US4021261A - Method for drying coatings - Google Patents

Method for drying coatings Download PDF

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Publication number
US4021261A
US4021261A US05/648,798 US64879876A US4021261A US 4021261 A US4021261 A US 4021261A US 64879876 A US64879876 A US 64879876A US 4021261 A US4021261 A US 4021261A
Authority
US
United States
Prior art keywords
phenanthroline
drying
methyl
drier
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US05/648,798
Other languages
English (en)
Inventor
Alan E. Ardis
Lawrence E. Katz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Olin Corp
Original Assignee
Olin Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Olin Corp filed Critical Olin Corp
Priority to US05/648,798 priority Critical patent/US4021261A/en
Priority to GB51690/76A priority patent/GB1512889A/en
Priority to DE2658694A priority patent/DE2658694C2/de
Priority to FR7639322A priority patent/FR2338317A1/fr
Priority to JP227377A priority patent/JPS5287423A/ja
Application granted granted Critical
Publication of US4021261A publication Critical patent/US4021261A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
    • C09F9/00—Compounds to be used as driers, i.e. siccatives

Definitions

  • the present invention relates to a method for promoting the drying of coatings which cure by oxidative polymerization and which contain drying or semi-drying oils. More particularly, the invention relates to a method for promoting drying of paints by incorporating therein 5-methyl-1,10-phenanthroline and to paint formulations containing 5-methyl-1,10-phenanthroline as a drier catalyst.
  • unsubstituted o-phenanthroline also known as 1,10-phenanthroline
  • 1,10-phenanthroline is useful for promoting the drying of paints.
  • Such a product is marketed under the trademark "ACTIV-8" by the R. T. Vanderbilt Company and is the subject of U.S. Pat. No. 2,565,897.
  • 1,10-phenanthroline has numerous disadvantages, one of which is that it is extremely costly to produce, making it undesirable for use in paints. More cost-effective alternatives which are better than unsubstituted 1,10-phenanthroline are required.
  • a number of substituted 1,10-phenanthrolines have been shown to be substantially less effective as paint drier catalysts than 1,10-phenanthroline itself.
  • 2,5,9-trimethyl-1,10-phenanthroline and 2,9-dimethyl-1,10-phenanthroline are both quite inferior to the unsubstituted counterpart.
  • 5-methyl-1,10-phenanthroline is a highly effective drier catalyst for coatings containing drying and semi-drying oils and particularly for those containing manganese or cobalt paint driers.
  • 1,10-phenanthroline It is less costly to produce than 1,10-phenanthroline, is superior at comparable use levels in improving Surface and Hard Dry Times, is more effective in promoting low temperature drying of paints, and is superior to 1,10-phenanthroline in its ability to promote drying after prolonged storage of the formulated paint.
  • the present invention there is provided a method for promoting drying of coatings which contain drying or semi-drying oils, and particularly for those which contain a manganese or cobalt drier, by incorporating therein 5-methyl-1,10-phenanthroline.
  • the invention also comprises novel paint formulations containing 5-methyl-1,10-phenanthroline as a drier catalyst.
  • Suitable substrates for use in accordance with the present invention are oleoresinous coatings, principally paints, printing inks and plastics in which the film-forming component is a drying or semi-drying oil which cures by oxidative polymerization and which generally contain driers based on manganese or cobalt.
  • the metallic driers which may be employed in these formulations include the salts of manganese and/or cobalt which are commonly utilized as paint driers, for example, the naphthenates, octoates, oleates, linoleates, and resinates of manganese and/or cobalt. All are well known to those skilled in this art. These driers are conventionally used in coatings which are to be air dried in an amount such that the amount of metallic manganese or cobalt is present at a concentration of at least 0.003% by weight, advantageously at a concentration in the range of 0.003% by weight up to 0.3%, preferably 0.006% up to about 0.02% by weight of the formulation.
  • the coating formulation may suitably contain the usual pigments, fillers, extenders, solvents, thinners, plasticizers and the like, other drier catalysts and also auxiliary driers such as salts of calcium, zinc, lead, iron, cerium, zirconium or a combination of these.
  • 5-methyl-1,10-phenanthroline which as used herein includes suitable solvates, hydrates or salts thereof including but not limited to the monohydrate and borate salts thereof.
  • Very small quantities of 5-methyl-1,10-phenanthroline are required to produce superior drying.
  • a concentration of at least 0.003% by weight based on the weight of total formulation is sufficient but any amount in excess of this may be employed if desired, advantageously from about 0.005% up to about 1%, preferably 0.006% to about 0.05%.
  • a suitable ratio of 5-methyl-1,10-phenanthroline to metallic drier is in the range of 0.2:1 to 10:1 and preferably in the range of 0.3 to 5:1.
  • a solution of 6% manganese naphthenate was added to linseed oil to produce a 0.059% manganese solution (based on metallic manganese present) in linseed oil.
  • a control sample, C was prepared by mixing equal parts by volume of the manganese solution and linseed oil.
  • Each sample was spread on a 6 ⁇ 6 inch glass plate with a BOSTON-BRADLEY applicator set to deliver a 1 mil wet film.
  • a GARDNER circular drying time recorder was placed on each of the plates and surface dry time recorded in an environment controlled at 75° F. and 10% relative humidity.
  • Example 2 was repeated for comparative purposes with 1,10-phenanthroline and 5-methyl-1,10-phenanthroline using 0.006% manganese or 0.018% cobalt and the reported levels of drier catalyst. Both Surface Dry Time and Hard Dry Time at 75° F. were measured and are reported in Table III.
  • Example 3 was repeated except that the resulting formulation was dried in a controlled environment at 50° F. -55° F.
  • the formulation contained 0.006% manganese and 0.006% drier catalyst. Results are reported in Table IV in hours.
  • Example 2 The formulation of Example 2, utilizing the designated percentages of metal drier and drier catalyst was stored for one month at 120° F. and then tested to determine Surface and Hard Dry Time at 75° F. The results are reported in Table V.
  • Example 2 was repeated except that both Surface and Hard Dry Time were recorded and are reported in Table V.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Catalysts (AREA)
US05/648,798 1976-01-13 1976-01-13 Method for drying coatings Expired - Lifetime US4021261A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US05/648,798 US4021261A (en) 1976-01-13 1976-01-13 Method for drying coatings
GB51690/76A GB1512889A (en) 1976-01-13 1976-12-10 Method for drying coatings
DE2658694A DE2658694C2 (de) 1976-01-13 1976-12-23 Verwendung von 5-Methyl-1,10-phenanthrolin als Trockenkatalysator in Farbanstrichen und Überzugsmitteln
FR7639322A FR2338317A1 (fr) 1976-01-13 1976-12-28 Procede pour faciliter et accelerer le sechage de revetements
JP227377A JPS5287423A (en) 1976-01-13 1977-01-12 Method of accelerating dryness of coating materials and paint compositions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/648,798 US4021261A (en) 1976-01-13 1976-01-13 Method for drying coatings

