomer deposits from textile materials
EP0041328A1 (en) * 1980-05-16 1981-12-09 Unilever Plc Method of depositing perfume on fabrics and product for use therein
US4313895A (en) * 1980-06-24 1982-02-02 Akzona Incorporated Alkoxylated diquaternary ammonium compounds
US4326967A (en) * 1980-06-24 1982-04-27 Lever Brothers Company Liquid formulations for depositing perfumes on fabrics
US4394127A (en) * 1980-02-07 1983-07-19 Lever Brothers Company Method of depositing perfume and compositions therefor
US4395342A (en) * 1980-06-06 1983-07-26 The Procter & Gamble Company Granular fabric softening composition
US4496357A (en) * 1981-06-10 1985-01-29 Hollister Incorporated Skin barrier composition
US4547301A (en) * 1983-05-07 1985-10-15 The Procter & Gamble Company Surfactant compositions
US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
US4551506A (en) * 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4636330A (en) * 1980-03-11 1987-01-13 Lever Brothers Company Perfume depositing detergents containing perfume in a particulate matrix of a cationic compound
US4659802A (en) * 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4661288A (en) * 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
US4911851A (en) * 1987-11-06 1990-03-27 The Procter & Gamble Company Detergent compatible, dryer released fabric softening/antistatic agents
US4950412A (en) * 1985-01-15 1990-08-21 Lever Brothers Company Fabric conditioning composition
US4954285A (en) * 1988-03-07 1990-09-04 The Procter & Gamble Company Perfume, particles, especially for use in dryer released fabric softening/antistatic agents
US4964873A (en) * 1985-01-15 1990-10-23 Lever Brothers Company Fabric conditioning method
WO1991013143A1 (en) * 1990-02-20 1991-09-05 The Procter & Gamble Company Coated perfume particles
WO1992002605A1 (en) * 1990-07-31 1992-02-20 The Procter & Gamble Company Laundry perfume carriage and delivery system
US5126060A (en) * 1991-01-09 1992-06-30 Colgate-Palmolive Co. Biodegradable fabric softening compositions based on pentaerythritol esters and free of quaternary ammonium compounds
WO1992015745A1 (en) * 1991-03-08 1992-09-17 The Procter & Gamble Company Concentrated fabric softening compositions
US5185088A (en) * 1991-04-22 1993-02-09 The Procter & Gamble Company Granular fabric softener compositions which form aqueous emulsion concentrates
US5188753A (en) * 1989-05-11 1993-02-23 The Procter & Gamble Company Detergent composition containing coated perfume particles
US5240498A (en) * 1991-01-09 1993-08-31 Martin Marietta Magnesia Specialties Inc. Carbonaceous binder
US5246603A (en) * 1991-09-25 1993-09-21 Lever Brothers Company, Division Of Conopco, Inc. Fragrance microcapsules for fabric conditioning
US5254269A (en) * 1991-11-26 1993-10-19 Lever Brothers Company, Division Of Conopco, Inc. Fabric conditioning composition containing an emulsified silicone mixture
AU644358B2 (en) * 1989-05-11 1993-12-09 Minnesota Mining And Manufacturing Company Coated perfume particles
US5332513A (en) * 1990-01-09 1994-07-26 Colgate-Palmolive Co. Particulate fabric softening and detergent compositions
US5358647A (en) * 1991-01-09 1994-10-25 Colgate-Palmolive Company Fabric softening products based on a combination of pentaerythritol compound and bentonite
US5454983A (en) * 1992-01-23 1995-10-03 The Procter & Gamble Company Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol
US5536421A (en) * 1992-09-28 1996-07-16 The Procter & Gamble Company Method for using solid particulate fabric softener in automatic dosing dispenser
US5562847A (en) * 1995-11-03 1996-10-08 The Procter & Gamble Company Dryer-activated fabric conditioning and antistatic compositions with improved perfume longevity
EP0771785A1 (en) 1995-11-02 1997-05-07 The Procter & Gamble Company Beta-amino ester compounds of perfume alcohols and their use in cleaning or laundry compositions
US5716918A (en) * 1995-12-20 1998-02-10 The Procter & Gamble Company Sulfonate perfumes for dryer-activated fabric conditioning and antistatic compositions
EP0839899A1 (en) 1996-10-30 1998-05-06 The Procter & Gamble Company Fabric softening compositions
AU698882B2 (en) * 1994-02-21 1998-11-12 Unilever Plc Fabric softening composition
US5955419A (en) * 1995-09-18 1999-09-21 The Procter & Gamble Company High efficiency delivery system comprising zeolites
US6022845A (en) * 1995-11-03 2000-02-08 The Procter & Gamble Co. Stable high perfume, low active fabric softener compositions
US6042792A (en) * 1997-09-18 2000-03-28 International Flavors & Fragrances Inc. Apparatus for preparing a solid phase microparticulate composition
US6048830A (en) * 1996-03-22 2000-04-11 The Procter & Gamble Company Delivery system having release barrier loaded zeolite
US6156826A (en) * 1997-09-18 2000-12-05 International Flavors & Fragrances Inc. Matrix composition comprising surfactant and matrix useful for targeted delivery articles
WO2001027234A1 (de) * 1999-10-08 2001-04-19 Henkel Kommanditgesellschaft Auf Aktien Reinigungsmittelkomponente mit doppeltkontrollierter duftfreisetzung
US6245732B1 (en) 1996-03-22 2001-06-12 The Procter Gamble Co. Delivery system having release inhibitor loaded zeolite and method for making same
WO2002004585A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company Anaerobically biodegradable perfume delivery system
WO2002004586A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company A particle perfume delivery system
WO2002004584A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company A biodegradable perfume delivery system
US6495172B1 (en) 1998-12-21 2002-12-17 Procter & Gamble Method of using steam ironing of fabrics as a way of causing reduction of physiological and/or subjective reactivity to stress in humans
US20030045446A1 (en) * 2001-02-12 2003-03-06 Dihora Jiten Odhavji Delivery system having encapsulated porous carrier loaded with additives
US20030044441A1 (en) * 2000-02-17 2003-03-06 Schmid Karl Heinz Cosmetic preparations containing pearly lustre waxes in the form of dispersed systems
US6531444B1 (en) 2000-11-09 2003-03-11 Salvona, Llc Controlled delivery system for fabric care products
