US3897349A - Anti-rust additive composition - Google Patents
Anti-rust additive composition Download PDFInfo
- Publication number
- US3897349A US3897349A US474257A US47425774A US3897349A US 3897349 A US3897349 A US 3897349A US 474257 A US474257 A US 474257A US 47425774 A US47425774 A US 47425774A US 3897349 A US3897349 A US 3897349A
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- Prior art keywords
- composition
- acid
- alkanolamine
- alkanolamines
- acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/20—Rosin acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/042—Sulfate esters
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- C—CHEMISTRY; METALLURGY
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/135—Steam engines or turbines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
- C10N2070/02—Concentrating of additives
Definitions
- the invention relates to an additive composition which is intended for use as an anti-rust agent in hydrocarbon-based compositions, for example petroleum oil compositions such as lubricants, liquid fuels and motor fuels; and more especially in emulsifiable oils for metalworking, whether or not those oils are hydrocarbon based.
- the invention further relates to compositions, for example emulsifiable oils, containing the additive.
- liquid hydrocarbon-based compositions are brought into contact with material made of iron, steel or cast iron, in the presence of water.
- liquid fuels and motor fuels are stored in tanks containers or holders, at the bottom of which there is always a certain quantity of water.
- certain lubricants are used for lubricating mechanism that is exposed to water. Additives are commonly embodied in all these various compositions for the purpose of preserving the material from rust.
- an antirust additive in the emulsifiable oils which are used for machine metals.
- the proper workingof a machine tool, lathe, milling and planing machines etc, requires the tool to be lubricated and cooled by spraying on to it a suitable liquid.
- the liquid used in an emulsion of oil in water containing from 1 to 10% oil.
- this emulsion is prepared in situ, in the machining shop, by diluting an. emulsifiable lubricating composition in water.
- the emulsifiable lubricating composition must meet a certain number of requirements.
- alkanolamides of low melting point derived from fatty acids.
- alkanolamine fatty ester compounds and salts formed by neutralizing an acid such as oleic acid with the equivalent quantity of an alkanolamine.
- these types give rise to heavy foaming during their use in, for example, cutting oils.
- One object of the present invention is an anti-rust additive which is intended for use in hydrocarbon-based compositions and also for use in emulsifiable oils, whether they are hydrocarbon-based or, for'example, are based on synthetic lubricant compounds.
- the invention also includes an emulsifiable oil containing such an additive and, still further, an emulsion formed from such an oil.
- an anti-rust additive essentially comprises l a. at least one salt of at least onealiphatiecarboxylic acid having 6 to 20 carbon atoms per molecule and at where R is a hydroxyalkyl group and X and Y are the same or different groups'selected from hydrogemalkyl and hydroxyalkyl.
- the free alkanolamine is very preferably the same as that present in the salt.
- the additive contains several alkanolamines, a chemical balance is established spontaneously between the free alkanolaminesand the alkanolamines contained in the salts.
- the alkanolamines can be primary, secondary and tertiary alkanolamines. having only one alcohol func-- tional group, for example-monoethanolamine isopropanolamine.
- They can also be secondary or tertiary alkanolamines having two or three alcohol functional groups, forexample diethanolamine, N-methyl diethanolamine, .N-
- a mixture of alkanolamines is present, for instance a mixture of mono, di andtri-ethanolamine, or a mixture diand tri-isopropanolamine.
- the mixture is of diisopropanolamine and triisopropanolamine.
- the carboxylic acids are those whose molecule contains from 6 to 20 carbon atoms, inclusive, preferably 10 to 20, advantageously 10 to l8.
- Suitable aliphatic acids are saturated acids, for example caprylic, decanoic, lauric, myristic, palmitic and stearic acids; or un-- saturated acids, for example linoleic, linolenic, oleic and undecylenic'acids'A mixture of aliphatic acids may be used, for example tall oil acids.
- the weight ratio (calculated as freeacids) of aromatic acid to aliphatic acid is from 0.1,: l to 10": I
- the aromatic acid is preferably a direct ringsubstituted compound, for example benzoic acid or a naphthoic acid.
- the molecule of the aromatic acid may also containother functional groups, for example hydroxy, amino, amido, nitro, :alkoxy groups. For instance, hydroxybenzoic or an amino-benzoic acid may be used.
- the molecule of aromatic acid may also contain one or more lower alkyl groups, such as methyl, ethyl, isopropyl,-isobutyl, provided that the total numso that thegtemper-ature of reaction is less than 130C,
- the additive of the present invention has several advantages over the alkanolamides generally used as antirust agents in emulsifiable oils. First of all, it is more effective. Moreover, contrary to the usual alkanolamides, it is not detrimental tothe emulsibility of the oils. Finally it has unexpected anti-foaming properties.