Publications (1)

Publication Number Publication Date
US4021261A true US4021261A (en) 1977-05-03

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
US05/648,798 Expired - Lifetime US4021261A (en) 1976-01-13 1976-01-13 Method for drying coatings

Country Status (5)

Country Link
US (1) US4021261A (de)
JP (1) JPS5287423A (de)
DE (1) DE2658694C2 (de)
FR (1) FR2338317A1 (de)
GB (1) GB1512889A (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070044689A1 (en) * 2005-08-30 2007-03-01 Martyak Nicholas M Antiskinning compound and compositions containing them

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4032546A1 (de) * 1990-10-13 1992-04-16 Link Guenter Ing Grad Autoxidationskatalysator zur verbesserung der trocknung von oxidativ trocknenden ungesaettigten bindemitteln

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2526718A (en) * 1950-10-24 Coating compositions
US2565897A (en) * 1951-08-28 Drier compositions

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2526718A (en) * 1950-10-24 Coating compositions
US2565897A (en) * 1951-08-28 Drier compositions

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Chem Abst.: 56: 14,423e, 1962. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070044689A1 (en) * 2005-08-30 2007-03-01 Martyak Nicholas M Antiskinning compound and compositions containing them

Also Published As

Publication number Publication date
JPS5613734B2 (de) 1981-03-31
JPS5287423A (en) 1977-07-21
FR2338317A1 (fr) 1977-08-12
DE2658694A1 (de) 1977-07-14
FR2338317B1 (de) 1980-03-07
DE2658694C2 (de) 1982-07-01
GB1512889A (en) 1978-06-01

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