US20030053974A1 (en) * 2001-01-29 2003-03-20 Adi Shefer Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric
KR100389684B1 (ko) * 2000-05-10 2003-07-04 김진원 대전방지제가 흡착된 신규한 비스코스레이온섬유 부직포 및 그 제조방법
US20030132109A1 (en) * 2001-11-30 2003-07-17 Andrew Bullen Pipette configurations and arrays thereof for measuring cellular electrical properties
WO2003060046A1 (en) * 2002-01-09 2003-07-24 Croda, Inc. Mixtures of quaternary compounds
US20030186834A1 (en) * 2002-01-09 2003-10-02 Croda, Inc. Immidazoline quats
US20030194416A1 (en) * 2002-04-15 2003-10-16 Adl Shefer Moisture triggered release systems comprising aroma ingredients providing fragrance burst in response to moisture
US20030195133A1 (en) * 2002-04-10 2003-10-16 Adi Shefer Targeted controlled delivery compositions activated by changes in pH or salt concentration
US20030207776A1 (en) * 2002-04-26 2003-11-06 Adi Shefer Multi component controlled delivery system for soap bars
WO2003082356A3 (en) * 2002-04-03 2003-11-20 Dow Corning Fragrance containing emulsions
US20040029765A1 (en) * 2001-02-07 2004-02-12 Henriette Weber Washing and cleaning agents comprising fine microparticles with cleaning agent components
WO2004020566A1 (en) * 2002-08-27 2004-03-11 Unilever N.V. Perfume composition
AU771929B2 (en) * 1998-12-31 2004-04-08 Akzo Nobel N.V. Cationic gemini and related multiple hydrophilic/hydrophobic functional compounds and their use as surfactants
US6740631B2 (en) 2002-04-26 2004-05-25 Adi Shefer Multi component controlled delivery system for fabric care products
US20040109894A1 (en) * 2002-12-09 2004-06-10 Adi Shefer PH triggered targeted controlled release systems for the delivery of pharmaceutical active ingredients
US20040138088A1 (en) * 2002-01-09 2004-07-15 Croda, Inc. Immidazoline quats
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
US20040216327A1 (en) * 2003-04-30 2004-11-04 Samsung Electronics Co., Ltd Washing machine and method of controlling drying process thereof
US20040224019A1 (en) * 2004-03-03 2004-11-11 Adi Shefer Oral controlled release system for targeted drug delivery into the cell and its nucleus for gene therapy, DNA vaccination, and administration of gene based drugs
EP1477152A1 (de) * 2003-05-12 2004-11-17 Beiersdorf AG Trägersystem für kosmetische oder pharmazeutische Wirkstoffe
US6830754B2 (en) * 1998-12-25 2004-12-14 Kao Corporation Amphipatic lipid dispersion
WO2004113485A1 (en) 2003-06-18 2004-12-29 The Procter & Gamble Company Blooming soap bars
US20050065047A1 (en) * 2002-04-26 2005-03-24 Adi Shefer Multi component controlled delivery system for soap bars
US20050101501A1 (en) * 2002-06-27 2005-05-12 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Perfume composition
US20050227905A1 (en) * 2002-10-11 2005-10-13 Raymond Heinz Method for the production of a solid fragrance concentrate
WO2005102261A1 (en) * 2004-03-26 2005-11-03 Dow Corning Corporation Controlled release compositions
US20050262757A1 (en) * 2004-05-27 2005-12-01 The Procter & Gamble Company Self-steaming compositions, articles comprising such compositions and methods of preparing such compositions
US20060030511A1 (en) * 2002-04-26 2006-02-09 Makins Holland Lynette A Fragrance release
US20060029653A1 (en) * 1997-01-29 2006-02-09 Cronk Peter J Therapeutic delivery system
US20060128601A1 (en) * 2002-01-09 2006-06-15 Croda, Inc. Imidazoline quats
US20070010407A1 (en) * 2003-12-10 2007-01-11 Wilfried Rahse Scent composites
US20070031369A1 (en) * 2005-08-03 2007-02-08 Alberto-Culver Company Quick dispersing hair conditioning composition
WO2007028495A1 (en) 2005-09-09 2007-03-15 Unilever Plc Fabric conditioning composition
EP1767185A1 (en) 2005-09-23 2007-03-28 Takasago International Corporation Core shell capsules containing an oil or waxy solid
US20070071780A1 (en) * 2005-06-16 2007-03-29 Dubois Zerlina G Personal care composition comprising a perfume booster accord
US20070098148A1 (en) * 2005-10-14 2007-05-03 Sherman Kenneth N Aroma releasing patch on mobile telephones
WO2007115871A1 (de) * 2006-04-06 2007-10-18 Henkel Ag & Co. Kgaa Feste, textil-affine zusammensetzung auf basis eines schmelzbaren materials
US20090148392A1 (en) * 2005-01-12 2009-06-11 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
US20090162408A1 (en) * 2005-01-12 2009-06-25 Amcol International Corporation Compositions containing cationically surface-modified microparticulate carrier for benefit agents
US20090263337A1 (en) * 2005-01-12 2009-10-22 Amcol International Corporation Detersive compositions containing hydrophobic benefit agents pre-emulsified using sub-micrometer-sized insoluble cationic particles
US20090287280A1 (en) * 2008-05-15 2009-11-19 Wyeth Portable moist heat system
WO2010001269A2 (en) 2008-06-30 2010-01-07 Kimberly-Clark Worldwide, Inc. Fragranced water-sensitive film
WO2010083124A1 (en) 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
WO2010083125A1 (en) 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
WO2010149966A1 (en) 2009-06-24 2010-12-29 Bell Flavors & Fragrances Duft Und Aroma Gmbh Microparticles and method of making microparticles
US20110000483A1 (en) * 2009-05-01 2011-01-06 Matthias Joseph A External nasal dilator
US7888306B2 (en) 2007-05-14 2011-02-15 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20110104221A1 (en) * 2008-02-27 2011-05-05 Galeone Fabrizio S Deposition Of Lipophilic Active Material In Surfactant Containing Compositions
WO2011124706A1 (en) 2010-04-09 2011-10-13 Basf Se In-situ sol-gel encapsulation of fragrances, perfumes or flavours
US8188022B2 (en) 2008-04-11 2012-05-29 Amcol International Corporation Multilayer fragrance encapsulation comprising kappa carrageenan
WO2012162331A2 (en) 2011-05-26 2012-11-29 The Procter & Gamble Company Compositions comprising an efficient perfume bloom
WO2013128431A2 (en) 2012-02-27 2013-09-06 The Procter & Gamble Company Methods for producing liquid detergent products
DE112011103631T5 (de) 2010-10-25 2013-11-14 The Armor All/Stp Products Company Silikon-Schutzmittelzusammensetzungen
