Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
  • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
  • C09C1/44—Carbon
  • C09C1/48—Carbon black
  • C09C1/56—Treatment of carbon black ; Purification
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/02—Elements
  • C08K3/04—Carbon
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
  • C09K3/00—Materials not provided for elsewhere
  • C09K3/16—Anti-static materials
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2006/00—Physical properties of inorganic compounds
  • C01P2006/10—Solid density
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2006/00—Physical properties of inorganic compounds
  • C01P2006/12—Surface area
• • C—CHEMISTRY; METALLURGY
  • C01—INORGANIC CHEMISTRY
  • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
  • C01P2006/00—Physical properties of inorganic compounds
  • C01P2006/40—Electric properties
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
  • Y10S524/91—Antistatic compositions

Definitions

• a process used in the rubber processing industries for improving the electric conductivity and mechanical properties of rubber comprises incorporating special types of carbon black. Attempts made to use this process for the treatment of plastics material have shown that a good deal of commercially available grades of carbon black is not as effective in plastics as in rubber. It has also been found that the plastics' mechanical properties are considerably impaired upon the incorporation of carbon black in the standard proportions employed for rubber.
• the present invention relates more particularly to an improved process for imparting antistatic properties to plastics by blending a pulverulent plastics material and, if desired further addends, with conductive carbon black and making the resulting blend into a moulding composition, the improvement according to which the plastics material is blended with about 4 to 12 weight % of conductive carbon black having a water absorption stiffness (AS-number) of 15 to 35, a specific electric resistance of 10 -1 up to 10 -3 ohms ⁇ cm under a moulding pressure of 100 to 180 atmospheres absolute, a bulk density of 100 to 180 g/liter, a BET-surface area of 100 to 1000 m 2 /g, and having been made by a process wherein an aqueous suspension of carbon black having an AS-number higher than 15 and being prepared by subjecting hydrocarbons, which are liquid at room temperature, to thermal conversion at 1200 to 2000° C, under pressures within the range 1 and 80 atmospheres absolute, and in the presence of oxygen or an oxygen-containing gas, and water
• the process of the present invention enables antistatic properties to be imparted, e.g. to polyethylene, polyvinyl chloride, polypropylene or polystyrene.
• the resulting blend of pulverulent plastics material, carbon black and, if desired, addends and processing aids is readily workable, e.g. by extrusion and granulation with the resultant formation of a moulding composition.
• additiveends and “processing aids” as used herein comprise, e.g. stabilizers, softeners and lubricants.
• the starting materials used for making the carbon black are selected, for example, from high-boilling hydrocarbons, such as heavy fuel oil. These are burnt in conventional manner at about 1400° C and under pressure, and the resulting carbon black is separated from the combustion gases by scrubbing with water.
• the aqueous carbon black suspension so obtained which has a pH of 7 to 10 and contains between about 5 and 40 g of carbon black per liter of suspension, is intimately blended with one or more vaporizable hydrocarbons, preferably with those which have a boiling point within the range 30° and 90° C, e.g. gasoline, and the resulting carbon black is separated from the liquid phase.
• the carbon black is dried at about 200° C and then annealed for 5 to 15 minutes at a preferred temperature within the range 1400° and 1800° C in the presence of nitrogen, hydrogen or carbon monoxide. It is also possible for the carbon black to be annealed at the above temperatures in the presence of chlorine gas, hydrogen chloride or one or more halogen-yielding compounds.
• the carbon black into the plastics material, it is good practice in a mixer to prepare a homogeneous blend of the pulverulent plastics material with the carbon black and standard addends, such as stabilizers, softeners, lubricants and similar aids.
• the resulting blend is plasticized in an extruder, made into strands and granulated.
• the resulting granulate may be further processed according to the use the plastics material is put to.
• the process of the present invention compares favorably with the prior art methods inasmuch as the carbon black used in accordance with this invention enables the flow resistance and passage resistance of plastics material to be reduced to an extent not accessible heretofore without any significant adverse effects on the plastics' mechanical properties.
• This desirable technical effect is a result of the special treatment with vaporizable aliphatic or cycloaliphatic hydrocarbons which the carbon black or an aqueous suspension thereof is subjected to.
• the starting material used for making the carbon black was carbon black, which was obtained in the form of an aqueous suspension containing 15 g of carbon black per liter by subjecting heavy fuel oil to a thermal conversion reaction with hydrogen and steam at 1400° C and under a pressure of 50 atm. abs., and waterscrubbing the resulting reaction gas.
• the carbon black specimens so made were incorporated into various plastics materials and the latter were identified as to their flowability, notched impact strength, ball indentation hardness, flow resistance and surface resistance.
• the notched impact strength was determined according to DIN 53 453.
• the moulded sheets were tested at 23° C, 3 and 24 hours, respectively, after preparation. The results are expressed in kp cm/cm 2 !.
• the ball indentation hardness was determined according to DIN 53 456. The results are expressed in kg/cm 2 !.
• the resulting pulverulent blend was placed in an extruder and made into strands which were granulated.
• the granules were placed on an automatic press and made into round sheets 4 mm thick and 120 mm wide, at a moulding temperature of 120° C and under a moulding pressure equal to 2 up to 10 metric tons total pressure, and the specimens for use in the individual tests were made from the sheets so produced.
• Example 2 The procedure was the same as that described in Example 1 save that carbon black grades annealed at 300°, 400°, 600°, 1000°, 1500° and 1800° C, respectively, were used.
• the mechanical and electric properties of the individual test specimens are indicated in Table II hereinafter, and the characteristic properties of the various carbon black grades are indicated in Table I hereinafter.
• Acetogen carbon black has an AS-number of 22 ml/5 g, determined by the ball method, and a BET-surface area of 70 m 2 /g.
• An queous suspension of Acetogen carbon black has a pH of 7.
• the AS-number indicates that quantity in ml of a water/acetone-mixture (mixing ratio 9:1) which is needed to form a single ball from 5 g of carbon black in a round flask.
• CORAX L (this is a registered trade mark), a commercially available product of Degussa, Frankfurt/Main.
• CORAX L has a BET-surface area of 150 m 2 /g, and an aqueous suspension thereof has a pH of 7.
• the resulting powder mixture was placed on a mixing roll mill and homogenized and plasticized for 5 minutes at 160° C at a peripheral speed of 11 rpm.
• the rough sheet taken from the mill was placed on a press and made at 175° C, under 10 min. contact pressure and a moulding pressure of 150 kg/cm 2 into sheets with the dimensions of 150 ⁇ 120 ⁇ 6 mm.
• Specimens were prepared from the sheets so made and the flow resistance and surface resistance were identified. The results obtained are indicated in Table III hereinafter.
• Example 12 The procedure was the same as that described in Example 12, but the carbon black was ACETOGEN carbon black. The resistance of test specimens was determined. The results obtained are indicated in Table III hereinafter.
• Example 13 The procedure was the same as that described in Example 13, but the carbon black was ACETOGEN carbon black. The resistance of test specimens was determined. The results obtained are indicated in Table III hereinafter.
• Table II shows that the plastics specimens treated with the carbon black of this invention compare very favorably with specimens treated with conventional carbon black grades in respect of the values determined for the flow resistance and surface resistance. As results from the Table, those specimens which contained conventional carbon black in the concentrations indicated, could not be found to show an antistatic behaviour. The result is similar in Table III.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Treatments Of Macromolecular Shaped Articles (AREA)
• Pigments, Carbon Blacks, Or Wood Stains (AREA)