- the invention also provides an anti-rust emulsifiable composition
- an anti-rust emulsifiable composition comprising the foregoing anti-rust additive and an emulsifying agent, forexample one or more sodium alkylbenzene sulphonates.
- the cmulsifiable composition may also contain a solubilizing agent forassisting'andstabilizing oil-in-wateremulsions formed from the cmulsifiable composition.
- a solubilizing agent forassisting'andstabilizing oil-in-wateremulsions formed from the cmulsifiable composition.
- Such an agent is, for examp1e,-butyl glycol or butyl cellosolve.
- This oil contains the usual constituents of cmulsifiable metal-working oilsult is based on a mineral oil having a viscosity of 10 to 200 cSt at 50C.
- the cmulsifiable oil contains emulsifiers in sufficient quantity'ito confer on it the desired emulsibility. This proportion is for preference between 10 and by weight.
- This cmulsifiable oil contains for preference up to 5% by weight of an extreme pressure lubricating agent of the-usualappropriate type. It contains advantageously up to 3% of a bactericidal agent. for instance a quaternary ammonium salt. lt is characterised essentially in that includes from 1 to 5% by weight of' the anti-rust agent of the present invention.
- the product obtained is one according to the invention and is an homogeneous liquid'(Product A).
- Example 2 A 'emulsifiable anti-rust oil (Hlwas obtained by adding 2 parts by weight of product A as described in example 1, to IOO'parts by weight of an cmulsifiable oil (HO) whose composition was as follows:
- Lubricant base 70% The lubricant base was a mineral oil of the spindle oil type. characterised by a viscosity of 13.3 cSt at 50C. By mere dilution of oil H in water. in 1 vol% concentration, a lubricating emulsion for metal-working was obtained.
- Example 3 The same test was carried out as in Example 2, the product A being replaced by various commercial antirust additives bearing the reference B. C, D and E.
- B and C are alkanolamides of oleic acid.
- D is a mixture of alkanolamides obtained by condensing tall oil acids with diethanolamine.
- E is a salt formed by neutralizinga C oxoacid with one equivalent of tripropanolamine.
- Example '4 This example shows the anti-foaming properties of the product to which the invention refers.
- the emulsifiable anti-rust oil' H defined in Example 2- was diluted 5 vol% in water.
- the emulsion thus obtained was subjected to the test which is described in ASTM standard D-892.
- test-tube were placed 190 ml. of the emulsion.
- the test-tube wasplaced in a bath kept at 24C. Glass was blown into the sample through a glass frit plate arranged at the bottom of the test-tube. After 5 minutes the blowing in of air was stopped and the volume. of froth formed was at once noted. Finally. minutes later, the volume of froth still remaining was noted.
- Example 5 To prepare another anti-rust additive and according to the invention, the following were mixed together:
- Example 6 Additives were made by forming salts of various carboxylic acids (l mole) with triethanolamine (T.E.A.) 3 M7: of each additive was added to the oil composition HO (see EX. 2). The appearance of the final mix was observed. 5 ml. of the final mix was then added to 95 ml. of water in a stoppered 100 ml. pyrex cylinder and the cylinder rotated. The time taken for complete emulsion to form was noted the emulsibility time. The IP performance test results (See Ex. 2) were also obtained for each sample.
- Example 7 Various additives were prepared and incorporated into the oil composition HO (see Ex. 2).
- the IP test (see Ex. 2) was conducted and the results tabulated.
- the table shows firstly the results with a series of salts using both benzoic and lauric acids and secondly using only benzoic acid and only laurie acid.
- the anti-rust agent forming the object of the invention is particularly suitable for cmulsifiable metal-working oils. Nevertheless, this anti-rust agent can be used in other applications. Generally speaking, it can be incorporated advantageously in hydrocarbon compositions that are stored or used in contact with a certain quantity of water. For instance, it can be incorporated with fuels of liquid type or motor fuels. It is also possible to embody it in the composition of certain lubricating greases, in lubricating oils for steam engines, in turbine lubricating oils etc.
- An anti-rust additive composition comprising:
- alkanolamines in total, there are 1.5 to 3.0 equivalents of alkanolamine present per equivalent of acid; the alkanolamines being compounds containing up to carbon atoms per molecule and having the formula a hydroxyalkyl group and X and Y are the same or different groups selected from hydrogen, alkyl and hydroxyalkyl.
- composition as claimed in claim I wherein acids.
- composition as claimed in claim 1 wherein the aromatic acid is benzoic acid or p-aminobenzoic acid.