FR2992208A1 (fr) * 2012-06-21 2013-12-27 Oreal Composition cosmetique comprenant des particules solides insolubles, un corps gras non liquide, un tensioactif
EP2689836A1 (en) 2012-07-26 2014-01-29 Basf Se Composition of microcapsules with a silica shell and a method for preparing them
WO2014047502A2 (en) 2012-09-20 2014-03-27 The Procter & Gamble Company Anhydrous compositions having microcapsules and non-volatile oils
WO2014047507A2 (en) 2012-09-20 2014-03-27 The Procter & Gamble Company Compositions and articles having a parent fragrance and microcapsules encapsulating a non-parent fragrance
WO2014026842A3 (de) * 2012-08-17 2014-07-17 Henkel Ag & Co. Kgaa Kosmetische zusammensetzungen mit zeitverzögerter wirkstofffreisetzung
US8834514B2 (en) 2006-08-30 2014-09-16 Xennovate Medical Llc Resilient band medical device
WO2014151171A1 (en) 2013-03-15 2014-09-25 The Procter & Gamble Company Personal care compositions
US20140322145A1 (en) * 2011-12-06 2014-10-30 Rohm And Haas Company Antimicrobial composition
EP2799863A1 (en) 2013-05-03 2014-11-05 The Procter and Gamble Company Method to evaluate fragrance compositions
WO2014182993A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
WO2014182995A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
WO2014182996A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
WO2015111060A1 (en) 2014-01-23 2015-07-30 Maori S.C. Ltd. Scented body compositions
WO2016003948A1 (en) 2014-06-30 2016-01-07 The Procter & Gamble Company Personal care compositions and methods
WO2016003947A1 (en) 2014-06-30 2016-01-07 The Procter & Gamble Company Method of manufacturing stick comprising antiperspirant
WO2016049390A1 (en) 2014-09-25 2016-03-31 The Procter & Gamble Company Fragrance compositions comprising ionic liquids
CN105936773A (zh) * 2016-06-07 2016-09-14 吴江市屯村颜料厂 一种导电颜料组合物及其应用
CN105936774A (zh) * 2016-06-07 2016-09-14 吴江市屯村颜料厂 一种高分散性的水性涂料颜料组合物及其应用
EP3103431A1 (en) 2015-06-12 2016-12-14 The Procter and Gamble Company Fragrance compositions and uses thereof
EP3103523A1 (en) 2015-06-12 2016-12-14 The Procter and Gamble Company Absorbent article comprising fragrance composition
WO2016200759A1 (en) 2015-06-12 2016-12-15 The Procter & Gamble Company Fragrance composition
WO2016200760A1 (en) 2015-06-12 2016-12-15 The Procter & Gamble Company Fragrance compositions and uses thereof
WO2016205301A1 (en) 2015-06-15 2016-12-22 The Procter & Gamble Company Fragrance fixatives and compositions comprising thereof
WO2017075299A1 (en) 2015-10-28 2017-05-04 The Procter & Gamble Company Fragrance compositions comprising ionic liquids
EP3170552A1 (en) 2015-11-23 2017-05-24 Basf Se Microcapsule comprising a polymeric shell and a hydrophilic or hydrophobic core material
WO2017105725A1 (en) 2015-12-14 2017-06-22 S. C. Johnson & Son, Inc. Compositions, delivery systems and refills for emitting two or more compositions
US9693941B2 (en) 2011-11-03 2017-07-04 Conopco, Inc. Liquid personal wash composition
WO2017120134A1 (en) 2016-01-06 2017-07-13 The Procter & Gamble Company Antiperspirant compositions
US10301575B2 (en) 2015-04-14 2019-05-28 The Procter & Gamble Company Consumer product composition comprising a polyethylene glycol carrier with silicone particles dispersed therein
US10329519B2 (en) 2016-10-19 2019-06-25 The Procter & Gamble Company Consumer product composition comprising a polyethyleneglycol carrier, silicone conditioner, and particulate spacer material
EP3501487A1 (en) 2017-12-22 2019-06-26 Juice Beauty, Inc. Thin emulsion base for cosmetics
WO2019232165A1 (en) 2018-05-31 2019-12-05 The Procter & Gamble Company Antibacterial particles and methods
WO2020006156A1 (en) 2018-06-28 2020-01-02 The Procter & Gamble Company Deodorant sticks
EP3535359B1 (en) 2016-11-03 2020-05-13 Unilever PLC Laundry treatment compositions comprising perfume and silica microparticles
EP3708145A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3708147A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3708146A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
RU2736718C2 (ru) * 2016-04-08 2020-11-19 Басф Се Сополимеры, содержащие полиалкиленоксидные группы и четвертичные атомы азота
EP3754007A1 (en) * 2019-06-18 2020-12-23 The Procter & Gamble Company A coated non-woven sheet
EP3754006A1 (en) * 2019-06-18 2020-12-23 The Procter & Gamble Company An anhydrous perfume particle
WO2022086766A1 (en) 2020-10-21 2022-04-28 Aki, Inc. Anhydrous alcohol-free silky fragrance formulation
WO2022119783A1 (en) 2020-12-01 2022-06-09 The Procter & Gamble Company Aqueous hair conditioner compositions containing solubilized anti-dandruff actives
WO2022261268A1 (en) 2021-06-10 2022-12-15 The Procter & Gamble Company Transparent soap bar
WO2023197252A1 (en) 2022-04-14 2023-10-19 The Procter & Gamble Company Personal cleansing composition free of alkyl sulfate or alkyl ether sulfate type of surfactants
WO2023230018A1 (en) 2022-05-23 2023-11-30 The Procter & Gamble Company Antibacterial cleansing composition, uses and methods
WO2024040007A1 (en) 2022-08-15 2024-02-22 Energizer Auto, Inc. Surface treating formulation and method of making and using the same
WO2024207396A1 (en) 2023-04-07 2024-10-10 The Procter & Gamble Company Personal cleansing composition substantially free of alkyl sulfate or alkyl ether sulfate type of surfactants
DE112012001495B4 (de) 2011-03-31 2024-10-24 Energizer Auto, Inc. (n.d.Ges.d. Staates Delaware) Zusammensetzungen zur Behandlung von Automobiloberflächen und ihre Verwendung
WO2025025191A1 (en) 2023-08-03 2025-02-06 The Procter & Gamble Company Personal cleansing composition substantially free of alkyl sulfate or alkyl ether sulfate type of surfactants

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1596791A (en) * 1977-02-15 1981-08-26 Unilever Ltd Deodorant detergent composition
FR2446310A1 (fr) * 1977-09-02 1980-08-08 Airwick Ag Produit d'entretien en poudre pour les tapis
FR2440433A1 (fr) * 1978-11-03 1980-05-30 Unilever Nv Composition d'assouplissement des etoffes et procede pour la preparer
ATE4600T1 (de) * 1979-09-21 1983-09-15 The Procter & Gamble Company Wasch- und weichmittelzusammensetzungen und verfahren zu ihrer herstellung.