Applications Claiming Priority (2)

Publications (1)

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Family Applications (1)

Country Status (14)

Cited By (15)

Families Citing this family (7)

Citations (8)

Family Cites Families (4)

• 1975
  • 1975-04-10 DE DE2515632A patent/DE2515632C2/de not_active Expired
• 1976
  • 1976-02-24 CH CH227576A patent/CH597289A5/xx not_active IP Right Cessation
  • 1976-03-30 GB GB12743/76A patent/GB1479277A/en not_active Expired
  • 1976-03-31 CA CA249,272A patent/CA1073582A/en not_active Expired
  • 1976-04-07 US US05/674,573 patent/US4097656A/en not_active Expired - Lifetime
  • 1976-04-07 NL NL7603650A patent/NL7603650A/nl not_active Application Discontinuation
  • 1976-04-08 AT AT255176A patent/AT347133B/de not_active IP Right Cessation
  • 1976-04-08 DD DD192275A patent/DD123611A5/xx unknown
  • 1976-04-08 SE SE7604147A patent/SE415265B/xx not_active Application Discontinuation
  • 1976-04-09 DK DK167676A patent/DK167676A/da not_active IP Right Cessation
  • 1976-04-09 BE BE166017A patent/BE840588A/xx not_active IP Right Cessation
  • 1976-04-09 ES ES446838A patent/ES446838A1/es not_active Expired
  • 1976-04-09 JP JP51040153A patent/JPS51123279A/ja active Pending
  • 1976-04-09 FR FR7610540A patent/FR2307028A1/fr active Granted

Patent Citations (8)

Non-Patent Citations (1)

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