US3883762A - Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon - Google Patents
Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon Download PDFInfo
- Publication number
- US3883762A US3883762A US480199A US48019974A US3883762A US 3883762 A US3883762 A US 3883762A US 480199 A US480199 A US 480199A US 48019974 A US48019974 A US 48019974A US 3883762 A US3883762 A US 3883762A
- Authority
- US
- United States
- Prior art keywords
- oxide
- weight
- coating
- conducting
- electrically semi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 239000012212 insulator Substances 0.000 title claims abstract description 20
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 claims abstract description 30
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011224 oxide ceramic Substances 0.000 claims abstract description 18
- 238000010304 firing Methods 0.000 claims abstract description 17
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 28
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 19
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 17
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims description 17
- 229940112669 cuprous oxide Drugs 0.000 claims description 17
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000919 ceramic Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 7
- 150000004706 metal oxides Chemical class 0.000 abstract description 7
- 239000000758 substrate Substances 0.000 description 13
- 239000010410 layer Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- 229910052574 oxide ceramic Inorganic materials 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000005388 borosilicate glass Substances 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- 210000003141 lower extremity Anatomy 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 206010020400 Hostility Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009760 electrical discharge machining Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T13/00—Sparking plugs
- H01T13/52—Sparking plugs characterised by a discharge along a surface
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
Definitions
- shunted ceramic tips are of two varieties, a surface treated insulator and the homogenous type wherein the entire insulator is a semi-conductor.
- An example of the former is described in US. Pat. No. 2,953,704, wherein an aluminum oxide ceramic insulator is coated with a sintered mixture of cuprous oxide and ferric oxide.
- An example of the latter is described in US. Pat. No. 3,558,959, wherein a semi-conducting ceramic body is formed of bonded particles of silicon carbide.
- insulators comprised essentially of beryllium oxide have been found to be superior to more commonly used aluminum oxide insulators, both with respect to improved thermal conductivity and resistance to thermal shock.
- semi-conducting coatings developed for aluminum oxide based ceramics have proved unsatisfactory when applied to beryllium oxide ceramics.
- FIG. I is a partially schematic view, in longitudinal cross section, of the lower tip portion of an igniter plug embodying the invention.
- FIG. 2 is a view similar to FIG. 1, showing a differently configured lower tip portion of an igniter plug embodying the invention.
- a low-voltage igniter plug 10 comprises a hollow, cylindrical body shell 11 which is generally made of a nickel-steel alloy.
- the lower extremity of shell 11 is formed as a radially inwardly directed flange 12.
- the inner edge surface 13 of flange 12 is cylindrical and coaxial with the shell 11, which surface 13 of flange l2 constitutes a ground electrode.
- a central electrode 14 extends longitudinally within the shell 11 and is coaxial therewith, the firing tip 15 of the electrode 14 terminating in spaced relationship with the surface 13 thus forming an annular spark gap 16.
- the flanged portion 12 When the plug 10 is installed in an engine, the flanged portion 12 is in direct communication with the combustion chamber of the engine and is grounded to the engine by contact between the shell 11 and the en gine block.
- the upper end of central electrode l4 is seated in an annular insulating member 17 disposed within the shell 11 which insulates the central electrode 14 from the shell II.
- the insulating member 17 may be formed of any suitable insulating material such as porcelain, borosilicate glass, aluminum oxide ceramic, beryllium oxide ceramic or the like.
- Another insulating member 18, formed principally of beryllium oxide, is annularly disposed about the lower end of the central electrode 14, and extends from the lower end of insulating member 17 to the upper radially inwardly directed surface of the flange 12.
- the lower periphery and the lower face of the insulating member 18 is coated with a semi-conducting layer 19, said layer 19 being in intimate contact with the lower end of the central electrode 14 and the upper surface of the radially inwardly directed flange 12, whereby current flow can occur across the semi-conducting coating 19 upon the application of low voltage, the current flow resulting in ionization of the spark gap 16, thus enabling a high energy, low voltage spark to discharge across the gap 16 and between the firing tip 15 of the central electrode 14 and the surface 13 of flange l2.