US4446032A (en) * 1981-08-20 1984-05-01 International Flavors & Fragrances Inc. Liquid or solid fabric softener composition comprising microencapsulated fragrance suspension and process for preparing same
US4464271A (en) * 1981-08-20 1984-08-07 International Flavors & Fragrances Inc. Liquid or solid fabric softener composition comprising microencapsulated fragrance suspension and process for preparing same
AU3164989A (en) * 1988-03-23 1989-09-28 Union Camp Corporation Fragrance carriers for laundry compositions
CA2015736A1 (en) * 1989-05-11 1990-11-11 Diane G. Schmidt Perfume particles for use in cleaning and conditioning compositions
FR2658829B1 (fr) * 1990-02-23 1993-12-24 Oreal Compositions fluides contenant une microdispersion de cire et d'un tensio-actif cationique, leur preparation et leur utilisation.
DE10063428A1 (de) * 2000-12-20 2002-07-11 Henkel Kgaa Dispersionen nanopartikulärer riechstoffhaltiger Kompositmaterialien
US7211556B2 (en) 2004-04-15 2007-05-01 Colgate-Palmolive Company Fabric care composition comprising polymer encapsulated fabric or skin beneficiating ingredient
DE102006034051A1 (de) * 2006-07-20 2008-01-24 Henkel Kgaa Verfahren zur Herstellung einer festen, Textil-weichmachenden Zusammensetzung
US8470762B2 (en) 2007-05-31 2013-06-25 Colgate-Palmolive Company Fabric softening compositions comprising polymeric materials
JP2010285737A (ja) * 2009-05-12 2010-12-24 Lion Corp 香りが長続きする繊維製品用処理剤組成物
JP7590136B2 (ja) * 2020-09-03 2024-11-26 花王株式会社 香料粒子及びそれを含有する繊維製品処理剤組成物
JP7672848B2 (ja) * 2021-03-16 2025-05-08 花王株式会社 繊維製品処理剤組成物

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137631A (en) * 1959-12-01 1964-06-16 Faberge Inc Encapsulation in natural products
US3856699A (en) * 1969-08-08 1974-12-24 Fuji Photo Film Co Ltd Process for producing capsules having walls of a waxy material
US3936538A (en) * 1974-03-18 1976-02-03 Calgon Consumer Products Company Inc. Polymeric film dryer-added fabric softening compositions
US3936537A (en) * 1974-11-01 1976-02-03 The Procter & Gamble Company Detergent-compatible fabric softening and antistatic compositions
US4012326A (en) * 1971-06-29 1977-03-15 Lever Brothers Company Additives for clothes dryers
US4051159A (en) * 1976-01-12 1977-09-27 Avon Products, Inc. Transparent fragrance releasing composition and method of making same
US4067824A (en) * 1976-09-27 1978-01-10 Anheuser-Busch, Incorporated Gelled perfume

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1204123A (en) * 1966-11-29 1970-09-03 Unilever Ltd Detergent composition
DE2631129A1 (de) * 1975-07-14 1977-02-03 Procter & Gamble Verfahren zum konditionieren von geweben und mittel zur durchfuehrung des verfahrens

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3137631A (en) * 1959-12-01 1964-06-16 Faberge Inc Encapsulation in natural products
US3856699A (en) * 1969-08-08 1974-12-24 Fuji Photo Film Co Ltd Process for producing capsules having walls of a waxy material
US4012326A (en) * 1971-06-29 1977-03-15 Lever Brothers Company Additives for clothes dryers
US3936538A (en) * 1974-03-18 1976-02-03 Calgon Consumer Products Company Inc. Polymeric film dryer-added fabric softening compositions
US3936537A (en) * 1974-11-01 1976-02-03 The Procter & Gamble Company Detergent-compatible fabric softening and antistatic compositions
US4051159A (en) * 1976-01-12 1977-09-27 Avon Products, Inc. Transparent fragrance releasing composition and method of making same
US4067824A (en) * 1976-09-27 1978-01-10 Anheuser-Busch, Incorporated Gelled perfume

Cited By (220)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4272386A (en) * 1978-11-16 1981-06-09 The Procter & Gamble Company Antistatic, fabric-softening detergent additive
EP0011499A1 (en) * 1978-11-17 1980-05-28 Unilever Plc Liquid formulations for depositing perfumes on fabric surfaces
US4294576A (en) * 1979-06-23 1981-10-13 Basf Aktiengesellschaft Removal of oligomer deposits from textile materials
US4394127A (en) * 1980-02-07 1983-07-19 Lever Brothers Company Method of depositing perfume and compositions therefor
US4636330A (en) * 1980-03-11 1987-01-13 Lever Brothers Company Perfume depositing detergents containing perfume in a particulate matrix of a cationic compound
EP0041328A1 (en) * 1980-05-16 1981-12-09 Unilever Plc Method of depositing perfume on fabrics and product for use therein
US4511495A (en) * 1980-05-16 1985-04-16 Lever Brothers Company Tumble dryer products for depositing perfume
US4395342A (en) * 1980-06-06 1983-07-26 The Procter & Gamble Company Granular fabric softening composition
US4313895A (en) * 1980-06-24 1982-02-02 Akzona Incorporated Alkoxylated diquaternary ammonium compounds
US4326967A (en) * 1980-06-24 1982-04-27 Lever Brothers Company Liquid formulations for depositing perfumes on fabrics
US4496357A (en) * 1981-06-10 1985-01-29 Hollister Incorporated Skin barrier composition
US4664848A (en) * 1982-12-23 1987-05-12 The Procter & Gamble Company Detergent compositions containing cationic compounds having clay soil removal/anti-redeposition properties
US4551506A (en) * 1982-12-23 1985-11-05 The Procter & Gamble Company Cationic polymers having clay soil removal/anti-redeposition properties useful in detergent compositions
US4659802A (en) * 1982-12-23 1987-04-21 The Procter & Gamble Company Cationic compounds having clay soil removal/anti-redeposition properties useful in detergent compositions
US4661288A (en) * 1982-12-23 1987-04-28 The Procter & Gamble Company Zwitterionic compounds having clay soil removal/anti/redeposition properties useful in detergent compositions
US4676921A (en) * 1982-12-23 1987-06-30 The Procter & Gamble Company Detergent compositions containing ethoxylated amine polymers having clay soil removal/anti-redeposition properties
US4547301A (en) * 1983-05-07 1985-10-15 The Procter & Gamble Company Surfactant compositions
US4548744A (en) * 1983-07-22 1985-10-22 Connor Daniel S Ethoxylated amine oxides having clay soil removal/anti-redeposition properties useful in detergent compositions
US4964873A (en) * 1985-01-15 1990-10-23 Lever Brothers Company Fabric conditioning method
US4950412A (en) * 1985-01-15 1990-08-21 Lever Brothers Company Fabric conditioning composition