- alkanolamine is selected from monoethanolamine, isopropanolamine, N-dimethylethanolamine, N- diethylethanolamine, N-dimethyl isopropanolamine, N-diethylisopropanolamine. diisopropanolamine. triisopropanolamine. diethanolamine. N- methyldiethanolamine and N-ethyldiethanolamine.
- the alkanolamines consist of a mixture of at least two alkanolamines selected from isopropanolamine, diisopropanolamine and triisopropanolamine.
- An emulsifiable composition comprising a composition as claimed in claim 1. further containing a dium alkylbenzene sulphonate emulsifying agent.
- composition of claim 11 further containing a mineral oil base having a viscosity of ID to 200 est at 50C, and wherein the amount of the emulsifier is from 10 to 30 weight percent and the amount of the anti-rust additive composition is from 1 to 5 weight'percent.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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FR7319388A FR2231739B1 (hu) | 1973-05-29 | 1973-05-29 |
Publications (1)
Publication Number | Publication Date |
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US3897349A true US3897349A (en) | 1975-07-29 |
Family
ID=9120126
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US474257A Expired - Lifetime US3897349A (en) | 1973-05-29 | 1974-05-29 | Anti-rust additive composition |
Country Status (6)
Country | Link |
---|---|
US (1) | US3897349A (hu) |
DE (1) | DE2426114C2 (hu) |
FR (1) | FR2231739B1 (hu) |
GB (1) | GB1415638A (hu) |
IT (1) | IT1012921B (hu) |
NL (1) | NL184848C (hu) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3981808A (en) * | 1975-10-15 | 1976-09-21 | Continental Oil Company | Soluble oil concentrate |
US4074013A (en) * | 1975-05-07 | 1978-02-14 | Henkel Kgaa | Corrodible iron-containing surfaces carrying corrosion-inhibiting coating |
US4121009A (en) * | 1974-09-03 | 1978-10-17 | Gaf Corporation | Anti-static fabric softening compositions and processes for drying and softening textiles therewith |
US4144188A (en) * | 1976-08-12 | 1979-03-13 | Kozo Sato | Tablet for preventing deterioration of a water-soluble cutting liquid |
US4192769A (en) * | 1978-05-12 | 1980-03-11 | The Lubrizol Corporation | Rust inhibitor additive compositions, method of making, and aqueous fluids containing the same |
US4342596A (en) * | 1980-04-10 | 1982-08-03 | Conner Alvin James Sen | Non-petroleum based metal corrosion inhibitor |
US4359393A (en) * | 1981-03-09 | 1982-11-16 | The Cincinnati Vulcan Company | Water active metalworking lubricant compositions |
US4370244A (en) * | 1978-12-21 | 1983-01-25 | Akademie Der Wissenschaften Der Ddr | Process for cold mechanical working of metallic materials |
US4394135A (en) * | 1978-09-25 | 1983-07-19 | Mobil Oil Corporation | Liquid hydrocarbon fuel composition |
US4395286A (en) * | 1982-06-30 | 1983-07-26 | The Cincinnati-Vulcan Company | Water-based coating oil |
US4402839A (en) * | 1981-05-11 | 1983-09-06 | Mobil Oil Corporation | Metal working lubricant containing an alkanolamine and a cycloaliphatic acid |
US4419253A (en) * | 1981-11-06 | 1983-12-06 | Nalco Chemical Company | Synthetic post-pickle fluid |
US4473491A (en) * | 1981-06-22 | 1984-09-25 | Basf Aktiengesellschaft | Alkanolamine salts of cyclic amide acids and their use as metal corrosion inhibitors in aqueous systems |
US4490275A (en) * | 1983-03-28 | 1984-12-25 | Betz Laboratories Inc. | Method and composition for neutralizing acidic components in petroleum refining units |
US4657689A (en) * | 1986-04-01 | 1987-04-14 | Texaco Inc. | Corrosion-inhibited antifreeze/coolant composition containing hydrocarbyl sulfonate |
US4820344A (en) * | 1985-06-20 | 1989-04-11 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous compositions for visual inspection and cleaning of metallic surfaces |