- a low voltage igniter plug 20 comprises a hollow, cylindrical body shell 21.
- the lower extremity of body shell 21 is formed as a radially inwardly directed flange 22, the inner edge surface 23 of which is cylindrical and coaxial with the shell 21 which surface 23 of flange 22 constitutes a ground electrode.
- a central electrode 24 extends longitudinally within the shell 21 and coaxial therewith, the lower end of electrode 24 terminating in an annular, outwardly directed flange 25, said flange 25 having a lesser diameter than the diameter of radially inwardly directed flange 22 of shell 21, said flanges defining between them an annular spark gap 26.
- central electrode 24 is seated in an annular insulating member 27 disposed within body shell 21, which insulates the central electrode 24 from the shell 21.
- the insulating member 27 may be formed of any suitable insulating material, such as porcelain, borosilicate glass, aluminum oxide ceramic, beryllium oxide ceramic or the like.
- Another insulating member 28 formed principally of beryllium oxide is annularly disposed about the lower end of the central electrode 24 and extends from the lower end of insulating member 27 to both the upper surface of flange 22 and the upper surface of flange 25, forming a bridge across the spark gap 26 formed between flange 25 and surface 23 of flange 22.
- the lower face of the insulating member 28 is coated with a semi-conducting layer 29, said layer 29 being in intimate contact with the upper surfaces of flanges 22 and 25, whereby current flow can occur along the semiconducting coating 29 upon the application of low voltage, the current flow resulting in ionization of the spark gap 26, thus enabling a high energy, low voltage spark to discharge across the gap 26 and between flange 25 of central electrode 24 and surface 23 of flange 22.
- the electrically semiconducting layer (designated at 19 in FIG. 1 and at 29 in FIG. 2) which shunts the electrodes of the spark gap is in the form of a film-like coating formed on the beryllium oxide ceramic insulator member.
- the semiconducting layer is comprised of a fired mixture of lanthanum oxide (La O and copper oxide, preferably cuprous oxide (Cu O).
- the said mixture may also contain iron oxide, preferably ferric oxide (Fe-
- the firing of the mixture of oxides is carried out at such temperature and for such length of time that at least one of the oxides is sintered, i.e. heated to the point of incipient fusion.
- the liquid vehicle in which the oxides are preferably applied to the beryllium oxide substrate is driven-off or volatilized and the resulting electrically semiconducting layer is compacted into a low resistance, smooth-surfaced coating layer which is firmly bonded to the surface of the beryllium oxide substrate.
- an electrically semi-conducting layer shunting the electrodes of such plugs must have a relatively smooth and unblemished outer surface confronting the gap; a relatively low resistivity both initially and during the life of the plug under the varying temperatures and other service conditions encountered during use; and must be well-bonded to the ceramic refractory substrate.
- the semi-conducting layer is smooth and substantially free from imperfections, it will not function uniformly over the area of the spark gap.
- such layer is of relatively low resistivity, i.e. from about 10,000 to about 500,000 ohms, preferably from about 10,000 to about 100,000 ohms. it will not sufficiently strongly ionize the gap between the electrodes prior to spark discharge.
- the layer is well-bonded to the ceramic substrate, it will flake or spall-off the substrate under prolonged, arduous service conditions.
- an electrically semiconducting coating material possessed of the abovementioned desirable properties and suitable for coating predominantly beryllium oxide (i.e. from about to 99% by weight BeO) based ceramic insulator bodies comprises a sintered mixture of from 25% to by weight lanthanum oxide (La O from 5% to 75% by weight cuprous oxide (Cu O) and from 0% to 25% by weight ferric oxide (F6203).
- a preferred semiconducting coating comprises a sintered mixture of from 65% to 90% by weight lanthanum oxide (La- 0 from 10% to 30% by weight cuprous oxide (Cu O) and from 0% to 5% by weight ferric oxide (Fe O).