US4911851A (en) * 1987-11-06 1990-03-27 The Procter & Gamble Company Detergent compatible, dryer released fabric softening/antistatic agents
US4954285A (en) * 1988-03-07 1990-09-04 The Procter & Gamble Company Perfume, particles, especially for use in dryer released fabric softening/antistatic agents
US5188753A (en) * 1989-05-11 1993-02-23 The Procter & Gamble Company Detergent composition containing coated perfume particles
AU644358B2 (en) * 1989-05-11 1993-12-09 Minnesota Mining And Manufacturing Company Coated perfume particles
US5332513A (en) * 1990-01-09 1994-07-26 Colgate-Palmolive Co. Particulate fabric softening and detergent compositions
WO1991013143A1 (en) * 1990-02-20 1991-09-05 The Procter & Gamble Company Coated perfume particles
TR25559A (tr) * 1990-02-20 1993-07-01 Minnesota Mining & Mfg KAPLI PARFüM TANECIKLERI
US5066419A (en) * 1990-02-20 1991-11-19 The Procter & Gamble Company Coated perfume particles
WO1992002605A1 (en) * 1990-07-31 1992-02-20 The Procter & Gamble Company Laundry perfume carriage and delivery system
US5126060A (en) * 1991-01-09 1992-06-30 Colgate-Palmolive Co. Biodegradable fabric softening compositions based on pentaerythritol esters and free of quaternary ammonium compounds
US5240498A (en) * 1991-01-09 1993-08-31 Martin Marietta Magnesia Specialties Inc. Carbonaceous binder
US5358647A (en) * 1991-01-09 1994-10-25 Colgate-Palmolive Company Fabric softening products based on a combination of pentaerythritol compound and bentonite
US5290459A (en) * 1991-01-09 1994-03-01 Colgate-Palmolive Company Biodegradable fabric softening compositions based on pentaerythritol esters and free of quaternary ammonium compounds
WO1992015745A1 (en) * 1991-03-08 1992-09-17 The Procter & Gamble Company Concentrated fabric softening compositions
US5185088A (en) * 1991-04-22 1993-02-09 The Procter & Gamble Company Granular fabric softener compositions which form aqueous emulsion concentrates
US5246603A (en) * 1991-09-25 1993-09-21 Lever Brothers Company, Division Of Conopco, Inc. Fragrance microcapsules for fabric conditioning
EP0539025A3 (en) * 1991-09-25 1994-07-27 Unilever Plc Fragrance microcapsules for fabric conditioning
US5254269A (en) * 1991-11-26 1993-10-19 Lever Brothers Company, Division Of Conopco, Inc. Fabric conditioning composition containing an emulsified silicone mixture
US5454983A (en) * 1992-01-23 1995-10-03 The Procter & Gamble Company Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol
EP0570237A3 (en) * 1992-05-15 1995-03-08 Colgate Palmolive Co Particulate laundry softeners and detergents.
TR27464A (tr) * 1992-05-15 1995-05-29 Colgate Palmolive Co Partikül camasir yumusatici ve deterjan bilesimleri.
US5792219A (en) * 1992-09-28 1998-08-11 The Procter & Gamble Company Method for using solid particulate fabric softener in automatic dosing dispenser
US5536421A (en) * 1992-09-28 1996-07-16 The Procter & Gamble Company Method for using solid particulate fabric softener in automatic dosing dispenser
AU698882B2 (en) * 1994-02-21 1998-11-12 Unilever Plc Fabric softening composition
US5955419A (en) * 1995-09-18 1999-09-21 The Procter & Gamble Company High efficiency delivery system comprising zeolites
EP0771785A1 (en) 1995-11-02 1997-05-07 The Procter & Gamble Company Beta-amino ester compounds of perfume alcohols and their use in cleaning or laundry compositions
US6022845A (en) * 1995-11-03 2000-02-08 The Procter & Gamble Co. Stable high perfume, low active fabric softener compositions
US5562847A (en) * 1995-11-03 1996-10-08 The Procter & Gamble Company Dryer-activated fabric conditioning and antistatic compositions with improved perfume longevity
US5716918A (en) * 1995-12-20 1998-02-10 The Procter & Gamble Company Sulfonate perfumes for dryer-activated fabric conditioning and antistatic compositions
US6048830A (en) * 1996-03-22 2000-04-11 The Procter & Gamble Company Delivery system having release barrier loaded zeolite
US6245732B1 (en) 1996-03-22 2001-06-12 The Procter Gamble Co. Delivery system having release inhibitor loaded zeolite and method for making same
EP0839899A1 (en) 1996-10-30 1998-05-06 The Procter & Gamble Company Fabric softening compositions
US8506996B2 (en) 1997-01-29 2013-08-13 Peter J. Cronk Therapeutic delivery system
US20060029653A1 (en) * 1997-01-29 2006-02-09 Cronk Peter J Therapeutic delivery system
US8852224B2 (en) 1997-01-29 2014-10-07 Peter J. Cronk Therapeutic delivery system
US6042792A (en) * 1997-09-18 2000-03-28 International Flavors & Fragrances Inc. Apparatus for preparing a solid phase microparticulate composition
US6156826A (en) * 1997-09-18 2000-12-05 International Flavors & Fragrances Inc. Matrix composition comprising surfactant and matrix useful for targeted delivery articles
US6495172B1 (en) 1998-12-21 2002-12-17 Procter & Gamble Method of using steam ironing of fabrics as a way of causing reduction of physiological and/or subjective reactivity to stress in humans
US6830754B2 (en) * 1998-12-25 2004-12-14 Kao Corporation Amphipatic lipid dispersion
AU771929B2 (en) * 1998-12-31 2004-04-08 Akzo Nobel N.V. Cationic gemini and related multiple hydrophilic/hydrophobic functional compounds and their use as surfactants
WO2001027234A1 (de) * 1999-10-08 2001-04-19 Henkel Kommanditgesellschaft Auf Aktien Reinigungsmittelkomponente mit doppeltkontrollierter duftfreisetzung
US6790814B1 (en) 1999-12-03 2004-09-14 Procter & Gamble Company Delivery system having encapsulated porous carrier loaded with additives, particularly detergent additives such as perfumes
US20030044441A1 (en) * 2000-02-17 2003-03-06 Schmid Karl Heinz Cosmetic preparations containing pearly lustre waxes in the form of dispersed systems
KR100389684B1 (ko) * 2000-05-10 2003-07-04 김진원 대전방지제가 흡착된 신규한 비스코스레이온섬유 부직포 및 그 제조방법
WO2002004586A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company A particle perfume delivery system
WO2002004584A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company A biodegradable perfume delivery system
WO2002004585A1 (en) * 2000-07-06 2002-01-17 The Procter & Gamble Company Anaerobically biodegradable perfume delivery system