US4889648A (en) * | 1986-04-21 | 1989-12-26 | The Nisshin Oil Mills, Ltd. | Cold-rolling oils for steel plates |
US5633222A (en) * | 1992-12-17 | 1997-05-27 | Berol Nobel Ab | Use of a secondary amine as a corrosion inhibiting and antimicrobial agent and an aqueous alkaline industrial fluid containing said amine |
US6074994A (en) * | 1996-10-10 | 2000-06-13 | Pennzoil Products Company | Non-aqueous solvent-free lamellar liquid crystalline lubricants |
US20060225605A1 (en) * | 2005-04-11 | 2006-10-12 | Kloeckener James R | Aqueous coating compositions and process for treating metal plated substrates |
CN102002415A (zh) * | 2009-09-02 | 2011-04-06 | 中国石油天然气股份有限公司 | 一种可用于工业润滑油的无灰防锈添加剂及其制备方法 |
US20110180759A1 (en) * | 2010-01-22 | 2011-07-28 | Midcontinental Chemical Company, Inc. | Methods and compositions for reducing stress corrosion cracking |
CN103361651A (zh) * | 2012-04-03 | 2013-10-23 | 第一工业制药株式会社 | 防锈剂组合物及使用其的防锈方法 |
US9115431B2 (en) | 2010-01-22 | 2015-08-25 | Midcontinental Chemical | Methods and compositions for reducing stress corrosion cracking |
US20150329728A1 (en) * | 2012-12-18 | 2015-11-19 | Angus Chemical Company | Amine compounds and their use as zero or low voc neutralizers |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4130493A (en) * | 1976-07-20 | 1978-12-19 | Inoue-Japax Research Incorporated | Machining fluid |
PL131859B1 (en) * | 1979-05-09 | 1985-01-31 | Conner Alvin J | Metal corrosion inhibitor |
DE2943963A1 (de) * | 1979-10-31 | 1981-05-14 | Basf Ag, 6700 Ludwigshafen | Verwendung von alkanolaminsalzen von alkenylbernsteinsaeuren als korrosionsinhibitoren in waessrigen systemen |
EP0192358B1 (en) * | 1985-02-04 | 1991-01-02 | Ge Chemicals, Inc. | Metal working fluid composition |
US4670172A (en) * | 1985-03-29 | 1987-06-02 | Borg-Warner Corporation | Process and kit for working metals |
DE19955651A1 (de) * | 1999-11-19 | 2001-05-23 | Basf Ag | Verwendung von Festsäuresalzen von alkoxylierten Oligoaminen als Schmierfähigkeitsverbesserer für Mineralölprodukte |
RU2464359C2 (ru) * | 2010-12-15 | 2012-10-20 | Открытое акционерное общество "НАПОР" | Ингибитор коррозии-бактерицид |
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US3398095A (en) * | 1967-11-13 | 1968-08-20 | Shell Oil Co | Vapor-space inhibitors |
US3502581A (en) * | 1967-11-13 | 1970-03-24 | Universal Oil Prod Co | Antioxidant composition and use thereof |
FR1567540A (hu) * | 1968-05-28 | 1969-05-16 | ||
DE1769769B2 (de) * | 1968-06-15 | 1973-05-03 | Fuji Iron & Steel Co Ltd , Tokio | Schmier- und korrosionsschutzmittel fuer die spanlose stahlbearbeitung, insbesondere fuer tiefziehbleche |
US3773665A (en) * | 1971-11-17 | 1973-11-20 | Mobil Oil Corp | Lubricants containing amine antioxidants |
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- 1974-05-28 IT IT23305/74A patent/IT1012921B/it active
- 1974-05-29 US US474257A patent/US3897349A/en not_active Expired - Lifetime
- 1974-05-29 DE DE2426114A patent/DE2426114C2/de not_active Expired
- 1974-05-29 NL NLAANVRAGE7407200,A patent/NL184848C/xx not_active IP Right Cessation
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US2512949A (en) * | 1945-12-22 | 1950-06-27 | Nox Rust Chemical Corp | Corrosion inhibitor for metals |
US2668146A (en) * | 1949-07-23 | 1954-02-02 | Standard Oil Co | Metal-working compositions |
US2695272A (en) * | 1952-05-21 | 1954-11-23 | Standard Oil Dev Co | Soluble metalworking oil |
US2832742A (en) * | 1954-06-09 | 1958-04-29 | Alox Corp | Corrosion inhibitor composition |
US2941944A (en) * | 1955-03-29 | 1960-06-21 | Exxon Research Engineering Co | Soluble oil composition |
US3769214A (en) * | 1971-09-15 | 1973-10-30 | Mobil Oil Corp | Aqueous lubricant compositions containing alkanolamine salts of carboxylic acids |
Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4121009A (en) * | 1974-09-03 | 1978-10-17 | Gaf Corporation | Anti-static fabric softening compositions and processes for drying and softening textiles therewith |