- the above ranges of weight percentages of the said oxides were determined by preparing about two hundred fifty mixtures of lanthanum, cuprous and ferric oxides of broadly varying compositions ranging from 0% to 100% by weight lanthanum oxide, from 0% to 100% by weight cuprous oxide and from 0% to 100% by weight ferric oxide and coating each composition on individual beryllium oxide discs as will be more fully described hereinafter.
- the coated discs were fired at temperatures ranging from 2150F to 2450F and the resistance of the fired coatings was measured.
- the resistance values were plotted on ternary diagrams and correlated with the respective metal oxide composition which yielded the respective resistance value.
- Metal oxide compositions in the above ranges were, from analyses of the ternary diagrams, found to produce coatings having acceptable low resistance properties and, a fortiori, would be suitable in the preparation of electrically semi-conducting coatings particularly compatible with beryllium oxide ceramic substrates.
- the coating is preferably prepared, generally speaking, by grinding the dry oxides to a fine powder and slurrying the same with a liquid media comprising water, a wetting agent and a glycol.
- the oxide slurry is painted on the beryllium oxide substrate by brushing or spraying to a thickness of between about 0.005 to 0.010 inches (5 to 10 mils).
- the coated substrate is then fired in a kiln or the like at a temperature of from about 2150F to 2450F until a smooth coated surface is observed, the liquid carrier, of course, being volatilized.
- the beryllium oxide is somewhat porous, the coating will to some extent penetrate the pores, thus enhancing the adherence of the coating to the substrate.
- composition of preferred embodiments of electrically semi-conducting coatings on beryllium oxide ceramic substrates in accordance with the invention and a preferred manner of forming electrically semiconducting coatings on beryllium oxide ceramic substrates are set forth in the following example, which example is intended solely for the purpose of illustration and is not to be construed as in anyways limiting the scope of the invention.
- EXAMPLE 1 A series of one-gram samples of lanthanum oxide (La O Kerr-McGee, Code 528), cuprous oxide (Cu O, Fisher C-477, Lot 723251) and ferric oxide (Fe- 0 Columbia 347 Grade) having the weight percentages indicated in Table l are prepared, each constituent of each sample being weighed, on a Mettler H15 analytical balance, to the nearest milligram.
- the dry oxides constituting each sample are ground together in a mortar and pestle and are placed in individual plastic vials. To each vial is added the following.
- Glycerol 3 drops Tcrgitol No. 4 (trade name for a wetting agent manufactured by Union Carbide Corp.) 1 drops Distilled Water 12 drops Note: The drops" in which the volumes of glycerol. 'l'ergilnl No. 4 and JlLf are given are drops from a standard anal ticul hurctte
- the dry oxides are thoroughly mixed with the liquid additives to form a uniform slurry or suspension of the oxides in the liquid carrier.
- Each slurried sample is painted on a separate disc of beryllium oxide, each disc measuring approximately 0.5 inches in diameter by 0.070 inches thick and having a BeO content of about 99% by weight. To assure uniform application of each sample on each disc the following procedure is used.
- Pressure sensitive masks or stencils are made by punching 0.25 inch diameter holes in masking tape, cutting off a section containing one hole and pressing the tape section onto a disc. positioning the hole in the center of the disc. Each sample is then painted, to a thickness of about 5 mils, over the hole in the tape section and when the mask is peeled away a 0.25 inch diameter sample is centered and coated on each disc.
- the discs are then fired in an electrically heated resistance element-type kiln (Burrel, Model 90) to the temperatures indicated in Table l.
- the samples are heated at about 200F per hour to a temperature of about 800F to evaporate the liquid carrier after which heating is continued at a rate of about 400F per hour until the desired temperature is attained, Orton pyrometric cones being used to indicate the heat output and uniformity of firing.
- the discs are cooled and observed for smoothness and uniformity of coating.
- the resistance of the sintered coating is measured 22C with at Simpson 260 Ohmeter, the resistance for each sample at the respective firing temperature is tabulated in Table l, in Ohms X l0*.