US6531444B1 (en) 2000-11-09 2003-03-11 Salvona, Llc Controlled delivery system for fabric care products
US7119060B2 (en) 2000-11-09 2006-10-10 Salvona Ip, Llc Controlled delivery system for fabric care products
EP1337613A4 (en) * 2000-11-09 2004-05-12 Salvona Llc DOSING SYSTEM FOR LAUNDRY CARE PRODUCTS
US6979440B2 (en) * 2001-01-29 2005-12-27 Salvona, Llc Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric
US20030053974A1 (en) * 2001-01-29 2003-03-20 Adi Shefer Compositions and method for targeted controlled delivery of active ingredients and sensory markers onto hair, skin, and fabric
US7601678B2 (en) * 2001-02-07 2009-10-13 Henkel Ag & Co. Kgaa Washing and cleaning agents comprising fine microparticles with cleaning agent components
US20040029765A1 (en) * 2001-02-07 2004-02-12 Henriette Weber Washing and cleaning agents comprising fine microparticles with cleaning agent components
US20030045446A1 (en) * 2001-02-12 2003-03-06 Dihora Jiten Odhavji Delivery system having encapsulated porous carrier loaded with additives
US20030132109A1 (en) * 2001-11-30 2003-07-17 Andrew Bullen Pipette configurations and arrays thereof for measuring cellular electrical properties
CN1639311B (zh) * 2002-01-09 2010-05-12 克洛达股份有限公司 季化合物的混合物
US20040138088A1 (en) * 2002-01-09 2004-07-15 Croda, Inc. Immidazoline quats
US20040167057A1 (en) * 2002-01-09 2004-08-26 Croda, Inc. Mixtures of quaternary compounds
US20030186834A1 (en) * 2002-01-09 2003-10-02 Croda, Inc. Immidazoline quats
US20060128601A1 (en) * 2002-01-09 2006-06-15 Croda, Inc. Imidazoline quats
US20040220062A1 (en) * 2002-01-09 2004-11-04 Croda, Inc. Imidazoline quats
US6953773B2 (en) * 2002-01-09 2005-10-11 Croda, Inc. Mixtures of imidazoline quaternary ammonium and alkyl quaternary ammonium compounds
US6838419B2 (en) 2002-01-09 2005-01-04 Croda, Inc. Mixtures of quaternary compounds
WO2003060046A1 (en) * 2002-01-09 2003-07-24 Croda, Inc. Mixtures of quaternary compounds
WO2003082356A3 (en) * 2002-04-03 2003-11-20 Dow Corning Fragrance containing emulsions
US20050143282A1 (en) * 2002-04-03 2005-06-30 Serge Creutz Emulsions
US20030195133A1 (en) * 2002-04-10 2003-10-16 Adi Shefer Targeted controlled delivery compositions activated by changes in pH or salt concentration
US7053034B2 (en) 2002-04-10 2006-05-30 Salvona, Llc Targeted controlled delivery compositions activated by changes in pH or salt concentration
US20030194416A1 (en) * 2002-04-15 2003-10-16 Adl Shefer Moisture triggered release systems comprising aroma ingredients providing fragrance burst in response to moisture
US7208460B2 (en) 2002-04-26 2007-04-24 Salvona Ip, Llc Multi component controlled delivery system for soap bars
US20050065047A1 (en) * 2002-04-26 2005-03-24 Adi Shefer Multi component controlled delivery system for soap bars
US6825161B2 (en) 2002-04-26 2004-11-30 Salvona Llc Multi component controlled delivery system for soap bars
US6740631B2 (en) 2002-04-26 2004-05-25 Adi Shefer Multi component controlled delivery system for fabric care products
US20060030511A1 (en) * 2002-04-26 2006-02-09 Makins Holland Lynette A Fragrance release
US20030207776A1 (en) * 2002-04-26 2003-11-06 Adi Shefer Multi component controlled delivery system for soap bars
US20050101501A1 (en) * 2002-06-27 2005-05-12 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Perfume composition
US7015186B2 (en) 2002-06-27 2006-03-21 Unilever Home & Personal Care Usa A Division Of Conopco, Inc. Perfume composition
US20050079991A1 (en) * 2002-08-27 2005-04-14 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Perfume composition
WO2004020566A1 (en) * 2002-08-27 2004-03-11 Unilever N.V. Perfume composition
US7049274B2 (en) 2002-08-27 2006-05-23 Unilever Home & Personal Care Usa, A Division Of Conopco, Inc. Process for preparing perfume film chips
US20050227905A1 (en) * 2002-10-11 2005-10-13 Raymond Heinz Method for the production of a solid fragrance concentrate
US7485610B2 (en) * 2002-10-11 2009-02-03 Bell Flavors & Fragrances Duft Und Aroma Gmbh Method for the production of a solid fragrance concentrate
US7670627B2 (en) 2002-12-09 2010-03-02 Salvona Ip Llc pH triggered targeted controlled release systems for the delivery of pharmaceutical active ingredients
US20040234597A1 (en) * 2002-12-09 2004-11-25 Adi Shefer pH triggered site specific targeted controlled drug delivery system for the treatment of cancer
US20040109894A1 (en) * 2002-12-09 2004-06-10 Adi Shefer PH triggered targeted controlled release systems for the delivery of pharmaceutical active ingredients
US20040216327A1 (en) * 2003-04-30 2004-11-04 Samsung Electronics Co., Ltd Washing machine and method of controlling drying process thereof
EP1477152A1 (de) * 2003-05-12 2004-11-17 Beiersdorf AG Trägersystem für kosmetische oder pharmazeutische Wirkstoffe
WO2004113485A1 (en) 2003-06-18 2004-12-29 The Procter & Gamble Company Blooming soap bars
US20070010407A1 (en) * 2003-12-10 2007-01-11 Wilfried Rahse Scent composites
US20040224019A1 (en) * 2004-03-03 2004-11-11 Adi Shefer Oral controlled release system for targeted drug delivery into the cell and its nucleus for gene therapy, DNA vaccination, and administration of gene based drugs
WO2005102261A1 (en) * 2004-03-26 2005-11-03 Dow Corning Corporation Controlled release compositions
US20070207942A1 (en) * 2004-03-26 2007-09-06 Serge Creutz Controlled Release Compositions
US20050262757A1 (en) * 2004-05-27 2005-12-01 The Procter & Gamble Company Self-steaming compositions, articles comprising such compositions and methods of preparing such compositions
US7856948B2 (en) 2004-05-27 2010-12-28 Wyeth Llc Self-steaming compositions, articles comprising such compositions and methods of preparing such compositions
EP2264118A2 (en) 2004-05-27 2010-12-22 Wyeth LLC Self-steaming compositions, articles comprising such compositions and methods of preparing such compositions
US7977288B2 (en) 2005-01-12 2011-07-12 Amcol International Corporation Compositions containing cationically surface-modified microparticulate carrier for benefit agents
US20090148392A1 (en) * 2005-01-12 2009-06-11 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