US4074013A (en) * | 1975-05-07 | 1978-02-14 | Henkel Kgaa | Corrodible iron-containing surfaces carrying corrosion-inhibiting coating |
US3981808A (en) * | 1975-10-15 | 1976-09-21 | Continental Oil Company | Soluble oil concentrate |
US4144188A (en) * | 1976-08-12 | 1979-03-13 | Kozo Sato | Tablet for preventing deterioration of a water-soluble cutting liquid |
US4192769A (en) * | 1978-05-12 | 1980-03-11 | The Lubrizol Corporation | Rust inhibitor additive compositions, method of making, and aqueous fluids containing the same |
US4394135A (en) * | 1978-09-25 | 1983-07-19 | Mobil Oil Corporation | Liquid hydrocarbon fuel composition |
US4370244A (en) * | 1978-12-21 | 1983-01-25 | Akademie Der Wissenschaften Der Ddr | Process for cold mechanical working of metallic materials |
US4342596A (en) * | 1980-04-10 | 1982-08-03 | Conner Alvin James Sen | Non-petroleum based metal corrosion inhibitor |
US4359393A (en) * | 1981-03-09 | 1982-11-16 | The Cincinnati Vulcan Company | Water active metalworking lubricant compositions |
US4402839A (en) * | 1981-05-11 | 1983-09-06 | Mobil Oil Corporation | Metal working lubricant containing an alkanolamine and a cycloaliphatic acid |
US4473491A (en) * | 1981-06-22 | 1984-09-25 | Basf Aktiengesellschaft | Alkanolamine salts of cyclic amide acids and their use as metal corrosion inhibitors in aqueous systems |
US4419253A (en) * | 1981-11-06 | 1983-12-06 | Nalco Chemical Company | Synthetic post-pickle fluid |
US4395286A (en) * | 1982-06-30 | 1983-07-26 | The Cincinnati-Vulcan Company | Water-based coating oil |
US4490275A (en) * | 1983-03-28 | 1984-12-25 | Betz Laboratories Inc. | Method and composition for neutralizing acidic components in petroleum refining units |
US4820344A (en) * | 1985-06-20 | 1989-04-11 | Henkel Kommanditgesellschaft Auf Aktien | Aqueous compositions for visual inspection and cleaning of metallic surfaces |
US4657689A (en) * | 1986-04-01 | 1987-04-14 | Texaco Inc. | Corrosion-inhibited antifreeze/coolant composition containing hydrocarbyl sulfonate |
US4889648A (en) * | 1986-04-21 | 1989-12-26 | The Nisshin Oil Mills, Ltd. | Cold-rolling oils for steel plates |
US5633222A (en) * | 1992-12-17 | 1997-05-27 | Berol Nobel Ab | Use of a secondary amine as a corrosion inhibiting and antimicrobial agent and an aqueous alkaline industrial fluid containing said amine |
US6074994A (en) * | 1996-10-10 | 2000-06-13 | Pennzoil Products Company | Non-aqueous solvent-free lamellar liquid crystalline lubricants |
US20060225605A1 (en) * | 2005-04-11 | 2006-10-12 | Kloeckener James R | Aqueous coating compositions and process for treating metal plated substrates |
CN102002415A (zh) * | 2009-09-02 | 2011-04-06 | 中国石油天然气股份有限公司 | 一种可用于工业润滑油的无灰防锈添加剂及其制备方法 |
US20110180759A1 (en) * | 2010-01-22 | 2011-07-28 | Midcontinental Chemical Company, Inc. | Methods and compositions for reducing stress corrosion cracking |
US9115431B2 (en) | 2010-01-22 | 2015-08-25 | Midcontinental Chemical | Methods and compositions for reducing stress corrosion cracking |
CN103361651A (zh) * | 2012-04-03 | 2013-10-23 | 第一工业制药株式会社 | 防锈剂组合物及使用其的防锈方法 |
TWI500740B (zh) * | 2012-04-03 | 2015-09-21 | Dai Ichi Kogyo Seiyaku Co Ltd | 防銹劑組合物及防銹方法 |
US20150329728A1 (en) * | 2012-12-18 | 2015-11-19 | Angus Chemical Company | Amine compounds and their use as zero or low voc neutralizers |
Also Published As
Publication number | Publication date |
---|---|
DE2426114C2 (de) | 1985-09-19 |
NL184848C (nl) | 1989-11-16 |
DE2426114A1 (de) | 1975-01-02 |
NL184848B (nl) | 1989-06-16 |
FR2231739B1 (hu) | 1980-04-04 |
FR2231739A1 (hu) | 1974-12-27 |
NL7407200A (hu) | 1974-12-03 |
GB1415638A (en) | 1975-11-26 |
IT1012921B (it) | 1977-03-10 |
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