- the semiconducting metal oxide coating compositions according to the invention each have satisfactory resistances when coated on a beryllium oxide insulator material. It will be observed that. generally speaking, the resistance of the coating increases with increasing firing temperature, and significantly increases at a firing temperature of 2450F, as
- Samples No. and 31 are illustrative of the unsuitability of mixtures of lanthanum oxide and ferric oxide as coatings prepared from mixtures of these oxides are also electrically non-conducting.
- Samples No. 23, 24 and 29 are indicative of the unsuitability of coatings respectively consisting entirely of lanthanum oxide.
- cuprous oxide or ferric oxide satisfactory coatings bcing produced only when a mixture of lanthanum and cuprous oxides is employed or a mixture of these oxides plus ferric oxide, the presence of the latter believed to promote lower resistivity at higher lanthanum oxide ratios and appears to improve somewhat the adherence of the coating to the beryllium oxide substrate.
- the coating composition itself, it is to be understood that the use of ferric oxide as a constitutent of the mixture is optional and is not critical to the formation of a satisfactory semi-conducting coating, the essential constitutents of the coating being lanthanum oxide and cuprous oxide.
- the metal oxide coating of the invention is particularly intended for application to beryllium oxide ceramic substrates, it may also be applied to insulating bodies composed of, for example, aluminum oxides.
- a shunt-type igniter plug comprising an outer metal shell, a ground electrode integral with said shell, a central electrode having a firing tip, said central electrode mounted in an insulator disposed within said shell, the firing tip of said central electrode being in opposed spaced relation to the ground electrode forming a spark gap therebetween, and improved electrically semi-conducting means adjacent said spark gap and in electrical contact with the opposed electrodes, said improved electrically semi-conducting means comprising a beryllium oxide ceramic body disposed about said central electrode, said ceramic body having formed thereon and bonded thereto an electrically semiconducting coating, said coating comprising a sintered mixture of lanthanum oxide and cuprous oxide, said coating being in electrical contact with said opposed electrodes and forming a bridge across said spark gap.
- said electrically semi-conducting coating comprises a sintered mixture of lanthanum oxide, cuprous oxide and ferric oxide.
- said electrically semi-conducting coating comprises a sintered mixture of from 25% to 90% by weight of lanthanum oxide, from 5% to by weight of cuprous oxide and from 0% to 25% by weight offerric oxide.
- said electrically semi-conducting coating comprises a sintered mixture of from 65% to by weight of lanthanum oxide, from 10% to 30% by weight of cuprous oxide and from 0% to 5% by weight of ferric oxide.
Landscapes
- Spark Plugs (AREA)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US480199A US3883762A (en) | 1974-06-17 | 1974-06-17 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
US05/530,922 US3968303A (en) | 1974-06-17 | 1974-12-09 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
US05/530,921 US3970591A (en) | 1974-06-17 | 1974-12-09 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
CA217,913A CA1054785A (en) | 1974-06-17 | 1975-01-14 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
GB1988475A GB1470482A (en) | 1974-06-17 | 1975-05-12 | Ceramic insulator having an electrically semi-conducting coating formed thereon |