US20090162408A1 (en) * 2005-01-12 2009-06-25 Amcol International Corporation Compositions containing cationically surface-modified microparticulate carrier for benefit agents
US7855173B2 (en) 2005-01-12 2010-12-21 Amcol International Corporation Detersive compositions containing hydrophobic benefit agents pre-emulsified using sub-micrometer-sized insoluble cationic particles
US20090263337A1 (en) * 2005-01-12 2009-10-22 Amcol International Corporation Detersive compositions containing hydrophobic benefit agents pre-emulsified using sub-micrometer-sized insoluble cationic particles
US7871972B2 (en) 2005-01-12 2011-01-18 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
US20070071780A1 (en) * 2005-06-16 2007-03-29 Dubois Zerlina G Personal care composition comprising a perfume booster accord
US20070031369A1 (en) * 2005-08-03 2007-02-08 Alberto-Culver Company Quick dispersing hair conditioning composition
US8277788B2 (en) 2005-08-03 2012-10-02 Conopco, Inc. Quick dispersing hair conditioning composition
WO2007028495A1 (en) 2005-09-09 2007-03-15 Unilever Plc Fabric conditioning composition
US20090036346A1 (en) * 2005-09-09 2009-02-05 Nigel Peter Bird Fabric Conditioning Composition
EP1767185A1 (en) 2005-09-23 2007-03-28 Takasago International Corporation Core shell capsules containing an oil or waxy solid
US20070149424A1 (en) * 2005-09-23 2007-06-28 Takasago International Corporation Perfume for capsule composition
US20070098148A1 (en) * 2005-10-14 2007-05-03 Sherman Kenneth N Aroma releasing patch on mobile telephones
WO2007115871A1 (de) * 2006-04-06 2007-10-18 Henkel Ag & Co. Kgaa Feste, textil-affine zusammensetzung auf basis eines schmelzbaren materials
US8834514B2 (en) 2006-08-30 2014-09-16 Xennovate Medical Llc Resilient band medical device
US7888306B2 (en) 2007-05-14 2011-02-15 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US8715702B2 (en) 2008-02-27 2014-05-06 Dow Corning Corporation Deposition of lipophilic active material in surfactant containing compositions
US20110104221A1 (en) * 2008-02-27 2011-05-05 Galeone Fabrizio S Deposition Of Lipophilic Active Material In Surfactant Containing Compositions
US8188022B2 (en) 2008-04-11 2012-05-29 Amcol International Corporation Multilayer fragrance encapsulation comprising kappa carrageenan
US8430921B2 (en) 2008-05-15 2013-04-30 Wyeth Portable moist heat system
US9566186B2 (en) 2008-05-15 2017-02-14 Wyeth Llc Portable moist heat system
US20090287280A1 (en) * 2008-05-15 2009-11-19 Wyeth Portable moist heat system
WO2010001269A2 (en) 2008-06-30 2010-01-07 Kimberly-Clark Worldwide, Inc. Fragranced water-sensitive film
US20100180387A1 (en) * 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
US8053402B2 (en) 2009-01-16 2011-11-08 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules and a stabilizing agent
US20100180386A1 (en) * 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
WO2010083125A1 (en) 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
WO2010083124A1 (en) 2009-01-16 2010-07-22 The Procter & Gamble Company Bleaching compositions containing perfume microcapsules
US20110000483A1 (en) * 2009-05-01 2011-01-06 Matthias Joseph A External nasal dilator
WO2010149966A1 (en) 2009-06-24 2010-12-29 Bell Flavors & Fragrances Duft Und Aroma Gmbh Microparticles and method of making microparticles
US9493728B2 (en) 2009-06-24 2016-11-15 Bell Flavors & Fragrances Duft Und Aroma Gmbh Microparticles and method of making microparticles
WO2011124706A1 (en) 2010-04-09 2011-10-13 Basf Se In-situ sol-gel encapsulation of fragrances, perfumes or flavours
DE112011103631T5 (de) 2010-10-25 2013-11-14 The Armor All/Stp Products Company Silikon-Schutzmittelzusammensetzungen
DE112012001495B4 (de) 2011-03-31 2024-10-24 Energizer Auto, Inc. (n.d.Ges.d. Staates Delaware) Zusammensetzungen zur Behandlung von Automobiloberflächen und ihre Verwendung
WO2012162331A2 (en) 2011-05-26 2012-11-29 The Procter & Gamble Company Compositions comprising an efficient perfume bloom
US9693941B2 (en) 2011-11-03 2017-07-04 Conopco, Inc. Liquid personal wash composition
US20140322145A1 (en) * 2011-12-06 2014-10-30 Rohm And Haas Company Antimicrobial composition
WO2013128431A2 (en) 2012-02-27 2013-09-06 The Procter & Gamble Company Methods for producing liquid detergent products
FR2992208A1 (fr) * 2012-06-21 2013-12-27 Oreal Composition cosmetique comprenant des particules solides insolubles, un corps gras non liquide, un tensioactif
WO2013190079A1 (en) * 2012-06-21 2013-12-27 L'oreal Cosmetic composition comprising insoluble solid particles, a non-liquid fatty substance and a surfactant
EP2689836A1 (en) 2012-07-26 2014-01-29 Basf Se Composition of microcapsules with a silica shell and a method for preparing them
WO2014016367A1 (en) 2012-07-26 2014-01-30 Basf Se Composition of microcapsules with a silica shell and a method for their preparation
US9517195B2 (en) 2012-08-17 2016-12-13 Henkel Ag & Co. Kgaa Cosmetic compounds having time-delayed active ingredient release
RU2642968C2 (ru) * 2012-08-17 2018-01-29 Хенкель Аг Унд Ко. Кгаа Косметические композиции с замедленным высвобождением действующего вещества
WO2014026842A3 (de) * 2012-08-17 2014-07-17 Henkel Ag & Co. Kgaa Kosmetische zusammensetzungen mit zeitverzögerter wirkstofffreisetzung
WO2014047502A2 (en) 2012-09-20 2014-03-27 The Procter & Gamble Company Anhydrous compositions having microcapsules and non-volatile oils
WO2014047507A2 (en) 2012-09-20 2014-03-27 The Procter & Gamble Company Compositions and articles having a parent fragrance and microcapsules encapsulating a non-parent fragrance
WO2014151171A1 (en) 2013-03-15 2014-09-25 The Procter & Gamble Company Personal care compositions
WO2014151555A1 (en) 2013-03-15 2014-09-25 The Procter & Gamble Company Personal care compositions
EP2799864A1 (en) 2013-05-03 2014-11-05 The Procter and Gamble Company Method to evaluate fragrance compositions
EP2799863A1 (en) 2013-05-03 2014-11-05 The Procter and Gamble Company Method to evaluate fragrance compositions
WO2014182996A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
EP3777820A1 (en) 2013-05-10 2021-02-17 Noxell Corporation Modular emulsion-based product differentiation
WO2014182995A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
WO2014182993A2 (en) 2013-05-10 2014-11-13 The Procter & Gamble Company Modular emulsion-based product differentiation
WO2015111060A1 (en) 2014-01-23 2015-07-30 Maori S.C. Ltd. Scented body compositions
WO2016003947A1 (en) 2014-06-30 2016-01-07 The Procter & Gamble Company Method of manufacturing stick comprising antiperspirant
WO2016003948A1 (en) 2014-06-30 2016-01-07 The Procter & Gamble Company Personal care compositions and methods
WO2016049390A1 (en) 2014-09-25 2016-03-31 The Procter & Gamble Company Fragrance compositions comprising ionic liquids
US10301575B2 (en) 2015-04-14 2019-05-28 The Procter & Gamble Company Consumer product composition comprising a polyethylene glycol carrier with silicone particles dispersed therein
US10138441B2 (en) 2015-06-12 2018-11-27 The Procter & Gamble Company Fragrance compositions and uses thereof
WO2016200759A1 (en) 2015-06-12 2016-12-15 The Procter & Gamble Company Fragrance composition
WO2016200761A2 (en) 2015-06-12 2016-12-15 The Procter & Gamble Company Fragrance compositions and uses thereof
EP3141239A1 (en) 2015-06-12 2017-03-15 The Procter and Gamble Company Fragrance compositions and uses thereof
US10501706B2 (en) 2015-06-12 2019-12-10 The Procter & Gamble Company Fragrance compositions and uses thereof
US10336966B2 (en) 2015-06-12 2019-07-02 The Procter & Gamble Company Fragrance compositions and uses thereof
EP3103431A1 (en) 2015-06-12 2016-12-14 The Procter and Gamble Company Fragrance compositions and uses thereof
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EP3103523A1 (en) 2015-06-12 2016-12-14 The Procter and Gamble Company Absorbent article comprising fragrance composition
WO2016205301A1 (en) 2015-06-15 2016-12-22 The Procter & Gamble Company Fragrance fixatives and compositions comprising thereof
WO2017075299A1 (en) 2015-10-28 2017-05-04 The Procter & Gamble Company Fragrance compositions comprising ionic liquids
WO2017089116A1 (en) 2015-11-23 2017-06-01 Basf Se Microcapsule comprising a polyester-urethane shell and a hydrophobic core material
WO2017089115A1 (en) 2015-11-23 2017-06-01 Basf Se Microcapsule comprising a polyester-urethane shell and a hydrophilic core material
US11077417B2 (en) 2015-11-23 2021-08-03 Basf Se Microcapsule comprising a polyester-urethane shell and a hydrophobic core material
EP3170552A1 (en) 2015-11-23 2017-05-24 Basf Se Microcapsule comprising a polymeric shell and a hydrophilic or hydrophobic core material
US10695734B2 (en) 2015-11-23 2020-06-30 Basf Se Microcapsule comprising a polyester-urethane shell and a hydrophilic core material
WO2017105725A1 (en) 2015-12-14 2017-06-22 S. C. Johnson & Son, Inc. Compositions, delivery systems and refills for emitting two or more compositions
WO2017120134A1 (en) 2016-01-06 2017-07-13 The Procter & Gamble Company Antiperspirant compositions
US10292915B2 (en) 2016-01-06 2019-05-21 The Procter & Gamble Company Antiperspirant compositions
RU2736718C2 (ru) * 2016-04-08 2020-11-19 Басф Се Сополимеры, содержащие полиалкиленоксидные группы и четвертичные атомы азота
CN105936773A (zh) * 2016-06-07 2016-09-14 吴江市屯村颜料厂 一种导电颜料组合物及其应用
CN105936774A (zh) * 2016-06-07 2016-09-14 吴江市屯村颜料厂 一种高分散性的水性涂料颜料组合物及其应用
US10329519B2 (en) 2016-10-19 2019-06-25 The Procter & Gamble Company Consumer product composition comprising a polyethyleneglycol carrier, silicone conditioner, and particulate spacer material
EP3535359B1 (en) 2016-11-03 2020-05-13 Unilever PLC Laundry treatment compositions comprising perfume and silica microparticles
EP3501487A1 (en) 2017-12-22 2019-06-26 Juice Beauty, Inc. Thin emulsion base for cosmetics
WO2019232165A1 (en) 2018-05-31 2019-12-05 The Procter & Gamble Company Antibacterial particles and methods
WO2020006156A1 (en) 2018-06-28 2020-01-02 The Procter & Gamble Company Deodorant sticks
WO2020185457A1 (en) 2019-03-12 2020-09-17 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3708146A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3708145A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
WO2020185458A1 (en) 2019-03-12 2020-09-17 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
WO2020185456A1 (en) 2019-03-12 2020-09-17 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3708147A1 (en) 2019-03-12 2020-09-16 The Procter & Gamble Company Anhydrous cosmetic compositions and uses
EP3754007A1 (en) * 2019-06-18 2020-12-23 The Procter & Gamble Company A coated non-woven sheet
EP3754006A1 (en) * 2019-06-18 2020-12-23 The Procter & Gamble Company An anhydrous perfume particle
WO2022086766A1 (en) 2020-10-21 2022-04-28 Aki, Inc. Anhydrous alcohol-free silky fragrance formulation
WO2022119783A1 (en) 2020-12-01 2022-06-09 The Procter & Gamble Company Aqueous hair conditioner compositions containing solubilized anti-dandruff actives
WO2022261268A1 (en) 2021-06-10 2022-12-15 The Procter & Gamble Company Transparent soap bar
WO2023197252A1 (en) 2022-04-14 2023-10-19 The Procter & Gamble Company Personal cleansing composition free of alkyl sulfate or alkyl ether sulfate type of surfactants
WO2023230018A1 (en) 2022-05-23 2023-11-30 The Procter & Gamble Company Antibacterial cleansing composition, uses and methods
WO2024040007A1 (en) 2022-08-15 2024-02-22 Energizer Auto, Inc. Surface treating formulation and method of making and using the same
WO2024207396A1 (en) 2023-04-07 2024-10-10 The Procter & Gamble Company Personal cleansing composition substantially free of alkyl sulfate or alkyl ether sulfate type of surfactants
WO2025025191A1 (en) 2023-08-03 2025-02-06 The Procter & Gamble Company Personal cleansing composition substantially free of alkyl sulfate or alkyl ether sulfate type of surfactants

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DE2747726C2 (enrdf_load_stackoverflow) 1992-01-09
GB1587122A (en) 1981-04-01
CA1111616A (en) 1981-11-03
FR2369340B1 (enrdf_load_stackoverflow) 1982-11-19
DE2747726A1 (de) 1978-05-03
IT1143767B (it) 1986-10-22
AU520108B2 (en) 1982-01-14
GR62860B (en) 1979-07-06
FR2369340A1 (fr) 1978-05-26
AU3013877A (en) 1979-05-03
JPS5394042A (en) 1978-08-17

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