FR7517704A FR2274578A1 (fr) | 1974-06-17 | 1975-06-06 | Revetement electriquement semi-conducteur pour oxyde de beryllium |
JP50072617A JPS5845148B2 (ja) | 1974-06-17 | 1975-06-14 | 放電装置 |
IT24376/75A IT1044572B (it) | 1974-06-17 | 1975-06-16 | Dispositivo di scarica elettrica includente un isolatore rivestito di una composizione elettricamente conduttrice |
DE19752526836 DE2526836A1 (de) | 1974-06-17 | 1975-06-16 | Elektrisch halbleitende belagsverbindung und ein funkenentladungsgeraet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US480199A US3883762A (en) | 1974-06-17 | 1974-06-17 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/530,922 Division US3968303A (en) | 1974-06-17 | 1974-12-09 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
US05/530,921 Division US3970591A (en) | 1974-06-17 | 1974-12-09 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
Publications (1)
Publication Number | Publication Date |
---|---|
US3883762A true US3883762A (en) | 1975-05-13 |
Family
ID=23907042
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US480199A Expired - Lifetime US3883762A (en) | 1974-06-17 | 1974-06-17 | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon |
Country Status (7)
Country | Link |
---|---|
US (1) | US3883762A (enrdf_load_stackoverflow) |
JP (1) | JPS5845148B2 (enrdf_load_stackoverflow) |
CA (1) | CA1054785A (enrdf_load_stackoverflow) |
DE (1) | DE2526836A1 (enrdf_load_stackoverflow) |
FR (1) | FR2274578A1 (enrdf_load_stackoverflow) |
GB (1) | GB1470482A (enrdf_load_stackoverflow) |
IT (1) | IT1044572B (enrdf_load_stackoverflow) |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4439707A (en) * | 1980-07-23 | 1984-03-27 | Nippon Soken, Inc. | Spark plug with a wide discharge gap |
US4713574A (en) * | 1985-10-07 | 1987-12-15 | The United States Of America As Represented By The Secretary Of The Air Force | Igniter electrode life control |
US4748947A (en) * | 1987-06-22 | 1988-06-07 | Ford Motor Company | Ignition system and method for multi-fuel combustion engines |
US4951173A (en) * | 1987-12-18 | 1990-08-21 | Ngk Spark Plug Co., Ltd. | Creeping discharge type igniter plug |
EP0407975A3 (en) * | 1989-07-14 | 1992-05-27 | Yazaki Corporation | Gas-filled discharge tube and high tension cable device |
US5187404A (en) * | 1991-08-05 | 1993-02-16 | Cooper Industries, Inc. | Surface gap igniter |
US6133146A (en) * | 1996-05-09 | 2000-10-17 | Scb Technologies, Inc. | Semiconductor bridge device and method of making the same |
US6265814B1 (en) * | 1997-09-24 | 2001-07-24 | Nippon Soken, Inc. | Spark plug having a bypass electrode extending along a bypass path between center and ground electrode |
US6583538B1 (en) * | 1999-10-21 | 2003-06-24 | Beru Ag | Spark plug |
US20090033194A1 (en) * | 2005-01-26 | 2009-02-05 | Renault S.A.S. | Plasma-generating plug |
US20100165539A1 (en) * | 2008-12-26 | 2010-07-01 | Ngk Spark Plug Co., Ltd. | Ignition plug and ignition system |
CN102884686A (zh) * | 2010-04-16 | 2013-01-16 | 雷诺股份公司 | 配备有用于防止短路的装置的火花塞 |
CN103190045A (zh) * | 2010-12-29 | 2013-07-03 | 费德罗-莫格尔点火公司 | 改进间隙控制的电晕点火器 |
CN103210556A (zh) * | 2010-12-14 | 2013-07-17 | 费德罗-莫格尔点火公司 | 改进电晕控制的电晕点火器 |
US20150188292A1 (en) * | 2013-12-26 | 2015-07-02 | John Zink Company, Llc | High energy ignition spark igniter |
US9787064B2 (en) | 2013-05-03 | 2017-10-10 | Federal-Mogul Ignition Company | Corona ignition with hermetic combustion seal |
CN109538357A (zh) * | 2018-11-19 | 2019-03-29 | 陕西航空电气有限责任公司 | 一种小型半导体电嘴结构及加工方法 |
US20190170066A1 (en) * | 2017-12-05 | 2019-06-06 | General Electric Company | High temperature articles for turbine engines |
US20190214796A1 (en) * | 2018-01-04 | 2019-07-11 | Tenneco Inc. | Shaped collet for electrical stress grading in corona ignition systems |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4419601A (en) | 1979-11-05 | 1983-12-06 | Nissan Motor Company, Limited | Spark plug for internal combustion engine |
US4378385A (en) | 1980-03-28 | 1983-03-29 | United Kingdom Atomic Energy Authority | Method of making oxygen ion conducting solid electrolyte device |
JPH01225085A (ja) * | 1988-03-03 | 1989-09-07 | Ngk Spark Plug Co Ltd | 沿面放電型スパークプラグ |
JP7051381B2 (ja) * | 2017-11-16 | 2022-04-11 | 日本特殊陶業株式会社 | スパークプラグ |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2684665A (en) * | 1949-06-09 | 1954-07-27 | Bendix Aviat Corp | Electrical apparatus |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5132181B2 (enrdf_load_stackoverflow) * | 1971-10-14 | 1976-09-10 |
-
1974
- 1974-06-17 US US480199A patent/US3883762A/en not_active Expired - Lifetime
-
1975
- 1975-01-14 CA CA217,913A patent/CA1054785A/en not_active Expired
- 1975-05-12 GB GB1988475A patent/GB1470482A/en not_active Expired
- 1975-06-06 FR FR7517704A patent/FR2274578A1/fr active Granted
- 1975-06-14 JP JP50072617A patent/JPS5845148B2/ja not_active Expired
- 1975-06-16 IT IT24376/75A patent/IT1044572B/it active
- 1975-06-16 DE DE19752526836 patent/DE2526836A1/de not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2684665A (en) * | 1949-06-09 | 1954-07-27 | Bendix Aviat Corp | Electrical apparatus |
Cited By (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4439707A (en) * | 1980-07-23 | 1984-03-27 | Nippon Soken, Inc. | Spark plug with a wide discharge gap |
US4713574A (en) * | 1985-10-07 | 1987-12-15 | The United States Of America As Represented By The Secretary Of The Air Force | Igniter electrode life control |
US4748947A (en) * | 1987-06-22 | 1988-06-07 | Ford Motor Company | Ignition system and method for multi-fuel combustion engines |
US4951173A (en) * | 1987-12-18 | 1990-08-21 | Ngk Spark Plug Co., Ltd. | Creeping discharge type igniter plug |
EP0407975A3 (en) * | 1989-07-14 | 1992-05-27 | Yazaki Corporation | Gas-filled discharge tube and high tension cable device |
US5166574A (en) * | 1989-07-14 | 1992-11-24 | Yazaki Corporation | High-tension cable device |
US5187404A (en) * | 1991-08-05 | 1993-02-16 | Cooper Industries, Inc. | Surface gap igniter |
US6133146A (en) * | 1996-05-09 | 2000-10-17 | Scb Technologies, Inc. | Semiconductor bridge device and method of making the same |
US6265814B1 (en) * | 1997-09-24 | 2001-07-24 | Nippon Soken, Inc. | Spark plug having a bypass electrode extending along a bypass path between center and ground electrode |
US6583538B1 (en) * | 1999-10-21 | 2003-06-24 | Beru Ag | Spark plug |
US7843117B2 (en) * | 2005-01-26 | 2010-11-30 | Renault S.A.S. | Plasma-generating plug |
US20090033194A1 (en) * | 2005-01-26 | 2009-02-05 | Renault S.A.S. | Plasma-generating plug |
US20100165539A1 (en) * | 2008-12-26 | 2010-07-01 | Ngk Spark Plug Co., Ltd. | Ignition plug and ignition system |
US8243415B2 (en) * | 2008-12-26 | 2012-08-14 | Ngk Spark Plug Co., Ltd. | Ignition plug and ignition system |
CN102884686A (zh) * | 2010-04-16 | 2013-01-16 | 雷诺股份公司 | 配备有用于防止短路的装置的火花塞 |
CN103210556A (zh) * | 2010-12-14 | 2013-07-17 | 费德罗-莫格尔点火公司 | 改进电晕控制的电晕点火器 |
CN103210556B (zh) * | 2010-12-14 | 2015-04-01 | 费德罗-莫格尔点火公司 | 改进电晕控制的电晕点火器 |
CN103190045A (zh) * | 2010-12-29 | 2013-07-03 | 费德罗-莫格尔点火公司 | 改进间隙控制的电晕点火器 |
US9787064B2 (en) | 2013-05-03 | 2017-10-10 | Federal-Mogul Ignition Company | Corona ignition with hermetic combustion seal |
US9484717B2 (en) * | 2013-12-26 | 2016-11-01 | Chentronics, Llc | High energy ignition spark igniter |
US20150188292A1 (en) * | 2013-12-26 | 2015-07-02 | John Zink Company, Llc | High energy ignition spark igniter |
US20190170066A1 (en) * | 2017-12-05 | 2019-06-06 | General Electric Company | High temperature articles for turbine engines |
US10815896B2 (en) * | 2017-12-05 | 2020-10-27 | General Electric Company | Igniter with protective alumina coating for turbine engines |
US20190214796A1 (en) * | 2018-01-04 | 2019-07-11 | Tenneco Inc. | Shaped collet for electrical stress grading in corona ignition systems |
US10879677B2 (en) * | 2018-01-04 | 2020-12-29 | Tenneco Inc. | Shaped collet for electrical stress grading in corona ignition systems |
CN109538357A (zh) * | 2018-11-19 | 2019-03-29 | 陕西航空电气有限责任公司 | 一种小型半导体电嘴结构及加工方法 |
CN109538357B (zh) * | 2018-11-19 | 2021-01-01 | 陕西航空电气有限责任公司 | 一种小型半导体电嘴结构及加工方法 |
Also Published As
Publication number | Publication date |
---|---|
IT1044572B (it) | 1980-03-31 |
FR2274578A1 (fr) | 1976-01-09 |
FR2274578B1 (enrdf_load_stackoverflow) | 1977-07-08 |
JPS5845148B2 (ja) | 1983-10-07 |
JPS5113032A (enrdf_load_stackoverflow) | 1976-02-02 |
DE2526836A1 (de) | 1976-01-02 |
GB1470482A (en) | 1977-04-14 |
CA1054785A (en) | 1979-05-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3883762A (en) | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon | |
US5009708A (en) | Printing paste and method of applying said paste | |
US4173731A (en) | Resistor composition for spark plug having a resistor enclosed therein | |
CN102484355A (zh) | Esd保护器件及其制造方法 | |
US3968303A (en) | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon | |
CA1074642A (en) | Metallized glass seal resistor compositions and resistor spark plugs | |
US3970591A (en) | Electrical discharge device comprising an insulator body having an electrically semi-conducting coating formed thereon | |
US3037140A (en) | Electrically semi-conducting ceramic body | |
KR900002344A (ko) | 점화 및 가열기구용 도전성 세르메트 조성물 및 그의 제조방법 | |
US2459282A (en) | Resistor and spabk plug embodying | |
US3278785A (en) | Spark plug having porcelain insulator protected by plasma-jet deposited refractory coating | |
US2434555A (en) | Electrical insulator | |
JPH01124983A (ja) | サージ吸収素子 | |
US3813296A (en) | Insulating coating for electrical devices | |
US5250358A (en) | Palladium thick film resistor containing boron nitride | |
US4198443A (en) | Sinterless zinc oxide varistor devices | |
JPH0429204B2 (enrdf_load_stackoverflow) | ||
US2926275A (en) | Pgras | |
US3791859A (en) | Stress grading coatings for insulators | |
US2699158A (en) | Electrical apparatus | |
US3737718A (en) | Ignition noise suppression center electrode assembly for spark plugs | |
GB745016A (en) | Improvements in or relating to surface discharge sparking plugs or other igniters | |
US3397083A (en) | Insulator body having an electrically conductive surface and method | |
US3162741A (en) | Overvoltage arrestor having a light dispersion of fine metallic dust on its inside walls | |
JPS5919062B2 (ja) | 変性された銅−アルミニウムサプレツサ−エレメント |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: UNISON INDUSTRIES LIMITED PARTNERSHIP, A DE LIMITE Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:ALLIED-SIGNAL INC.;REEL/FRAME:005320/0613 Effective date: 19900416 Owner name: ALLIED CORPORATION, A CORP. OF NY Free format text: MERGER;ASSIGNOR:BENDIX CORPORATION, THE, A DE CORP.;REEL/FRAME:005320/0593 Effective date: 19890609 Owner name: ALLIED-SIGNAL INC., A DE CORP. Free format text: MERGER;ASSIGNOR:ALLIED CORPORATION, A DE CORP.;REEL/FRAME:005320/0603 Effective date: 19870930 |